夏季自然水体与大气界面间气态总汞的交换通量

利用动力学通量箱法与高时间分辨率大气测汞仪的联用技术, 在瑞典西南的Kristineberg海洋观测站(KMRS)和Knobesholm的Hovgårdsån河分别测定了夏季海水和河水表面与大气间汞的交换通量. 在夏季, 河水和海水都是大气汞的源. 河水和海水表面与大气间汞的交换通量在夏季具有一致的昼夜变化规律, 白天由水体向大气排汞且在正午达到最大值; 夜间排汞量相对较小且有时会出现大气汞向水体沉降. 河水与大气间汞的交换通量与光照强度呈线性正相关关系, 与大气相对湿度呈线性负相关性, 同时还与水体温度存在指数相关性. 海水与大气间汞交换通量只与光照强度存在良好的线性正相关关系. 水体中溶解态气汞的过饱和是水体汞向大气释放的驱动力.     

洱海湖气界面水汽和二氧化碳通量交换特征

基于2012年涡动相关法取得的洱海湖气之间湍流通量资料,计算了湖面反照率、空气动力学粗糙度和整体输送系数等湖气交换过程的基本物理参数;分析高原湖泊表面动量通量、感热通量、潜热通量和二氧化碳通量的变化特征及其主要的控制因子;采用神经网络法对缺失蒸发量数据进行填补,估算了洱海湖面全年蒸发量。2012年全年蒸发量为（1165±15）mm,大于年实际降水量（2012年的年降水量为818mm）。洱海局地环流在全年范围内较显著;全年主导风向为东南（谷风／湖风）和西北风（山风／陆风）。高原湖泊感热通量通常只有每平方米几十瓦,通常午后感热通量为负值;即湖面向大气输送热量。夏季湖泊大气界面感热通量最大值出现在清晨,与湖气温差的出现时间一致;在白天湖面的有效能量主要分配为潜热通量;湖气温差和水汽压差分别是感热通量和潜热通量日变化的主要控制因子。湖气界面二氧化碳通量除夏季存在弱的吸收外,其余季节（冬季）表现为弱的排放。湖面反照率的季节变化规律与太阳高度角的季节变动有关,同时湖面反照率与水的浑浊度等有关。与实际观测得到的湖面反照率相比,CLM4湖泊模式在冬季低估（夏季高估）了湖面反照率。     

鄱阳湖夏季水热通量特征及环境要素影响分析

气候变化加速了全球水文循环过程,然而,气候变化如何影响水体蒸发及其水热通量交换仍然不清楚.基于涡度相关系统观测鄱阳湖水体水热通量过程,在小时和日尺度分析了水热通量的变化规律及其主要影响因子.研究表明,潜热通量日变化波动剧烈,大部分为正值,变化范围在-50~580 W/m2之间.而感热通量数值较小,变化范围在-50~50 W/m2之间.8月份潜热通量和感热通量均呈波动下降趋势,均值分别为167.4和15.9 W/m2.8月份日平均潜热通量和感热通量之和大于净辐射,这是由于这一时段储存在水体中的热量释放并补充潜热通量和感热通量.小时尺度上潜热通量日变化在相位上与净辐射无显著相关性,而与风速显著相关.在日尺度变化趋势上,8月份日平均潜热通量仍主要受到风速和水温的影响,感热通量则主要受到风速和饱和水汽压差的影响.     

三峡水库澎溪河CO2、CH4气泡释放通量初探

气泡释放是天然水体中水-气交换的重要途径之一.采用改进的倒置漏斗型气泡通量监测装置于2012年3-8月期间对三峡支流澎溪河高阳平湖库湾水域进行气泡释放通量的监测研究.研究期间,研究水域CH4气泡释放通量变化范围为0.01 ～ 23288.64 μmol/(m2·d);CO2气泡释放通量变化范围为0～799.89 μmol/(m2·d).不同常规采样点CH4、CO2气泡释放通量均呈现出高度的时空异质性特征.但CH4气泡释放通量显著高于CO2气泡释放通量,且二者释放过程具有同步性.同国外已有水库监测结果相比,澎溪河回水区高阳平湖库湾水域CH4、CO2气泡释放通量位于中等水平.CH4气泡释放通量约为同期CH4扩散通量的0～ 1893.90％,超量释放下CH4气泡释放通量可达同水域CH4扩散通量的6270.5％±390.0％.CO2气泡释放通量仅占同期扩散通量绝对值的0～ 21.74‰,超量释放下,CO2气泡释放通量亦仅为同期扩散通量绝对值的40.33‰ ±0.93‰.CH4气泡释放通量在支流库湾水域对总通量的贡献不可忽视.     

基于同步观测信息利用的高寒湖泊湍流通量数据插补方法

源区划分和质量过滤提高湖面涡动相关通量数据可靠性的同时,却降低了通量时间序列的连续性.为此,本文基于TensorFlow机器学习框架构建了一种超宽人工神经网络(ANN)模型.在选择输入ANN模型的特征变量信息时,我们采取了尽可能获取湍流输送过程中热力、动力学同步观测背景强迫信息的原则.通过ANN模型模拟通量的插补,本文实现了通量时间序列连续性的优化,插补后的羊卓雍错湖面通量数据的时间覆盖率从不足0.40提升至超过0.98.基于10次折叠交叉验证的ANN模型通量模拟性能检验则表明,各个检验组之间ANN模型的模拟误差波动较小,这显示出了较好的稳健性.具体地讲,感热通量、潜热通量和水汽通量原始观测平均值分别约为18.8 W/m~2、81.5 W/m~2和1.84 mmol/(s·m~2),10组交叉验证的插补感热通量、潜热通量和水汽通量平均绝对误差分别为5.4 W/m~2、15.7 W/m~2和0.35 mmol/(s·m~2).这表明本文所探索的ANN建模结构和同步观测变量筛选原则可更充分地利用观测点局地同步观测信息估算通量强度,有效地优化湍流通量数据的时间连续性,从而提升通量数据的可分析性.     

TOGA-COARE IOP期间的海气通量观测结果

在TOGA－COAREIOP期间用涡度相关法对海气热通量进行了船载直接观测．对垂直风速、温度和湿度湍流脉动观测数据的谱分析显示它们在高频区基本满足"－2／3次方律"．对船体简谐震荡影响的讨论从理论上证明该影响在热通量计算中可被忽略．根据以此方法得到的通量求出了中性层结条件下感热和潜热的整体输送系数分别为2．25×10（－3）和1．26×10（－3）．对海气边界层特性的分析表明该海域的近海层主要呈中性或弱不稳定层结．海气通量的变化与背景环流形势密切相关,潜热通量主要受海面风场强度的影响,而感热通量变化除了风场的影响外,层结变化也是一个重要因素．用整体输送法计算TOGA－COAREIOP期间以及TOGA期间8个航次的通量结果而得到的Bowen比约为0．1,显示潜热通量是暖池大气的主要热源．     

四种常见湖泊沉积物氮磷通量估算方法对比分析

湖泊沉积物-水界面营养盐释放是研究湖泊环境行为的重点关注对象,但目前对于湖泊通量的估算方法选择缺乏横向定量比较.以南京莫愁湖为研究对象,在冬春夏3季采用静态释放培养法、机械搅拌培养法、流动培养法和间隙水浓度扩散模型法4种常见的湖泊通量培养方法进行氮磷释放对比实验.结果表明,非扩散模型法（静态释放、机械搅拌、流动培养）在冬季存在负通量,随着气温升高,夏季通量估算值为正,且该3种方法通量数值差异不显著.间隙水扩散模型法在三季实验中结果数值无负值,对比非扩散模型组具有显著差异,约低一个数量级.不同方法在培育过程中溶解氧和pH变化差异显著,流动培养法最为稳定.4种方法的通量结果在不同季节变化趋势具有显著相关性,非扩散模型法估算结果作为表观通量值,适用于计算湖泊沉积物营养盐释放总量,其中静态释放法结果稳定性较差,平行组相对标准偏差最高达70%;流动培养法稳定性最好,平行组相对标准偏差最高仅21%.扩散模型法估算结果作为理论释放值,在估算浅水湖泊通量时低于实际释放通量,适于探究深水湖泊沉积物间隙水动态释放过程,有助于分析湖泊沉积物性质.不同培养方法,有其侧重点,根据不同湖泊状况,应选取合适方法进行通量估算.     

TOGA-COARE IOP期间的海气通量观测结果

在TOGA－COAREIOP期间用涡度相关法对海气热通量进行了船载直接观测．对垂直风速、温度和湿度湍流脉动观测数据的谱分析显示它们在高频区基本满足"－2／3次方律"．对船体简谐震荡影响的讨论从理论上证明该影响在热通量计算中可被忽略．根据以此方法得到的通量求出了中性层结条件下感热和潜热的整体输送系数分别为2．25×10^－3和1．26×10^－3．对海气边界层特性的分析表明该海域的近海层主要呈中性或弱不稳定层结．海气通量的变化与背景环流形势密切相关,潜热通量主要受海面风场强度的影响,而感热通量变化除了风场的影响外,层结变化也是一个重要因素．用整体输送法计算TOGA－COAREIOP期间以及TOGA期间8个航次的通量结果而得到的Bowen比约为0．1,显示潜热通量是暖池大气的主要热源．     

蓄水初期三峡水库草堂河水-气界面CO2和CH4通量日变化特征及其影响因素

为查明三峡水库蓄水初期典型支流水-气界面CO_2和CH_4通量的日变化特征,采用LGR在线分析仪-通量箱法,于2015年9月初在库腹一级支流草堂河回水区开展连续24 h的定位观测.结果表明,24 h监测期内,支流库湾水-气界面CO_2通量变幅为-81.642~180.991 mg/(m~2·h),呈"昼吸夜放"特征,均值为17.346 mg/(m~2·h),总体为释放特征;CH_4全天均表现为释放状态,释放通量均值为0.064 mg/(m~2·h),呈"昼弱夜强"变化.相关分析结果表明,CH_4和CO_2释放通量与风速呈正相关,与表层水温、溶解氧浓度、叶绿素a浓度呈负相关,说明风速物理扰动、浮游植物光合作用是控制草堂河水-气界面气体通量最重要的环境因素.同时,干-支流相互作用形成的特殊水环境(如异重流、水温分层)也与水-气界面温室气体通量过程密切相关,但是其作用机制更为复杂,应开展进一步系统观测和深入研究.     

一种气泡释放过程连续监测方法及其在三峡水库香溪河CH4通量监测的应用

气泡释放是天然水体释放CH₄的主要途径之一,准确量化水体气泡释放量对于辨析其“汇、源”特性至关重要。自然水体释放气泡的不连续性、不确定性使得监测其过程较为困难。本研究针对水体气泡释放监测难题,通过改进倒置漏斗型气泡通量监测装置提出了一种气泡释放过程连续监测方法。本方法测量对象为定长时间监测水域释放气泡的体积,经室内外实验验证,其理论量程为3.6～132 mL/(m²·min),测量结果能够较好的表征10～40 m水深缓流水体气泡体积通量变化特征。运用该方法于2021年6—11月对三峡水库支流香溪河库湾开展CH4气泡通量连续监测,并分析不同环境因子对其产生的影响。结果表明:监测期间,研究水域CH₄气泡通量变化范围为0.02～8.13 mg/(m²·d),且各采样点间CH₄气泡通量呈现较高的时空变异性;CH₄气泡通量与水温、水体pH呈显著正相关关系,与水深及水体电导率呈显著负相关关系。其中,水深可能是决定水体是否通过气泡形式释放CH₄的重...     

Exchange flux of total gaseous mercury between air and natural water surfaces in summer season

The exchanges of mercury between surface and air are of significance in the biogeochemical cycling of Hg in the environment, but there are still few reliable data on air/surface exchange in aquatic systems. Field measurement campaigns over seawater surface at Kristineberg Marine Research Station (KMRS) and over Hovg?rds?n River surface at Knobesholm in southwestern Sweden were conducted to measure mercury flux using a dynamic flux chamber technique coupled with automatic mercury vapor-phase analyzers. Both sites show net emissions during summer time. Mercury fluxes measured over both river and seawater surfaces exhibit a consistently diurnal pattern with maximum fluxes during the daytime period and minimum fluxes during the nighttime period. At freshwater site, mercury flux is strongly correlated with the intensity of net solar radiation, and negatively correlated with relative humidity. A typical exponential relationship between mercury flux and water temperature was observed at freshwater measurement site. At seawater site, a strong correlation between mercury flux and intensity of solar radiation was obtained. The driving force of mercury emission from water surface to air is the super-saturation of dissolved gaseous mercury in aqueous phase.     

云南阳宗海大气氮、磷沉降特征

大气氮、磷沉降是湖泊水体氮、磷入湖的重要途径之一.为了解阳宗海氮、磷沉降对湖泊富营养化的潜在影响,于2012年5月-2014年4月通过监测阳宗海大气氮、磷沉降,估算氮、磷的大气沉降通量,揭示阳宗海大气氮、磷沉降随时间变化的特征,分析其来源、影响因素等.由于阳宗海是磷限制湖泊,本研究在估算大气氮、磷沉降通量的基础上,特别比较了大气磷沉降入湖量与非点源磷的入湖量,以此评估大气沉降输入磷对湖泊富营养化的潜在影响.研究结果表明:阳宗海总氮年平均沉降通量为248 mg/m~2,春、夏、秋和冬季平均分别为200、306、274和214 mg/m~2,其中夏季沉降通量最大,原因与降雨量增加有关;总磷年平均沉降通量为24 mg/m~2,春、夏、秋和冬季平均分别为18、31、19和27 mg/m~2.大气磷沉降与输入阳宗海的总磷量相比很小,对阳宗海富营养化影响较小.     

Nutrient fluxes induced by disturbance in Meiliang Bay of Lake Taihu

A wave flume experiment was conducted to study nutrient fluxes at water-sediment interface of Meiliang Bay under different hydrodynamic conditions. The results reveal that hydrodynamics has remarkable effects on nutrient fluxes in this area. With a bottom wave stress of 0.019 N m-2 (equivalent to disturbance caused by wind SE 5-7 m s-1 at the sediment sample site of Meiliang Bay), the fluxes of TN, TDN and NH4+-N were separately 1.92× 10-3, -1.81 × 10-4 and 5.28× 10-4 mg m-2 s-1(positive for upward and negative for downward), but for TP, TDP and SRP, the fluxes were 5.69 × 10-4, 1.68 × 10-4 and -1.29 × 10-4 mgm-2 s-1. In order to calculate the released amount of nutrients based on these results, statistic analysis on the long-term meteorological data was conducted.The result shows that the maximum lasting time for wind SE 5-7 m s-1 in this area is about 15 h in summer. Further calculation shows that 111 t TN, 32 t NH4+-N, 34 t TP and 10 t TDP can be released into water (the sediment area was 47.45% of the whole surface area), resulting in concentration increase of 0.025, 0.007, 0.007 and 0.002 mg L-1 separately. With stronger disturbance (bottom wave stress is 0.217 N m-2 which is equivalent to disturbance caused by wind SE 10-11 m s-1 at the same site), there has been significant increase of nutrient fluxes (1.16× 10-2, 6.76×10-3, 1.14× 10-2 and 2.14× 10-3 mgm-2 s-1 for TN, DTN and NH4+-N and TP). The exceptions were TDP with flux having a decrease (measured to be 9.54× 10-5 mgm-2 s-1 ) and SRP with flux having a small increase (measured to be 5.42 × 10-5 mgm-2 s-1). The same statistic analysis on meteorological data reveal that the maximum lasting time for wind SE 10-11 m s-1 is no more than 5 h. Based on the nutrient fluxes and the wind lasting-time, similar calculations were also made suggesting that 232 t TN, 134.9 t TDN, 228 t NH4+-N, 42.7 t TP, 2.0 t TDP and 1.1 t SRP will be released from sediment at this hydrodynamic condition resulting in the concentration increases of 0.050, 0.029, 0.049, 0.009, 0.0004 and 0.0002 mg L-1. Therefore in shallow lakes, surface disturbance can lead to significant increase of nutrient concentrations although some components in water column had negative flux with weak disturbance (e.g. TDN and SRP in this experiment). In this case, sediment looks to be a source of nutrients. These nutrients deposited in sediment can be carried or released into water with sediment resuspension or changes of environmental conditions at water-sediment interface, which can have great effects on aquatic ecosystem and is also the characteristics of shallow lakes.     

Experimental study on soil CO2 emission in the alpine grassland ecosystem on Tibetan Plateau

The Tibetan Plateau, the Roof of the World, is the highest plateau with a mean elevation of 4000 m. It is characterized by high levels of solar radiation, low air temperature and low air pressure compared to other regions around the world. The alpine grassland, a typical ecosystem in the Tibetan Plateau, is distributed across regions over the elevation of 4500 m. Few studies for carbon flux in alpine grassland on the Tibetan Plateau were conducted due to rigorous natural conditions. A study of soil respiration under alpine grassland ecosystem on the Tibetan Plateau from October 1999 to October 2001 was conducted at Pangkog County, Tibetan Plateau (31.23°N, 90.01°E, elevation 4800 m). The measurements were taken using a static closed chamber technique, usually every two weeks during the summer and at other times at monthly intervals. The obvious diurnal variation of CO2 emissions from soil with higher emission during daytime and lower emission during nighttime was discovered. Diurnal CO2 flux fluctuated from minimum at 05:00 to maximum at 14:00 in local time. Seasonal CO2 fluxes increased in summer and decreased in winter, representing a great variation of seasonal soil respiration. The mean soil CO2 fluxes in the alpine grassland ecosystem were 21.39 mgCO2 · m-2 · h-1, with an average annual amount of soil respiration of 187.46 gCO2 · m-2 · a-1. Net ecosystem productivity is also estimated, which indicated that the alpine grassland ecosystem is a carbon sink.     

Quantitative aspects of inorganic nutrient fluxes in the Gazi Bay (Kenya): implications for coastal ecosystems

Fluxes of dissolved inorganic nutrients: NH4+, NO2-, NO3-, PO4(3-) and Si(OH)4 from nearshore sediments of Gazi Bay were measured in situ within mangrove, seagrass and coral reef biotopes using benthic flux bell-jar chambers of cross-sectional area 0.066 m2 and volume 0.0132 m3. The objectives were: (1) to determine the influence of benthic fluxes, fluvial discharge and seasonal variations on the nutrient budget in the Bay waters; (2) to determine the effect of tidal and spatial variations on nutrient loads in the water column and (3) to establish the relative importance of the nutrient sources with regard to total community production of the Bay. The directly measured fluxes ranged from -270 to +148 micromol NH4+-N/m2/h; -60 to +63 micromol NO2(-)-N/m2/h; -79 to +41 micromol NO3(-)-N/m2/h; -79 to +75 micromol PO4(3-)-P/m2/h and +30 to +350 micromol Si(OH)4-Si/m2/h for and respectively. It was established that benthic fluxes are the major sources of dissolved inorganic NH4+, NO2- and Si(OH)4 while fluvial sources are important for NO3- and PO4(3-) into Gazi Bay waters. Seasonal variations had an appreciable effect on the PO4(3-) fluxes, N:Si ratio, river nutrient discharge, plankton productivity and important environmental factors such as salinity and temperature. Tidal and spatial variations had no significant effect on nutrient concentrations and net fluxes within the water column. The results imply that benthic fluxes are largely responsible for the nutrient dynamics of the nearshore coastal ecosystems especially where direct terrestrial inputs do not contribute significantly to the nutrient budget.     

鄱阳湖洪泛区碟形湖湿地系统地表—地下水交互作用

洪泛系统具有复杂动态的水文环境,在季节性洪水脉冲影响下,地表—地下水交互转化对洪泛区水循环和生态环境保护等方面具有重要意义.本文采用野外试验、统计分析和达西定律等研究方法,开展了鄱阳湖洪泛区碟形湖湿地系统(河流—洲滩湿地—碟形湖)地表—地下水文学特征、相互作用和交换通量研究.数据资料显示,在地形地貌影响下,研究区洲滩地...     

Mercury levels in feathers of Magellanic penguins

Feathers are useful to determine mercury (Hg) contamination. We evaluated the mercury concentration in feathers of Magellanic penguins (Spheniscus magellanicus) age 1.5 years to 25 years at Punta Tombo, Argentina before and during their molt. Mercury ranged between <1.4 and 367 ng/g dry weight, with three extreme high values (8996 ng/g, 3011 ng/g and 1340 ng/g) all in young adults. The median concentration was lowest for juveniles and significantly higher for adults but with high variation among older adults. Males and females had similar mercury loads. Compared with other penguin species, concentrations in Magellanic penguins were low. Mercury levels for Magellanic penguins in the Southwest Atlantic for older adults averaged 206±98 ng/g, and serve as a baseline for biomonitoring and/or ecotoxicological studies.     

广州麓湖大气多环芳烃的干湿沉降

以广州麓湖为小型城市湖泊的代表,对大气中多环芳烃的颗粒态沉降进行了连续一年的采样与分析. 结果表明,年均颗粒态多环芳烃的沉降通量为0.47mg/( m2·a). 全年直接由大气输入到麓湖的颗粒态多环芳烃总量约为0.1kg. 不同季节相比,夏季多环芳烃的沉降通量略高于秋季,而冬春季最高. 对比大气总悬浮颗粒物中多环芳烃的组成发现,当降雨量增大时,沉降颗粒物中多环芳烃的组成逐渐趋近于大气总悬浮物中多环芳烃的组成. 广州地区雨热同期、干冷咸至的季风气候特点,以及由此导致的大气颗粒物粒径变化和PAHs的气-粒分配变化,与大气PAHs污染程度一起,共同控制着沉降颗粒物中PAHs相对组成的季节变化.     

The volcanic acidification of glacial Lake Caviahue,Province of Neuquen,Argentina

Lake Caviahue (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano. The lake and the feeding rivers were sampled annually from 1997 till early 2006, including the eruptive period of 2000. Lake Caviahue waters evolved over time, with the most concentrated waters in 2000 during the eruptive period, followed by gradual dilution that was interrupted by renewed acidification in 2003–2004. Inversion of the lake water data and application of a dynamic non-steady state model for the lake provides our best quantitative estimates for the variation in element fluxes over the 9-year period. The model flux results agree well with most of the measured fluxes. The Copahue hydrothermal system had gently declining element fluxes between 1997 and mid-1999, although the lake was still becoming more concentrated. About 2–3 months before the 2000 eruption, element fluxes increased strongly, but the hydrothermal fluxes almost shutoff directly after the main eruptive events. The fluxes of several elements recovered post-2001, with an increase in element fluxes in 2003–2004; the lake became more dilute between 2004 and 2006. The intrusion of new magma into the hydrothermal system just prior to the 2000 eruption led to enhanced water rock interaction, with higher concentrations of the rock forming elements in the fluids, and the hot spring flow rate increased as a result of the higher pressure in the reservoir. The fluids became saturated in alunite and jarosite, and they were already saturated with anhydrite. Precipitation of these minerals possibly led to a decreased permeability of the hydrothermal reservoir, leading to the strongly reduced element fluxes just after the eruption. In addition, K, Al and S were retained in the newly precipitated minerals as well, further diminishing their export. The acidification in 2003–2004 may have resulted from a new small intrusion of magma or resulted from seismic activity that created new permeability and fresh rock surfaces for water rock interaction. The volcano is a significant source of toxic trace elements such as F, As, B and Li as well as a nutrient (P) for the local watershed. Monitoring of the hydrothermal fluids in the river that drains Copahue, especially the S/Cl, Mg/Cl and Mg/K values as well as the magnitude of the element fluxes would provide the best information for eruption forecasting for this volcano.     

Water transport through Lake Kinneret sediments traced by tritium

The transport of water through the sediments of Lake Kinneret was estimated using tritium of fallout origin as a tracer. The calculation model takes into account the diffusion of the tracer and its decay, and allows for the advective flux through the sediment pores as a free parameter. The dependence of the interstitial diffusion constant on the porosity was assumed identical to that for chloride ions. Tritium profiles in nine cores were used for estimating the advective fluxes and velocities, by finding the best fit between data and model. Water advective fluxes of 3.4 g cm^?2 yr^?1 into the lake were found. This water flux is negligible in the hydrological balance of Lake Kinneret; but it carries along 7% of the unaccounted-for chloride input to the lake.