Heat Tracing in a Fractured Aquifer with Injection of Hot and Cold Water

Heat as a tracer in fractured porous aquifers is more sensitive to fracture-matrix processes than a solute tracer. Temperature evolution as a function of time can be used to differentiate fracture and matrix characteristics. Experimental hot (50 °C) and cold (10 °C) water injections were performed in a weathered and fractured granite aquifer where the natural background temperature is 30 °C. The tailing of the hot and cold breakthrough curves, observed under different hydraulic conditions, was characterized in a log–log plot of time vs. normalized temperature difference, also converted to a residence time distribution (normalized). Dimensionless tail slopes close to 1.5 were observed for hot and cold breakthrough curves, compared to solute tracer tests showing slopes between 2 and 3. This stronger thermal diffusive behavior is explained by heat conduction. Using a process-based numerical model, the impact of heat conduction toward and from the porous rock matrix on groundwater heat transport was explored. Fracture aperture was adjusted depending on the actual hydraulic conditions. Water density and viscosity were considered temperature dependent. The model simulated the increase or reduction of the energy level in the fracture-matrix system and satisfactorily reproduced breakthrough curves tail slopes. This study shows the feasibility and utility of cold water tracer tests in hot fractured aquifers to boost and characterize the thermal matrix diffusion from the matrix toward the flowing groundwater in the fractures. This can be used as complementary information to solute tracer tests that are largely influenced by strong advection in the fractures.     

Attenuation tomography of the Southern Apennines (Italy)

The aim of this study is to improve our knowledge of the attenuation structure in the Southern Apennines using a new amplitude ratio tomography method (Phillips et al., Geophys Res Lett 32(21):L21301, 2005) applied on both direct and coda envelope measurements derived from 150 events recorded by 47 stations of the Istituto Nazionale di Geofisica e Vulcanologia National Seismic Network (Rete Sismica Nazionale Centralizzata). The two-dimensional (2-D) analysis allows us to take into account lateral crustal variations and heterogeneities of this region. Using the same event and station distribution, we also applied a simple 1-D methodology, and the performance of the 1-D and 2-D path assumptions is tested by comparing the average interstation variance for the path-corrected amplitudes using coda and direct waves. In general, coda measurement results are more stable than using direct waves when the same methodology is applied. Using the 2-D approach, we observe more stable results for both waves. However, the improvement is quite small, probably because the crustal heterogeneity is weak. This means that, for this region, the 1-D path assumption is a good approximation of the attenuation characteristics of the region. A comparison between Q tomography images obtained using direct and coda amplitudes shows similar results, consistent with the geology of the region. In fact, we observe low Q along the Apennine chain toward the Tyrrhenian Sea and higher values to the east, in correspondence with the Gargano zone that is related to the Apulia Carbonate Platform. Finally, we compared our results with the coda Q values proposed by Bianco et al. (Geophys J Int 150:10–22, 2002) for the same region. The good agreement validates our results as the authors used a completely independent methodology.     

The 1627 Gargano earthquake (Southern Italy): Identification and characterization of the causative fault

We present the results of a study of the subsurface tectonic features of the Basso Molise, Western Gargano and Northern Capitanata regions (Southern Italy) aimed at the identification of the source of the disastrous 1627 Gargano earthquake. In the maximum-damage area of this earthquake we have recognised a normal fault, here called the Apricena Fault, which has been identified as the fault that caused the seismic event. The Apricena Fault, striking WNW-ESE and dipping towards SSW, extends in the subsurface for about 30 kilometres from Serracapriola to Santa Maria di Stignano cutting through the whole Quaternary sequence. Other important tectonic structures trending WNW-ESE recognized in the area belong to an inactive Pleistocene strike-slip-fault system that is linked to the Mattinata Fault and to its offshore continuation in the Gondola-Grifone structural high. The Mattinata Fault and the Gondola-Grifone High form a quite complex structural feature whose kinematic behaviour is still matter of debate in the regional geological literature. NW-SE structural features recognized in the area are extensional faults whose activity was probably related to the late flexure-hinge retreat of the Adria plate margin during the Late Pliocene-Early Pleistocene eastward migration of the thrust belt-foredeep-foreland system.     

The Correlation Between Bedrock Uranium and Dissolved Radon in Ground Water of a Fractured Carbonate Aquifer in Southwestern Ohio

Two hypotheses have previously been proposed for the source of elevated radon in ground water of southwestern Ohio: (1) penecontemporaneous uranium at the Silurian-Ordovician unconformity, and/or (2) parent radionuclides transported from fragments of uranium-rich Ohio Shale within the glacial drift above the aquifer. To further test the first hypothesis, vertical profiles of dissolved radon in ground water and uranium in rock cores were obtained at two locations immediately underlain by the Silurian/Ordovician unconformity. Radon concentrations exceeding 1000 pCi/l occurred in zones where the bedrock had uranium concentrations greater than 1.5 ppm. Radon concentrations of less than 500 pCi/l occurred in zones where the rock had uranium concentrations below 0.25 ppm. A log-linear regression model between uranium and radon had a correlation coefficient of 0.82. Three aspects of the results support the hypothesis that the source is transported, although not necessarily from fragments of Ohio Shale. First, the high uranium-radon zones did not occur consistently or exclusively at the Silurian/Ordovician unconformity. Second, the high uranium-radon zones are correlated to fracture zones having a higher hydraulic conductivity and thus appear to be related to the zones of greater flow and transport. Third, the amount of uranium-radon disequilibrium increases exponentially with increasing hydraulic conductivity. The hypothesis of a penecontemporaneous source, not supported by our study, arose when previous investigators conducted regional surveys of domestic wells and springs and found a correspondence between elevated radon and the location of the Silurian-Ordovician unconformity. The observations of the previous investigators can be explained by the fact that the basal Silurian is in some places a horizon of higher hydraulic conductivity that facilitates transport. The two most probable external sources of uranium would be uranium-containing detritus in the glacial drift or uranium-containing phosphate fertilizers spread on the surface. Given that the uranium was transported into the aquifer during the Holocene, it could not have generated enough radium in the time elapsed since entering the aquifer to produce the radon levels that were measured. This observation indicates that radium was cotransported with uranium into the zones of high radon.     

Geological evidence for strong historical earthquakes in an “aseismic” region: The Pollino case (Southern Italy)

The Pollino Range is the southernmost segment of the Southern Apennines at the boundary with the Calabrian Arc. While several strong earthquakes (magnitude 6.5–7.0) have occurred in nearby regions, the Pollino area has no known historical record of seismic events of magnitude > 5. We carried out an aerial photograph interpretation and a field survey of the Pollino fault (the major Quaternary normal fault of the area) in order to characterize geologically the seismic potential of this structure. We dug two sets of trenches across fault scarps within the apecies of latest Pleistocene to Holocene alluvial fans at the Masseria Quercia Marina (MQM) and Grotta Carbone (GC) sites, in the central segment of the southern Pollino Range front. At both sites we identified two surface faulting events affecting the alluvial fan deposits and two overlying colluvial units of historical age. The penultimate event produced a vertical offset of 80–90 cm at GC and 50–60 cm at MQM; while the last event produced a vertical offset of 40–50 cm at GC and few centimeters of offset at MQM. Detailed geomorphological field observations suggest that the two historical earthquakes reactivated the entire length of the Masseria Marzano-Civita segment of the Pollino fault (rupture length about 18 km). For events in this range of rupture length and vertical displacement, comparison with surface faulting earthquakes in the Apennines (and abroad) indicates a magnitude of 6.5–7.0. Therefore, the maximum potential earthquake and the seismic hazard of the Pollino area are significantly larger than that suggested by the available historical seismic catalogue.     

3-D density model of Mt. Etna Volcano (Southern Italy)

A detailed density model of Mt. Etna and its surrounding areas has been evaluated using a 3-D inversion of the gravimetric data acquired in the 1980's. Several high-density and low-density bodies are found, penetrating from shallow depths as far down as 12 km bsl. A positive correlation (in terms of location, extent, density, and velocity) is established between several anomalies of the density model and features identified in previously published seismic tomographies. A prominent high-density body extending down to 7 km bsl is recognized in the southern part of the Valle del Bove, and interpreted as a solidified magmatic intrusion. On the western boundary of this anomaly, a low-density body is interpreted as a bubble and liquid magma mixture. Outside the central area, three other high-density anomalies are imaged and attributed to the earliest phases of volcanic activity in the area. Several interesting low-density anomalies are also identified and correlated with known fault lines and other structural features of the region.     

Structural setting of the Southern Apennine fold-and-thrust belt (Italy) at hypocentral depth: The Calore Valley case history

The reconstruction of the main structural features of the Southern Apennines (Italy), in correspondence with the focal volume of some strong earthquakes that have affected this chain, can be attempted by analysing reflection seismic lines and deep well logs in comparison with surface geology.For instance, the Calore Valley and its surroundings have been the object of intense hydrocarbon exploration, and a wealth of subsurface data is available. Moreover, this area was affected by the 1688 Sannio earthquake (macroseismic magnitude 7.1), and a new location has recently been proposed for the related causative fault system. The present work defines the structural setting of the Southern Apennine chain in correspondence with this new location, and compares it with similar cases along the Italian peninsula.The analysis was focussed on the reconstruction of deep tectonic units (formed by the buried Apulia carbonate platform succession), which generally correspond to the hypocentral depths of strong earthquakes along the axis of the Southern Apennines. The results show that the Apulia platform succession is affected by three main thrusts, locally accompanied by backthrusts. The top of this succession is relatively shallow: the maximum depth does not exceed 1.8 s TWT (i.e. about 3500 m b.s.l.), while minimum depths occur in correspondence with the ramp anticlines culminations, at ∼0.5 s TWT (i.e. at about 500 m b.s.l.). Moreover, data suggest that the underlying Paleozoic basement is possibly involved in thrusting.In a regional perspective, extensional seismogenic structures along the axis of the Southern Apennines seem to share some common characteristics. Indeed, they develop (i) in correspondence with an uplifted Paleozoic basement; (ii) at the rear of a set of thrusts that account for the shallow Apulia units; (iii) at the surface, in proximity to the leading edge of a surficial tectonic unit formed by the Apennine carbonate platform succession. The 1688 seismogenic fault system fits in with these common traits. In the light of this, we finally speculate that these common characteristics in the architecture of the chain could provide a key to the location of the major seismicity along the axis of the Southern Apennines and an interpretative model for the identification of possible areas of seismic gap in this part of the Italian peninsula.     

Structural setting of the Southern Apennine fold-and-thrust belt (Italy) at hypocentral depth: The Calore Valley case history

The reconstruction of the main structural features of the Southern Apennines (Italy), in correspondence with the focal volume of some strong earthquakes that have affected this chain, can be attempted by analysing reflection seismic lines and deep well logs in comparison with surface geology.For instance, the Calore Valley and its surroundings have been the object of intense hydrocarbon exploration, and a wealth of subsurface data is available. Moreover, this area was affected by the 1688 Sannio earthquake (macroseismic magnitude 7.1), and a new location has recently been proposed for the related causative fault system. The present work defines the structural setting of the Southern Apennine chain in correspondence with this new location, and compares it with similar cases along the Italian peninsula.The analysis was focussed on the reconstruction of deep tectonic units (formed by the buried Apulia carbonate platform succession), which generally correspond to the hypocentral depths of strong earthquakes along the axis of the Southern Apennines. The results show that the Apulia platform succession is affected by three main thrusts, locally accompanied by backthrusts. The top of this succession is relatively shallow: the maximum depth does not exceed 1.8 s TWT (i.e. about 3500 m b.s.l.), while minimum depths occur in correspondence with the ramp anticlines culminations, at 0.5 s TWT (i.e. at about 500 m b.s.l.). Moreover, data suggest that the underlying Paleozoic basement is possibly involved in thrusting.In a regional perspective, extensional seismogenic structures along the axis of the Southern Apennines seem to share some common characteristics. Indeed, they develop (i) in correspondence with an uplifted Paleozoic basement; (ii) at the rear of a set of thrusts that account for the shallow Apulia units; (iii) at the surface, in proximity to the leading edge of a surficial tectonic unit formed by the Apennine carbonate platform succession. The 1688 seismogenic fault system fits in with these common traits. In the light of this, we finally speculate that these common characteristics in the architecture of the chain could provide a key to the location of the major seismicity along the axis of the Southern Apennines and an interpretative model for the identification of possible areas of seismic gap in this part of the Italian peninsula.     

Macroseismic Magnitude Evaluation of Earthquakes of Calabria and Northeastern Sicily (Southern Italy)

A comparison of the most used magnitude-intensity relations is carried out, with reference to a spatial window coinciding with Calabria and northeastern Sicily, evaluating their consistency with different data sets taken from several catalogues. M values indicated in the catalogues and the corresponding average value have been used choosing the relation to be adopted on the basis of the level of their adaptability to points, rather than prearranged models.     

Anthropogenic sinkholes in the territory of the city of Naples (Southern Italy)

About 190 anthropogenic sinkholes occurred within the territory of the city of Naples (Southern Italy) between 1915 and 2010.In the study area, the genesis of sinkholes can be ascribed to two major factors, often strongly interacting with each other: the existence of a complex network of underground man-made cavities, and the inadequacy of the sewage disposal system.Rainfall has been identified as the main triggering factor combined with anthropogenic activity. Based on such predisposing factors, in addition to the geological setting, a susceptibility map of the territory has been realised.     

Lava-flow hazard on the SE flank of Mt. Etna (Southern Italy)

A method for mapping lava-flow hazard on the SE flank of Mt. Etna (Sicily, Southern Italy) by applying the Cellular Automata model SCIARA_-fv is described, together with employed techniques of calibration and validation through a parallel Genetic Algorithm. The study area is partly urbanised; it has repeatedly been affected by lava flows from flank eruptions in historical time, and shows evidence of a dominant SSE-trending fracture system. Moreover, a dormant deep-seated gravitational deformation, associated with a larger volcano-tectonic phenomenon, affects the whole south-eastern flank of the volcano.     

Time probabilistic evaluation of seismically induced landslide hazard in Irpinia (Southern Italy)

A recently proposed method, which incorporates the Newmark model to evaluate the earthquake-induced landslide hazard at regional scale, was applied to Irpinia, one of the most seismically active regions of Italy. The method adopts a probabilistic approach to calculate values of critical acceleration a_c representing the minimum strength required for a slope not to fail at a fixed probability level in a given time interval. Regional probabilistic hazard maps were generated for the two failure types most common in Irpinia (slump–earthflows and rock falls). The results suggest that quite moderate critical acceleration (0.05–0.08 g) could suffice to keep the slope failure probability low. However, the available data indicate that potential slide surfaces with a_c below these values could be common in Irpinia, where, perhaps in relation to particular geo-environmental conditions, a relative large number of marginally stable slopes might survive other destabilising actions and fail even on occasion of not particularly strong earthquake shaking.     

Merging active and passive data sets in traveltime tomography: The case study of Campi Flegrei caldera (Southern Italy)

We propose a strategy for merging both active and passive data sets in linearized tomographic inversion. We illustrate this in the reconstruction of 3D images of a complex volcanic structure, the Campi Flegrei caldera, located in the vicinity of the city of Naples, southern Italy. The caldera is occasionally the site of significant unrests characterized by large ground uplifts and seismicity. The P and S velocity models of the caldera structure are obtained by a tomographic inversion based on travel times recorded during two distinct experiments. The first data set is composed of 606 earthquakes recorded in 1984 and the second set is composed of recordings for 1528 shots produced during the SERAPIS experiment in 2001. The tomographic inversion is performed using an improved method based on an accurate finite‐difference traveltime computation and a simultaneous inversion of both velocity models and earthquake locations. In order to determine the adequate inversion parameters and relative data weighting factors, we perform massive synthetic simulations allowing one to merge the two types of data optimally. The proper merging provides high resolution velocity models, which allow one to reliably retrieve velocity anomalies over a large part of the tomography area. The obtained images confirm the presence of a high P velocity ring in the southern part of the bay of Pozzuoli and extends its trace inland as compared to previous results. This annular anomaly represents the buried trace of the rim of the Campi Flegrei caldera. Its shape at 1.5 km depth is in good agreement with the location of hydrothermalized lava inferred by gravimetric data modelling. The Vp/Vs model confirms the presence of two characteristic features. At about 1 km depth a very high Vp/Vs anomaly is observed below the town of Pozzuoli and is interpreted as due to the presence of rocks that contain fluids in the liquid phase. A low Vp/Vs body extending at about 3–4 km depth below a large part of the caldera is interpreted as the top of formations that are enriched in gas under supercritical conditions.     

Geolithological and anthropogenic controls on the hydrochemistry of the Volturno river (Southern Italy)

The present work aims to study the main chemical and physical water parameters in the upper and middle Volturno river catchment (southern Italy), between the Capo Volturno springs and the confluence with the Calore river. This study makes use of morphology, geolithology, tectonic, land use, and physico‐chemical (pH, electrical conductivity, redox potential, temperature, major ions, and ²²²Rn) data for the identification of the main sources of surface and groundwaters in the Volturno catchment and of their evolution and mixing both in base flow and peak flow conditions. The study was also performed to assess whether the alteration due to potential anthropogenic contamination may hamper the identification of natural “primitive” sources of surface waters, especially in the populated and farmed plains far from the river headwaters. Our data suggest that water chemistry of this stretch of the Volturno river is dominated mainly by lithology and, only marginally, by the intense exogenous activities and that this trend is appreciable in both base flow and peak flow conditions. The proposed simple geochemical approach based on easy‐to‐sample matrices and on cost‐effective standard methods is a valuable tool to address catchment functionality especially in upland areas, where complex geologic and structural settings, heterogeneous groundwater flow, and logistical issues are the rule rather than the exception. Because the upper and middle Volturno catchment is comparable with numerous valleys of the Mediterranean area, this study could be a reference for analogous applications.