Argon‐40‐argon‐39 chronology and petrogenesis along the eastern limb of the Moon from Luna 16, 20 and 24 samples

Abstract— Eighteen new lithic fragments from the Soviet Luna missions have been analyzed with electron microprobe and ⁴⁰Ar‐³⁹Ar methods. Luna 16 basalt fragments have aluminous compositions consistent with previous analyses, but have two distinct sets of well‐constrained ages (3347 ± 24 Ma, 3421 ± 30 Ma). These data, combined with other Luna 16 basalt ages, imply that there were multiple volcanic events filling Mare Fecunditatis. The returned basalt fragments have relatively old cosmicray exposure (CRE) ages and may have been recovered from the ejecta blanket of a young (1 Ga), nearby crater. A suite of highlands rocks (troctolites and gabbros) is represented in the new Luna 20 fragments. One fragment is the most compositionally primitive (Mg# = 91–92) spinel troctolite yet found. Both troctolites have apparent crystallization ages of 4.19 Ga; other rocks in the suite have progressively younger ages and lower Mg#s. The age and composition progression suggests that these rocks may have crystallized from a single source magma, or from similar sources mobilized at the same time. Within the new Luna 24 basalt fragments is a quench‐textured olivine vitrophyre with the most primitive composition yet analyzed for a Luna 24 basalt, and several much more evolved olivine‐bearing basalts. Both new and previously studied Luna 24 very low‐Ti (VLT) basalt fragments have a unimodal age distribution (3273 ± 83 Ma), indicating that most returned samples come from a single extrusive episode within Mare Crisium much later than the Apollo 17 VLT basalts (3.6–3.7 Ga).     

Searching for high alumina mare basalts using Clementine UVVIS and Lunar Prospector GRS data: Mare Fecunditatis and Mare Imbrium

In the context of sample evidence alone, the high-alumina (HA) basalts appear to be an unique, and rare variety of mare basalt. In addition to their distinct chemistry, radiometric dating reveals these basalts to be among the oldest sampled mare basalts. Yet, HA basalts were sampled by four missions spanning a lateral range of ∼2400 km, with ages demonstrating that aluminous volcanism lasted at least 1 billion years. This evidence suggests that HA basalts may be a widespread phenomenon on the Moon. Knowing the distribution of HA mare basalts on the lunar surface has significance for models of the origin and the evolution of the Lunar Magma Ocean. Surface exposures of HA basalts can be detected with compositional remote sensing data from Lunar Prospector Gamma Ray Spectrometer and Clementine. We searched the lunar surface for regions of interest (ROIs) that correspond to the intersection of three compositional constraints taken from values of sampled HA basalts: 12-18 wt% FeO, 1.5-5 wt% TiO₂, and 0-4 ppm Th. We then determined the “true” (unobscured by regolith) composition of basalt units by analyzing the rims and proximal ejecta of small impacts (0.4-4 km in diameter) into the mare surface of these ROIs. This paper focuses on two ROIs that are the best candidates for sources of sampled HA basalts: Mare Fecunditatis, the landing site of Luna 16; and northern Mare Imbrium, hypothesized origin of the Apollo 14 HA basalts. We demonstrate our technique's ability for delineating discrete basalt units and determining which is the best compositional match to the HA basalts sampled by each mission. We identified two units in Mare Fecunditatis that spectrally resemble HA basalts, although only one unit (Iltm) is consistent with the compositional and relative age of the Luna 16 HA samples. Northern Mare Imbrium also reveals two units that are within the compositional constraints of HA basalts, with one (Iltm) best matching the composition of the basalts sampled by Apollo 14.     

Temporal changes in the flux of meteorites in the recent past

The depth variations of the fossil cosmic ray tracks and agglutinates have been examined in the (0.6–0.7)m deep Apollo 12 and 16 drive cores, in the 2.4 m Apollo 15 deep drill core and in a 0.6 m long section of the Apollo 17 deep drill core. These data indicate Moon-wide short duration episodes of impacts of meteorites of size 10 cm^–1m on the lunar surface. Based on the longest continuous Apollo 15 deep drill core record, these impact episodes occurred about 150, 400 and 700 m.y. ago. The enhancements in the meteorite flux may be due to solar dynamical processes or they may be related to excursions of the solar system, once in each orbit, through a certain dusty region of the galaxy.Paper dedicated to Professor Hannes Alfvén on the occasion of his 70th birthday, 30 May 1978.     

Bearing strength of lunar soil

Bearing load vs penetration curves have been measured on a 1.3 g sample of lunar soil from the scoop of the Surveyor 3 soil mechanics surface sampler, using a circular indentor 2 mm in diameter. Measurements were made in an Earth laboratory, in air. This sample provided a unique opportunity to evaluate earlier, remotely controlled, in-situ measurements of lunar surface bearing properties. Bearing capacity, measured at a penetration equal to the indentor diameter, varied from 0.02–0.04 N cm^–2 at bulk densities of 1.15 g cm^–3 to 30-100 N cm^–2 at 1.9 g cm^–3. Deformation was by compression directly below the indentor at bulk densities below 1.61 g cm^–3, by outward displacement at bulk densities over 1.62 g cm^–3. Preliminary comparison of in-situ remote measurements with those on returned material indicates good agreement if the lunar regolith at Surveyor 3 has a bulk density of 1.6 g cm^–3 at 2.5 cm. depth; definitive comparison awaits both better data on bulk density of the undisturbed lunar soil and additional mechanical-property measurements on returned material.     

Apollo drill core depth relationships

Preliminary depth relationships are presented for the Apollo 15, 16 and 17 drill core samples. For a given depth in any of these drill stems, thein situ lunar surface depth can be estimated. Ranges of uncertainty are also established, based on percent core recovery and degree of sample disturbance. The most likely explanation for the sample disturbance observed in the top three sections of the Apollo 16 drill stem is sample migration after the stem was capped on the lunar surface; essentially no sample was lost. Similar disturbance occurred in the Apollo 17 drill core, although to a lesser degree. The average original bulk densities (i.e., before any disturbance occurred) of the Apollo 15, 16 and 17 drill cores are 1.76, 1.59, and 1.87 g cm^?3, respectively. The Apollo 15 and 17 values are probably close to thein situ values; but the Apollo 16 averagein situ density could be as much as 13% less than the already low density in the drill core.     

Constraints on the flux of meteoritic and cometary water on the Moon from volatile element (N–Ar) analyses of single lunar soil grains,Luna 24 core

We report new nitrogen and argon isotope and abundance results for single breccia clasts and agglutinates from four different sections of the Luna 24 drill core in order to re-evaluate the provenance of N trapped in lunar regolith, and to place limits on the flux of planetary material to the Moon’s surface. Single Luna 24 grains with ⁴⁰Ar/³⁶Ar ratios <1 show δ¹⁵N values between ?54.5‰ and +123.3‰ relative to terrestrial atmosphere. Thus, low-antiquity lunar soils record both positive and negative δ¹⁵N signatures, and the secular increase of the δ¹⁵N value previously postulated by Kerridge (Kerridge, J.F. [1975]. Science 188(4184), 162–164. doi:10.1126/science.188.4184.162) is no longer apparent when the Luna and Apollo data are combined. Instead, the N isotope signatures, corrected for cosmogenic ¹⁵N, are consistent with binary mixing between isotopically light solar wind (SW) N and a planetary N component with a δ¹⁵N value of +100‰ to +160‰. The lower δ¹⁵N values of Luna 24 grains compared to Apollo samples reflect a higher relative proportion of solar N, resulting from the higher SW fluence in the region of Mare Crisium compared to the central near side of the Moon. Carbonaceous chondrite-like micro-impactors match well the required isotope characteristics of the non-solar N component trapped in low-antiquity lunar regolith. In contrast, a possible cometary contribution to the non-solar N flux is constrained to be ?3–13%. Based on the mixing ratio of SW to planetary N obtained for recently exposed lunar soils, we estimate the flux of micro-impactors to be (2.2–5.7) × 10³ tons yr^?1 at the surface of the Moon. Our estimate for Luna 24 agrees well with that for young Apollo regolith, indicating that the supply of planetary material does not depend on lunar location. Thus, the continuous influx of water-bearing cosmic dust may have represented an important source of water for the lunar surface over the past ～1 Ga, provided that water removal rates (i.e., by meteorite impacts, photodissociation, and sputtering) do not exceed accumulation rates.     

Shear strength of lunar soil from oceanus procellarum

Soil from the scoop of Surveyor 3, returned to Earth by Apollo 12 astronauts, has been tested in a miniature shear box at five bulk densities, from 0.99 to 1.87 g cm^–3. Cohesion increased with bulk density from 3 × 10^–2 to 3 × 10^–1 N cm^–2; internal friction angle increased from 13° to 56°. Shear stress vs normal stress data fit a logarithmic relationship better than a linear one, at normal stresses of 3 × 10^–3 to 3 x 10⁰ N cm^–2. Results of these tests, in air, show no systematic differences from those for tests made elsewhere in vacuum and nitrogen. Results agree with those obtained in remotely controlled lunar surface operations with Surveyor 3 and other spacecraft provided that the bulk density was slightly underestimated for the on-surface measurements.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.This work represents one phase of research conducted at the Jet Propulsion Laboratory, California Institute of Technology, for the National Aeronautics and Space Administration, under Contract NAS 7-100.     

PETROLOGICAL CHARACTER OF THE LUNA 16 SAMPLE FROM MARE FECUNDITATIS

We have classified 1858 lithic and vitreous fragments from the Luna 16 core-tube sample. They were taken from the soil fractions ranging in size from 150 to 425 μ, at levels A and G (γ). No important differences are observed between the proportions of particle types in levels A and G, nor between the soils of Luna 16 and those from the Apollo 11 landing site in the nearby Mare Tranquillitatis. Luna 16 basalts are texturally and mineralogically similar to Apollo 11 basalts, though the former are characterized by more Fe-rich olivines and pyroxenes and by lower ilmenite contents than are Apollo 11 basalts. The atomic ratio Al/Ti in Luna 16 basalt pyroxenes in about 1.5; Apollo 11 basalt pyroxenes have Al/Ti = 2.0, indicating the possibility of a lower mean valence for Ti in the Luna 16 material than in the Apollo 11 material. Most light-colored lithic fragments are anorthositic rather than noritic in character and are comparable to Apollo 11 anorthosites in mineral chemistry. We believe they are samples of terra regions to the north of the Luna 16 landing site. Triangular diagrams plotting normative plagioclase, normative mafics plus oxides, and normative orthoclase plus apatite neatly separate the three major types of lunar materials — mare basalts, anorthosites, and noritic rocks — and reveal that the Luna 16 regolith is composed of mare basalt and anorthosite, with very little norite component. Colorless-to-greenish glass occurs in the Luna 16 sample, which has high Fe and low Ti; it may represent gabbroic rock related to the anorthosites     

Observations of water vapor ions at the lunar surface

The Apollo 14 Suprathermal Ion Detector Experiment observed a series of bursts of 48.6 eV water vapor ions at the lunar surface during a 14-h period on March 7, 1971. The maximum flux observed was 10⁸ ions cm^–2 s^–1 sr^–1. These ions were also observed at Apollo 12, 183 km to the west. Evaluation of specific artificial sources including the Apollo missions and the Russian Lunokhod leads to the conclusion that the water vapor did not come from a man-made source. Natural sources exogenous to the Moon such as comets and the solar wind are also found to be inadequate to explain the observed fluxes. Consequently, these water vapor ions appear to be of lunar origin.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Solar-wind interactions with the moon: Role of oxygen ions

The solar-wind interacts directly with the lunar surface due to tenuous atmosphere and magnetic field. The interaction results in an almost complete absorption of the solar-wind corpuscles producing no upstream bowshock but a cavity downstream. The solar-wind oxygen ionic species induce and undergo a complex set of reactions with the elements of the lunar minerals and the solar-wind derived trapped gases. The oxygen concentration indegeneous to the lunar surface material is about 60 at.%. Some of these oxygen are displaced from their crystal lattice locations by interactions of the solar-wind corpuscles. A small fraction of these displaced oxygen is in active state. The solar-wind oxygen species flux is about 6×10⁴ cm^–2 s^–1. Besides inducing and undergoing various reactions these species become trapped as oxygen atoms in the lunar grains. Only a portion of these trapped oxygen atoms is in active state. For the contribution of oxygen atoms and molecules from the lunar surface grains to the atmosphere and their reactions with other species, the diffusion coefficients of oxygen atom and molecule should be known. However their values in the highly radiation-damaged lunar surface material are not known. The coefficients are calculated by using the apparent lifetimes of atomic and molecular oxygen in the lunar material. The atmospheric concentration of oxygen atoms and molecules near the lunar surface are found to be about 20 and 3 cm^–3, respectively. These values appear to be very reasonable in comparison with the experimental data. The Apollo 17 lunar orbital UV spectrometer data indicate the atomic oxygen concentration is <8×10¹ cm^–3. The Apollo 17 lunar surface mass spectrometer (sensitivity: 1 count=2×10² molecules cm^–3) did not detect any oxygen molecules on the dayside of the Moon, but the sunrise concentration was reported to be 1±×10³ cm^–3. At the time of the sample collection on the Moon the oxygen content in the trapped gas layer was partly as oxygen atoms and partly as oxygen molecules. At the time of sample analysis on the Earth the concentrations of these two species did not change appreciably.     

The velocity structure of the lunar crust

Seismic refraction data, obtained at the Apollo 14 and 16 sites, when combined with other lunar seismic data, allow a compressional wave velocity profile of the lunar near-surface and crust to be derived. The regolith, although variable in thickness over the lunar surface, possesses surprisingly similar seismic properties. Underlying the regolith at both the Apollo 14 Fra Mauro site and the Apollo 16 Descartes site is low-velocity brecciated material or impact derived debris. Key features of the lunar seismic velocity profile are: (i) velocity increases from 100–300 m s^–1 in the upper 100 m to 4 km s^–1 at 5 km depth, (ii) a more gradual increase from 4 km s^–1 to 6 km s^–1 at 25 km depth, (iii) a discontinuity at a depth of 25 km and (iv) a constant value of 7 km s^–1 at depths from 25 km to about 60 km. The exact details of the velocity variation in the upper 5 to 10 km of the Moon cannot yet be resolved but self-compression of rock powders cannot duplicate the observed magnitude of the velocity change and the steep velocity-depth gradient. Other textural or compositional changes must be important in the upper 5 km of the Moon. The only serious candidates for the lower lunar crust are anorthositic or gabbroic rocks.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

The evolution of the lunar Nectaris multiring basin

Nectaris is an 820-km-diameter, multiring impact basin located on the near side of the Moon. The transient cavity is estimated to have been less than 90 km in depth and materials were excavated from a depth of less than 30 km. About 2 km thickness of impact melt is believed to line the cavity center. The impact event probably took place at about 3.98 ± 0.03 × 10⁹ years ago. Nectaris ejecta forms a substantial proportion of the surface materials at the Apollo 16 site. Inter-ring plains deposits were deposited after the formation of the Nectaris basin. The most persuasive origin for the smooth plains is one of extrusives overlain by a thin veneer of ejecta. Basaltic fragments within Apollo 16 samples are believed to have been largely derived from Nectaris. A titanium-rich Apollo 16 mare basalt fragment has an age of 3.79 ± 0.05 × 10⁹ years but, although some relatively titanium-enriched basalts occur in southern Nectaris, titanium-rich basalts are nowhere seen at the surface of the mare. The earliest recognized eruptives appear to be low-titanium (perhaps VLT) basalts found as pyroclastic materials on Daguerre and in the Gaudibert region. The majority of the surface basalts are of intermediate composition (possibly similar to Apollo 12 basalts) and have an age of approximately 3.6 × 10⁹ years. The basalt fill is estimated to have a minimum thickness of 3 km. Flood-style eruptions appear to have been the main form of extrusion. Mare ridges exhibit a strong north-south preferential alignment and appear to postdate basalt emplacement. The lack of basin-related graben in Nectaris is consistent with a thick lithosphere. The basin ring structure is best preserved in the southwest and least preserved in the northeast. This is believed to result from horizontal variations in the crust and lithosphere thicknesses and from the influence of the preexisting Fecunditatis and Tranquillitatis basins; the ring structure is best preserved where the lithosphere was thickest. Floor-fractured craters within Nectaris are intimately associated with the basalt fill both in terms of age and location. Theophilus ejecta, small craters, and Tycho rays, combined with subsidence and mare ridge development, were the only modifying influences on Nectaris since the termination of basalt eruptions.     

Refinement of lunar TiO2 analysis with multispectral features of Chang’E-1 IIM data

We develop a method based on the samples from Apollo and Luna landing sites to determine lunar TiO₂ content with Chang’E-1 interference imaging spectrometer (IIM) imagery. By analyzing the nonlinear relationship between the optical and compositional parameters of lunar soil samples, the method employs two Support Vector Machines (SVMs) to estimate the titanium abundance of the lunar surface. Developed with the soil compositions of the Apollo and Luna sample-return stations, the RMS (root mean square) error of our method is 0.24 wt% TiO₂, and the correlation coefficient of the TiO₂ values and our predicted ones is 99.72 %. Compared with the other 3 models, the method proposed in this paper exhibits a good performance for determining the chemical composition of the lunar surface. TiO₂ maps of Sinus Iridum, part of the Marius Hills plateau, and part of Mare Smythii are produced using our method, which could be useful for future lunar missions.     

Comparison of the analytical results from the surveyor,Apollo, and Luna missions

The principal chemical element composition and inferred mineralogy of the powdered lunar surface material at seven mare and one terra sites on the Moon are compared. The mare compositions are all similar to one another and comparable to those of terrestrial ocean ridge basalts except in having higher titanium and much lower sodium contents than the latter. These analyses suggest that most, if not all, lunar maria have this chemical composition and are derived from rocks with an average density of 3.19 g cm^–3. Mare Tranquillitatis differs from the other maria in having twice the titanium content of the others.The chemical composition of the single highland site studied (Surveyor 7) is distinctly different from that of any of the maria in having much lower amounts of titanium and iron and larger amounts of aluminium and calcium. Confirmation of these general characteristics of lunar highland material has come from recent observations by the Apollo 15 Orbiter. The inferred mineralogy is 45 mole percent high anorthite plagioclase and the parent rocks have an estimated density of 2.94 g cm^–3. The Surveyor 7 chemical composition is the principal contributor to present estimates of the overall chemical composition of the lunar surface.Presented at the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 14–25, 1971. This paper is an expanded and updated version of a paper presented at the Apollo 12 Lunar Science Conference, Houston, Texas, January 11–14, 1971, and published in the Proceedings of this Conference (Turkevich, 1971).     

Petrography and geochemistry of five new Apollo 16 mare basalts and evidence for post‐basin deposition of basaltic material at the site

Abstract— We present the petrography and geochemistry of five 2–4 mm basalt fragments from the Apollo 16 regolith. These fragments are 1) a high‐Ti vitrophyric basalt compositionally similar to Apollo 17 high‐Ti mare basalts, 2) a very high‐Ti vitrophyric basalt compositionally similar to Apollos 12 and 14 red‐black pyroclastic glass, 3) a coarsely crystalline high‐Al basalt compositionally similar to group 5 Apollo 14 high‐Al mare basalts, 4) a very low‐Ti (VLT) crystalline basalt compositionally similar to Luna 24 VLT basalts, and 5) a VLT basaltic glass fragment compositionally similar to Apollo 17 VLT basalts. High‐Ti basalt has been reported previously at the Apollo 16 site; the other basalt types have not been reported previously. As there are no known cryptomaria or pyroclastic deposits in the highlands near the Apollo 16 site (ruling out a local origin), and scant evidence for basaltic material in the Apollo 16 ancient regolith breccias or Apollo 16 soils collected near North Ray Crater (ruling out a basin ejecta origin), we infer that the basaltic material in the Apollo 16 regolith originated in maria near the Apollo 16 site and was transported laterally to the site by small‐ to medium‐sized post‐basin impacts. On the basis of TiO₂ concentrations derived from the Clementine UVVIS data, Mare Tranquillitatis (?300 km north) is the most likely source for the high‐Ti basaltic material at the Apollo 16 site (craters Ross, Arago, Dionysius, Maskelyne, Moltke, Sosigenes, Schmidt), Mare Nectaris/Sinus Asperitatis (?220 km east) is the most likely source for the low‐Ti and VLT basaltic material (craters Theophilus, Madler, Torricelli), and a large regional pyroclastic deposit near Mare Vaporum (?600 km northwest) is the most likely source region for pyroclastic material (although no source craters are apparent in the region).     

A lunar crustal gravity model across the Triesnecker-Hyginus area,Mare Tranquillitatis,and Mare Fecunditatis

LOS Bouguer gravity anomalies have been calculated from a low altitude LOS free air Doppler gravity profile across northern Mare Fecunditatis, southern Mare Tranquillitatis and the Aridaeus Rille. The Hyginus-Triesnecker area has been included in model calculations, though here only free air anomalies are present. A crustal density model has been fitted to the Bouguer anomalies and to the free air anomalies in the case of the Hyginus-Triesnecker area.On a regional scale northern Fecunditatis has Bouguer anomalies up to 80 mgal and lithostatic stresses of 29 bar and thus is nearly in isostatic equilibrium. Tranquillitatis can be divided into three regions of different crustal structure: (1) northern Tranquillitatis with only minor free air gravity anomalies is more or less in isostatic balance, (2) the southeastern region with Bouguer anomalies to –100 mgal and lithostatic stresses of –73 bar has a considerable mass deficit, (3) the southwestern basin is dominated by the local structure Lamont with a Bouguer maximum of 200 mgal and extremely high lithostatic stresses of 285 bar.The Bouguer minimum of –180 mgal of the Aridaeus area has been modelled by two alternative models: (i) a crustal thickening of 33 km and associated lithostatic stresses of –164 bar, and (ii) a crustal thickening of 20 km plus a low density intrusion. The free air maximum of the Hyginus-Triesnecker area has been fitted by a mantle plug connected with stresses of 116 bar.As the old irregular maria could not sustain large mascon stresses, it has been concluded that the local high stresses of Lamont, Aridaeus, and Hyginus-Triesnecker have been evolved after the impacts of the circular maria. Intrusional activities in these areas could have proceeded to fault zones generated by the large impacts.Contribution No. 211, Institut für Geophysik der Universität Kiel, F.R.G.     

On the thermal history of a moon of fission origin

Model calculations show that the thermal history of a Moon which originated by fission from the proto-Earth is the same as that for the Moon as it is currently understood. In particular, a fissioned Moon currently has a small percent of partial melt or at least near solidus temperatures below depths of 800 km in accord with the seismic data which show that the deep interior of the Moon has a very lowQ. The models have moderate (20–50%) degrees of partial melting in the upper mantle (depths < 300 or 200 km) in the period between 3 to 4 × 10⁹ years ago and, therefore, can account for the mare filling epoch. Finally the heat flow of the models is 18 ergs cm^–2 s^–1 which is close to the average of 19 ergs cm^–2 s^–1 derived from the Apollo heat flow experiments. These findings add further support for the fission origin of the Moon.     

Stratigraphy,evolution, and volume of basalts in Mare Serenitatis

Abstract– Fourteen major basaltic units in Mare Serenitatis have been identified and mapped from differences in TiO₂ wt%. The ages of these units have been inferred from their crater densities and reference to isotopically dated Apollo samples. It has been found that FeO and TiO₂ wt% of the units do not show any apparent trend with time. However, the oldest units have much greater variation in FeO and TiO₂ wt% than younger ones. No lateral trend in the age of the basaltic units is apparent within the basin. A vertical profile of Mare Serenitatis has been produced based on the depth of basalt within impact craters. The minimum depth of basalt has been estimated where craters have not exposed underlying highland material. The profile has been used to estimate the minimum volume of basalt within the basin to be ≈500,000 km³.     

The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317

Miller Range (MIL) 13317 is a heterogeneous basalt‐bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near‐surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al₂O₃ 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare‐highland boundary that is KREEP‐rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low‐Ti to low‐Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon‐bearing phases and Ca‐phosphate grains in basalt clasts and matrix grains yield ²⁰⁷Pb/²⁰⁶Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient ²⁰⁷Pb/²⁰⁶Pb ages indicate that the meteorite has sampled a range of Pre‐Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.     

The charge state in a highly dense molecular cloud

We have calculated the desorption rates of both physisorbed and chemisorbed ions from grain surfaces, due to the temperature increase at densities higher than 10^–13 g cm^–3. It has been found that physisorbed ions desorb from grain surfaces at neutral densities ofn>1.3×10¹¹ cm^–3, assuming that the desorption energyD is equal to 0.1 eV, while the desorption of chemisorbed ions from grain surface can only occur at neutral densities ofn>10¹⁵ cm^–3, at which point thermal ionization becomes more dominant.The electrons are assumed to be emitted from grain surfaces in a manner similar to the thermonic emission from heated solid surfaces. It was found that the temperature at which electrons are emitted from negatively charged grains depends on the value of the work function of the material of the grain.The charge state has been calculated for two limiting cases. Neglecting the grain surface reactions in case 1, the resulting relative charge density represents an upper limit, such that the electrical conductivity remains high. In this situation the magnetic flux dissipation is mainly contributed by ambipolar diffusion. In the second case, it has been assumed that the charged particles are chemically adsorbed on grain surfaces such that their desorption is negligible. In this case the charge density decreases sharply with increase of neutral density. Therefore, the electrical conductivity decreases sufficiently and Ohmic dissipation becomes effective.