Mercury: Absence of crystalline Fe2+ in the regolith

Reflectance spectra of terrain on Mercury containing both smooth plains and intercrater plains were obtained using a charge-coupled device spectrograph on 24 November 1984. The composite spectrum covers the 0.53- to 1.02-μm spectral range with a resolution of 17 Å. Absorption features due to telluric H₂O absorption are clearly mapped around 0.73, 0.82, and 0.93 μm. No evidence exists in the new spectrum for the proposed orthopyroxene absorption centered near 0.9 μm seen in older spectra of this terrain. The surface material is probably highly reduced, with any iron present in metallic form. Based upon the new spectrum, a history of heavy micrometeoroid bombardment of the Mercurian surface is suggested, resulting in a surface regolith primarily comprised of agglutinates.     

Mercury's albedo from Mariner 10: Implications for the presence of ferrous iron

Mariner 10 clear filter (490 nm) images of Mercury were recalibrated and photometrically normalized to produce a mosaic of nearly an entire hemisphere of the planet. Albedo contrasts are slightly larger than seen in the lunar highlands (excluding maria). Variegations indicative of compositional differences include diffuse low albedo units often overlain by smooth plains, the high albedo smooth plains of Borealis Planitia, and high-albedo enigmatic crater floor deposits. A higher level of contrast between immature crater ejecta and average mature material on Mercury compared to the Moon is consistent with a more intense space weathering environment on Mercury that results in a more mature regolith. Immature lunar highlands materials are ∼1.5 times higher in reflectance than analogous immature mercurian materials. Immature materials of the same composition would have the same reflectance on both bodies, thus this observation requires that Mercury's crust contains a significant darkening agent, either opaque minerals or ferrous iron bearing silicates, in abundances significantly higher than those of the lunar highlands. If the darkening agent is opaque minerals (e.g. ilmenite or ulvospinel) Mercury's crust may contain significant ferrous iron and yet not exhibit a 1-μm absorption band.     

The formation of Mercury's smooth plains

There has been extensive debate about whether Mercury's smooth plains are volcanic features or impact ejecta deposits. We present new indirect evidence which supports a volcanic origin for two different smooth plains units. In Borealis Planitia, stratigraphic relations indicate at least two distinct stages of smooth plains formation. At least one of these stages must have had a volcanic origin. In the Hilly and Lineated Terrain, Petrarch and several other anomalously shallow craters apparently have been volcanically filled. Areally extensive smooth plains volcanism evidently occurred at these two widely separated areas on Mercury. These results, combined with work by other researchers on the circum-Caloris plains and the Tolstoi basin, show that smooth plains volcanism was a global process on Mercury. Present data suggest to us that the smooth and intercrater plains may represent two distinct episodes of volcanic activity on Mercury and that smooth plains volcanism may have been triggered by the Caloris impact. High-resolution and multispectral imaging from a future Mercury spacecraft could resolve many of the present uncertainties in our understanding of plains formation on Mercury.     

Effects of space weathering on diagnostic spectral features: Results from He+ irradiation experiments

We performed ion irradiation of mineral samples with 50 keV He⁺, aimed to investigate ion irradiation effects on diagnostic spectral features. Reflectance spectra of samples in 0.375–2.5 μm are measured before and after ion irradiation. Silicates, including Luobusha olivine, plagioclase and basaltic glass, have shown reddening and darkening of reflectance spectra at the VIS–NIR range. Olivine is more sensitive to ion irradiation than plagioclase and basaltic glass. Irradiated Panzhihua ilmenite exhibits higher reflectance and stronger absorption features, which is totally different from lunar soil and analog silicate materials in other experiments. Using continuum removal and MGM fit, we extracted and compared absorption features of olivine spectra before and after irradiation. Ion irradiation can induce band strength decrease of olivine but negligible band centers shift. We estimate band centers shift caused by ion irradiation are quite limited, even less than variations due to chemical composition in silicates. It provides one possible explanation for no systematic shift in band positions in lunar soil. Irradiated Luobusha olivine spectrum matches spectra of olivine-dominated asteroids. Our results suggest space weathering should be new clues to explain the subtle difference between A-type asteroid spectra and laboratory spectra of olivine.     

Lunar pure anorthosite as a spectral analog for Mercury

Abstract— Plans are underway for spacecraft missions to the planet Mercury beginning in the latter part of this decade (NASA's MESSENGER (MErcury, Surface, Space ENvironment, GEochemistry, Ranging) and ESA's BepiColombo). Mercury is an airless body whose surface is apparently very low in ferrous iron. Much of the mercurian surface material is expected to be optically mature, a state produced by the “space weathering” process from direct exposure to the space environment. If appropriate analog terrains can be identified on the Moon, then study of their reflectance spectra and composition will improve our understanding of space weathering of low‐Fe surfaces and aid in the interpretation of data returned from Mercury by the spacecraft. We have conducted a search for areas of the lunar surface that are optically mature and have very low ferrous iron content using Clementine ultraviolet‐visible (UV‐vis) image products. Several regions with these properties have been identified on the farside. These areas, representing mature pure anorthosites (>90% plagioclase feldspar), are of interest because only relatively immature pure anorthosites have previously been studied with Earth‐based spectrometry. A comparison of Mercury with the lunar analogs reveals similarities in spectral characteristics, and there are hints that the mercurian surface may be even lower in FeO content than the lunar pure anorthosites. We also investigate the potential for use of spectral features other than the commonly studied “1 μm” mafic mineral absorption band as tools for compositional assessment when spacecraft spectral measurements of Mercury become available. Most low‐Fe minerals plausibly present on Mercury lack absorption bands, but plagioclase possesses an iron impurity absorption at 1.25 μm. Detection of this diagnostic band may be possible in fresh crater deposits.     

An analysis of the Mariner 10 color ratio map of mercury

The results of a geological analysis of the Mariner 10 orange/UV color ratio man of Mercury (B. Hapke, C. Christman, B. Rava, and J. Mosher, Proc. Lunar Planet Sci. Conf. 11th 1980, pp. 817–822) are given. Certain errors that occured in reproducing the published version of the 1980 map are pointed out. The relationships between color and terrain are distinctly nonlunar. There is no correlation between color boundaries and the smooth plains on Mercury, in contrast to the strong correlation between color and maria-highlands contacts on the Moon. There are no large exposures of low-albedo, blue material that could be considered to be Mercurian analogs of high-FeTi lunar maria basalts on any part of Mercury imaged by Mariner 10. Three lines of evidence imply that the crust is low in Fe²⁺ and Ti⁴⁺: rays and ejecta blankets are bluer than most areas on Mercury; the Fe²⁺ band in Mercury's reflectance spectrum is very weak or nonexistent and the albedo contrasts are smaller than those on the Moon. There is no evidence in the spectral or albedo data that a lunar type of second wave of melting ever occured on Mercury; rather, the observations are most consistent with the hypothesis that the smooth plains are extrusive landforms derived from local material, possibly mobilized by the Caloris event. In several places correlations between color and topography can be explained if older, redder, higher-Fe materials underlie younger, bluer, lower-Fe surfaces. There is some evidence of late Fe-rich pyroclastic-like activity.     

Mercury crater statistics from MESSENGER flybys: Implications for stratigraphy and resurfacing history

The primary crater population on Mercury has been modified by volcanism and secondary craters. Two phases of volcanism are recognized. One volcanic episode that produced widespread intercrater plains occurred during the period of the Late Heavy Bombardment and markedly altered the surface in many areas. The second episode is typified by the smooth plains interior and exterior to the Caloris basin, both of which have a different crater size-frequency distribution than the intercrater plains, consistent with a cratering record dominated by a younger population of impactors. These two phases may have overlapped as parts of a continuous period of volcanism during which the volcanic flux tended to decrease with time. The youngest age of smooth plains volcanism cannot yet be determined, but at least small expanses of plains are substantially younger than the plains associated with the Caloris basin. The spatial and temporal variations of volcanic resurfacing events can be used to reconstruct Mercury's geologic history from images and compositional and topographic data to be acquired during the orbital phase of the MESSENGER mission.     

The 0.7-5.3 μm IR spectra of Mercury and the Moon: Evidence for high-Ca clinopyroxene on Mercury

We present infrared spectra of Mercury and the Moon in the wavelength range 0.7-5.3 μm obtained with the SpeX spectrograph at the NASA Infrared Telescope Facility. The spectra were acquired from pole and terminator locations of Mercury's surface and of Mersenius C and the Copernicus central peak on the Moon. Spectra of both bodies were measured in close temporal succession and were reduced in the same manner with identical calibration stars to minimize differences in the reduction process. The Copernicus spectra display the expected absorption features due to mafic minerals in the near infrared and show spectral features in the SiO combination/overtone vibrational band region above 4 μm. The spectra of Mercury from longitude 170° and north and south mid-latitudes display a 1-μm absorption band indicative of high-Ca clinopyroxene, while a spectrum from longitude 260° and northern mid-latitudes does not. The Mercury spectra show a broad feature of low emittance over the full 3-5 μm thermal infrared region, but no narrow features in this spectral range. The longitude 260° spectrum shows excess thermal emission around 5 μm attributable to the existence of a thermal gradient in the insolated dayside regolith. The thermal-IR spectra suggest a significant difference in the compositional and/or structural properties of Mercury and the Moon that may be due to grain size, absorption coefficient, or the magnitude of near-surface thermal gradients. The results indicate that the composition of Mercury's surface is heterogeneous on regional scales, and that the near infrared wavelength range provides more discriminative information on the surface composition than the 2-4 μm region, where the solar reflected and thermally emitted radiation contribute approximately equally to the observed flux of these bodies.     

Martian cratering revisited: Implications for early geologic evolution

Improved crater statistics from varied Martian terrains are compared to lunar crater populations. The distribution functions for the average Martian cratered terrain and the average lunar highlands over the diameter range 8–2000 km are quite similar. The Martian population is less dense by approximately 0.70 from 8 to 256 km diameter and diverges to proportionally lower densities at greater diameters. Crater densities on Martian “pure” terra give a lower limit to the Mars/Moon integrated crater flux of 0.75 since the last stabilization of the respective planetary crusts. The crater population >8 km diameter postdating the Martian northern plains is statistically indistinguishable from that population postdating the lunar maria. Monte Carlo simulations were performed to constrain plausible mechanisms of crater obliteration. The models demonstrate that if the crater density difference between the lunar and Martian terra has been due to resurfacing processes, random intercrater plains formation cannot be the sole process. If plains preferentially form in and obliterate larger craters, then the observed Martian distribution retains its “shape” as the crater density decreases. This result is consistent with the morphology of Martian intercrater plains.     

Mineralogical interpretation of reflectance spectra of Eros from NEAR near‐infrared spectrometer low phase flyby

Abstract— High signal‐to‐noise near‐infrared spectrometer (NIS) spectra acquired during the low phase flyby of the near‐Earth asteroid rendezvous (NEAR) mission to 433 Eros are analyzed to determine mineral chemistry and proportions of mafic silicates across the asteroid's surface at 2.68 × 5.50 km spatial resolution. Spectral band parameters are derived, and compared with those of laboratory samples of known mineral composition, grain size distribution and terrestrial, meteoritic and lunar pyroxene spectral properties. The NIS derived band parameters are consistent with ordinary chondrite meteorites. We invoke the presence of a clinopyroxene component in the spectra, which is consistent with ordinary chondrite mineralogy and/or some degree of partial melting of ordinary chondritic material. Spectra measured across the surface of Eros can reveal small but real spectral variations. Most relative spectra are uniform to within 1–2%. Some areas suggest compositional variations of a few percent. Spectral slope variations of a few percent are seen indicating a non‐uniform distribution of materials affecting the slope parameter but with no resolved absorption bands. We find no correlation of slope with viewing geometry or compositional variation. The band parameter values do not consistently indicate a specific ordinary chondrite class but Eros is definitely undifferentiated with possible compositional variations of no more than 1–2%.     

Planetary cratering 1. The question of multiple impactor populations: Lunar evidence

Abstract— This paper addresses several current issues related to use of craters in interpreting planetary surface histories. The primary goal is to test the widely adopted hypothesis of multiple populations of impactors at different times or places in the Solar System. New data presented here revise a “lunar highland” crater diameter distribution that has been widely used as evidence of an early distinct population of impactors. This curve, which has a depression of the size distribution at mid-sizes, does not, in fact, represent the lunar highlands generally. I show that it is associated with regions of intercrater plains. The more extensive the obliteration by intercrater plains, the deeper the depression. Modeling indicates that the depression of the curve is caused by the obliteration process itself. The oldest, most cratered regions of lunar highlands do not show the depression. These findings call into question earlier interpretations of multiple populations of impactors in the Solar System and of a distinctive primordial population. The present work is consistent, instead, with (1) a relatively uniform size distribution of interplanetary impactors, of mixed origins, back to 4 Ga ago and throughout the sampled Solar System; (2) fragmentation as the process that produced that size distribution; (3) saturation equilibrium on the most heavily cratered surfaces; and (4) differences in structure in the size distribution caused not by distinct impactor populations but by episodes of endogenic obliteration. If accepted, these results would modify some studies of solar system evolution, including assertions of two to five distinct populations of impactors, assumptions of lack of saturation equilibrium, and identifications of specific heliocentric or planetocentric sources for impactors within outer planet satellite systems.     

Spectral properties of plagioclase and pyroxene mixtures and the interpretation of lunar soil spectra

The effects of particle size and mineral proportions on the spectral characteristics of plagioclase and pyroxene mixtures are investigated. Size separates (<25 μm, 25–45 μm, 45–75 μm, 75–125 μm, 125–250 μm, and 250–500 μm) have been prepared for the following labradorite/enstatite compositional mixtures: 100/0%, 95/5%, 85/15%, 50/50%, and 0/100%. Spectrally, the labradorite and enstatite samples are representative of the plagioclase feldspars and the orthopyroxenes: the labradorite exhibits a weak, broadband centered near 1.25 μm and the enstatite exhibits two well-defined bands centered near 0.9 and 1.9 μm. From analysis of the plagioclase bands of the mixtures, it is found that (1) the amount of plagioclase necessary for the plagioclase band to be observed as a discrete absorption band is dependent on particle size and (2) plagioclase can be detected by flattening of the pyroxene reflectance “peak” between the 0.9- and 1.9-μm absorption bands if significant amounts of plagioclase are present. Analogs for immature and mature lunar highland soils have been created to examine the combined effects of particle size and mineral proportions on spectra of plagioclase and pyroxene mixtures. bidirectional reflectance spectra of these soil analogs are used to examine the detectability of plagioclase in soil-like particle size distributions. Plagioclase in significant amounts is detected by the flattening of the pyroxene reflectance “peak” between the 0.9- and 1.9-μm absorption bands, and the plagioclase absorption band itself is observed with 85% plagioclase present. The soil analogs reveal that particle size accounts for only a minor spectral difference between immature and mature lunar highland soils. From comparisons with spectra of returned lunar samples, agglutinates are found to dominate the spectral variations associated with soil maturity. Spectra of the immature soil analogs can be used to estimate the minimum pyroxene abundance for immature regions observed remotely.     

Does crater “saturation equilibrium” occur in the solar system?

Similarity is found in crater densities on the most heavily cratered surfaces throughout the solar system. This is hypothesized to result from a steady-state “saturation equilibrium” being approached or achieved by cratering processes. This hypothesis conflicts with some recent interpretations. However, it accounts for (1) a similarity in maximum relative crater density, below certain theoretically predicted values, on all heavily cratered surfaces; (2) a leveling off at this same relative density among 100-m scale (secondary?) craters in populations on lunar maria and other sparsely cratered lunar surfaces; (3) the approximate uniformity of maximum relative densities on Saturn satellites (in spite of dramatic variations predicted from nonsaturation models assuming heliocentric impactors). The lunar frontside upland crater population, sometimes described as a well-preserved production function useful for interpreting other planetary surfaces, is found not to be a production function. It was modified by intercrater plains formed (at least partly) by early upland basaltic lava flooding, recently confirmed spectrophotometrically. Consistent with this, counts in “pure uplands” (those lacking intercrater plains) match the proposed saturation equilibrium density. Variations among large (D > 64 km) crater populations are found, but these may involve several hypothesized mechanisms that rapidly obliterate large craters, especially on icy surfaces. Recent models, in which different populations of interplanetary bodies hit different planets, need further appraisal.     

Mercurian volcanism questioned

The Mariner 10 television team has argued that extensive plains on Mercury were formed by volcanism and compared them with the demonstrably lunar maria. I believe, however, that in stratigraphic relations, surface morphology, and albedo contrast, the Mercurian plains more closely resemble the lunar light plains. These lunar plains were interpreted as volcanic on the basis of data comparable to that available to the Mariner 10 investigators but have been shown by the Apollo missions to be of impact origin. The plains on Mercury might also be formed of impact materials, perhaps of impact melt or other basin ejecta that behaved more like a fluid when emplaced that did lunar basin ejecta.     

Fluvial morphology of Naktong Vallis,Mars: A late activity with multiple processes

The morphology of fluvial valleys on Mars provides insight into surface and subsurface hydrology, as well as to Mars’ past climate. In this study, Naktong Vallis and its tributaries were examined from high-resolution stereoscopic camera (HRSC) images, thermal emission imaging system (THEMIS) daytime IR images, and mars orbiter laser altimeter (MOLA) data. Naktong Vallis is the southern part of a very large fluvial basin composed by Mamers, Scamander, and Naktong Vallis with a total length of 4700 km, and is one of the largest fluvial system on Mars. Naktong Vallis incised along its path a series of smooth intercrater plains. Naktong's main valley cut smooth plains during the Early Hesperian period, estimated ～3.6–3.7 Gyr, implying a young age for the valley when compared to usual Noachian-aged valley networks. Branching valleys located in degraded terrains south of the main Naktong valley have sources inside a large plateau located at more than 2000 m elevation. Connections between these valleys and Naktong Vallis have been erased by the superimposition of late intercrater plains of Early to Late Hesperian age, but it is likely that this plateau represents the main source of water. Small re-incisions of these late plains show that there was at least one local reactivation. In addition, valley heads are often amphitheatre-shaped. Despite the possibility of subsurface flows, the occurrence of many branching valleys upstream of Naktong's main valley indicate that runoff may have played an important role in Naktong Vallis network formation. The importance of erosional landforms in the Naktong Vallis network indicates that fluvial activity was important and not necessarily lower in the Early Hesperian epoch than during the Noachian period. The relationships between overland flows and sapping features suggest a strong link between the two processes, rather than a progressive shift from surface to subsurface flow.     

Resolved images of an unknown sector on the surface of Mercury

We took electronic photographs of Mercury on the side of the planet that was not photographed from the Mariner-10 spacecraft in 1973–1975 by the millisecond-exposure method in ground-based observations. Based on these photographs, we synthesized resolved images of the surface of unknown regions of the planet. The capabilities of the method are limited by the small angular size of the planetary disk (only 7.3 arcsec at average quadrature), specific difficulties of Mercury’s ground-based observations, their very limited duration, and the laboriousness of the subsequent computer-aided observational data processing. The millisecond-exposure method is complex, but a sufficient number of primary electronic photographs can be taken under good seeing conditions for the subsequent synthesis of Mercurian images with a resolution of no worse than the diffraction limit. A giant basin about 2000 km in diameter and other large structures are distinguished in the synthesized images of the planet. In the regions where radar data are available, these structures can be identified with previously found ones. In some measure, the synthesized images allow the relief of the longitude sector 210°–290° W to be reconstructed on Mercury. It can be asserted with caution that the large relief features are distributed asymmetrically over the surface of Mercury, much as observed on other terrestrial planets, the Moon, and many satellites of giant planets.     

The surface of Mercury from ground-based astronomical observations

Recent ground-based astronomical short-exposure observations of Mercury have yielded more than 50000 electronic pictures of the planet at different phases and different positions relative to the Earth. The work was fulfilled in several observatories. The use of available and newly developed processing methods applied to large volumes of electronic frames allowed the images of a considerable portion of Mercury’s surface to be synthesized. We present the images of the 90°–180°W, 215°–280°W, and 50°–90°W sectors containing, among others, the longitudes not covered by spacecraft imaging. Along with the listed images, we present the results of recent observations of Mercury carried out on November 20–24, 2006 during the morning elongation at the Special Astrophysical Observatory of the Russian Academy of Sciences (SAO RAS) (Nizhnii Arkhyz, Karachai-Circassia, the Caucasus). The 265°–350°W longitude sector of Mercury was observed. The observations were made under good weather conditions. Among the main tasks of the new observations was obtaining a complete view of the S Basin. Previously, this basin had been investigated in fragments only by the actual solar illumination conditions. During the period of November 20–24, 2006, the S Basin was on the sunlit side of the planet. The complete image of the basin was obtained from the processing of a large number of electronic frames. The appearance of the S Basin is compared with the data on its relief acquired with radar methods. In this longitude sector, a number of other unusual surface features were found; among them, are a huge “Medallion” crater and other formations. The results considered in the present and earlier published studies are compared with the Mariner 10 data (1974–1975) and with the data received from the Messenger spacecraft during its first flyby of the planet (January 2008).     

Reflectance spectra of analog anorthosites: Implications for lunar highland mapping

Lunar highland region and associated craters are mostly composed of anorthosite. In the present study, we studied the reflectance spectra of terrestrial anorthosites collected from Sittampundi Anorthosites Complex, which is considered as equivalent (simulant) of lunar highland anorthosites. The objective of the study is to interpret diagnostic spectral features of analog anorthosite for remotely exploring lunar highland region. Reflectance spectra of anorthosites were measured under two different environments, such as controlled field and laboratory conditions. In these two procedures, the laboratory spectra give clear, diagnostic spectral information in the present study. Reflectance spectra captured under 350-2500 nm covering UV, Visible, NIR, and SWIR part of the electromagnetic spectrum. The spectral characteristics of anorthosites measured under various parts of electromagnetic spectrum have diagnostic absorption features at 380-387, 700-740, 930-1100, 1160-1200, 1415, 1920, 2200 and 2330 nm correspondingly due to plagioclase UV absorption, Fe³⁺ electron transition absorption, Fe²⁺ pyroxene and olivine absorption, OH/Mn³⁺ crystal transition absorption, pyroxene absorption, Al-OH absorption and Mg-OH absorption. Mineralogical and chemical analyses were carried out for four anorthosites and compared with the results of chemical component of lunar anorthosite. The percentage of plagioclase content, relative abundance of low and high calcium pyroxene and olivine in different anorthosite samples are correlated with the albedo range, absorption shape, absorption centers and band depth. The similarity in the diagnostic spectral features of the anolog anorthosite with lunar anorthosites could be effectively utilized for remotely mapping the lunar highland region.     

Identification of mercurian volcanism: Resolution effects and implications for MESSENGER

Abstract— The possibility of volcanism on Mercury has been a topic of discussion since Mariner 10 returned images of half the planet's surface showing widespread plains material. These plains could be volcanic or lobate crater ejecta. An assessment of the mechanics of the ascent and eruption of magma shows that it is possible to have widespread volcanism, no volcanism on the surface whatsoever, or some range in between. It is difficult to distinguish between a lava flow and lobate crater ejecta based on morphology and morphometry. No definite volcanic features have been identified on Mercury. However, known lunar volcanic features cannot be identified in images with similar resolutions and viewing geometries as the Mariner 10 dataset. Examination of high‐resolution, low Sun angle Mariner 10 images reveals several features which are interpreted to be flow fronts; it is unclear if these are volcanic flows or ejecta flows. This analysis implies that a clear assessment of volcanism on Mercury must wait for better data. MESSENGER (MErcury: Surface, Space ENvironment, GEochemistry, Ranging) will take images with viewing geometries and resolutions appropriate for the identification of such features.     

Comments on the paper by C. R. Chapman: Chronology of terrestrial planet evolution—the evidence from Mercury

Despite the negative tone of Chapman's article, it is pointed out that there is substantial agreement between his opinions and those given in my previous publications on this subject. These areas of agreement are identified and distinguished from those which require further investigation or discussion. It is also pointed out that the apparent discrepancy between the small crater population on the Mercury intercrater terrain and the lunar plains may argue against a simultaneous late heavy bombardment. Suggested ways to resolve this discrepancy should be thoroughly evaluated. The primary need at this time is to identify further specific observational, experimental, or theoretical tests in order to advance beyond the stage of agreeing that the available evidence permits a simultaneous late heavy bombardment, to the more difficult task of determining whether or not it probably occurred.