Photodissociation of nitric oxide in the middle and upper atmosphere

Absorption of solar radiation of wavelengths between 175 to 205 nm plays a fundamental role in the photochemistry of the middle atmosphere. Nitric oxide photodissociates in the δ(0-0) and δ(1-0) bands near 191 and 183 nm, respectively, initiating the primary mechanisms for NO_x removal in the middle atmosphere. The spectrally rich Schumann-Runge (S-R) bands of O₂ are the main source of atmospheric opacity at these wavelengths. A re-evaluation of O₂ absorption has been made based on recent advances in understanding of S-R line shapes, leading to differences with conventional approaches assuming Voigt line profiles in line-by-line calculations of the O₂ cross section. The new results are used to examine the impact of O₂ transmission on the photodissociation of NO in the δ(0,0) and δ(1,0) bands.     

Far-infrared photometry of planets: Saturn and Venus

We present far-infrared observations of Saturn and Venus made within four spectral bands (31 to 38, 47 to 67, 71 to 94, and 114 to 196 μm) using a 32-cm airborne telescope during May 1977. The set of brightness temperatures obtained from Saturn is analyzed on the basis of thermal models of the atmosphere of this planet. The best agreement is obtained with an effective temperature of about 95°K for the planet itself and a ring contribution corresponding to brightness temperatures ranging from 55 to 70°K. These values of the temperature of the ring system are smaller than the ones measured at shorter wavelengths and could be indicative of a decreasing emissivity of the rings in the far infrared.     

The solar spectral irradiance and its action in the atmospheric photodissociation processes

A critical analysis has been made of solar irradiance in the spectral region covering wavelengths from 100 nm upwards; the absorption characteristics of molecules of oxygen and ozone have been taken into account with a view to the direct application of the results to atmospheric photochemistry. The absorption of radiation by these molecules results in the photodissociation of both of them in the homosphere, and it also makes possible the penetration of solar radiation from the thermosphere, through the mesosphere and the stratosphere, down to the troposphere.Special attention has been given to each of the following spectral regions: Lyman-alpha radiation at 121.6 nm, the O₂ Schumann-Runge continuum at wavelengths less than 175 nm, the O₂ Schumann-Runge band system from 200 to 175 nm, and the O₂ Herzberg continuum at 242.4 nm. For absorption by ozone, the solar spectrum has been analysed in the following regions: the Hartley band at wavelengths less than 310 nm, the Huggins bands at wavelengths above 310 nm and the visible Chappuis bands. Finally, for the photodissociation of O₃, particular attention has been given to the transition region (300–320 nm) in which there is a change-over from the production of the excited atom O(¹D) to that of the atom in its ground state O(³p).     

Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere

New low-temperature methane absorption coefficients pertinent to the Titan environment are presented as derived from the Huygens DISR spectral measurements combined with the in-situ measurements of the methane gas abundance profile measured by the Huygens Gas Chromatograph/Mass Spectrometer (GCMS). The visible and near-infrared spectrometers of the descent imager/spectral radiometer (DISR) instrument on the Huygens probe looked upward and downward covering wavelengths from 480 to 1620 nm at altitudes from 150 km to the surface during the descent to Titan's surface. The measurements at continuum wavelengths were used to determine the vertical distribution, single-scattering albedos, and phase functions of the aerosols. The gas chromatograph/mass spectrometer (GCMS) instrument on the probe measured the methane mixing ratio throughout the descent. The DISR measurements are the first direct measurements of the absorbing properties of methane gas made in the atmosphere of Titan at the pathlengths, pressures, and temperatures that occur there. Here we use the DISR spectral measurements to determine the relative methane absorptions at different wavelengths along the path from the probe to the sun throughout the descent. These transmissions as functions of methane path length are fit by exponential sums and used in a haze radiative transfer model to compare the results to the spectra measured by DISR. We also compare the recent laboratory measurements of methane absorption at low temperatures [Irwin et al., 2006. Improved near-infrared methane band models and k-distribution parameters from 2000 to 9500 cm⁻¹ and implications for interpretation of outer planet spectra. Icarus 181, 309-319] with the DISR measurements. We find that the strong bands formed at low pressures on Titan act as if they have roughly half the absorption predicted by the laboratory measurements, while the weak absorption regions absorb considerably more than suggested by some extrapolations of warm measurements to the cold Titan temperatures. We give factors as a function of wavelength that can be used with the published methane coefficients between 830 and 1620 nm to give agreement with the DISR measurements. We also give exponential sum coefficients for methane absorptions that fit the DISR observations. We find the DISR observations of the weaker methane bands shortward of 830 nm agree with the methane coefficients given by Karkoschka [1994. Spectrophotometry of the jovian planets and Titan at 300- to 1000-nm wavelength: the methane spectrum. Icarus 111, 174-192]. Finally, we discuss the implications of our results for computations of methane absorption in the atmospheres of the outer planets.     

Scattering in the Atmosphere of Venus. I. Line profiles and curves of growth for isotropic scattering

We have computed line profiles and curves of growth for both reflected and transmitted radiation for typical lines in CO₂ bands (in the photographic infrared) which occur in the spectrum of Venus. In our model the pressure variation with altitude was considered and the base of the cloud deck was set at the 2 bar level. The temperature was held constant at 250K and a Voigt profile was used for the lineshape. We also assumed that the scale height of the cloud particles was equal to the scale height of the gas. The calculations were made for four values of the scattering optical thickness (τ_c = 0.1, 1.0, 10, and 100) using a continuum single scattering albedo $\text{ω}{}_{\mathrm{<mtext>c</mtext>}}\text{= 0.9975}$ (which gives a Bond albedo of 0.896 for τ_c = 100, the value observed for Venus at these wavelengths). Curves of growth are also presented for reflected radiation which has been averaged over the visible disk for three values of the Venus phase angle (0, 86, and 166°).     

An improvement to the volcano-scan algorithm for atmospheric correction of CRISM and OMEGA spectral data

The observations of Mars by the CRISM and OMEGA hyperspectral imaging spectrometers require correction for photometric, atmospheric and thermal effects prior to the interpretation of possible mineralogical features in the spectra. Here, we report on a simple, yet non-trivial, adaptation to the commonly-used volcano-scan correction technique for atmospheric CO₂, which allows for the improved detection of minerals with intrinsic absorption bands at wavelengths between 1.9 and 2.1 μm. This volcano-scan technique removes the absorption bands of CO₂ by ensuring that the Lambert albedo is the same at two wavelengths: 1.890 and 2.011 μm, with the first wavelength outside the CO₂ gas bands and the second wavelength deep inside the CO₂ gas bands. Our adaptation to the volcano-scan technique moves the first wavelength from 1.890 μm to be instead within the gas bands at 1.980 μm, and for CRISM data, our adaptation shifts the second wavelength slightly, to 2.007 μm. We also report on our efforts to account for a slight ∼0.001 μm shift in wavelengths due to thermal effects in the CRISM instrument.     

Detection and discrimination of sulfate minerals using reflectance spectroscopy

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.     

Some properties of the He-w star HD 35502

This is a preliminary study of the star HD 35502. Its magnetic field has been measured in different phases of its period. Preliminary values of the magnetic field parameters have been obtained based on a central quadrupole model. The effective magnetic field Be varies over 0-5000 G, the average surface magnetic field ranges over 6300-6700 G, the field at the poles is Bp=7000 G, and the angle between the quadrupole axis and the axis of rotation is β = 80o. As a first approximation, the surface helium is concentrated around the (negative) pole and for τ > 1 its abundance is reduced by approximately 2-4 dex, which confirms the hypothesis of helium diffusion under the action of gravitation and wind in a stable atmosphere. The chemical elements Si and Cr are concentrated in four spots on the magnetic equator between the magnetic poles, or in a ring coincident with the magnetic equator; precisely which is not clear at present.     

Lyman-alpha line intensity as a solar activity index in the far ultraviolet range

The relations between variations of far UV (FUV) emission in 115–210 nm waveband and L 121.6 nm and F_10.7 are studied. The changes of FUV flux are found to lag changes of F_10.7 - as a rule for 1 day. It is shown that such a difference may be caused by two factors: 1) differences between the rates of decrease of local sources' (active regions) brightness in FUV and 10.7 cm; 2) differences between limb-darkening curves for different wavelengths. One may expect the fluxes at different wavelengths to exhibit phase shifts of one relative to another. Cross-correlation analysis reveals no time-delay between emission fluxes within the FUV waveband, in spite of different laws for limb-brightening (darkening) for different spectral intervals. The absence of a phase delay can be caused by relatively small contribution of active regions to the flux of the whole Sun at these wavelengths. Thus the Lyman-alpha line intensity variation reflects variations of Solar FUV emission more precisely than F_10.7. Therefore, using the L intensity for flux intensity calculations of other FUV wavelengths is preferable to using the F_10.7 index.     

Saturn: UBV photoelectric pinhole scans of the disk,II

During the 1980 Saturn apparition, calibrated UBV pinhole scans of the disk were obtained with a photoelectric area-scanning photometer. Point spread function data were also taken. Equatorial and polar scans were used to investigate the structure of the Satur atmosphere. The observational geometry was optimum. Not only was Saturn at opposition, but the ring system was essentially edge on to both the Sun and Earth. Our analysis indicates that the atmosphere of Saturn can be represented by a finite clear H₂ layer overlaying a semi-infinite absorbent aerosol haze. The extent of the clear H₂ region appears to be latitude dependent. The H₂ column density varies systematically from ～15 km-am over the equatorial and polar regions to ～ 31 km-am at temperate latitudes. The hemispheres of the planet are similar. Our earlier conclusion, that the aerosol haze is strongly absorbent in the ultraviolet, is confirmed; its effective U-band single-scattering albedo is ～0.4. Latitudinal disk structure at visual wavelengths appears to be the result of local variations in the volume density of absorbent particles in the aerosol layer.     

The significance of pressure shifts for the interpretation of H2 quadrupole lines in planetary spectra

The effects of pressure shifts on the formation of H₂ quadrupole absorption lines in the atmospheres of the major planets have not previously been considered. It is shown that, although pressure shifts have not been measured for the 3-0 and 4-0 H₂ bands, they can be estimated from existing experimental and theoretical knowledge. Using these estimates, it is shown that the effect of pressure shifts is negligible for Jupiter and small for Saturn, but quite large for Uranus. Consideration of the shifts reduces H₂ abundances determined for Uranus by from 25% to 50% as compared to calculations in which the shifts are ignored. The effect may be even larger for Neptune.     

Impact of the Quadrupole Moment of the Sun on the Dynamics of the Earth-Moon System

Range of values of the Sun's mass quadrupole moment of coefficient J₂ arising both from experimental and theoretical determinations enlarge across literature on two orders of magnitude, from around 10^-7 until to 10^-5. The accurate knowledge of the Moon's physical librations, for which the Lunar Laser Ranging data reach an outstanding precision level, prove to be appropriate to reduce the interval of J₂ values by giving an upper bound of J₂. A solar quadrupole moment as high as 1.1 10^-5 given either from the upper bounds of the error bars of the observations, or from the Roche's theory, is not compatible with the knowledge of the lunar librations accurately modeled and observed with the LLR experiment. The suitable values of J₂ have to be smaller than 3.0 10^-6. As a consequence, this upper bound of 3.0 10^-6 is accepted to study the impact of the Sun's quadrupole moment of mass on the dynamics of the Earth-Moon system. Such as effect (with J₂ = 5.5±1.3 × 10^-6) has been already tested in 1983 by Campbell & Moffat using analytical approximate equations, and thus for the orbits of Mercury, Venus, the Earth and Icarus. The approximate equations are no longer sufficient compared with present observational data and exact equations are required. As if to compute the effect on the lunar librations, we have used our BJV relativistic model of solar system integration including the spin-orbit coupled motion of the Moon. The model is solved by numerical integration. The BJV model stems from general relativity by using the DSX formalism for purposes of celestial mechanics when it is about to deal with a system of n extended, weakly self-gravitating, rotating and deformable bodies in mutual interactions. The resulting effects on the orbital elements of the Earth have been computed and plotted over 160 and 1600 years. The impact of the quadrupole moment of the Sun on the Earth's orbital motion is mainly characterized by variations of , , and . As a consequence, the Sun's quadrupole moment of mass could play a sensible role over long time periods of integration of solar system models. This revised version was published online in July 2006 with corrections to the Cover Date.     

Jupiter's polar clouds and waves from Cassini and HST images: 1993-2006

For a variety of reasons, Jupiter's polar areas are probably the less observed regions of the planet. To study the dynamics and cloud vertical structure in the polar regions of the planet (latitudes 50° to 80° in both hemispheres) we have used images of Jupiter obtained from the ultraviolet to near infrared (258 to 939 nm) by the Cassini Imagining Science Subsystem (ISS) in December 2000. The temporal coverage was complemented with archived images from the Hubble Space Telescope (1993-2006) in a similar spectral range. The zonal wind velocities have been measured at three Cassini ISS wavelengths (CB2, MT3 and UV1, corresponding to 750, 890 and 258 nm) sounding different altitude levels. The three eastward jets detected in CB2 images (lower cloud) go to zero velocity when measured in the UV1 filter (upper haze). A radiative transfer analysis has been performed to characterize the vertical structure of cloud and hazes distribution at the poles. We also present a characterization (phase speed, amplitude and zonal wavenumber) of the previously detected circumpolar waves at 67° N and S at 890 nm and at about 50° N and −57° S at 258 nm that are a permanent phenomenon in Jupiter with some variability in its structure during the analyzed period. From the ensemble of data analyzed we propose the waves are Rossby waves whose dynamic behavior constrains plausible values for their meridional and vertical wavenumbers. This work demonstrates the long-term nature of Jupiter's polar waves, providing a dynamical and vertical characterization which supports a detailed analysis of these phenomena in terms of a Rossby wave model.     

The Violet Opacity in the Red Peculiar Stars – III. Spectral analysis of the SC star GP Ori

Medium-resolution (1.5-2.5 Å) spectrum has been obtained for SC star GP Ori in a wide range of wavelengths from 3730 to 6250 Å. It is characterised mainly by strong atomic lines, as well as moderately strong bands of the CN violet system and CH (0,0) and (0,1) bands at 4315 and 4890 Å. Weak bands of C₂, C₃, and ZrO molecules are observed, however, no evidence is found for the presence of either SiC₂ (Merrill-Sanford bands) or YO. The most prominent atomic lines along with the NaID12 are those of CaII (K,H), CaI at 4227 Å, SrI at 4607 Å, SrII at 4077 and 4215 Å, and BaII at 4554 Å. H seems to be in emission.     

Lunar photometric properties at wavelengths 0.5-1.6 μm acquired by SELENE Spectral Profiler and their dependency on local albedo and latitudinal zones

The lunar photometric function, which describes the dependency of the observed radiance on the observation geometry, is used for photometric correction of lunar visible/near-infrared data. A precise photometric correction parameter set is crucial for many applications including mineral identification and reflectance map mosaics. We present, for the first time, spectrally continuous photometric correction parameters for both sides of the Moon for wavelengths in the range 0.5-1.6 μm and solar phase angles between 5° and 85°, derived from Kaguya (SELENE) Spectral Profiler (SP) data. Since the measured radiance also depends on the surface albedo, we developed a statistical method for selecting areas with relatively uniform albedos from a nearly 7000-orbit SP data set. Using the selected data set, we obtained empirical photometric correction parameter sets for three albedo groups (high, medium, and low). We did this because the photometric function depends on the albedo, especially at phase angles below about 20° for which the shadow hiding opposition effect is appreciable. We determined the parameters in 160 bands and discovered a small variation in the opposition effect due to the albedo variation of mafic mineral absorption. The consistency of the photometric correction was checked by comparing observations made at different times of the same area on the lunar surface. Variations in the spectra obtained were lower than 2%, except for the large phase angle data in mare. Lastly, we developed a correction method for low solar elevation data, which is required for high latitude regions. By investigating low solar elevation data, we introduced an additional correction method. We used the new photometric correction to generate a 1° mesh global lunar reflectance map cube in a wavelength range of 0.5-1.6 μm. Surprisingly, these maps reveal that high latitude (?75°) regions in both the north and south have much lower spectral continuum slopes (color ratio r_1547.7nm/r_752.8nm ? 1.8) than the low and medium latitude regions, which implies lower degrees of space weathering.     

Remote sensing D/H ratios in methane ice: Temperature-dependent absorption coefficients of CH3D in methane ice and in nitrogen ice

The existence of strong absorption bands of singly deuterated methane (CH₃D) at wavelengths where normal methane (CH₄) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer Solar System bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 μm to study CH₃D bands at 2.47, 2.87, and 4.56 μm, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH₃D is diluted in CH₄ ice and also when it is dissolved in N₂ ice, and describe how these absorption coefficients can be combined with data from the literature to simulate arbitrary D/H ratio absorption coefficients for CH₄ ice and for CH₄ in N₂ ice. We anticipate these results motivating new telescopic observations to measure D/H ratios in CH₄ ice on Triton, Pluto, Eris, and Makemake.     

The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10⁻⁴, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν₅ + 3ν₆ and 2ν₃ + 2ν₆ bands of CH₃D.     

Intensity and polarization line profiles in a semi-infinite Rayleigh-scattering planetary atmosphere. I. Integrated flux

Absorption and polarization line profiles as well as the curves of growth in the integrated light of a planet over the whole range of phase angles have been computed assuming a semi-infinite atmosphere scattering according to Rayleigh’s phase-matrix which takes polarization into account. The relative change in line depth and equivalent widths qualitatively agree with the observations of the CO₂ bands in Venus reported by Young, Schorn and Young (1980). It is pointed out that the bands might be formed in a part of the atmosphere which is different from that where continuum polarization originates.     

Imaginary part of the refractive index of aerosol in latitudinal belts of Jupiter’s disc

The values of the imaginary part of the refractive index n _i of aerosol in bright (EZ, NTrZ, and STrZ) and dark (NTB, NEB, SEB, and STB) latitudinal bands of Jupiter’s disc have been determined. They are averaged over the effective depth where the intensity of radiation diffusely reflected by the planet is formed. These values turned out to be lower in the zones than in the belts: specifically, 0.00017–0.00041 vs. 0.00063–0.00098, 0.00019–0.00041 vs. 0.00065–0.00097, 0.00017–0.00041 vs. 0.00070–0.00112, and 0.00019–0.00044 vs. 0.00069–0.00111 at λ = 605, 631, 714, and 742 nm, respectively. These results probably indicate the difference in the vertical stratification of the nature of cloud layers, as well as in the sizes of aerosol particles (they are larger in the belts).     

Analysis of infrared photometry of algol

Infrared (JHKLM) photometry of Per, due to Zeilik (1980), has been analysed by computer-based optimization methods. The data have been used primarily to find empirical mean flux ratios at known IR wavelengths for the two photospheres of the eclipsing pair. These flux ratios have then been compared with values predicted by various model atmosphere calculations. The ratio of effective temperatures can be given asT _B/T _A=0.42±0.02, but there remains some small discrepancy between the empirical results and model calculations at the longest wavelengths (KLM). The possibility of IR-excess at longer wavelengths is considered, but the evidence is marginal.