Diagenetic paths in the margin of a Triassic Basin: NW zone of the Iberian Chain, Spain

Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins.     

Evaluation of weathering-resistance classes in clastic rocks on the example of Polish sandstones

The scope of the paper is an attempt at the identification of the weathering-resistance classes within clastic rocks by means of analysis of capillary pressure saturation curves. The porosimetric parameters corresponding to the cementing character and the grains’ mineralogical content are very important features of stone building materials, because of the weathering processes. The analysed rocks were Polish sandstones and muddy sandstones used for building purposes, collected from different geological units of Poland (i.e. Sudety Mts. Carpathian Mts. and Holy Cross Mts.) The results indicate the usefulness of sandstone materials for building purposes. They could also be used in conservation procedures and for the reconstruction of existing buildings and monuments. Basing on the parameterisation, with the van Genuchten function, of cumulative capillary pressure saturation curves, it was possible to distinguish four groups of the sampled rocks. The lithological features and weathering sustainability within the groups are quite uniform, what allow identifying the weathering resistance classes. Taking into account the complicated nature of all the factors influencing weathering processes, it is supposed that the presented parameterisation could be a useful tool for weathering-resistance classification of clastic rocks. The classification could be useful in building industry and in conservation of historical stone monuments.     

The role of porosity in the development of authigenic dolomite and palygorskite. An example in siliceous sandstones of continental origin in Western Spain

During the Tertiary, the Hercynian basement of the Iberian Peninsula was uneven due to Alpine tectonism which led to the development of a set of horsts and grabens forming its main geological structure. One of these grabens is the Ciudad Rodrigo Basin, located close to the Portuguese border. The south-western margin of this graben is filled with arkosic sandstones of continental origin that, once deposited, underwent important low-grade diagenetic processes related to the surface processes. The main diagenetic processes were hydrolysis, replacement by carbonate, and argillization to palygorskite. These three processes led to the differentiation of three main levels within the outcrops studied: (1) the Lower Level, where the original clayey sandstone outcrops, displaying fairly hydromorphic traits; (2) the Middle Level, where part of the clayey matrix has been replaced by dolomitic carbonate; and (3) the Upper Level, where palygorskite is the new neoformed clay. The change in porosity seems to have been the controlling factor, since it governs the dynamics of the solutions inside the rocks. These conditions changed from being diffusion-driven, at the start of the diagenesis, to flow-driven as porosity increased.     

Calcareous nannofossils and the Santonian/Campanian and Campanian/Maastrichtian boundaries on the Brazilian Continental Margin: historical overview and state of the art

Recognition of the Campanian stage on the Brazilian Continental Margin, using calcareous nannofossils, has been historically problematic. This paper constitutes an overview of earlier works, showing how nannofossil biostratigraphic ideas have evolved since Troelsen & Quadros provided the first biozonation of this region in 1971. Recent studied have provided data which have helped to clarify these apparent biostratigraphic problems, and allows this region to be placed in a global biostratigraphic context.The earliest researchers identified the Santonian/Campanian boundary by the last occurrences of ‘Lithastrinus grillii’ andPetrobrasiella venata. P. venatawas later abandoned as an index species due to its rarity and, instead, the last occurrences ofMarthasterites furcatusand ‘Lithastrinus grillii’ became the most-used markers. However, the stratigraphic age of these biohorizons diverged from those quoted in the literature. In the Brazilian basins, these extinctions, rather than having occurred in the Campanian as was recorded elsewhere, were considered to mark the top of the Santonian, as suggested by correlations with other microfossil groups (primarily foraminifera and palynomorphs). To explain this phenomenon, the existence of a condensed sequence was postulated for most of the Brazilian marginal basins, where the uppermost Santonian deposits were apparently indistinguishable from those of the lowermost Campanian. In line with current correlations presented in the nannofossil literature, and with new information obtained from core and side-wall samples, it is now believed that the extinction of these speciesdidoccur in the Campanian in the Brazilian basins, whilst the last occurrence ofLithastrinus moratus(previously misidentified asLithastrinus grillii) has become a useful Santonian marker. Thus the Santonian/Campanian boundary in Brazil lies in a stratigraphic position similar to elsewhere in nannofossil terms, that is below CC18.The Campanian/Maastrichtian boundary was initially characterised in nannofossil terms in Brazil by the last occurrence ofBroinsonia parca constricta, and later by the last occurrence ofEiffellithus eximius. Recently acquired data has shown that the sequence of events in the Brazilian marginal basins is similar to that of the Sissingh/Perch-Nielsen standard biozonation scheme through this interval. Again, correlations in the literature with the recently defined boundary (in macrofossil terms) thus allow the boundary to be determined between the last occurrences ofBroinsonia parca constrictaandUniplanarius trifidus, that is, in CC23b.     

Conditions of kaolin illitization in the Permo-Triassic sandstones from the SE Iberian Ranges, Spain

Kaolin is a widespread authigenic clay mineral in the Permo-Triassic sandstones from the marginal areas of the SE Iberian Basin. However, relatively more extensive illitization of kaolin occurs in the SW basin margin compared with the slight occurrence in the NE margin. SEM analysis of sandstones reveals that illite replaced small kaolinite crystals while blocky dickite remained unaltered. Kaolin illitization is suggested to take place in relation to the maximum burial depth reached during Late Cretaceous post-rift stage. Vitrinite reflectance data denotes a maximum burial temperature of 118  °C and 144 °C in the NE basin margin and in the SW basin margin, respectively. Thus, the extent of illitization in the SW margin is attributed to the higher T_peak reached by the Permo-Triassic succession. Regarding the lack of K-feldspars observed in the sandstones and interbedded mudrocks, the source of K⁺ is mainly related to the alteration of detrital mica.     

Quaternary reactivation of a basement structure in the Barreirinhas Basin, Brazilian Equatorial Margin

The Pirapemas Lineament is a remarkable 200-km-long, NE-SW trending structure in the Barreirinhas Basin, one of the several Brazilian coastal basins. This lineament splits the study area in two sectors of distinctive morphology, drainage patterns, and sedimentary covers. Terrain northward of the lineament presents a smooth topography with sub-parallel to sub-dendritic drainage patterns, whereas a dissected plateau characterized by incised valleys and rectangular drainage pattern occurs southward, suggesting a structural control by joints and faults. Geological field data, crossed with thermal luminescence (TL) and optically stimulated luminescence (OSL) dating, revealed that the surface southward of the lineament consists mostly of Miocene and late Pleistocene sedimentary deposits, represented by the Barreiras Formation and the Post-Barreiras sediments, respectively. In contrast, relatively younger sands mantle most of the northward terrain, as indicated by well-preserved paleodune deposits that grade into active aeolian dunes of the Lençóis Maranhenses National Park. Geomorphological and geological data analysis suggests that the northern sector is under the effect of subsidence, proving that the Pirapemas Lineament is an active agent modeling the landscape in the region. Geophysical data (gravity and seismic) confirm that such a structural feature is the surface expression of an active deep-seated basement fault.     

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.     

新生代的气候节律:赤道太平洋IODP320、321航次

新生代以来,地表气候在大趋势上逐渐变冷,并呈现出冷暖交替的变化节律.影响气候变化的因素主要包括太阳辐射量和地内气候系统的反馈效应.揭示气候变化的最终规律需要更准确的天文计算和更长、更可靠的气候替代性指标的重建.综合大洋钻探计划IODP 320、321航次在东赤道太平洋钻取了一系列保存完好、连续的深海沉积钻孔,为揭示新生代气候演变的规律提供了良好的研究材料.从全球视野的角度研究古海洋学和古气候学问题是揭示气候演变规律的良好方法,值得中国研究者借鉴.     

Dolomite formation in the dynamic deep biosphere: results from the Peru Margin

Early diagenetic dolomite beds were sampled during the Ocean Drilling Programme (ODP) Leg 201 at four reoccupied ODP Leg 112 sites on the Peru continental margin (Sites 1227/684, 1228/680, 1229/681 and 1230/685) and analysed for petrography, mineralogy, δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values. The results are compared with the chemistry, and δ¹³C and ⁸⁷Sr/⁸⁶Sr values of the associated porewater. Petrographic relationships indicate that dolomite forms as a primary precipitate in porous diatom ooze and siliciclastic sediment and is not replacing the small amounts of precursor carbonate. Dolomite precipitation often pre‐dates the formation of framboidal pyrite. Most dolomite layers show ⁸⁷Sr/⁸⁶Sr‐ratios similar to the composition of Quaternary seawater and do not indicate a contribution from the hypersaline brine, which is present at a greater burial depth. Also, the δ¹³C values of the dolomite are not in equilibrium with the δ¹³C values of the dissolved inorganic carbon in the associated modern porewater. Both petrography and ⁸⁷Sr/⁸⁶Sr ratios suggest a shallow depth of dolomite formation in the uppermost sediment (<30 m below the seafloor). A significant depletion in the dissolved Mg and Ca in the porewater constrains the present site of dolomite precipitation, which co‐occurs with a sharp increase in alkalinity and microbial cell concentration at the sulphate–methane interface. It has been hypothesized that microbial ‘hot‐spots’, such as the sulphate–methane interface, may act as focused sites of dolomite precipitation. Varying δ¹³C values from −15‰ to +15‰ for the dolomite are consistent with precipitation at a dynamic sulphate–methane interface, where δ¹³C of the dissolved inorganic carbon would likewise be variable. A dynamic deep biosphere with upward and downward migration of the sulphate–methane interface can be simulated using a simple numerical diffusion model for sulphate concentration in a sedimentary sequence with variable input of organic matter. Thus, the study of dolomite layers in ancient organic carbon‐rich sedimentary sequences can provide a useful window into the palaeo‐dynamics of the deep biosphere.     

Relations between shallow cataclastic faulting and cementation in porous sandstones: First insight from a groundwater environmental context

The interplay between fault zone cataclasis and cementation is important since both processes can drastically reduce the permeability of faults in porous sandstones. Yet the prediction of fault cementation in high-porosity sandstone reservoirs remains elusive. Nevertheless, this process has rarely been investigated in shallowly buried faults (<2 km; T°<80 °C) where its sealing capacity could be acquired early in the geological history of a reservoir. In this paper, the macro- and microscopic analysis of a fault zone in the porous Cenomanian quartz arenite sands of Provence (France) shows that silica diagenesis occurs in the most intensely-deformed cataclastic parts of the fault zone. This fault zone shows 19–48% of its total thickness occupied by low-porosity quartz-cemented cataclastic shear bands whose porosities range from 0 – ca. 5%. The analysis of the weathering profile around the fault zone reveals the presence of groundwater silcretes in the form of tabular, tightly silicified concretions cross-cut by the fault. Detailed transmitted light, cold-cathodoluminescence and scanning electron microscopy analyses of the silica cements (from the fault and the silcrete) reveal that all the silica cements originate from groundwater diagenetic processes. This study therefore shows that silica cementation can occur specifically in fault zones and as groundwater silcrete in the shallow context of a groundwater system, generated at the vicinity of an erosional unconformity.     

鄂尔多斯盆地镇泾区块延长组长81储层成岩作用特征及其对储集物性的影响

鄂尔多斯盆地镇泾区块上三叠统延长组长81储层具有成分成熟度低,结构成熟度中等到好的特点,岩性以岩屑长石砂岩和长石岩屑砂岩为主.长81砂岩属于特低孔特低渗储层,以次生溶蚀粒间孔为主要储集空间.目前储层正处于中成岩阶段A期,主要发育压实、胶结、溶解和交代4种成岩作用类型.机械压实作用是造成长81储层埋深小于2000 m砂岩...     

达县—宣汉地区长兴组礁滩白云岩成岩作用与成岩环境研究

达县—宣汉长兴组礁滩白云岩主要成岩作用类型有压实作用、压溶作用、胶结作用、白云石化作用、新生变形作用、溶蚀作用、破裂作用和充填胶结作用等,对研究区储层贡献最大的成岩作用主要是溶蚀作用、新生变形作用和破裂作用。根据岩石中所形成的大量溶蚀孔隙、晶间溶孔和晶间孔以及裂缝的特征,该套礁滩白云岩储层的良好物性主要形成于中—深埋藏环境。