四川三江北段地区金及多金属成矿规律及靶区优选

四川三江北段地区位于我国十九个重点成矿区带之一的西南三江成矿带中东部,区内多种类型的沉积建造、频繁的火山-岩浆活动以及复杂的地质构造背景,产出了丰富的有色金属、贵金属矿产资源,本次通过DPIS预测,在区内圈定金找矿靶区6处,分别为：甘孜县找矿靶区、卓达找矿靶区、根洛找矿靶区、沙马找矿靶区、拉波找矿靶区、水洛找矿靶区。下步应有针对性的加强对6处金找矿靶区的研究、勘查工作,在区内有发现金及多金属矿床的可能。     

成矿地质体找矿预测理论与方法在矿产勘查中的应用

成矿地质体找矿预测理论与方法的创建为中国勘查区找矿工作提供了理论指导和方法遵循,已广泛应用于矿集区、老矿山深部与外围的找矿预测和矿产勘查中。在河南省银洞坡金银矿集区、甘肃省早子沟金矿、四川省拉拉铜矿集区等83个矿集区和168座矿山取得了良好的找矿效果。该理论方法的核心是构建成矿地质体-成矿构造和成矿结构面-成矿作用特征标志“三位一体”找矿预测地质模型。总结了应用成矿地质体找矿预测理论与方法开展找矿预测工作的流程和要点：开展预研究提出找矿思路,研究典型矿床确定主攻矿床类型;研究成矿地质体确定找矿方向,研究成矿构造与成矿结构面确定矿体赋存位置,研究成矿作用特征标志提供矿体赋存依据,构建找矿预测地质模型确定成矿作用中心;综合地质、物探、化探方法,预测深部矿体空间位置;探矿工程验证实现找矿突破。本次研究为找矿预测工作提供了思路和示范,为新一轮找矿突破战略行动提供了支撑服务。     

藏东玉龙斑岩型铜矿带综合信息找矿预测

对藏东玉龙斑岩型铜矿带进行二维综合信息找矿预测与分析,提取与深入分析多源找矿信息,揭露研究区的隐伏矿体,为该区日后的矿产资源勘查与开发提供有利证据。通过对研究区的地层、构造、岩浆岩、地球化学信息及蚀变等要素与成矿之间的关联性进行研究,建立该区的证据权找矿模型。利用证据权重法进行找矿预测,圈定了8处成矿有利地段,其中A类靶区4处、B类靶区2处、C类靶区2处。A类靶区可作为重点勘查区,B类靶区为研进一步找矿区。     

新疆鄯善县恰特卡尔地区基性-超基性岩型铜镍找矿模型及矿产预测

在野外地质调查基础上,对研究区地质、航磁、重力、化探信息进行分析研究,结合典型成矿岩体岩石学、岩相学、岩石化学及同位素研究成果,对岩体、构造、航磁、重力、化探及矿化标志信息进行提取,建立研究区铜镍找矿模型。采用综合信息地质单元法、特征分析法、地质体积法进行预测区的圈定、优选及资源量定量预测,圈定A类找矿靶区11处,B类找矿靶区13处,C类找矿靶区15处,估算镍资源量358×104t,显示了研究区铜镍矿巨大的找矿前景。     

云南德钦羊拉铜矿综合信息找矿模型及外围找矿预测

羊拉铜矿是金沙江成矿带北端的典型矿床。在充分收集数据资料和总结前人成果的基础上,通过对研究区的区域地质背景、典型矿床地质特征、成矿类型、地质控矿因素、物化探异常特征、遥感线环解译和蚀变特征的研究,获取区域找矿标志,并建立了羊拉铜矿区综合信息找矿模型。利用此模型,对研究区进行了找矿预测,共圈定和评价了6个找矿靶区。     

青海北巴颜喀拉成矿带基于专家证据权重法锑金矿资源潜力评价

青海北巴颜喀拉成矿带虽然总体研究程度低,但显示出巨大的找矿潜力,急需寻求新的找矿突破。利用前人的地质、矿产、化探等资料,建立了青海北巴颜喀拉成矿带基于GIS的空间数据库。在此基础上重新建立了研究区锑金矿区域找矿模型,其中主要找矿标志包括金水系沉积物异常、锑水系沉积物异常、砷水系沉积物异常、重砂异常、NW－NWW向线性构造和巴颜喀拉山群。采用作者提出的专家证据权重法,对研究区首次进行了基于GIS下的专家证据权重法矿产资源评价工作。据此重新圈定找矿远景区和找矿靶区,将后验概率大于0.001的区域作为找矿远景区,将后验概率大于0.005的区域作为找矿靶区;并依据找矿靶区内预测含矿区域后验概率二重积分大小,将找矿靶区的找矿潜力级别由高到低分别划分为A 、B 、C 3级,其中A级6处,B级10处,C级13处。     

地电化学集成技术在云南西邑铅锌矿区的找矿应用

以"已知剖面试验研究—建立找矿模型—未知区找矿预测"的研究思路,在云南西邑矿区开展了地电化学集成技术找矿应用研究。通过研究验证了地电化学集成技术在该区寻找类似隐伏铅锌矿的可行性,并结合成矿地质条件,建立了地质—地电化学找矿模型,基于该模型,在研究区董家寨内共圈出1个Ⅰ级预测靶区,2个Ⅱ级预测靶区,1个Ⅲ级预测靶区。     

低植被覆盖区斑岩铜矿遥感找矿模型及其应用——以环巴尔喀什-西准噶尔成矿带为例

针对遥感找矿过程中所面临的干扰因素多、地表覆盖类型多样导致的遥感找矿困难的问题,提出了低植被覆盖区斑岩铜矿"小型侵入岩体异常+线性构造异常+蚀变矿物异常"的多尺度遥感找矿模型,并系统总结了该模型的基本原理和技术流程。以环巴尔喀什-西准噶尔成矿带为研究区,分析了研究区的成矿地质背景;在遥感找矿模型的指导下,依据遥感找矿技术流程提取了研究区的岩性、构造和蚀变矿物等控矿要素;结合野外地表验证情况,综合多源数据,圈定了5处重点远景区;结合大比例尺遥感蚀变矿物填图、地质、地球物理、地球化学和探槽取样的分析结果,圈定3处遥感找矿靶区。     

龙江—神山地区成矿预测

本文通过对该区成矿地质背景、成矿地质特征、成矿规律的研究,提出了找矿预测区。找矿靶区为六九班岩系列铜多金属成矿区;找矿远景区为神山铜多金属成矿区。     

豫西南杜关—云阳钼多金属成矿预测研究

选取豫西南杜关—云阳钼多金属成矿带为研究区,利用多学科资料,使用非线性方法提取了多元、多维、多尺度、多类型找矿信息。在应用层次分析法集成多元信息的基础上,进一步用"Kriging+Natural Breaks"和C-A分形法分别圈定了找矿靶区。结果表明,两者所圈定的找矿靶区基本一致,但后者在局部地段能够更细致地刻画靶区的细节,将找矿靶区进一步划分为Ⅰ、Ⅱ、Ⅲ级。其中Ⅰ、Ⅱ级预测区内包含有已知矿床,Ⅲ级预测区具有较好的找矿潜力。该成果为本地区的下一步找矿工作提供了依据。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

电感耦合等离子体发射光谱法同时测定卤水中锂钠钾钙镁硼硫氯

建立了电感耦合等离子体发射光谱法(ICP-AES)同时测定碳酸盐型、硫酸盐型、氯化物型三种类型卤水中Li、Na、K、Ca、Mg、B、S、Cl等高低含量元素的分析方法。选择仪器最佳的工作条件为射频功率1400W,炬管位置位于-3,载气流量0.60 L/min。确定了各元素测定谱线,使用ICP-AES的双向观测模式、轴向观测模式测定Li、Ca、B、S、Cl以及低含量的K、Mg,径向观测模式测定高含量的Na、K、Mg,可确保卤水中不同含量的元素同时检出。Li、Na、K、Ca、Mg、B、S的检测下限为0.07～3.00 mg/L,Cl的测定下限为165mg/L。方法精密度(RSD,n=10)均小于5%,回收率为92.4%～109.7%。其中Na、K、Mg、S、Cl测定结果与传统方法测定结果基本吻合。     

Slope hummock development, Fosheim Peninsula, Ellesmere Island, Nunavut, Canada

Slope hummocks, a type of nonsorted patterned ground, are composed of stratified, organic, silty sand, and develop through the interaction of niveo-eolian deposition, solifluction, slopewash, and vegetation growth. Fields of hummocks show consistent patterns: forms on convex slopes increase in height downslope until the channel is reached, whereas those on convexo-concave slopes increase on the upper convexity but are buried by niveo-eolian deposition downslope of the snowbank remnant. These trends can be reproduced using a simple numerical model based on measured slope and snow depth profiles, sediment concentrations in the snow and solifluction rates. The model indicates that hummocks transit slopes of 20-40 m in about 2-4 ka, a time-frame that is plausible given site emergence, measured rates of solifluction, and published dates for organic horizons within hummocks on northern Ellesmere Island. Sensitivity analyses show that long-term effect of climate warming on hummock heights may differ depending on whether it is accompanied by precipitation increase or decrease. The required combination of two-sided freezing to promote plug-like movement, incomplete vegetation cover and thin snow that enable eolian erosion during winter and spring, and vegetation growth in snow-bed sites to stabilize niveo-eolian deposits may explain why these forms are important regionally but apparently are not present throughout the Arctic.