洋中脊富钛铁氧化物辉长岩成因的一个新思路:以西南印度洋脊ODP 735B岩心为例

西南印度洋脊的ODP 735B岩心中拥有大量富含钛铁氧化物的含氧化物辉长岩,此现象在岩性单元Ⅳ中表现尤为显著.同时,岩性单元1中主要硅酸盐矿物亦具有独特的成分变化趋势.以前研究将造成岩性单元I中氧化物辉长岩成因和主要造岩矿物成分变化趋势归因于具浮力的、高度分异的富钛铁熔体的作用,这些熔体应形成于735B钻孔之下或其附近...     

老挝沙耶晚三叠世火山岩地球化学特征及地质意义

老挝沙耶武里地区广泛出露晚三叠世火山岩。通过对其火山岩主微量元素的地球化学特征研究,火山岩全岩Si O2含量为41.54%~64.44%,K2O+Na2O含量为3.59%~9.30%,在化学成分上属于钙碱性岩石。稀土元素地球化学特征表现为轻稀土元素分馏程度明显高于重稀土元素,具有壳幔混合的特点。通过其轻稀土元素富集,亏损重稀土元素和高场强元素Nb、Ta,具有岛弧型火山岩的特征。     

超高压变质过程中的元素地球化学行为——CCSD主孔榴辉岩的矿物化学研究

中国大陆科学钻探主孔位于江苏东海县,苏鲁超高压变质带的南部.该钻孔的0～2050m深度获取了六种不同类型的榴辉岩和少量石榴石辉石岩岩心,它们是典型的基性超高压变质岩,为研究大陆深俯冲过程中的元素地球化学行为提供了非常好的样品.本文对各种超高压变质矿物的微量元素成分进行了系统的原位微区分析,结合全岩化学成分和矿物主量元素成分,深入地研究了超高压变质岩的微量元素赋存特征、分配规律、控制因素,及其对变质条件和流体.岩石相互作用的限定意义.结果表明,超高压榴辉岩中的LREE和Sr主要赋存在磷灰石、帘石和单斜辉石中,HREE赋存在石榴石中,Ba、Rb和Cs等LILE赋存在多硅白云母中,Ti、Nb和Ta等HFSE主要赋存在金红石、钛铁矿中,V、Sc、Co和Ni等元素大多赋存在石榴石和单斜辉石中.研究表明,全岩化学成分和矿物组成、及其含量的变化明显控制着超高压矿物的微量元素含量和分布形式.本研究也获得了如下重要的认识:超高压变质矿物之间的微量元素分配达到了化学平衡,并具有与地幔榴辉岩矿物之间类似的分配系数,表明榴辉岩的峰期变质温度很可能达到900℃～1000℃.部分高Ti和高Fe-Ti榴辉岩中的石榴石和绿辉石有明显的稀土元素成分环带,表明超高压变质岩经历了快速折返过程.金红石的Zr含量明显受到全岩成分和退变质作用影响,并不仅仅与形成温度有关,不是可靠的温度计.在超临界流体的作用下,榴辉岩中金红石的Nb、Ta发生了明显的分异,导致其Nb/Ta比值增大,由此推测俯冲到地幔深处的大量榴辉岩是地球内部高Nb/Ta比值的物质源区.在榴辉岩的不同程度退变质阶段,参与变质反应的流体具有不同的来源、成分和流体活动规模.     

贵州马依勘探区凝灰岩和Tonsteins元素地球化学特征研究

运用X射线荧光光谱(XRF)、X射线衍射(XRD)、电感耦合等离子体质谱(ICP-MS)等方法,对贵州马依勘探区晚二叠世煤系地层基性凝灰岩和tonsteins的矿物学和地球化学特征进行了研究。结果表明,Tonsteins和凝灰岩中黏土矿物以高岭石为主,锐钛矿和黄铁矿在所有样品中普遍存在。Nb、Ta、Zr、Hf、REE等微量元素富集,LREE和REE分馏程度高。原始地幔标准化的不相容元素蜘蛛网图与洋岛玄武岩(OIB)相似,推测形成基性凝灰岩和tonsteins的火山灰是地幔柱衰退期的产物,Nb/Ta比值表明存在大陆地壳或岩石圈的混染作用。Sr表现出现明显的负异常,这主要是由于斜长石分离结晶造成的,Eu负异常不明显,反映了岩浆中Eu3+/Eu2+有着较高的比值。     

中条山铜矿峪铜矿含矿岩系地球化学特征及矿床成因

中条山铜矿峪斑岩型铜矿床位于秦岭造山带北端,矿体主要赋存于变质花岗闪长斑岩、黑云母片岩和变质基性火山岩中。矿区内含铜岩系的全岩地球化学分析显示,主量元素表明矿区的含铜岩系均表现出富钾、富铝的特征;微量元素表明所有样品均显示出相对富集大离子亲石元素(K、Rb、Ba等),亏损高场强元素(P、Y、Ti、Nb、Ta等),反映岩浆源区可能遭受过俯冲带流体的交代作用,具有岛弧玄武岩的地球化学特征;稀土元素特征显示出明显的轻重稀土分馏,轻稀土富集,所有样品都表现出弱的铕负异常。研究认为,变质花岗斑岩、黑云母片岩和绢英岩的原岩初步定为钙碱性玄武岩或拉斑玄武岩,铜矿峪铜矿床形成于挤压与拉张构造环境的转换阶段,其成因类型应属于斑岩型铜矿床。     

超高压榴辉岩金红石中高场强元素变化的控制因素及其地球动力学意义

利用LA-ICP-MS对CCSD-MH超高压榴辉岩中金红石进行了详细的原位微区微量元素组成分析.金红石中高场强元素Nb和Ta含量主要受全岩Nb、Ta和TiO₂含量控制, Zr、Hf含量比较稳定基本不受全岩含量影响.粒间金红石中, 同一颗粒金红石核部Zr含量系统高于边部, 而边部则出现了明显的Pb和Sr富集特征.CCSD-MH榴辉岩中金红石与全岩的Nb/Ta比值呈现明显的不一致性.全岩Nb/Ta比值明显低于金红石且与全岩TiO₂含量负相关, 而金红石的Nb/Ta比值与全岩Nb、Ta含量和Nb/Ta比值没有明显的相关关系.金红石和全岩之间非完全耦合的Nb/Ta组成表明, 金红石并非形成于原岩的结晶过程中而是在超高压变质作用过程中形成, 尽管金红石是榴辉岩中Nb、Ta含量的主要载体矿物, 但金红石的Nb/Ta比值并不一定能完全代表全岩的特征, 而与全岩Nb、Ta和TiO₂的含量有关.粒间金红石核部Zr含量所记录的温度与粒径之间具有明显的正相关性, 反映金红石中的Zr在其形成后没有封闭.粒间金红石所表现出的明显的边部富集Pb和Sr的特征, 反映了后期流体活动对金红石组成的影响.这些研究结果为金红石中Zr在高温下的扩散作用和后期流体活动的影响提供了重要证据, 这可能是利用金红石Zr含量地质温度计计算的苏鲁-大别榴辉岩变质温度(598~827℃) 偏低的主要原因.      

西藏南木林盆地林子宗群火山岩年代学和地球化学特征

为了更好地约束林子宗群火山岩的年龄格架、岩石成因及其演化历史,对拉萨地块中南部南木林盆地的林子宗群火山岩进行了详细的岩相学、锆石U-Pb年代学和全岩主微量元素地球化学研究.结果显示,南木林盆地林子宗群火山旋回时限依次为62.8～57.0 Ma、52.0～50.2 Ma、49.7 Ma.随着时间的演化,早期典中组以爆发相为主,年波组以喷发-沉积相为主,到晚期帕那组以喷溢相为主,且呈现出从中酸性向酸性演化,由钙碱性系列向高钾钙碱性系列再到钾玄岩系列逐渐过渡的趋势.其中,典中组英安质岩石为钙碱性系列,富集大离子亲石元素,亏损高场强元素,具有明显的Nb、Ta、Ti负异常,显示典型的弧火山岩特征;年波组和帕那组流纹质岩石为钙碱性-高钾钙碱性系列岩石,且有钾玄岩出现,富集大离子亲石元素,亏损高场强元素,除具有明显的Nb、Ta、Ti负异常外,还具有显著的Ba、Sr、P负异常,显示碰撞-碰撞后火山岩的特点.上述特征暗示典中组英安质岩石可能是新特提斯洋北向俯冲消减过程中岛弧区幔源岩浆底侵诱发上覆地壳部分熔融的产物,年波组和帕那组流纹质岩石则是印度-亚洲大陆碰撞初期阶段英安质岩石进一步分离结晶的产物.林子...     

黑龙江宝山一带海西晚期强过铝花岗岩地质地球化学及岩石成因

黑龙江宝山地区在构造上位于兴蒙造山带东部的松嫩地块和佳木斯地块之间的伊春-延寿花岗岩带北段,区内分布大面积的古生代-中生代花岗岩.其中海西晚期花岗岩,岩性主要为碱长花岗岩、二长花岗岩和花岗闪长岩等,锆石U-Pb法 LA-ICP MS测年结果为252.6±3 Ma.其主量元素表现出富Si、略富Al、富碱质和低Mg、低Ca的特点;微量元素表现出富集Rb、Nd、K、Pb、U和亏损Nb、Ta、P、Ti等高场强元素的特点,并且Sr、Ba呈明显的负异常;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,轻重稀土元素分馏程度较高.岩石总体上属于高钾钙碱性花岗岩,是岩浆经历了高度结晶分异作用的产物.矿物化学和岩石地球化学特征表明其特征类似于S型花岗岩,源岩物质来自于地壳.     

大兴安岭新林区中生代流纹岩年代学、地球化学特征及其地质意义

大兴安岭北段新林区满克头鄂博组火山岩主要由流纹岩、英安岩及其凝灰岩组成,LA-ICP-MS锆石U-Pb年龄为154.5±0.68 Ma,时代为晚侏罗世.白音高老组火山岩主要由流纹岩及其凝灰岩组成,LA-ICP-MS锆石U-Pb年龄为121.12±0.5 Ma,时代为早白垩世.满克头鄂博组火山岩属于高钾钙碱性系列-钾玄质系列.稀土元素配分模式图呈右倾型,轻重稀土分馏明显,具有中等的Eu负异常.微量元素显示相对富集大离子亲石元素K、Rb、Ba、Sr和轻稀土元素,亏损高场强元素Nb、Ta、Ti、P等.白音高老组火山岩属于高钾钙碱性系列.稀土元素配分模式图呈右倾型,轻重稀土分馏明显,明显Eu负异常.微量元素显示相对富集大离子亲石元素K、Rb和轻稀土元素,Ba、Sr明显亏损,高场强元素Nb、Ta,Ti强烈亏损.结合地球化学特征和前人研究资料,认为新林区满克头鄂博组火山岩来源于下地壳玄武质岩浆的结晶分异作用,与蒙古-鄂霍次克洋闭合造山后的伸展环境有关.白音高老组火山岩源于下地壳斜长角闪岩的非理想熔融,与太平洋板块俯冲影响的伸展作用有关.     

西南印度洋中脊钙质沉积物地球化学及矿物学特征

深海沉积物研究能够为海底资源开发利用提供丰富的信息,对推动沉积学发展具有重要的理论意义。以中国大洋科考20航次西南印度洋中脊附近的钙质沉积物为研究对象,选取了10个沉积物样品进行了X射线衍射物相分析、扫描电镜分析、碳氧同位素及微量元素测试。结果表明,研究区钙质沉积物矿物组成主要为方解石,黏土矿物含量较低。方解石以钙质超微化石颗石藻及有孔虫的形态存在,碳氧同位素特征显示超微化石生活在正常的近表层海水环境中,死亡后埋藏环境稳定。稀土元素具有总量低、轻重稀土元素分异明显、Eu中等负异常、Ce中等负异常的特征。微量元素中富亲石元素、贫亲铁元素,亲生物元素Sr、Ba含量远高于其他元素。微量元素特征及Ceanom值说明沉积环境偏氧化。沉积物中大量的生物成因方解石及地球化学特征反映了研究区物源以生物源为主、含有少量陆源及幔源物质的特点。     

Petrology and mineralogy of ophiolites in pull-apart structures of the Cayman Trough

New geological, mineralogical, and geochemical data on rocks dredged in the local spreading zone of the Cayman Trough (Caribbean Sea) make it possible to use this ophiolite complex as a reference one for pull-apart structures. The ophiolites form fault-bounded narrow elongated zones. Separate magmatic complexes within these zones can be of different ages, which decrease along the strike from the flanks to the central parts. The base of the ophiolite complex is mostly composed of lherzolites, while the gabbroid complex demonstrates clear magmatic layering formed through crystallization differentiation. At the same time, the crystalline and igneous rocks define a single geochemical series, which is characterized by the accumulation of lithophile and light rare-earth elements in more differentiated varieties. The REE distribution patterns are strongly correlated with the mineral composition of the rocks. The geochemical characteristics of the ophiolites indicate their affiliation to the plume type.     

陕西商州地区丹凤变质火山岩的地球化学特征

陕西商州地区丹凤变质火山岩具有洋内岛弧火山岩地球化学特征,它们是分别来自不同源区的拉斑玄武和钙碱性2个系列共存的一套变质火山岩。其Th/Ta比值高及Ni、Ta、Ti、Y和Yb含量低,表明岩石受到消减带组分的影响。种种证据表明,丹凤变质火山岩是早古生代华北地块南缘消减带之上洋内岛弧环境的产物。     

喜马拉雅淡色花岗岩——关键金属Sn-Cs-Tl的富集机制

关键金属是全球高科技产业不可或缺的战略性资源,其富集机制和成矿作用是目前国际矿床学研究的热点之一。我们对喜马拉雅带吉隆和亚东地区淡色花岗岩开展系统的地球化学研究,发现侵入到藏南拆离系的淡色花岗岩含有较高的Sn、Cs、Tl、Be、W、B、Li和Bi。全岩元素地球化学分析表明,这些淡色花岗岩具有如下特征：（1）富集关键金属元素;（2）为原始岩浆经历斜长石、锆石、独居石、磷灰石、云母分离结晶作用后的残余熔体;（3）关键元素的富集和矿化与花岗岩高度分离结晶作用密切相关。随着分异程度的增强,岩浆变为富挥发分的高SiO₂体系,关键金属元素在残余熔体中富集,并且最后可能形成具有工业价值的矿床。由于地球化学特征的相似性,Cs和Tl呈类质同象替代钾、铷进入云母中。富集关键金属元素的花岗岩在时间上和空间上属于与藏南拆离系相关的同构造侵位花岗岩,藏南拆离系的活动促使了原始岩浆的广泛分离结晶作用,以及后期的关键金属元素（如Rb、Cs和Tl）的富集。     

ODP 1144站钻孔沉积物中微玻璃陨石的元素地球化学特征

利用电子探针和激光探针等离子体质谱方法分析了取自南海北部的ODP1144钻孔沉积物中的微玻璃陨石和取自邻近的广东省湛江和吴川玻璃陨石的主元素和微量元素组成。结果显示，这些微玻璃陨石属于亚洲-澳大利亚散落区的普通微玻璃陨石。从成分上看，这些微玻璃陨石存在两种不同的类型，其中的绝大部分Al2O3含量在19.0%以上，属于高Al类型，相应的难熔微量元素含量也比较高；个别微玻璃陨石Al2O3含量（13.0%)和难熔微量元素含量较低，微量元素含量和特征比值都与邻近的广东省湛江和吴川的玻璃陨石相近。元素地球化学特征意味着，这些微玻璃陨石来源于同一靶源区，但靶区的物质组成并不均一。     

内蒙古双尖子山银多金属矿床区域地球化学特征

内蒙古双尖子山银多金属矿床是中国乃至亚洲规模最大的银多金属矿床,本研究在回顾矿床发现史的基础上对双尖子山矿床区域地球化学数据进行再分析。采用19级累积频率法制作研究区39种元素或氧化物的地球化学图,结果发现在双尖子山矿区范围内出现明显高值的有MgO、CaO、Fe₂O₃、Pb、Zn、Ag、V、Cr、Ni等多达22种氧化物或元素,其中主量成分的明显富集特征应受控于研究区的岩性分布情况。采用变值七级异常法制作研究区29种微量元素的地球化学异常图,结果发现在双尖子山矿区及其附近存在W、Sn、Mo、Bi、Pb、Zn、Ag、As、Sb计9种热液成矿元素的异常区,而其他微量元素在双尖子山矿区的明显富集情况可能是由双尖子山矿区及其附近母岩岩性及其风化作用所致。基于地球化学基因技术制作了研究区金矿化基因和钨矿化基因的矿化相似度地球化学图,结果发现在双尖子山矿区及其附近存在金矿化相似度和钨矿化相似度的异常区,表明矿化相似度可以作为该区金属矿产勘查的一种有效指标,认为区域化探工作在该区金属矿产勘查中具有很好的参考价值。     

Mantle Sources and the Highly Variable Role of Continental Lithosphere in Basalt Petrogenesis of the Kerguelen Plateau and Broken Ridge LIP: Results from ODP Leg 183

Ocean Drilling Program (ODP) Leg 183 was designed to investigatethe origin and evolution of the large igneous province composedof the Kerguelen Plateau and Broken Ridge. Of the eight sitesdrilled, basalt was recovered from seven, five on the plateauand two on Broken Ridge. We present results from four of thesesites, 1136, 1138, 1141 and 1142. Although this large igneousprovince is interpreted as being derived from the Kerguelenmantle plume, the geochemical characteristics of basalt fromsome parts of the province indicate a role for continental lithosphere.The 118–119 Ma basalt flows recovered in the SouthernKerguelen Plateau (Site 1136) have a more subtle continentalsignature than shown by basalt at Leg 119 Site 738. A continentalsignature is absent in the 100–101 Ma tholeiitic basaltsat Site 1138 in the Central Kerguelen Plateau (CKP); their age-correctedNd–Sr–Pb isotopic values and incompatible elementratios are similar to those estimated for primitive mantle.These flows may represent a major mantle source in the Kerguelenstarting-plume head. The 20 basalt units identified are a productof magma chamber replenishment, fractional crystallization,and resorption of crystallizing phases. The topmost unit, Unit1, is a dacite that evolved from a basalt magma similar to thoserepresented by Units 3–22; unlike the basalts the dacitemagma was probably influenced by continental material. MiddleCretaceous (     

Borborema Pegmatitic Province: geological and geochemical characteristics

The geological features of the pegmatites from the Borborerna Pegmatitic Province (BPP) are described, combining data from the literature with new field and laboratory observation. A geochemical study was performed against this geological background to test the crystallization model of mineralized pegmatites against barren pegmatites and to compare the BPP with other provinces, fields or individual pegmatites throughout the world. The field evidence (mode of emplacement, textural relationships, zonation and mineralogy) as well as the geochemical characteristics support the pegmatite crystallization model proposed by London (1990). The geochemical and mineralogical evidence places these pegmatites as “medium Ta-mineralized” compared to other pegmatite provinces.     

Petrology and geochemistry of the island of Sarigan in the Mariana arc; calc-alkaline volcanism in an oceanic setting

Isotopic studies of rocks from oceanic island arcs such as the Marianas indicate that little, if any, recycling of continental material (e.g. oceanic sediments) occurs in these arcs. Because oceanic arcs are on the average more mafic than the dominantly andesitic continental arcs, an important question is whether the andesites of continental arcs are produced by a fundamentally different (more complex?) mechanism than the lavas of oceanic arcs. An excellent opportunity for study of this question is provided by the island of Sarigan, in the Mariana active arc, on which calc-alkaline andesites (including hornblende-bearing types) are exposed along with more mafic lavas. Available isotope data suggest the Sarigan lavas (including the andesites) were derived from mantle material with little or no involvement of continental components. Ratios of incompatible elements suggest that most of the Sarigan lavas were derived from similar source materials. Absolute abundances of incompatible elements vary irregularly within the eruptive sequence and indicate at least 5 distinct magma batches are represented on Sarigan. Major element data obtained on the lavas and mineral phases in them, combined with modal mineral abundances, suggest that the calc-alkaline nature of the volcanic rocks on Sarigan results from the fractional crystallization of titanomagnetite in combination with other anhydrous phases. Amphibole, although present in some samples, is mainly a late-crystallizing phase and did not produce the calc-alkline characteristics of these lavas. Gabbroic samples found in the volcanic sequence have mineralogc and geochemical characteristics that would be expected of residual solids produced during fractional crystallization of the Sarigan lavas. When combined, data on the lavas and the gabbros suggest the following crystallization sequence: olivine — plagioclase — clinopyroxene — titanomagnetite — orthopyroxene±hornblende, biotite and accessory phases. These results lead to the conclusion that calc-alkaline magmas can be generated directly from mantle sources.     

宁镇中段燕山期中酸性侵入岩的稀土和微量元素地球化学研究

与铜多金属成矿相关的宁镇中段地区岩浆活动主要发生在燕山晚期,形成多个中酸性侵入岩体.文章在开展野外调查的基础上,主要从稀土元素和微量元素的实测资料,结合常量元素进行分析,探讨岩浆来源、结晶分异过程及铜多金属矿化特点.研究结果表明,宁镇中段岩浆为壳幔混合型,具有相同的演化趋势.并确定了6大岩体结晶分异程度的高低,提出了岩浆分异程度与矿化特点的关系.     

Tertiary anorogenic granites of the western border of the Yemen Plateau

North Yemen (Y.A.R.) was affected, from 30 to 20 Ma ago, by intense magmatic activity (Trap Series), contemporary with the main tensional tectonic phases of the Afro-Arabian Plate. In the Trap activity, two main phases have been recognized; the former, mainly basaltic, between 30 and 26 Ma; and the second, mainly acidic, between 23 and 20 Ma. During the latter period of activity, a basaltic dyke swarm and stock-like bodies and dykes (granophyres) were emplaced along the escarpment and coastal plain. Some granitic bodies intruded the Trap Series towards the end of the first phase and during the second one.

On the basis of geochemical and petrological data, the Tertiary granites of Yemen belong to alkaline or peralkaline associations of A-type. The textural characteristics indicate that the granites are either hypersolvus or subsolvus. The mafic mineral assemblages allow three main types of granites to be distinguished by their different environments of crystallization.

As regards the origin of these kinds of granites, several hypotheses account for the peculiarities observed. The lack of crustal xenoliths, the preliminary data on the Sr isotopic ratio, the data on major and trace elements point to a direct origin by fractional crystallization, without substantial crustal interaction. This agrees well with the strong tensile tectonics, linked with the uplift of the Afro-Arabian dome and with the lithosphere thinning, which provide a minimal opportunity for interaction of the magmas with the crust.