西藏南部错那洞矽卡岩型铍钨锡多金属矿体成矿母岩成岩时代及其地球化学特征

错那洞穹窿是北喜马拉雅片麻岩穹窿带(NHGD)中发现的新成员,并发育有超大型铍钨锡多金属成矿作用.错那洞矿床铍钨锡多金属矿体赋存于矽卡岩、断裂构造及(伟晶状)花岗岩中,以矽卡岩型矿体为主,形成矽卡岩型矿体的成矿母岩则为一套弱定向二云母花岗岩.针对弱定向二云母花岗岩开展了年代学及地球化学特征研究工作.年代学结果表明,弱定向二云母花岗岩锆石U-Pb年龄为16.5±0.3 Ma,为中新世淡色花岗岩浆活动,表明错那洞超大型铍钨锡多金属矿床形成于中新世,为喜马拉雅碰撞造山过程中伸展阶段的产物.地球化学结果表明,该套成矿弱定向二云母花岗岩具有富硅(73.36%~73.89%)、贫铁(0.96%~1.58%)、强过铝质的钙碱性花岗岩地球化学特征.其稀土元素总量较低,相对富集轻稀土元素,而相对亏损重稀土元素,具有明显负Eu异常,相对富集Rb、Th等大离子亲石元素,相对亏损Zr、Ti等高场强元素,地球化学特征综合显示其为一套高分异淡色花岗岩,可能为变泥质岩重融的产物,与藏南拆离系(STDS)的活动密切相关.      

藏南错那洞淡色花岗岩年代学研究及其对藏南拆离系活动时间的限定

北喜马拉雅片麻岩穹窿带(NHGD)内保存了大陆碰撞后青藏高原中下地壳的构造变形、高级变质、陆壳深熔作用等重要信息,是研究喜马拉雅造山带的深部岩浆作用和构造变形之间的耦合关系、深部岩浆活动乃至青藏高原隆升历史等大陆动力学过程的关键部位。本文对藏南错那洞穹窿内淡色花岗岩进行锆石LA MC-ICP-MS U-Pb、白云母~(40)Ar/~(39)Ar年代学和岩石地球化学分析。锆石U-Pb定年和白云母~(40)Ar/~(39)Ar测年结果表明错那洞淡色花岗岩形成于19.5±0.3Ma~19.7±0.7Ma,冷却年龄为15Ma。岩石地球化学特征显示该花岗岩具有明显的Eu负异常,稀土配分模式和微量元素蛛网图与以Manaslu为代表的高喜马拉雅淡色花岗岩一致,而不同于具有加厚地壳的埃达克岩的特征的北喜马拉雅淡色花岗岩,其形成于与南北向拆离相关的伸展环境。     

藏南错那洞淡色花岗岩成因：来自全岩地球化学和锆石U-Pb年龄的约束

藏南错那洞穹隆位于喜马拉雅造山带东部,淡色花岗岩是其核部组成部分之一。对其中的弱定向二云母花岗岩和含石榴子石二云母花岗岩进行LA-ICP-MS锆石U-Pb定年,显示其结晶年龄分别为(20.6±0.3) Ma和(16.7±0.2) Ma,属于喜马拉雅中新世淡色花岗岩。错那洞含石榴子石二云母花岗岩和弱定向二云母花岗岩均具有富硅(w(SiO2)为71.6%~74.6%)、富铝(w(Al2O3)为14.5%~16.1%)、富钾(w(K2O)为4%~4.7%)及高铝饱和指数(A/CNK=1.16~1.22)的特征,属高钾钙碱性系列的强过铝质花岗岩,并且两类花岗岩都富集Rb、U、K、Pb,相对亏损Nb、Ta、Zr、Ti。但含石榴子石淡色花岗岩具有明显的Eu负异常(Eu/Eu*=0.29~0.46),而弱定向二云母花岗岩Eu的负异常相对较弱(Eu/Eu*=0.58~0.80)。弱定向二云母花岗岩的Rb/Sr值为2.4~3.5,Ba含量为(200~253)×10-6,TiO2含量相对较低,表明错那洞弱定向二云母花岗岩是在无水条件下由变泥质岩中的白云母脱水熔融而形成,并且弱定向二云母花岗岩的产生可能与藏南拆离系(STDS)启动造成的构造减压有关。含石榴子石二云母花岗岩的K/Rb、Zr/Hf、Nb/Ta、Y/Ho值呈现出非球粒陨石异常,稀土四分组效应和异常高的Rb/Sr值(18.6~22.2)表明错那洞含石榴子石二云母花岗岩是经过岩浆高度演化而形成的。高度演化的岩浆有利于W、Sn、Be等稀有金属成矿。错那洞含石榴子石二云母花岗岩与错那洞穹隆的W-Sn-Be矿具有相邻的空间位置,两者之间可能存在一定的成因联系;而错那洞弱定向二云母花岗岩与扎西康Pb-Zn矿床在时间上和空间上都具有一致性,两者之间很可能也存在一定的成因联系。     

大兴安岭北段一脑丸地区花岗斑岩锆石U-Pb年代学及地球化学特征

大兴安岭北段一脑丸地区花岗斑岩锆石U-Pb年代学和地球化学特征研究结果表明该岩石的加权平均年龄为140.5±2.4 Ma,属早白垩世,同时含有较多中-晚三叠世的捕获锆石(223~232 Ma)。岩石的SiO_2含量为63.73%~64.35%,(K_2O+N_2O)为6.77%~7.31%,Al_2O_3含量为15.20%~15.40%,MgO含量和Mg#值分别为1.85%~2.01%和32~34,Fe_2O_3/FeO值为1.37~1.53,铝饱和指数(A/CNK值)为0.94~0.96之间,属于高钾钙碱性系列、准铝质I型花岗岩岩石。岩石的稀土总量相对较低(∑REE=110.37×10~(-6)~117.55×10~(-6)),轻重稀土元素分馏较高((La/Yb)N=22.39~31.72),Eu异常不明显(Eu/Eu*=0.91~1.07),富集轻稀土元素和Rb、K等大离子亲石元素,相对亏损重稀土元素和Nb、Ta、Ti、P等高场强元素,高Sr(515×10~(-6)~665×10~(-6)),低Y(6.73×10~(-6)~7.39×10~(-6)),具有埃达克岩性质。结合区域构造演化特征,认为该花岗斑岩起源于增厚下地壳部分熔融,应与蒙古—鄂霍茨克洋闭合后的陆陆碰撞造山作用有关。     

新疆西准噶尔阿克图约克花岗闪长岩地球化学特征、锆石LA-ICP-MS年龄及地质意义

阿克图约克花岗闪长岩富黑云母,具较高SiO_2(61.53%~67.01%),低里特曼指数(1.8~2.25),富钠贫钾,A/CNK小于1,稀土元素总量中等(∑REE=64.64×10~(-6)~76.12×10~(-6)),弱Eu亏损,富集大离子亲石元素(Th,K,Ba,LREE),亏损HREE和高场强元素(Ti,Ta,Nb,P),Nb/Ta小于1等特征。该岩体为钙碱性系列准铝质花岗闪长岩,并具I型花岗岩特征。岩体LA-ICP-MS锆石U-Pb年龄为(329.7±1.9)Ma,早于苏云河含矿岩体,为早石炭世洋壳俯冲背景下的火山弧花岗岩,暗示洋壳闭合时限晚于(329.7±1.9)Ma。     

新疆阿尔泰巴斯铁列克钨多金属矿区花岗质岩体年代学和地球化学特征及其对成矿的启示

巴斯铁列克钨多金属矿床位于新疆阿尔泰造山带南缘,是近年来在区内发现的首例中型钨多金属矿床。矿体主要产于二叠纪花岗岩与上志留统-下泥盆统康布铁堡组火山-沉积岩接触带的矽卡岩中。钨矿化与矿区花岗质岩石有明显的空间关系。然而,与钨矿化有关的花岗质岩石成因尚不清楚。本文对矿区出露的与矿化关系密切的黑云母花岗岩、二长花岗岩和二云母花岗岩进行了锆石U-Pb年代学和岩石地球化学研究。3个样品的LA-ICP-MS锆石U-Pb加权平均年龄分别为282.3±3.2Ma、284.3±2.2Ma和284.8±2.3Ma,属早二叠世岩浆活动的产物,与成矿年龄一致。所有岩石具有高硅(Si O_2=73.6%~78.3%)、富碱(K_2O+Na_2O=5.15%~9.62%)富钾(K_2O/Na_2O> 1.1)、贫钙(Ca O=0.19%~0.75%)和钛(Ti O_2=0.04%~0.24%)、弱过铝-强过铝质(A/CNK=1.01~1.39)特征。这些岩石稀土元素总量(∑REE)变化较大(变化于20.3×10^-6~328×10^-6),但二云母花岗岩显示轻重稀土元素分异不明显((La/Yb)N=0.96~2.06)、Eu强烈负异常(δEu=0.07~0.41)的深"V"型稀土元素分布特征,黑云母花岗岩和二长花岗岩显示轻稀土略富集((La/Yb)N分别为2.8~5.5和4.8~7.4)且Eu负异常(δEu=0.33~0.39和0.34~0.63)明显的右倾型稀土元素分布特征。所有样品均显示相对富集Rb、Th、U、Pb元素和相对亏损Nb、Ti、P、Sr、Ba元素,但二云母花岗岩中W含量(4.6×10^-6~9.4×10^-6)相对低于黑云母花岗岩和二长花岗岩中W含量(分别为15.1×10^-6~168×10^-6和8.4×10^-6~16.0×10^-6)。所有样品的锆石具有正的高εHf(t)值(+3.8~+11)和相对年轻的亏损地幔模式年龄(Hf的tDM2为0.60~1.0Ga)。以上特征说明,这些岩石属高钾钙碱性分异I-A过渡型花岗岩。结合区域地质背景,认为这些岩体是二叠纪时期后碰撞伸展环境下两个独立岩浆事件的产物,母岩浆均来源于新生地壳熔体与幔源岩浆,经过高度分异演化后结晶形成矿区岩石。花岗质岩浆活动为巴斯铁列克钨矿床提供了成矿物质,岩浆演化过程(结晶分异与熔体-流体作用)对成矿元素有富集作用。     

甘肃大佛寺、金佛寺花岗岩体的锆石U-Pb年龄、Hf-O同位素和全岩地球化学特征及地质意义

走廊过渡带大佛寺花岗岩为弱过铝质(A/CNK=1.03~1.06),SiO_2(76.7%~78.9%)、全碱(Na2O+K2O=7.7%~8.3%)、Rb(303×10~(-6)~383×10~(-6))、Nb(32×10~(-6)~42×10~(-6))、重稀土(Yb~8×10~(-6))含量以及和FeOT/MgO(6.3~7.6)、Ga/Al(3×10-4)、Rb/Ba(3.0~6.2)比值较高,MgO(~0.1%)、CaO(0.5%~0.6%)含量较低,Ba、Sr、Eu、Ti强烈亏损,属A型花岗岩,其源岩可能为泥质岩。大佛寺花岗岩中锆石δ18O和εHf(t)值分别为7.8‰~8.6‰(平均8.24±0.13‰)和-4.8~-2.0,Hf同位素两阶段亏损地幔模式年龄1540~1717Ma,岩浆温度达到~820℃以上。北祁连造山带北缘金佛寺花岗岩为过铝质(A/CNK=1.0~1.1),SiO_2(65.5%~75.0%)、MgO(0.6%~2.2%)、Fe2O3(1.9%~5.2%)、TiO_2(0.3%~0.8%)含量变化较大,其主量和微量元素特征与北祁连造山带的柴达诺花岗岩相似,源岩可能包括杂砂岩和角闪岩。金佛寺花岗岩的锆石δ18O为7.4%~9.7‰(平均8.03±0.36‰),εHf(t)在-0.5~+1.9之间,Hf同位素两阶段亏损地幔模式年龄为1289~1439Ma,岩浆温度达到800~900℃。走廊过渡带大佛寺花岗岩、北祁连造山带北缘金佛寺花岗岩的锆石U-Pb SIMS年龄分别为426.1±2.8Ma、424.0±1.6Ma,不同构造单元发育同时期岩浆活动以及A型花岗岩的出现,表明在~425Ma北祁连洋盆已经闭合,北祁连造山带及邻区进入到后碰撞拉伸阶段。     

新疆东准噶尔绿石沟高Ba-Sr石英二长岩的锆石U-Pb年龄、成因及地质意义

绿石沟岩体位于东准噶尔琼河坝矿集区,向东侵入到绿石沟铜矿赋矿围岩中泥盆统北塔山组火山岩中。LA-ICP-MS锆石U-Pb测年显示该岩体形成于354±1Ma,为早石炭世。其主要岩石类型为石英二长岩,含有大量的基性微粒包体,具有较高的硅、钙、钾含量(SiO_2=62.31%~65.31%,CaO=3.71%~4.89%,K_2O=2.85%~3.54%),属高钾钙碱性系列。铝含量较高(Al_2O_3=15.44%~16.29%),属准铝质(A/CNK=0.93~0.99,A/NK=1.68~1.96)Ⅰ型花岗岩。稀土元素总量较低(ΣREE=90.82×10~(-6)~111.36×10~(-6)),轻稀土元素相对富集,Eu呈弱的负异常(δEu=0.68~0.87)。富集大离子亲石元素(K、Rb、Ba、Sr等),亏损高场强元素(Nb、Ta、P、Ti等),具有高Ba(758×10~(-6)~1113×10~(-6))、Sr(401.8×10~(-6)~512.5×10~(-6))含量和高的(La/Yb)_N、Sr/Y值,显示出高Ba-Sr花岗岩的特征,应是幔源基性岩浆与壳源岩浆混合的产物,可能形成于俯冲环境向造山后环境的构造转换阶段。     

冈底斯南缘变形花岗岩锆石U-Pb年龄和Hf同位素组成：新特提斯洋早侏罗世俯冲作用的证据

本文对产于冈底斯南缘一个变形花岗岩进行了主量元素、微量元素、原位锆石 LA-ICP-MS U-Pb 定年和锆石 Hf 同位素组成研究。结果表明,变形花岗岩为高硅(SiO_2=73.38%～76.06%)钙碱性岩系,K_2O/Na_2O=0.69～1.17,铝指数(A/CNK)=1.03～1.07,为弱过铝质岩石。变形花岗岩微量元素组成显示贫大离子亲石元素(e.g.Rb=47×10~(-6)～71×10~(-6))和高场强元素(e.g.Nb=1.3l×10~(-6)～3.09×10~(-6),Ta=0.23×10~(-6)～0.54×10~(-6)),具有岛弧型花岗岩的地球化学属性。变形花岗岩锆石 U-Pb 年龄为178±1Ma,该年龄代表岩浆结晶年龄。锆石 Hf 同位素组成显示ε_(Hf)(178Ma)值变化于 14.1～ 17.7,表明变形花岗岩岩浆来自初生地壳物质的部分熔融。变形花岗岩的岩石成因与新特提斯洋向欧亚板块南缘的俯冲消减作用存在联系,其岩浆结晶年龄反映了新特提斯洋发生俯冲消减的开始时代不晚于早侏罗纪,说明了新特提斯洋经历了较长时间的演化。     

塔里木克拉通北部沙雅隆起古元古代A型花岗岩的发现及其构造意义

本文对塔里木克拉通北部沙雅隆起桥古2井(QG2)基底碱长花岗岩进行了岩石学、锆石U-Pb年代学和元素地球化学分析。LA-ICP-MS锆石U-Pb定年结果显示其形成时代为1847±19Ma,为古元古代晚期。岩石SiO_2=66.32%~76.39%,Na_2O+K_2O=7.13%~8.93%,Al2O3=11.21%~13.46%,FeO~T/Mg O=12.1~19.2,TiO_2=0.29%~0.57%,A/CNK=0.89~0.99,为高硅、富碱、富铁、低钙镁、贫钛的准铝质花岗岩。稀土元素总量相对较低(∑REE=64.4×10~(-6)~212.7×10~(-6)),轻稀土元素富集,(La/Yb)_N=10.2~13.8,轻重稀土元素分馏较明显,δEu值为0.67~1.03,富集Rb、Ba、Th、U等大离子亲石元素和Zr、Hf等高场强元素,亏损Sr、P、Ti、Ta、Nb等元素。锆石饱和温度介于856~959℃之间,Ga/Al比值高,显示A型花岗岩特征。岩石具有低Y、Yb、∑HREE、(La/Yb)N和Mg~#值及较高的Nb/Ta、Zr/Sm比值,推测岩浆源区为含有石榴石、斜长石、金红石、辉石等的麻粒岩相,岩浆的形成可能与加厚地壳的部分熔融有关。QG2井A型花岗岩可能代表了塔里木克拉通北部古元古代晚期(约1850Ma)造山期地壳增厚事件的结束,指示了区域构造环境从挤压体制开始转为造山后陆内伸展体制。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。