Assessment of the Role of Carbonate–Bicarbonate Fluids in the Transport and Deposition of REEs in the Process of Ore Formation (Thermodynamic Modeling)

Doklady Earth Sciences - Thermodynamic calculations on the impact of carbonate–bicarbonate fluids cooling from 500 to 100°C on a monazite + calcite association with a simultaneous...     

Evolution of the Landscape of the Western Part of the Turan–Uyuk Basin (Tuva Highland) in the Late Pleistocene

Doklady Earth Sciences - A complex of works including geomorphological deciphering, field survey, drilling, electric prospecting, and dating of deposits using the radiocarbon method and optically...     

History of the geological evolution of the Tsil’ma River basin (midle Timan) in the Devonian

The results of bio- and lithostratigraphic studies of the Givetian-Frasnian rocks in the Tsil’ma River basin are reported. They suggest regularities in sedimentation: distinct rhythmicity and similar succession in the structure of formations. We have identified five palynocomplexes that characterize the formations and make it possible to accomplish a confident biostratigraphic subdivision of sections. Their correlation with coeval complexes in the adjacent areas has been accomplished. The results made it possible to unravel specific features of miospore assemblages formed in the continental and coastal-marine facies.     

Change in carbon flux (1960–2015) of the Red River (Vietnam)

Global riverine carbon concentrations and fluxes have been impacted by climate and human-induced changes for many decades. This paper aims to reconstruct the longterm carbon concentrations and carbon fluxes of the Red River, a system under the coupled pressures of environmental change and human activity. Based on (1) the relationships between particulate and dissolved organic carbon (POC, DOC) or dissolved inorganic carbon (DIC), and suspended sediments (TSS) or river water discharge and on (2) the available detailed historical records of river discharge and TSS concentration, the variations of the Red River carbon concentration and flux were estimated for the period 1960–2015. The results show that total carbon flux of the Red River averaged 2555?±?639 kton C year^?1. DIC fluxes dominated total carbon fluxes, representing 64% of total, reflecting a strong weathering process from carbonate rocks in the upstream basin. Total carbon fluxes significantly decreased from 2816 kton C year^?1 during the 1960s to 1372 kton C year^?1 during the 2010s and showed clear seasonal and spatial variations. Organic carbon flux decreased in both quantity and proportion of the total carbon flux from 40.9% in 1960s to 14.9% in 2010s, reflecting the important impact of dam impoundment. DIC flux was also reduced over this period potentially as a consequence of carbonate precipitation in the irrigated, agricultural land and the reduction of the Red River water discharge toward the sea. These decreases in TSS and carbon fluxes are probably partially responsible for different negatives impacts observed in the coastal zone.     

Biostratigraphy of the Bajocian–Bathonian boundary beds in the basin of the Bolshoi Zelenchuk River (Northern Caucasus)

The study of ammonites from the upper part of the upper Bajocian and lower part of the lower Bathonian in the sections of the basin of the Bolshoi Zelenchuk (Karachay-Cherkessia) allowed the recognition of Beds with Parkinsonia djanelidzei (approximate equivalent of the middle part of the Parkinsonia parkinsoni Chronozone) and Beds with Oraniceras scythicum (lower part of the Zigzagiceras zigzag Chronozone). The taxonomic composition and distribution of foraminifers, ostracodes, dinoflagellate cysts, and miospores were studied in the samples from these deposits (upper part of the upper member of Djangura Formation). The recognized characteristic assemblages of microfauna and palynomorphs allowed ostracode and dinocyst subdivisions to be proposed for the Bajocian–Bathonian boundary beds of the Northern Caucasus for the first time. The most important taxa, including ammonites, foraminifers, ostracodes, and dinocysts, are illustrated.     

Some regional indicators of the Tertiary–Quaternary geodynamics in the paleocoastal part of the Bengal basin (India)

Sedimentary processes in the paleocoastal part of the Bengal basin that occured in the Tertiary and Quaternary have been addressed. Three indicators were used: sedimentary bedding forms, microstructure of the sediment, and trace fossils. Various forms of sedimentary structures developed under the influence of dynamic geomorphic processes in the study area in the Quaternary. The microstructure analysis of the sedimentary materials was made by two methods: microphotography and Digital Color Analysis (DCA). The microstructure analysis shows that the geomorphic process remained very dynamic in the Quaternary, influencing the form, thickness, and mineral composition of the sediment strata. The enrichment of the sediments in heavy minerals evidences either oscillating or combined flow sedimentation, while under stable conditions light-mineral deposition took place. The digital data of microfabric study by the DCA method also show that larger particles deposited in the oscillating or high-flow environment and evidence a greater amount of heavy minerals like ferruginous materials. Trace fossils found in the sediments of this area also strongly support the concept that the environment remained dynamic during the Tertiary and Quaternary. The Late Tertiary deposition shows that, during these periods, the sediments were transported from tide-dominated marine coast with low flow energy, which is typical of hot and humid conditions. From Late Tertiary to Early Quaternary, the macrotidal coast became mesotidal (wave-dominated). The second phase is the Middle Pleistocene, when the environment was stable, favoring the continuous deposition of finer particles under low- to medium-flow energy conditions. The third phase, the Recent, is marked by the shoreline shift and modification of the environment. In the Early–Middle Holocene, the shoreline started to shift, which modified the geomorphic conditions of this place from coastal to estuarine and, finally, inland fluvial.     

Comparison of the basalt copper deposits in the Keweenaw Peninsula of michigan (USA) and the adjacent area of Yunnan-Guizhou Provinces (China)EI北大核心CSCD

After years of prospecting and mining of the basaltic copper deposits in the border area of Yunnan-Guizhou provinces, many people think the potential of metallogenic prospect is dismay and the deposits are of small sized. However, some researchers proposed in 2002 that these deposits have characteristics similar to those of the Keweenaw copper deposits, and thus their significance is worthy of further consideration. To investigate the resource potential in the region, we carried out a comparative study of the deposits in the two regions. The results show that the existence of redbed may be an important facor controlling the potential of copper mineralization. Therefore, we suggest that the native copper mineralization in the mid-low Triassic sandrocks demands further investigation and it is promising for metallogenic prospecting. ©, 2015, Science Press. All right reserved.     

Analysis of trace elements (heavy metal based) in the surface soils of a desert–loess transitional zone in the south of the Tengger Desert

It is very important to strengthen the research about the heavy metal pollution of soil in vulnerable ecological regions of the south-central arid area of Northwest China for regulating and guiding local industrial and municipal activities and for protecting the environment. In this study, 48 surface soil samples were collected in the desert–loess transitional zone in the south of the Tengger Desert. The distributions of elements (heavy metal based) and the differences between urban and natural soils were analyzed. We observed that As, Pb, Cu, Zn and S were clearly enriched in the Baiyin area, and Ni and Cr were mainly enriched in the Zhongwei area. V, Mn, Ti, Bi, Co and W were enriched in the southeast margin of the Tengger Desert, where there is relatively little human activity. Over the entire study area, Ce, La and Nd were widely distributed across regions whether with strong or weak human activity. Based on the distributions of elements, we suggest that in the desert–loess transitional zone in the south of the Tengger Desert, the distribution and abundances of element As, Pb, Cu, Zn, S, Ni and Cr are strongly related to the human activities in the area, but the elements V, Mn, Ti, Bi, Co, W, Ce, La and Nd are derived mainly from natural sources.     

Photodissolution of lepidocrocite (γ-FeOOH) in the presence of desferrioxamine B and aerobactin

Batch adsorption and dissolution experiments with lepidocrocite (γ-FeOOH) and two siderophores, desferrioxamine B (DFOB) and aerobactin, were performed between pH 3 and 8 in the dark and under irradiation with UV-visible light. The increase in surface concentrations of adsorbed DFOB with increasing pH was explained in terms of electrostatic interactions between the protonated and charged terminal amine group of DFOB surface complexes and the charged lepidocrocite surface. The adsorption of aerobactin was consistent with the typical anion-like adsorption behavior of low molecular weight organic acids and indicated that the adsorption properties are strongly determined by the carboxylic acid groups. The adsorption experiments revealed furthermore that the Fe(III)-DFOB solution complex has a very low affinity for the surface, in contrast to Fe(III)-aerobactin solution complexes. In accordance with a surface-controlled mechanism of ligand-promoted dissolution, we found a linear correlation between dissolution rates of lepidocrocite and the surface concentrations of adsorbed DFOB. In the dark, 6- to 8-fold lower dissolution rate coefficients were determined for aerobactin in comparison to DFOB. These results suggested that aerobactin forms surface complexes that are less dissolution-active, characterized by a higher degree of multinuclear surface complexation and/or by less dissolution-active coordination modes of the involved iron-binding groups. For both DFOB and aerobactin, dissolution rate coefficients increased significantly under irradiation with UV-visible light. This increase was interpreted in terms of light-induced reduction of surface Fe(III), primarily by intrinsic photochemical processes of the lepidocrocite bulk phase, based on the observed photoreductive dissolution in the absence of organic ligands between pH 3 and 6. We hypothesize that the α-hydroxycarboxylate group of aerobactin may form a surface complex that additionally promotes photoreductive dissolution by a ligand-to-metal charge-transfer (LMCT) reaction, similar to citrate. However, LMCT reactions involving the α-hydroxycarboxylate group of aerobactin are rather ineffective, based on the comparison of light-induced dissolution rate coefficients determined in the presence of aerobactin and citrate.     

The distribution of calcareous nannofossils in the late Santonian–Late Maastrichtian deposits in the southwest of Iran (Khuzestan Province)

The first data on the distribution of calcareous nannofossils in the Behbehan section, the Kuh-e-Rish, are considered. According to the distribution of nannofossils, the Upper Cretaceous deposits of the section are subdivided into nine biostratigraphic zones. CC17 (Calculites obscurus zone) indicate the Late Santonian. Biozones CC18 (Aspidolithus parcus zone), CC19 (Calculites ovalis zone), CC20 (Ceratolithoides aculeus zone), CC21 (Quadrum sissinghii zone), and CC22 (Quadrum trifidum zone) represent the Campanian. Biozone CC23 (Tranolithus phacelosus zone) indicate the Late Campanian–Early Maastrichtian. Biozones CC24 (Reinhardtites levis zone) and CC25 (Arkhangelskiella cymbiformis zone) suggest the Middle and Late Maastrichtian, respectively. In the late Late Maastrichtian, due to decreasing in water depth at the study area, Nephrolithus frequens zone (CC26) defined in Tethysian domain was not recognized. The boundary between Gurpi–Pabdeh Formations represented a non-depositional period from the late Late Maastrichtian to the end of Early Paleocene. Also, it seems that predominant conditions of the sedimentary environment of Neotethys basin with the presence of index species calcareous nannofossils specified, which itself indicates that the warm climate and high depth of the basin in Late Santonian to Late Maastrichtian, in low latitudes has been prevalent.     

The long-term trends (1982–2006) in vegetation greenness of the alpine ecosystem in the Qinghai-Tibetan Plateau

The increased rate of annual temperature in the Qinghai-Tibetan Plateau exceeded all other areas of the same latitude in recent decades. The influence of the warming climate on the alpine ecosystem of the plateau was distinct. An analysis of alpine vegetation under changes in climatic conditions was conducted in this study. This was done through an examination of vegetation greenness and its relationship with climate variability using the Advanced Very High Resolution Radiometer satellite imagery and climate datasets. Vegetation in the plateau experienced a positive trend in greenness, with 18.0 % of the vegetated areas exhibiting significantly positive trends, which were primarily located in the eastern and southwestern parts of the plateau. In grasslands, 25.8 % of meadows and 14.1 % of steppes exhibited significant upward trends. In contrast, the broadleaf forests experienced a trend of degradation. Temperature, particularly summer temperature, was the primary factor promoting the vegetation growth in the plateau. The wetter and warmer climate in the east contributed to the favorable conditions for vegetation. The alpine meadow was mostly sensitive to temperature, while the steppes were sensitive to both temperature and precipitation. Although a warming climate was expected to be beneficial to vegetation growth in the alpine region, the rising temperature coupled with reduced precipitation in the south did not favor vegetation growth due to low humidity and poor soil moisture conditions.     

Geologic stages of the Paleogene and Neogene evolution of the Arctic shelf in the Ob’ region (West Siberia)

The paper is concerned with the structure of the Arctic shelf sediments in the Ob’ region in the Paleogene and Neogene, sampled from boreholes drilled on the Yamal Peninsula, in the lower reaches of the Pur and Taz Rivers. The specifics of Paleogene marine sedimentation in the central and northern West Siberian Plain are studied. The effect of abiotic (tectonic) factors on the completeness of the geologic record is considered as well as the effect of recent (Oligocene-Neogene) tectonic processes on topography and sedimentation. The borehole sections are compared with the main seismic sections of the Kara Sea and Lomonosov Ridge.     

Early Quaternary Age of the Final Stage of Volcanism in the Central Part of the Sredinny Range of Kamchatka (K–Ar Data)

Doklady Earth Sciences - A first set of K–Ar isotopic ages obtained, which allowed to estimate the age of the largest volcanoes of the Anaunsky Dol (3.2, 2.2 and 1.9 Ma) and eruptive centers...     

Age of overthrust-type granites in the accretionary‒collisional system of the early Caledonides (western Baikal region)

The western Baikal region (Ol’khon region, Nutgei zone, Kharikta area) is characterized by the development of packets of thrust-type folds and synkinematic granites corresponding to the stage of thrust deformations (overthrust-type granites). Two stages in the formation of thrust-type folds separated by episodes of granite emplacement are definable. The data obtained make it possible to estimate both the time of transition from thrust to strike-slip deformations and the duration of accretionary?collisional events that resulted in regional strike-slip deformations, which terminated in the western Baikal region 460?455 Ma ago.     

Tantalum mineralization in the apical part of the Cínovec (Zinnwald) granite stock

Summary Granite-hosted tantalum mineralization was studied in the apical part of the Cínovec (Zinnwald) granite stock (eastern Kruné hory, Czech Republic). Samples of granite and greisen from drill hole CS-1 (1596m deep), situated in the centre of the granite body were analysed chemically and examined by electron microprobe. The apical, mainly lepidolite granite with 24 to 212 ppm Ta contains Ta-rich Mn columbite, uranmicrolite and strueverite (tantalian rutile). During greisenization the contents of Ta decreased or remained the same, but the newly formed cassiterite has elevated contents of Ta, probably due to remobilization from albitized granites. Niobium and tantalum mineralization can be linked with both magmatic and postmagmatic stages of granite evolution. Ta-rich columbite formed as a result of albitization dominant at the top of the granite cupola, whereas magmatic Nb-rich columbite is present throughout the entire profile of the granite stock.The Cínovec granite stock is similar to some Palaeozoic Ta-bearing granite stocks in the Far East of Russia (Vosnesenka, Pogranichnyi) which are characterized by a vertical sequence of lepidolite, zinnwaldite and protolithionite granites. It shows minor similarities with Mesozoic amazonite-bearing granites in Transbaikalia (Etyka, Orlovka) and differs petrologically and mineralogically from the Palaeozoic lepidolite granite of Beauvoir (Échassieres) in France.

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Tantalvererzung im oberen Teil des Cínovec (Zinnwalder) Granitstocks

Zusammenfassung Eine granitgebundene Tantalvererzung wurde im oberen Teil des Cínovec (Zinnwalder) Granitstocks (östliches Erzgebirge, Tschechische Republik) untersucht. Granit- und Greisenproben aus der Mitte des Granitkörpers wurden chemisch und mittels Elektronenstrahl-Mikrosonde analysiert. Der apikale Lepidolitgranit mit 24-212 ppm Ta führt Ta-reichen Mangancolumbit, Uranmikrolit und Strueverit (Tantalrutil). Im Verlauf der Vergreisung wurden die Tantalgehalte erniedrigt oder blieben gleich. Nur der neugebildete Kassiterit zeigt, wahrscheinlich als Folge der Remobilisierung aus den albitisierten Graniten, erhöhte Tantalgehalte. Die Niob- und Tantalmineralisation ist an das magmatische und postmagmatische Stadium der Granitentwicklung gebunden. Tantalreiche Columbite wurden durch die Albitisierung im Apikalteil des Granitstockes gebildet, während die niobreichen Columbite des magmatischen Stadiums über das ganze Bohrprofil hinweg vorkommen.Der Zinnwalder Granitstock ist einigen paläozoischen Granitstöcken mit Tantalmineralisation im fernen Osten von Russland (Voznesenka, Pogranichnyi) ähnlich, welche durch eine vertikale Zonierung von Lepidolit-, Zinnwaldit- und Protolithionitgranit charakterisiert sind. Der Granitstock zeigt wenig ähnlichkeiten mit den mesozoischen Amazonitgraniten in Transbaikalien (Etyka, Orlovka) und unterscheidet sich petrologisch und mineralogisch vom paläozoischen Granit aus Beauvoir (Échassieres) in Frankreich.

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With 11 Figures     

An Analysis of the Enrichment Characteristics of Dispersed Elements Cd and In of the Lawu Deposit in Xizang(Tibet)

Please refer to the attachment(s) for more details.     

Natural background of hydrocarbon gases (C1–C5) in the waters of the Kara Sea

The distributions of methane and hydrocarbons (HC) C2+ throughout the vertical section of the water mass and sediments of the Kara Sea and the estuaries of the Ob and Yenisei rivers were examine during expeditions aboard the R/V “Akademik Boris Petrov” in 1997–2002. Data obtained during the expeditions and extensive information provided by the complex study of the carbon cycle in the aquatic area were used to analyze the genesis of hydrocarbon gases in marine water. The example of particulate matter was used to demonstrate that hydrocarbon gases of the composition C2–C5 contained in seawater are genetically related to aquatic organic matter (OM), regardless of seawater salinity. The hydrocarbon complex is dominated (80%) by higher C4–C5 homologues. The concentration of C4–C5 hydrocarbons in the estuarine fresh waters is comparable with the high methane concentration (2–3 μl/l), drastically decreases in the zone of water mixing, and then rapidly increases to values several times higher than the methane concentration in seawater outside the outer boundary of the sedimentation depocenter of riverine particulate matter. A direct correlation was established for the concentration of the C4 + C5 homologues with the OM of the water mass, and the leading role was demonstrated to be played by labile OM of the autochthonous biomass (marine phytoplankton) in the genesis of higher hydrocarbon gases (alkenes, alkanes, and isoalkanes) during the early diagenetic stage of OM transformations in water. Along with the biomass of phytoplankton, a significant role in the genesis of C2–C3 hydrocarbons is played by destruction products of terrigenous OM. The destruction of OM and generation of gaseous hydrocarbons, including methane, are restricted to the pycnocline and the water-sediment interface. The absolute predominance of the sum of the C4 + C5 homologues in the hydrocarbon C2+ gases and the presence of unsaturated C2–C4 hydrocarbons are typical of the natural background of hydrocarbons of the Kara Sea water mass.