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1.
T.E. Cravens  A.E.S. Green 《Icarus》1978,33(3):612-623
The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only “airglow” emissions initiated by the absorption of extreme ultraviolet radiation have been considered. The photoionizations of H2O, CO, CO2, and N2 are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H2O+ (A?2A1?X?2B1), CO+ (first negative), CO (fourth positive), CO (Cameron), CO2+ (B?2?u?X?2IIg), N2 (Vegard-Kaplan), N2+ (first negative), and OI (1304 Å). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance scattering and flourescence excitation mechanisms which are appropriate for the outer coma and tail.  相似文献   

2.
A mechanism has been proposed for uv-accelerated desorption from Fe2+ sites on mineral surfaces that satisfies kinetic constraints determined in the laboratory by Huguenin. The process is an integral step of the photochemical weathering mechanism for producing dust on Mars, and it now appears that it may play primary roles in stabilizing CO2 against dissociation by sunlight and in controlling the oxidation state of the atmosphere. We propose that adsorption occurs at octahedrally coordinated Fe2+ surface sites to form seven-coordinate transition-state complexes. These complexes acquire 16–18 kcal mole?1 of ligand field stabilization energy. During illumination (λ ≤ 0.35 μm), electrons are photoemitted from the surfaced Fe2+, temporarily oxidizing them to Fe3+. Fe3+ has no ligand field stabilization energy, and the complexes lose 16–18 kcal mole?1 of stabilization energy. This is a large fraction of the 19- to 28-kcal mole?1 activation energy for dissociating the complexes, and desorption should proceed spontaneously. The gases that were observed to undergo adsorption-photodesorption include O2, CO2, CO, H2O, N2, and Ar. Photodesorption can drive several catalytic reactions, one of which is the oxidation of CO to CO2. The rate of this reaction should be limited by the supply of CO and O2 to the surface to ~2 × 1012 cm?2 sec?1 (column photodissociation rate of CO2). By including this surface reaction in models of Martian atmospheric CO2 chemistry, CO2 can be stabilized against photodissociation with eddy diffusion coefficients of only 3 × 105?1 × 107 cm2 sec?1 below 40 km, raising to ~ 109 cm2 sec?1 at 140 km. Odd hydrogen is not needed to catalyze the oxidation of CO below 40 km, and odd hydrogen mixing ratios need only to be fH ? 10?10 to depress ozone concentrations below the observed upper limit in equatorial regions. Another catalytic reaction that should be driven by photodesorption on Mars is 20H?(ads)H2O + 12O2(g) + 2e?crystal. This is an important source of atmospheric O2, amounting to 7 × 1013?2 × 1017 O2 molecules cm?2 yr?1, and it could have a significant effect on atmospheric oxidation state.  相似文献   

3.
Previous studies based on radio scintillation measurements of the atmosphere of Venus have identified two regions of small-scale temperature fluctuations located in the vicinity of 45 and 60 km. A global study of the fluctuations near 60 km, which are consistent with wind-shear-generated turbulence, was conducted using the Pioneer Venus measurements. The structure constants of refractive index fluctuations cn2 and temperature fluctuations cT2 increase poleward, peak near 70° latitude, and decrease over the pole; cn2 varies from 2 × 10?15 to 1.5 × 10?14m23 and cT2 from 4 × 10?3 to 7 × 10?2°K2m?23. These results indicate greater turbulent activity at the higher latitudes. In the region near 45 km the refractive index fluctuations and the corresponding temperature fluctuations are substantially lower. Based on the analysis of one representative occultation measurement, cn2 = 2 × 10?16m?23and cT2 = 7.3 × 10?4°K2m?23 in the 45-km region. The fluctuations in this region also appear to be consistent with wind-shear-generated turbulence. The turbulence level is considerably weaker than that at 60 km; the energy dissipation rate ε is 4.9 × 10?5m2sec?3 and the small-scale eddy diffusion coefficient K is 2 × 103 cm2 sec?1.  相似文献   

4.
An investigation of Martian intracrater materials has been made using their thermophysical properties as derived from Viking IRTM observations. Over one-fourth of all craters larger than 25 km in diameter between ?50°S and 50°N have localized deposits of coarse material on the floor which are associated with dark “splotches” seen visually. Assuming homogeneous, unconsolidated materials, the measured thermal inertias of these deposits (I = 0.003 × 10?3to 0.026 × 10?3cal cm?2sec?12°K?1) imply effective grain sizes ranging from 0.1 mm to 1 cm, with a modal value of 0.9 mm. These deposits are coarser and darker than the surrounding terrains and the majority of the Martian surface, but are not compositionally distinct from materials with similar albedos. They occur more frequently in the south, in regions of relatively coarse material (0.2 to 2 mm), and in relatively dark areas. These features most likely formed by entrapment of marginally mobile material which can be transported into, but not out of, crater depressions by the wind. Very few have recognizable dune forms: those that do have effective grain sizes less than 0.5 mm. The majority of the “splotch” deposits are coarser than the dune-forming materials found in the north polar region and inside extreme southern latitude craters and probably form low, broad zibar dunes or lag deposits. Intracrater deposits are noticeably lacking from the interior of the large, northern hemisphere low-inertia region of Arabia (?10°S to 30°N, 300° to 360°W), interpreted to be a sink for suspended dust, but do occur around the perimeter of this region. This distribution suggests that the intracrater features have been buried in the interior of Arabia and that the dust deposit is less extensive at the margins and may currently be expanding. The occurrence of regional dust deposits in the north may be related to the maximum wind activity currently occurring in the southern hemisphere and suggests that the location of regional sinks may migrate with time as the solar insolation maximum migrates.  相似文献   

5.
Twenty-micrometer brightness temperatures are used to derive the thermal inertia for 81% of the Martian surface between latitudes ±60°. These data were acquired by the two Viking Infrared Thermal Mappers in 1977 and 1978 following the two global dust storms of 1977. The spatial resolution used is 2° in latitude by 2° in longitude and the total range in derived inertia is 1 to 15 × 10?3cal cm?2sec?12°K?1. The distribution of thermal inertia is strongly bimodal with all values of thermal inertia less than 4 × 10?3cal cm?2sec?12°K?1 being associated with three disjoint bright regions mostly in the northern hemisphere. Sufficient dust is raised in global storms to provide fine material adequate to produce these low-inertia areas but the specific deposition mechanism has not been defined. At the low resolution used, no complete exposures of clean rock were found. There is some tendency for darker material to be associated with higher thermal inertia, although the trend is far from one to one. The distribution of high- and low-inertia areas is sufficiently nonrandom to produce a variation in whole-disk brightness temperature with central meridian longitude. This variation and the change in surface kinetic temperature associated with dust storms are factors in establishing the whole-disk brightness temperature at radio and infrared wavelengths and will be important for those who use Mars as a calibration source.  相似文献   

6.
We examine the response of Martian climate to changes in solar energy deposition caused by variations of the Martian orbit and obliquity. We systematically investigate the seasonal cycles of carbon dioxide, water, and dust to provide a complete picture of the climate for various orbital configurations. We find that at low obliquity (15°) the atmospheric pressure will fall below 1 mbar; dust storms will cease; thick permanent CO2 caps will form; the regolith will release CO2; and H2O polar ice sheets will develop as the permafrost boundaries move poleward. At high obliquity (35°) the annual average polar temperature will increase by about 10°K, slightly desorbing the polar regolith and causing the atmospheric pressure to increase by not more than 10 to 20 mbar. Summer polar ground temperatures as high as 273°K will occur. Water ice caps will be unstable and may disappear as the equilibrium permafrost boundary moves equatorward. However, at high eccentricity, polar ice sheets will be favored at one pole over the other. At high obliquity dust storms may occur during summers in both hemispheres, independent of the eccentricity cycle. Eccentricity and longitude of perihelion are most significant at modest obliquity (25°). At high eccentricity and when the longitude of perihelion is close to the location of solstice hemispherical asymmetry in dust-storm generation and in polar ice extent and albedo will occur.The systematic examination of the relation of climate and planetary orbit provides a new theory for the formation of the polar laminae. The terraced structure of the polar laminae originates when eccentricity and/or obliquity variations begin to drive water ice off the dusty permanent H2O polar caps. Then a thin (meters) layer of consolidated dust forms on top of a dirty, slightly thicker (tens of meters) ice sheet and the composite is preserved as a layer of laminae composed predominately of water ice. Because of insolation variation on slopes, a series of poleward- and equatorward-facing scarps are formed where the edges of the laminae are exposed. Independently of orbital variations, these scarps propagate poleward both by erosion of the equatorward slopes and by deposition on the poleward slopes. Scarp propagation resurfaces and recycles the laminae forming the distinctive spiral bands of terraces observed and provides a supply of water to form new permanent ice caps. The polar laminae boundary marks the furthest eqautorward extension of the permanent H2O caps as the orbit varies. The polar debris boundary marks the furthest equatorward extension of the annual CO2 caps as the orbit varies.The Martian regolith is now a significant geochemical sink for carbon dioxide. CO2 has been irreversibly removed from the atmosphere by carbonate formation. CO2 has also benn removed by regolith adsorption. Polar temperature increases caused by orbital variations are not great enough  相似文献   

7.
The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10?20 cm2. The process can be explained as a transition from the X1 Σg+ ground state to a continuum level of the X2 Σg+ ionized state of H2 The branching ratio for proton (H+) vs molecular ion (H2+) production at this energy is 8 × 10?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found.  相似文献   

8.
Recent papers attributing the observed microwave opacity of the middle atmosphere of Venus to gaseous sulfur dioxide (SO2) and other cloud-related gases have motivated laboratory measurements of their microwave absorbing properties under simulated conditions for this region. In the pressure range from 1 to 5 atmospheres and in the temperature range from 297 to 355°K, the absorption of SO2 in a carbon dioxide (CO2) atmosphere, at 2.257 and 8.342 GHz, has been found to be approximately 50% larger than that calculated from Van Vleck-Weisskopf theory. The measured absorption is about 25 × 106 q?2p1.20 T?3.1 (dB km?1), where q is the sulfur dioxide number mixing ratio, ? is frequency in gigahertz, p is pressure in atmospheres, and T is temperature in degrees Kelvin. This represents the best-fit expression to the observed pressure dependence, while theoretical values of frequency and temperature dependence are accepted as being consistent with the measurements. Another cloud-related gas, sulfur trioxide (SO3), was also tested in a CO2 atmosphere and found to be relatively transparent. These results reduce the amount of SO2 in the Venus middle atmosphere required to explain the opacity measured by radio occulatation, but this amount still exceeds the abundance measured in situ by atmospheric probes, suggesting that there must be another important source of opacity. Preliminary measurements of the 13-cm absorptivity of gaseous sulfuric acid (H2SO4) show it to be a strong microwave absorber, and thus likely to be responsible for a significant and possibly major part of the observed opacity.  相似文献   

9.
In March 1979, the spectrum of Venus was recorded in the far infrared from the G.P. Kuiper Airborne Observatory when the planet subtended a phase angle of 62°. The brightness temperature was observed to be 275°K near 110 cm?1, dropping to 230°K near 270 cm?1. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO2, yield results consistently brighter than the observations. Supplementing the spectral data, Pioneer Venus OIR data at similar phase angles provide the constraint that any additional infrared opacity must be contained in the upper cloud, H2SO4 to the Pioneer-measured upper cloud structure serves to reconcile the model spectrum and the observations, but cloud microphysics strongly indicates that such a high particle density haze (N ? 1.6 × 107cm?3) is implausible. The atmospheric environment is reviewed with regard to the far infrared opacity and possible particle distribution modifications are discussed. We conclude that the most likely possibility for supplementing the far-infrared opacity is a population of large particles (r ? 1 μm) in the upper cloud with number densities less than 1 particle cm?3 which has remained undetected by in situ measurements.  相似文献   

10.
Geoffrey A. Briggs 《Icarus》1974,23(2):167-191
A model of the behavior of the Martian polar caps is described which incorporates the heating effects of the atmosphere, as well as insolation and conduction. This model is used to try to match the observed regression curves of the polar caps, and it predicts that all the seasonally condensed CO2 will be lost by around the summer solstice. The implication is that the residual caps are composed of water ice which, it is found by further modeling, should be stable during the Martian summers. However, it is also argued that this model may be too simplistic, and that the effects of wind in redistributing the seasonal condensate may lead to sufficient thickness of CO2 in the central polar region to allow the year-long existence of CO2 without significantly changing the retreat characteristics of the cap, and it is, therefore, concluded that at the present, the nature of the residual caps cannot be reliably determined.  相似文献   

11.
The photodissociation of water vapour in the mesosphere depends on the absorption of solar radiation in the region (175–200 nm) of the O2 Schumann-Runge band system and also at H-Lyman alpha. The photodissociation products are OH + H, OH + H, O + 2H and H2 + O at Lyman alpha; the percentages for these four channels are 70, 8, 12 and 10%, respectively, but OH + H is the only channel between 175 and 200 nm. Such proportions lead to a production of H atoms corresponding to practically the total photodissociation of H2O, while the production of H2 molecules is only 10% of the H2O photodissociation by Lyman alpha.The photodissociation frequency (s?1) at Lyman alpha can be expressed by a simple formula
JLyαH2O=4.5 ×10?61+0.2F10.7?65100exp[?4.4 ×10?19 N0.917]
where F10.7 cm is the solar radioflux at 10.7 cm and N the total number of O2 molecules (cm?2), and when the following conventional value is accepted for the Lyman alpha solar irradiance at the top of the Earth's atmosphere (Δλ = 3.5 A?) qLyα,∞ = 3 × 1011 photons cm?2 s1?.The photodissociation frequency for the Schumann-Runge band region is also given for mesospheric conditions by a simple formula
JSRB(H2O) = JSRB,∞(H2O) exp [?10?7N0.35]
where JSRB,∞(H2O) = 1.2 × 10?6 and 1.4 × 10?6 s?1 for quiet and active sun conditions, respectively.The precision of both formulae is good, with an uncertainty less than 10%, but their accuracy depends on the accuracy of observational and experimental parameters such as the absolute solar irradiances, the variable transmittance of O2 and the H2O effective absorption cross sections. The various uncertainties are discussed. As an example, the absolute values deduced from the above formulae could be decreased by about 25-20% if the possible minimum values of the solar irradiances were used.  相似文献   

12.
Special line shapes are derived fro the λ 1356 Å (5S0-3P) transition of atomic oxygen from metastable (5S0-3P) time-of-flight spectra produced by electron impact dissociative excitation of O2, CO2, CO, and NO, and they are compared with the broadened λ 1304 A resonance line shapes deduced by Poland and Lawrence (1973) from atomic oxygen absorption studies. The non-thermal line shapes for both airglow emission features are shown to have an effective width comparable to a 60,000 K thermal doppler line shape for an electron impact energy of 100eV. The variation of the effective line width with electron-impact energy from threshold to 300 eV is given. Since the effective line width of the resonance radiation produced by dissociative excitation is very large compared with the doppler absorption widths of the ambient O atoms at normal exospheric temperatures, the anomalously broadened resonance lines will propagate through a planetary atmosphere as though they were optically thin. Thus, electron-impact dissociation of CO and CO2 will contribute to the observed optically thin component of the λ 1304 Å emission in the upper atmospheres of Venus and Mars. However, the process cannot account for more than 10% of the observed optically thin emission because of the small magnitude of the excitation cross-section and the comparatively high-energy threshold for the process. The possibility that the source of the kinetically energetic O(3S) atoms is the dissociative recombination of vibrationally excited CO2+ ions is discussed.  相似文献   

13.
We have measured the linewidths of the NI multiplets [2p2 3p4D0?2p23s4P, λ8691 A?; 2p2 3p4P0 ?2p23s4P, λ8212 A?; 2p2 3s4P?2p34S0, λ1200 A?] produced in the dissociative excitation of N2 by energy electrons. The infrared transitions excite the N(4P) resonance state by cascade and they account for > 50% of the total N(4P) cross section at 100 eV. Both the i.r. and v.u.v. lines are found to be highly Doppler broadened ( ~ 25 times the thermal Doppler line width). These results indicate that dissociative excitation of N2 produces N (4P) atoms with sufficient kinetic energy so that the λ1200 A? resonance radiation [2p2 3s4P ?2p34S0] emitted by these excited atoms would be optically thin in the Earth's upper atmosphere. We also found that the line strength ratios for the resolved components of the λ1200 A? triplet excited by dissociative excitation differ from those predicted by the multiplicities of the states involved and used in current entrapment models; the intensity ratios also vary with the energy of the incident electron. These developments introduce new complications into the analysis of the terrestrial ultraviolet dayglow.  相似文献   

14.
The quenching rate kN2 of O(1D) by N2 and the specific recombination rate α1D of O2+ leading to O(1D) are re-examined in light of available laboratory and satellite data. Use of recent experimental values for the O(1D) transition probabilities in a re-analysis of AE-C satellite 6300 Å airglow data results in a value for kN2 of 2.3 × 10?11 cm3s?1 at thermospheric temperatures, in excellent agreement with the laboratory measurements. This implies a value of JO2 = 1.5 × 10?6s?1 for the O2 photodissociation rate in the Schumann-Runge continuum. The specific recombination coefficient α1D = 2.1 × 10?7cm3s?1 is also in agreement with the laboratory value. Implications for the suggested N(2D) + O2 → O(1D) + NO reaction are discussed.  相似文献   

15.
Results are given of the calculations of the group delay time propagating τ(ω, φ0) of hydromagnetic whistlers, using outer ionospheric models closely resembling actual conditions. The τ(ω, φ0) dependencies were compared with the experimental data of τexp(ω, φ0) obtained from sonagrams. The sonagrams were recorded in the frequency range ? ? (0.5?2.5) Hz at observation points located at geomagnetic latitudes φ0 = (53?66)° and in the vicinity of the geomagnetic poles. This investigation has led us to new and important conclusions.The wave packets (W.P.) forming hydromagnetic whistlers (H.W.) are mainly generated in the plasma regions at L = 3.5?4.0. This is not consistent with ideas already expressed in the literature that their generation region is L ? 3?10. The overwhelming majority of the τexp values differ considerably from the times at which wave packets would, in theory, propagate along the magnetic field lines corresponding to those of the geomagnetic latitudes φ0 of the observation points. The second important fact is that the W.P. frequency ω is less than ΩH everywhere along its propagation trajectory, including the apogee of the magnetic force line (ΩH is the proton gyrofrequency). Proton flux spectra E ? (30?120) keV, responsible for H.W. generation, were determined. Comparison of the Explorer-45 and OGO-3 measurements published in the literature, with our data, showed that the proton flux density energy responsible for the H.W. excitation Np(MV622) ? (5 × 10?3?10?1) Ha2 where Ha is the magnetic field force in the generation region of these W.P. The electron concentration is Na ? (102?103) cm?3. The values given in the literature are Na ? (10?10?103) cm?3. The e data considered also leads to the conclusion that the generating mechanism of the W.P. studied probably always co-exists with the mechanism of their amplification.  相似文献   

16.
The calculated radiative lifetime of the metastable ion is 6.4 × 10?3s. Used in conjunction with the results of measurements by Erdman, Espy and Zipf this sets 1.3 × 10?18 cm2 as the upper limit to the cross section for the formation of N+(5S) in e - N2 collisions at 100eV which leaves the possibility that the process is responsible for the λ2145A? feature in auroras only just open. The cross section for the formation of N+(5S) in e — N collisions is large. However for this process to lead to the observed intensity of λ2145A? relative to λ3914A? the N:N2 abundance ratio would have to be as high as 1.6 × 10?2.  相似文献   

17.
Infrared spectra obtained from the Mariner 9 spacecraft during the 1971–1972 dust storm are used to derive information on the composition and particle size distribution of the dust and to study the time evolution of the storm. The dust is not composed of pure granite, basalt, basaltic glass, obsidian, quartz, andesite, or montmorillonite. The infrared spectra suggest that the dust is a mixture of materials, dominated by igneous silicates with >62;60% SiO2, or weathering products such as clay minerals, but the dust could possibly have a significant component of lower SiO2 materials such as basalt. Substantial quantities of carbonates, nitrates, or carbon suboxide are excluded from the mixture. All infrared, visible, and ultraviolet data on the Martian surface composition seem consistent with a mixture of basalt and clay minerals or high SiO2 igneous rocks, with a surface patina of oxides of iron. For all candidate compositions, the data are best matched with a size distribution that approximates a differential power law function of slope ?4. This size distribution is quite similar to terrestial size distributions in regions remote from sources of dust. The relative abundance of particles between 1- and 10-μm radius did not change during the Mariner 9 mission; thus suspended particles did not experience Stokes-Cunningham fallout but instead were supported by turbulence with an eddy diffusion coefficient, Ke ? 7 × 106cm2sec?1. The aerosol optical depth, standardized to 0.3-μm wavelength, varied from about 1.5 early in the mission to about 0.2 at Orbit 200.  相似文献   

18.
Mariner 10 infrared brightness temperatures of the surface of Mercury at 11 and 45 μm are presented. The data were obtained during the first flyby along a nera-equatorial swath extending from 17 hours local time through local midnight to 9 hours local time. For an assumed emissivity of 0.9, derived surface thermal inertias are between 0.0031 and 0.0031 cal cm?2sec?12K?1 and the implied minimum predawn surface kinetic temperature for the warm pole at longitude 270° is near 93 K. Several pronounced thermal inhomogeneities were seen, one of which appears to coincide with a region of high radar reflectivity. The derived thermal properties and the electrical skin depth and loss tangent fall within the range of values found on the Moon.  相似文献   

19.
20.
P. Drossart  T. Encrenaz 《Icarus》1982,52(3):483-491
The abundance of H2O is derived from the 1900- to 2100-cm?1 region of the Voyager 1 IRIS spectra. Scale variations of about a factor of 2 are seen in the water abundance between the North and South Equatorial Belts. Averaged over the full disk, the mixing ratio is H2OH2=(4.0±1.0) × 10?6, if H2O is uniformly mixed in the atmospheric region having temperatures of 230 to 270°K; this result implies a solar depletion by a factor of 100 in this region. In the belts, the best agreement is obtained for a H2O/H2 mixing ratio of 4.0 × 10?6 in the NEB and 7.2 × 10?6 in the SEB, assuming a constant mixing ratio.  相似文献   

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