中国东海衫叶厥藻中二萜类化学成分的研究

运用硅胶柱层析、Sephadex LH-20凝胶柱层析和HPLC等技术,对采自浙江南麂岛海域的衫叶厥藻(Caulerpa taxifolia)的化学成分进行了研究。从丙酮浸取物中分离得到4个二萜类成分,经NMR、MS等波谱技术分析,其结构分别鉴定为α-tocospiros A(1)、cacospongionolide C(2)、phytene-3(20)-1,2-diol(3)和phytenal(4)。其中化合物1为首次从海洋生物中分离得到,2和3均为首次发现于海藻中,4为首次分离于厥藻属海藻中。化合物1~4对蛋白酪氨酸磷酸酯酶1B(PTP1B)均无明显的抑制活性。     

A Comparison Among Assemblages in Areas Invaded by Caulerpa taxifolia and C. racemosa on a Subtidal Mediterranean Rocky Bottom

Abstract.  This study compares the structure of Mediterranean macroalgal assemblages invaded by Caulerpa taxifolia and C. racemosa . Assemblages in areas colonized by the two algae and in reference areas were sampled and analyzed for 2 years. Significant differences were recorded both between reference and invaded areas and between areas invaded by different Caulerpa species. Macroalgal assemblages colonized by C. racemosa were more separated from references than those colonized by C. taxifolia . Differences between assemblages colonized by C. racemosa and the others decreased during the alga's period of vegetative rest and increased at the last sampling date. While erect and turf species showed similar patterns in invaded areas, covers of encrusting algae were lower in C. racemosa areas than in C. taxifolia areas.     

The spread of Caulerpa racemosa var. cylindracea in the Mediterranean Sea: an example of how biological invasions can influence beta diversity

The present study aims to evaluate if invasion of Caulerpa racemosa var. cylindracea can affect both alpha and beta diversity in Mediterranean coastal system. The following hypotheses were tested: (i) measures of alpha diversity differ between invaded and non-invaded assemblages (ii) this pattern is consistent between different habitats, (iii) assemblages from habitats which are naturally very different tend to be more similar when invaded compared to non-invaded situations. Results showed that Mediterranean benthic assemblages invaded by C. racemosa var. cylindracea were characterized by lower values of alpha diversity than non-invaded assemblages; moreover, differences between deep (25 m) and shallow water (5m) assemblages appeared lower in invaded than in non-invaded areas, with a decrease of beta diversity. This homogenisation of habitats was related to a lack of several characteristic species and to a higher abundance of few opportunistic species in invaded areas, particularly turf-forming algae. Moreover, variability in taxa composition was lower in invaded than in non-invaded assemblages in both habitats.     

地中海的泥火山

最近在地中海东部海底发现了大量的泥火山。地质学家将顶部带有漏斗状火山口的并具有通向深部的管孔 ,并且可涌出混有泥质粘土质沉积物的水、气的大型圆锥形山丘称之为泥火山 ,有时伴有类同于一般火山的强烈的喷发。泥火山的产生是由于细粒岩石 (通常是富含死火山角砾岩和水的粘土 )受到强烈的挤压 ,粘土中还混有气态的硫化氢。这样的混合物形成半液态粥状物 ,以冒气泡的流质形态向上被压出。在多次重复的喷发过程中 ,海底形成了大量布满污泥、经常浸透了石油产物的地下圆丘和“烤饼”。我们发现 ,这种形成物经常可以在由俯冲作用产生的增生…     

Changes in amphipod (Crustacea) assemblages associated with shallow-water algal habitats invaded by Caulerpa racemosa var. cylindracea in the western Mediterranean Sea

The effects of the invasive species Caulerpa racemosa var. cylindracea (hereafter C. racemosa) on amphipod assemblages associated with shallow-water rocky habitats were studied. Two habitats located along the SE Iberian Peninsula were compared; invaded and non-invaded. The results showed that growth of C. racemosa affects habitat structure, influencing the species composition and biomass of macroalgae, and detritus accumulation. In turn, such changes in habitat features affected the associated amphipod assemblages with different ecological requirements. However, the species richness of amphipods was relatively high in both habitats, while the species composition of amphipods changed completely. For example, some species such as Ampithoe ramondi and Hyale schmidti did not colonize invaded habitats, while others such as Apocorophium acutum were favoured by the spread of C. racemosa. Habitat invasion by C. racemosa can have an important influence on biotic assemblages, modifying both habitat structure and the associated fauna, with unknown effects on the overall ecosystem.     

Use of SPOT 5 and IKONOS imagery for mapping biocenoses in a Tunisian Coastal Lagoon (Mediterranean Sea)

Mapping marine biocenoses is an efficient method for providing useful data for the management and conservation of Mediterranean lagoons. Fused images from two satellites, SPOT 5 and IKONOS, were tested as management tools for identifying specific ecosystems in the El Bibane lagoon, situated in southern Tunisia near the Libyan border. The objectives of this study were to provide a precise map of the entire El Bibane lagoon using fused images from SPOT 5 and to compare fused images from SPOT 5 and IKONOS over a test-area. After applying a supervised classification, pixels are automatically classified in four classes: low seagrass cover, high seagrass cover, superficial mobile sediments and deep mobile sediments. The maps of the lagoon revealed and confirmed an extremely wide distribution of seagrass meadows within the lagoon (essentially Cymodocea nodosa; 19 546 ha) and a large area of mobile sediments more or less parallel to the shore (3 697 ha). A direct comparison of overall accuracy between SPOT 5 over the entire area, SPOT 5 over the test-area and IKONOS over the test-area revealed that these tools provided accurate mapping of the lagoon environment (83.25%, 85.91% and 73.41% accuracy, respectively). The SPOT 5 images provided greater overall accuracy than the IKONOS image, but did not take into account the heterogeneous spatial structure of the seagrasses and sediments present in the lagoon environment. Although IKONOS imagery provided lower overall accuracy than SPOT 5, it proved a very useful tool for the mapping of heterogeneous structures as it enabled the patchiness of formations to be better taken into account. The use of SPOT 5 and IKONOS fused images appears to be very promising for completing the mapping of lagoons in other regions and countries of the Mediterranean Sea.     

Managing Bluefin Tuna in the Mediterranean Sea

Atlantic Bluefin Tuna is an important but not well managed fishery in the Mediterranean Sea. In this paper, management system is evaluated with information on stock status, resource rent, and total employment. The non-restrictive implementation of International Commission for the Conservation of Atlantic Tunas (ICCAT) policies is found to be the institutional reason for its management failure, while the common-property and shared stock nature of this fishery is the fundamental reason. To address these major issues, policy schemes are proposed to help sustainably manage this valuable resource in the Mediterranean Sea.     

Mass balance of mercury in the Mediterranean Sea

The Mediterranean Basin is rich in mercury from natural and anthropogenic sources. During an extensive research from 2002–2005, measurements of different mercury forms were carried out in the Mediterranean Sea by the Italian research vessel Urania as a part of the Med Oceanor and MERCYMS projects funded by the EU Framework programme. Further on, transport and fate of mercury forms was simulated in water and air compartments by two different models, and an approximate coupling of both models was performed. The new 3-dimensional model PCFLOW3D was completed with the first version of a biogeochemical module which deals with various mercury species in dissolved and particulate forms. Exchange with the bottom and the atmosphere, methylation, demethylation, reduction and oxidation were taken into account. Based on the integrated hydrodynamic-atmospheric model and results of field measurements the mass balance of total mercury in the Mediterranean Sea was determined in order to estimate main sources and sinks and simulate future trends of mercury contamination in the Mediterranean. The following terms were taken into account: sources of mercury from major rivers and from point sources, exchange with the Atlantic Ocean and the Black Sea, estimated natural sources from geotectonic active areas in the sea, exchange with bottom sediments, and evasion to and deposition from the atmosphere.     

Another description of the Mediterranean Sea outflow

Papers about the outflow in the Strait of Gibraltar assume that (i) it is composed of only two Mediterranean Waters (MWs), the Levantine Intermediate Water (LIW) and the Western Mediterranean Deep Water (WMDW) from the eastern and western basins, respectively, (ii) both MWs are mixed near 6°W, hence producing a homogeneous outflow that is then split into veins, due to its cascading along different paths and to different mixing conditions with the Atlantic Water (AW).A re-analysis of 1985–1986 CTD profiles (Gibraltar Experiment) indicates two other MWs, the Winter Intermediate Water (WIW) from the western basin and the Tyrrhenian Dense Water (TDW) basically originated from the eastern basin. In the central Alboran subbasin, these four MWs are clearly differentiated, roughly lying one above the other in proportions varying from north to south. Proportions also vary with time, so that the outflow can be mostly of either eastern or western origin. While progressing westward, the MWs can still be differentiated and associated isopycnals tilt up southward as much as being, in the sill surroundings, roughly parallel to the Moroccan continental slope where the densest MWs are. The MWs at the sill are thus juxtaposed and they all mix with AW, leading to an outflow that is horizontally heterogeneous just after the sill (5°45′W) before progressively becoming vertically heterogeneous as soon as 6°15′W. There can be little LIW and/or no WMDW outflowing for a while.An analysis of new 2003–2008 time series from two CTDs moored (CIESM Hydro-Changes Programme) at the sill (270 m) and on the Moroccan shelf (80 m) confirms the juxtaposition of the MWs, their individual and generally intense mixing with AW, as well as the large temporal variability of the outflow composition. Only LIW and TDW were indicated at the sill while, on the shelf, only LIW, TDW sometimes denser there than 200 m below, and WMDW were indicated; but none of the MWs has been permanently outflowing at one or the other place.The available data can be analyzed coherently. Intermediate and deep MWs are formed in both basins in amounts that, although variable from year to year, allow their tracing up to the strait. Four major MWs circulate alongslope counterclockwise as density currents and as long as they are not trapped within a basin, which is necessarily the case for the deep MWs. In the Alboran, the intermediate MWs (WIW, LIW and upper-TDW) circulate in the north while the deep MWs (lower-TDW and WMDW) are uplifted, hence relatively motionless and mainly pushed away in the south. Since both the intermediate and deep MWs outflow at the sill, they are considered as light and dense MWs, the light–dense MWs interface possibly intersecting the AW–MWs interface in the sill surroundings. Considering an outflow east of the sill composed of only two (light–dense) homogeneous layers gives significant results. Across the whole strait, the outflow has spatial and temporal variabilities much larger than previously assumed. The MWs are superposed in the sea and lead at the sill to juxtaposed and vertically stratified suboutflows that will cascade independently before forming superposed veins in the ocean. These veins can have similar densities and hydrographic characteristics even if associated with different MWs, which accounts for the features permanency assumed up to now. The outflow structure downstream of the sill depends on its composition upstream and, more importantly, on that of AW in the sill surroundings where fortnightly and seasonal signals are imposed on the whole outflow.     

Baroclinic wind adjustment processes in the Mediterranean Sea

The wind-driven general circulation of the Mediterranean Sea is studied using a primitive equation model. The model uses a 0.25° horizontal resolution and eight or 16 levels in the vertical. The model uses the Mediterranean basin geometry, and the Strait of Gibraltar is closed. The vertical density structure is initialized with annual average data, and the temperature and salinity values are fixed at the surface to simulate perpetual annual mean conditions. The wind forcing consists of monthly mean climatological stresses.The results show that the general circulation of the Mediterranean Sea has a multiple time-scale character (seasonal excursions and steady state amplitudes are comparable) and it is composed by sub-basin scale gyres corresponding to the scale of the wind stress curl centers. The steady state circulation (annual mean average) is determined by a Sverdrup balacne modified by viscous effects.The unsteady vertically integrated transport circulation consists of sub-basin scale gyres similar to the steady state transport components, which amplify seasonally and the partial or total reversal of the currents in many subportions of the basin. The gyres can be stationary in position or propagating. This seasonal ocean response is partly constituted by Rossby modes due to the wind stress curl annual harmonic. The baroclinic circulation shows the seasonal shift of the North African Current from a position along the African coasts during winter to the center of the Balearic and Ionian basin during summer.     

Macrofauna Communities in the Eastern Mediterranean Deep Sea

Abstract. During two expeditions with RV ‘Meteor’ in summer 1993 and winter 1997/98 the structural and functional diversity of the benthic system of the highly oligotrophic eastern Mediterranean deep sea was investigated. The macrofauna communities were dominated by polychaetes even at the deepest stations. The fauna at shallow stations was dominated by surface deposit feeders, whereas subsurface deposit feeders and predators generally increased with depth. A high percentage of suspension‐feeding Porifera was found in the Levantine Basin. Mean abundance and number of taxa of both expeditions were significantly correlated to depth and distance to the nearest coast as well as to the total organic carbon (TOC) content in sediments. Numbers of taxa and abundance decreased generally with depth, although lowest numbers were not found at the deepest stations but in the extremely oligotrophic Levantine and Ierapetra Basin. Biomass measured during the second cruise was extremely low in the Ierapetra Basin and comparable to other extreme oligotrophic seas. The significant correlations found for TOC contents and macrofauna with distance to coast during both expeditions apparently reflect the role of hydrographically governed transport of organic matter produced in coastal regions into greater and extreme depths of the Mediterranean Sea. Seasonal differences in macrofauna communities due to seasonal differences in food supply were not found. However, recent large‐scale hydrographic changes (Eastern Mediterranean Transient, EMT) might change the oligotrophy and, thus, the structure of the benthic communities in the Eastern Mediterranean deep sea.     

Post-convection spreading phase in the Northwestern Mediterranean Sea

This is a study about the spreading of newly formed deep waters following open ocean deep convection in the Northwestern Mediterranean Sea. The main results are from the SOFARGOS large scale float experiment initiated in 1994–1995. During the SOFARGOS project, CTD stations and Lagrangian observations of ocean currents were carried out in the Gulf of Lion from December 1994 to July 1995. Hydrological observations confirmed that deep water formation occurred very early during winter 1994–1995 (late December, early January) in conjunction with atmospheric cooling, deep convection penetrating down to 2000 m in the so-called Medoc area. Numerous eddies (both anticyclonic and cyclonic) drifted away from the convection area and advected newly formed deep waters far away from the source region. In particular, compact anticyclones appeared to be the most coherent (long-lived) eddies and capable of transporting newly formed Western Mediterranean Deep Waters several hundreds of kilometers away from the convection area. Characterized by an inner core of about 5 km in radius, these eddies are submesoscale features in the outer domain and appear as key elements of the open ocean convection processes. During their long journeys, these eddies interacted with larger scale features such as the Northern Boundary Current, the North Balearic Front, topographic Rossby waves, and Sardinian eddies. These interactions influenced the long-term behavior of the eddies (mean drift, composition) and represented an important part of (1) the spreading phase following deep convection and (2) the large scale thermohaline circulation.     

Pulsed export of carbon in the north-western Mediterranean Sea

The short term(hourly scale) variability of heterotrophic prokaryote(HP) vertical distribution and respiratory activity,was investigated in the north-western(NW) Mediterranean Sea.HP vertical distribution was determined on board by flow cytometry analysis of seawater samples collected by series of CTD casts.Cell counts and viability were determined for all samples.HP respiratory rates were determined later in the laboratory from filtered seawater samples(23 dm³) from 300-1 150-m depth...     

Vertical export flux of metals in the Mediterranean Sea

We examined metal (Al, V, Cr, Mn, Fe, Ni, Cu, Zn, Cd and Pb) and particulate organic carbon (OC) concentrations of the marine vertical export flux at the DYFAMED time-series station in the Northwestern Mediterranean Sea. We present here the first data set of natural and anthropogenic metals from sediment trap moorings deployed at 1000 m-depth between 2003 and 2007 at the DYFAMED site. A highly significant correlation was observed between most metal concentrations, whatever the nature and emission source of the metal. Cu, Zn and Cd exhibit different behaviors, presumably due to their high solubility and complexation with organic ligands. The observed difference of atmospheric and marine fluxes in terms of temporal variability and elemental concentration suggests that dense water convection and primary production and not atmospheric deposition control the marine vertical export flux. This argument is strengthened by the fact that significant Saharan dust events did not result in concomitant marine vertical export fluxes nor did they generate significant changes in metal concentrations of trapped particles.     

Socio-economic impacts of ocean acidification in the Mediterranean Sea

Ocean acidification appears as another environmental pressure associated with anthropogenic emissions of carbon dioxide. This paper aims to assess the likely magnitude of this phenomenon in the Mediterranean region. This involves translating expected changes in ocean chemistry into impacts, first on marine and coastal ecosystems and then, through effects on services provided by these to humans, into socio-economic costs. Economic market and non-market valuation techniques are needed for this purpose. Important sectors affected are tourism and recreation, red coral extraction, and fisheries (both capture and aquaculture production). In addition, the costs associated with the disruption of ecosystem regulating services, notably carbon sequestration and non-use values will be considered. Finally, indirect impacts on other economic sectors will have to be estimated. The paper discusses the framework and methods to accomplish all of this, and offers a preliminary, qualitative overall assessment.     

规范养殖用海的几点思考

养殖用海属渔业用海范畴,是我国用海面积最大的用海类型.我国沿海有适宜发展海水养殖的浅海滩涂483万公顷,现有养殖用海面积145万公顷.由于养殖用海面广量大,养殖主体错综复杂,用海观念陈旧落后,尽管《中华人民共和国海域使用管理法》已颁布实施多年,但截至目前仍有30%以上的养殖用海项目未纳入海域使用管理的范畴.鉴于此,笔者就开展养殖用海专项执法工作,进一步规范养殖用海活动,结合工作实践谈几点粗浅的认识.     

Planktonic ciliates in the Mediterranean Sea: longitudinal trends

We analysed samples taken through the euphotic zone from 18 stations between the Ligurian Sea (6°E) and the Levantin Basin (32°E) from 24 May to 25 June 1996. Both ciliate and chlorophyll concentrations ranged over a factor of about 7, but ciliate concentrations (0.4–2.8 mg C m³) varied irregularly compared to a longitudinal decline, west to east, in chlorophyll concentration (0.07–0.48 mg m³). The lower chlorophyll concentrations (0.1 mg m²) of the eastern basin stations corresponded with a relatively high stock of ciliates (0.5 mg C m²). Large mixotrophic ciliates were more abundant, in both absolute and relative terms, in the eastern Mediterranean stations with less chlorophyll. The species diversity of tintinnid ciliates appeared higher in the central and eastern basins compared to the west. Our results suggest a shift from the western to eastern Mediterranean in the planktonic food towards a microbially dominated system.     

Seamont magnetism in the Ionian Sea,eastern Mediterranean

Several seamounts in the Ionian Sea, the largest unit in the eastern Mediterranean, have magnetic anomalies. The magnetization vectors of six of these seamounts have been calculated. These paleomagnetic data suggest that the Ionian Sea is composed of several crustal units which came to their present location from different directions. This implies that there has been relative motion in the past between various land masses around the Ionian Sea. The possibility that the Ionian Sea is composed of several crustal units is supported by observations of the magnetic field over the area which is of different character in the north and south. The major limitation in applying the paleomagnetic data into an evolutionary scheme is that all the seamounts in the Ionian Sea as well as its crust are undated.