On the surface composition of Io

The wavelength dependence of the reflectivity of Io indicates the presence of two materials on the surface of this satellite of Jupiter. These materials are sulfur and an unspecified material (R₁) which shows a wavelength dependence of its reflectivity for 0.3 μm < λ < 1.0 μm similar to the non-H₂O frost spectrum of the rings of Saturn. A 60/40 admixture of these two spectra matches the observed reflection spectrum of Io from 0.3μm–3 μm, if the spectrum of R₁ is featureless for λ > 1 μm. Sulfur will give rise to a posteclipse brightening. The variation with wavelength of the temperature dependence of the reflectivity of sulfur will allow an observational confirmation of the presence of sulfur on Io. The material R₁ should show a large geometrical albedo. The translucency of sulfur is consistent with the polarization-phase curve to Io. The material R₁ is also required to be translucent. The thermal conductivity of a cooled sulfur powder under vacuum was measured and found to agree with the value determined for the upper layer of Io from observations at 10 μm. It is shown that this agreement is not necessarily meaningful.     

Sputtering of sulfur by kiloelectronvolt ions: Application to the magnetospheric plasma interaction with Io

Measurements of total yields, temperature dependences, mass spectra, and energy spectra of molecules sputtered from condensed sulfur (S₈) at low temperatures by keV ions are reported and results are given for Jovian plasma ion bombardment of Io. A change in the reflectance of the sulfur, which can be removed by annealing, is produced by the most penetrating ions and may be connected with the darker, colder polar regions on Io. The measured sputtering yields are much lower than those estimated earlier for room temperature sulfur films but are comparable to previous measurements of keV ion sputtering of SO₂ at low temperatures. The corrected mass spectrum indicates that ≈66% of the total yield corresponds to S₂ ejection while only 5 and 16% correspond to S and S₃, respectively. Therefore, if ions reach the surface of Io its atmosphere will have a non-negligible sulfur component of primarily S₂. The ejection of S and S₂ is temperature independent for temperatures characteristic of most of the surface of Io. The energy spectrum for S has an approximate 1/E² dependence at high ejection energies, whereas S₂ and S₃ fall off more rapidly. Assuming 50% coverage of both sulfur and SO₂ and a thin atmosphere (e.g., nightside and polar region) the direct sputter injection of sulfur atoms and molecules into the Jovian plasma torus and the indirect injection due to coronal processes are estimated. These injection rates for sulfur are compared to those for SO₂ showing that injection from sulfur deposits contributes 13% to the total mass injection rate of ∼2–3 × 10²⁹ amu/sec.     

The composition of the Martian atmosphere: Minor constituents

The Mariner 6 and 7 infrared spectrometers provided data which, in principle, determine upper limits on the possible atmospheric abundance of every gaseous substance that was undetected but which has recognized absorptions in the accessible spectral region, 1.9 to 14.4 μ. Through supporting laboratory determinations of curves of growth under pressure broadening conditions appropriate to Mars, upper limits can be specified (expressed first in cm-atm, STP, for a vertical column and then in parts per million) for the following gases: NO₂ (<0.0016, 0.23); NH₃ (<0.0031, 0.44); C₃O₂ (<0.0032, 0.45); SO₂ (?0.0037, 0.52); OCS (<0.0040, 0.56); NO (<0.0050, 0.70); O₃ (<0.0061, 0.86); CH₄ (<0.026, 3.7); N₂O (<0.13, 18); HCl (<3.7, 520); HBr (?8.2, 1150); H₂S (<27, 3800). In addition, considerations of band contours, moments of inertia, and experimental absorption coefficients permit us to place useful upper limits on twenty-seven additional substances that were not detected and for which curves of growth have not been measured: less than 1.0ppm (or, <0.0071cm-atm); SF₆, NF₃, Cl₂CO, CF₄, CHF₃, Br₂CO, SiF₄; less than 6.0ppm (or, <0.035 cm-atm); C₂F₆, CO₃, F₂CO, C₂H₄, BF₃, CS₂, CHCl₃, C₂H₆, H₂CO, CH₃F, C₆H₆, CH₂I₂; less than 50ppm (or, <0.35 cm-atm): C₂H₂, HCN, CH₂Br₂, CH₂Cl₂, CH₃Br, PH₃, CH₃I, and CH₃Cl. These upper limits are compared to earlier limits based upon terrestrial measurements. The present limits placed upon the possible atmospheric content of the molecules C₃O₂ and CO₃ are of particular interest because of their relevance to the photochemistry of the Martian atmosphere.     

Upper limits for an atmosphere on Io

The 14 May 1971 occultation β Scorpi C by Io was successfully observed in ultraviolet light near Kingston, Jamaica. Within the limits established by time resolution and the signal-to-noise ratio, both the disappearance and reappearance were found to be instantaneous. Upper limits for the surface pressure for N₂, CH₄, and H₂ atmospheres are 0.09, 0.13, and 44.ubar, respectively. The corresponding number densities are 6.2 × 10¹², 9.4 × 10¹², and 3.2 × 10¹⁵ cm⁻³. An isothermal atmosphere at a temperature of 100°K was assumed.     

Spectral reflectance change and luminescence of selected salts during 2–10 KeV proton bombardment: Implications for Io

Radiation damage and luminescence, caused by magnetospheric charged particles, have been suggested by several authors as mechanisms for explaining some of the peculiar spectral/albedo features of Io. We have pursued this possibility by measuring the uv-visual spectral reflectance and luminescent efficiency of several proposed Io surface constituents during 2 to 10-keV proton irradiation at room temperature and at low temperature (120 < T < 140°K). The spectral reflectance of NaCl and KCl during proton irradiation exhibits the well-known F-center absorption bands at 4580 and 5560 Å. Na₂SO₄ shows a generalized darkening which increases toward longer wavelengths. NaNO₃ shows a spectral reflectance change indicative of the partial alteration of NaNo₃ to NaNo₂. NaNO₂ shows no change. The luminescent efficiencies of NaCl and KCl are ～10^?4 at 300°K and increase by one-half order of magnitude at ～130°K. The efficiencies of K₂CO₃, Na₂CO₃, Na₂SO₄, and NaNO₃ are 10^?4, 10^?4, 10^?5 and 10^?6, respectively, at 300°K and they all decrease by one-half order of magnitude at ～130°K. These results indicate that magnetospheric proton irradiation of Io could cause spectral features in its observed ultraviolet and visible reflection spectrum if salts such as those studied here are present on its surface. However, because the magnitude of these spectral effects is dependent on competing factors such as surface temperature, incident particle energy flux, solar bleaching effects, and trace element abundance, we are unable at this time to make a quantitative estimate of the strength of these spectral effects on Io. The luminescent efficiencies of pure samples that we have studied in the laboratory suggest that charged-particle induced luminescence from Io's surface might be observable by a spacecraft such as Voyager when viewing Io's dark side.     

Eclipse reappearances of Io: Time-resolved spectroscopy (1.9-4.2 μm)

We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO₂ frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO₂ induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO₂ bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν₁ + ν₃]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO₂ bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm⁻¹) 4ν₁ band of SO₂ frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO₂ bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO₂ in the vertical column above Io’s surface was ∼4 × 10⁻⁵ g cm⁻².     

Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5-μm spectrum

A high-resolution (0.6 cm^?1) spectrum of Jupiter at 5 μm recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH₄, H₂S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH₄), or actual detections (GeH₄), of molecules with mixing ratios with hydrogen as low as 10^?9. In future observations at 5 μm the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10^?10, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.     

Spectral reflectance of solid sulfur trioxide (0.25–5.2 μm): Implications for Jupiter's satellite Io

We have measured the reflection spectrum of solid sulfur trioxide and we have compared this spectrum to the spectral geometric albedo of Jupiter's satellite Io. We find that the laboratory spectrum of solid SO₃ has very strong absorption features at 3.38, and 4.08 μm. The 3.38- and 3.70-μm absorptions are present very weakly (if indeed at all) in the spectral geometric albedo of Io. This suggests that solid SO₃, if present at all, could exist only as a very minor component of Io's surface. We note that studies involving particle bombardment of SO₂ (a known Io surface constituent) produce SO₃ (Moore, 1984, Icarus 31, 40–80). Sulfur trioxide, once formed on Io's surface, would be extremely stable; however, it would not be expected to accumulate to levels detectable from Earth-based instruments. While it may be possible that the constant resurfacing of Io by volcanic ejecta may cover any SO₃ formed, the area subject to such extensive resurfacing on short time scales (∼ 1 year) is at best ∼10%. Therefore, we would expect that condensed SO₂ remote from volcanos should develop a small but significant SO₃ concentration that could be detected by instruments such as the near-infrared mapping spectrometer on the Galileo spacecraft.     

Sulfur in vacuum: Sublimation effects on frozen melts,and applications to Io's surface and torus

A form of sulfur that is white at room temperature, shows almost no color change on cooling, and is fluffy in texture has been found in experiments on the effects of vacuum sublimation on solid sulfur. The white sulfur is a residual skin that forms on frozen sulfur in vacuum by differential evaporation of molecular species in the solid. S₈ ring sulfur is the dominant sublimation phase lost to the vacuum sink, and polymeric sulfur is the dominant residual phase. The microtexture of the fluffy sulfur layer is skeletal with an organized structure of filamentary components constructed of chains and clumps of submicron polyhedra. The layer is very porous (∼98%) and attains a thickness of ∼0.5 mm after 800 hr at 10⁻⁷ Torr (∼10⁻¹⁰ atm), and does not thicken much thereafter. Its color changes from that of the original melt freeze—yellow, tan, or brown depending on the prefreeze melt temperature—to white at room temperature. The UV/VIS reflectance spectrum (0.35 to 0.70 μm) of the original sulfur is greatly modified by formation of the vacuum surface layer: the blue absorption band edge moves toward the UV resulting in an increase in reflectivity in the range 0.42−0.46 μm as much as 400% and the UV reflectivity below 0.40 μm is reduced to one-third its original level to as low as 2%. Initially the changing band-edge position remains temperature sensitive, as in unmodified sulfur, shifting to shorter wavelengths with decreasing temperature, and returning to its precooled wavelength with temperature recovery; but once vacuum “maturity” is reached the temperature-induced excursion range of the absorption edge is reduced by an order of magnitude and is mostly in the UV whereas for ordinary sulfur (S₈) it is mostly in the blue. The sublimation rate from fresh frozen sulfur at initial exposure to high vacuum (∼10⁻⁷ Torr) is ∼3 × 10¹⁵ S cm⁻² sec⁻¹ at 300°K, increases steeply with temperature, decreases with higher vacuum pressure, and decreases with vacuum exposure time reaching an equilibrium flux of ∼3 × 10¹⁴ S cm⁻² sec⁻¹ after ∼1200 hr. For fresh frozen sulfur evaporating at ∼300°K and ∼10⁻⁷ Torr there occur significant spectral, color, and albedo effects in as little as 10 hr; samples become uniformly whitened within ∼100 hr, and progressive whitening and change in surface spectral properties continue for at least 1200 hr.This vacuum sulfur should exist in large quantity on Jupiter's satellite Io if there is solid free sulfur there that has solidified from a melt. A sulfur volcanism model for Io based on these findings is outlined. Color and spectra of different sulfur areas of Io may indicate relative crystallization age and cooling history. Concepts to be developed from this work on vacuum sulfur may help in understanding properties of Io's surface such as composition, texture, adsorbtivity, thermal inertia, photometry, and posteclipse brightening. The inferred flux of subliming sulfur from hotspots on Io is consistent with estimated turnover rates of the surface and is sufficient to supply the requisite sulfur to the Io plasma torus.     

Sulfur dioxide on Io: Spatial distribution and physical state

Observations of the 4-μm SO₂ band on Jupiter's satellite Io and laboratory measurements of SO₂ frost are presented. The observations confirm the existence of a large longitudinal variation in band strength but show no evidence of temporal changes. Comparison of the band position and shape in Io's spectrum with those in the laboratory frost's suggests that the bulk of the absorption on Io is due to frost, not adsorbed gas. The derived SO₂ coverage is large enough to require that SO₂ be present in most terrain types on Io and not just in the white plains unit. To reconcile the infrared observations that indicate large amounts of SO₂ with the ultraviolet observations of Voyager and IUE that show little, the SO₂ must be mixed intimately with the sulfur (or other material) so that at each wavelength the darker component dominates the spectrum.     

Charting thermal emission variability at Pele,Janus Patera and Kanehekili Fluctus with the Galileo NIMS Io Thermal Emission Database (NITED)

Using the NIMS Io Thermal Emission Database (NITED), a collection of over 1000 measurements of radiant flux from Io’s volcanoes (Davies, A.G. et al. [2012]. Geophys. Res. Lett. 39, L01201. doi:10.1029/2011GL049999), we have examined the variability of thermal emission from three of Io’s volcanoes: Pele, Janus Patera and Kanehekili Fluctus. At Pele, the 5-μm thermal emission as derived from 28 night time observations is remarkably steady at 37 ± 10 GW μm^?1, re-affirming previous analyses that suggested that Pele an active, rapidly overturning silicate lava lake. Janus Patera also exhibits relatively steady 5-μm thermal emission (≈20 ± 3 GW μm^?1) in the four observations where Janus is resolved from nearby Kanehekili Fluctus. Janus Patera might contain a Pele-like lava lake with an effusion rate (Q_F) of ≈40–70 m³ s^?1. It should be a prime target for a future mission to Io in order to obtain data to determine lava eruption temperature. Kanehekili Fluctus has a thermal emission spectrum that is indicative of the emplacement of lava flows with insulated crusts. Effusion rate at Kanehekili Fluctus dropped by an order of magnitude from ≈95 m³ s^?1 in mid-1997 to ≈4 m³ s^?1 in late 2001.     

Io's 4-μm band and the role of adsorbed SO2

The role of adsorbed SO₂ on Io's surface particles in producing the observed spectral absorption band near 4 μm in Io's reflectance spectrum is explored. Calculations show that a modest 50% monolayer coating of adsorbed SO₂ molecules on submicron grains of sulfur of alkali sulfide, assumed to make up Io's uppermost optical surface (“radialith”), will result in a ν₁ + ν₃ absorption band near 4 μm with depth ～30% below the adjacent continuum, consistent with the observed strength of the Io band. The precise wavelength position of the ν₁ + ν₃ band of SO₂ in different phase states such as frost, ice, adsorbate, and gas are summarized from the experimental literature and compared with the available telescopic measurements of the Io band position. The results suggest that the 4-μm band in Io's full disk spectrum can best be explained by the presence on Io's surface of widespread SO₂ in the form of adsorbate rather than ice or frost.     

Studies of proton-irradiated SO2 at low temperatures: Implications for lo

The infrared absorption spectrum from 3.3 to 27 μm (3030-370 cm^?) of SO₂ ice films has been measured at 20 and 88°K before and after 1-MeV proton irradiation. The radiation flux was chosen to simulate the estimated flux of Jovian magnetospheric 1-MeV protons incident on Io. After irradiation, SO₃ is identified as the dominant molecule synthesized in the SO₂ ice. This is also the case after irradiation of composite samples of SO₂ with sulfur, or disulfites. Darkening was observed in irradiated SO₂ ice and in irradiated S₈ pellets. Photometric and spectral measurements of the thermoluminescence of irradiated SO₂ have been made during warming. The spectrum appears as a broad band with a maximum at 4450 Å. Analysis of the luminescence data suggests that, at Ionian temperatures, irradiated SO₂ ice would not be a dominant contributor to posteclipse brightening phenomena. After warming to room temperature, a form of SO₃ remains along with a sulfate and S₈. Based on these experiments, it is reasonable to propose that small amounts of SO₃ may exist on the surface of Io as a result of irradiation synthesis in SO₂ frosts.     

Alkali and Chlorine Photochemistry in a Volcanically Driven Atmosphere on Io

Observations of the Io plasma torus and neutral clouds indicate that the extended ionian atmosphere must contain sodium, potassium, and chlorine in atomic and/or molecular form. Models that consider sublimation of pure sulfur dioxide frost as the sole mechanism for generating an atmosphere on Io cannot explain the presence of alkali and halogen species in the atmosphere—active volcanoes or surface sputtering must also be considered, or the alkali and halide species must be discharged along with the SO₂ as the frost sublimates. To determine how volcanic outgassing can affect the chemistry of Io's atmosphere, we have developed a one-dimensional photochemical model in which active volcanoes release a rich suite of S-, O-, Na-, K-, and Cl-bearing vapor and in which photolysis, chemical reactions, condensation, and vertical eddy and molecular diffusion affect the subsequent evolution of the volcanic gases. Observations of Pele plume constituents, along with thermochemical equilibrium calculations of the composition of volcanic gases exsolved from high-temperature silicate magmas on Io, are used to constrain the composition of the volcanic vapor. We find that NaCl, Na, Cl, KCl, and K will be the dominant alkali and chlorine gases in atmospheres generated from Pele-like plume eruptions on Io. Although the relative abundances of these species will depend on uncertain model parameters and initial conditions, these five species remain dominant for a wide variety of realistic conditions. Other sodium and chlorine molecules such as NaS, NaO, Na₂, NaS₂, NaO₂, NaOS, NaSO₂, SCl, ClO, Cl₂, S₂Cl, and SO₂Cl₂ will be only minor constituents in the ionian atmosphere because of their low volcanic emission rates and their efficient photochemical destruction mechanisms. Our modeling has implications for the general appearance, properties, and variability of the neutral sodium clouds and jets observed near Io. The neutral NaCl molecules present at high altitudes in atmosph eres generated by active volcanoes might provide the NaX⁺ ion needed to help explain the morphology of the high-velocity sodium “stream” feature observed near Io.     

Infrared spectrum of Io, 2.8–5.2 μm

The reflectance spectrum of Io is presented from 2.8 to 5.2 μm, extending the earlier results of D. P. Cruikshank, T. J. Jones, and C. B. Pilcher (1978, Astrophys. J. 225, L89–L92), and demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 μm. Laboratory spectra of nitrates and carborates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on the recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds as reported in a companion paper (F. P. Fanale, R. H. Brown, D. P. Cruikshank, and R. N. Clark, 1979, Nature280, 761–763).     

Mapping of Io's thermal radiation by the Galileo photopolarimeter-radiometer (PPR) instrument

Between 1999 and 2002, the Galileo spacecraft made 6 close flybys of Io during which many observations of Io's thermal radiation were made with the photopolarimeter-radiometer (PPR). While the NIMS instrument could measure thermal emission from hot spots with T>200 K, PPR was the only Galileo instrument capable of mapping the lower temperatures of older, cooling lava flows, and the passive background. We tabulate all data taken by PPR of Io during these flybys and describe some scientific highlights revealed by the data. The data include almost complete coverage of Io at better than 250 km resolution, with extensive regional coverage at higher resolutions. We found a modest poleward drop in nighttime background temperatures and evidence of thermal inertia variations across the surface. Comparison of high spatial resolution temperature measurements with observed daytime SO₂ gas pressures on Io provides evidence for local cold trapping of SO₂ frost on scales smaller than the 60 km resolution of the PPR data. We also calculated the power output from several hot spots and estimated total global heat flow to be about 2.0-2.6 W m⁻². The low-latitude diurnal temperature variations for the regions between obvious hot spots are well matched by a laterally-inhomogeneous thermal model with less than 1 W m⁻² endogenic heat flow.     

The atmospheric signature of Io's Prometheus plume and anti-jovian hemisphere: evidence for a sublimation atmosphere

Using the Hubble Space Telescope's Space Telescope Imaging Spectrograph we have obtained for the first time spatially resolved 2000-3000 Å spectra of Io's Prometheus plume and adjoining regions on Io's anti-jovian hemisphere in the latitude range 60° N-60° S, using a 0.1″ slit centered on Prometheus and tilted roughly 45° to the spin axis. The SO₂ column density peaked at 1.25×10¹⁷ cm⁻² near the equator, with an additional 5×10¹⁶ cm⁻² enhancement over Prometheus corresponding to a model volcanic SO₂ output of 10⁵ kg s⁻¹. Apart from the Prometheus peak, the SO₂ column density dropped fairly smoothly away from the subsolar point, even over regions that included potential volcanic sources. At latitudes less than ±30°, the dropoff rate was consistent with control by vapor pressure equilibrium with surface frost with subsolar temperature 117.3±0.6 K, though SO₂ abundance was higher than predicted by vapor pressure control at mid-latitudes, especially in the northern hemisphere. We conclude that, at least at low latitudes on the anti-jovian hemisphere where there are extensive deposits of optically-thick SO₂ frost, the atmosphere is probably primarily supported by sublimation of surface frost. Although the 45° tilt of our slit prevents us from separating the dependence of atmospheric density on solar zenith angle from its dependence on latitude, the pattern is consistent with a sublimation atmosphere regardless of which parameter is the dominant control. The observed drop in gas abundance towards higher latitudes is consistent with the interpretation of previous Lyman alpha images of Io as indicating an atmosphere concentrated at low latitudes. Comparison with previous disk-resolved UV spectroscopy, Lyman-alpha images, and mid-infrared spectroscopy suggests that Io's atmosphere is denser and more widespread on the anti-jovian hemisphere than at other longitudes. SO₂ gas temperatures were in the range of 150-250 K over the majority of the anti-jovian hemisphere, consistent with previous observations. SO was not definitively detected in our spectra, with upper limits to the SO/SO₂ ratio in the range 1-10%, roughly consistent with previous observations. S₂ gas was not seen anywhere, with an upper limit of 7.5×10¹⁴ cm⁻² for the Prometheus plume, confirming that this plume is significantly poorer in S₂ than the Pele plume (S₂ /SO₂<0.005, compared to 0.08-0.3 at Pele). In addition to the gas absorption signatures, we have observed continuum emission in the near ultraviolet (near 2800 Å) for the first time. The brightness of the observed emission was directly correlated with the SO₂ abundance, strongly peaking in the equatorial region over Prometheus. Emission brightness was modestly anti-correlated with the jovian magnetic latitude, decreasing when Io intersected the torus centrifugal equator.     

Frost spectra: Comparison with Jupiter's Satellites

The near infrared spectral reflectance of pure CH₄, CO₂, H₂O, H₂S, NH₃ and NH₄SH frosts has been measured. Comparison with recent Galilean satellite spectra indicates that H₂O at approximately 150°K and with about 0.01 cm grain size is the major component on the surface of JII (Europa) and JIII (Ganymede); upper limits for the remaining frosts range from 5 to 28%. Materials other than these frosts must be present on the surface of JI (Io) and JIV (Callisto).     

Forbidden sulphur I lines in the solar spectrum

The [SI] lines are due to transitions within the 3s²3p⁴ ground configuration of neutral sulphur. The results are presented from a search for the [Si] lines in the Fraunhofer spectrum. Two identifications are proposed with faint features in the Fraunhofer spectrum: ¹D₂-¹S₀ at = 7725.02 Å and ³P₂-¹D₂ at = 10821.23 Å. Their measured equivalent widths are shown to confirm the value for the solar abundance of sulphur, logN _S = 7.21 (in the scale logN _H = 12.00), which is derived from the permitted high-excitation lines. These lines give the first convincing identification of [Si] lines in an astrophysical source.     

The sodium and hydrogen gas clouds of Io

Models are developed to describe the spatial distribution of gases emitted by Io and are applied to recent observations which indicate extensive gas clouds of hydrogen and sodium in orbit around Jupiter. Hydrogen and sodium atoms are emitted from Io with velocities in the range 2 to 3 km sec^?1, with fluxes of about 10¹⁰ and 10⁸cm^?2sec^?1 for hydrogen and sodium respectively. Hydrogen atoms may be formed by photodecomposition of gases such as NH₃ or H₂S released from the satellite surface and may escape thermally from an exosphere whose temperature is about 500 K. Sodium may be ejected from the surface by energetic particles or by ultraviolet radiation and it appears that a non-thermal mechanism drawing energy from Jupiter's magnetic field is required in order to account for its release to space.