Palynological studies on manganese ore layers in Úrkút (Transdanubia), Hungary

Samples of manganese carbonate and oxide layers from the Úrkút ore deposit were investigated for organic remains, especially for spores and pollen grains. Light (LM), Transmission Electron (TEM), and Scanning Electron Microscopy (SEM) methods were used. LM revealed several new sporomorph taxa; a microstratigraphic standard was established by reconstructing vegetation zones surrounding the sedimentary basin. Index fossils of palynomorphs and the relative abundance of other taxa support a Liassic (Lower Jurassic) age for these layers. TEM data were used to establish: (1) important new understanding about the phylogeny of the pollen-exine ultrastructure and, in particular, the tectate columellar ectexine of the Mesozoic gymnospermous pollen grain, Spheripollenites; and (2) the degree of destruction of the exine ultrastructure helps to reconstruct taphonomical processes during sedimentation and to unravel biopolymer-type molecular structures in the walls of palynomorphs. The SEM method aided in the taxonomy of the microfossils. Combined TEM and SEM methods revealed that submicroscopic surface degradation may be a consequence of bio-degradation during deposition of manganese ore.     

Sequence architecture and carbonate platform configuration (Late Cenomanian–Santonian), Sinai, Egypt

Abstract Relative sea‐level changes on the mixed carbonate–siliciclastic platform of Sinai are manifested in shifts of distinct facies belts (deep‐water facies, high‐energy subtidal, shallow subtidal, lagoon, shallow shoreface siliciclastics, supratidal) and are interpreted in terms of sequence stratigraphy. Eight sedimentary sequences are recognized for the Upper Cenomanian to Santonian. Their correlation along a north–south transect reveals distinct changes in lithofacies and progradation/retrogradation patterns within the individual systems tracts. The number and stratigraphy of the sequence boundaries of Sinai correlate well with those from adjacent areas. Patterns of increased subsidence are documented for the Central Sinai Basin since the Late Cenomanian by increased thickness of the stratal packages (post‐CeSin 7 HST, post‐TuSin 1 LST and HST, post‐TuSin 2 LST) and are balanced by varying accumulation rates. Based on new sedimentological and biostratigraphic data, large‐scale palaeogeographic maps and cross‐sections show the: (1) temporal and spatial evolution of the Central Sinai Basin, e.g. its latest Cenomanian initial formation, Lower Turonian deep‐water facies, Middle Turonian to Coniacian synsedimentary subsidence; (2) drowning of the Cenomanian platform coinciding with the latest Cenomanian to Early Turonian relative sea‐level rise; (3) re‐establishment of the platform in Middle–Late Turonian times; and (4) a Coniacian basin and swell morphology.     

Modelling the sorption of Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) on montmorillonite: Linear free energy relationships and estimates of surface binding constants for some selected heavy metals and actinides

In solution thermodynamics, and more recently in surface chemistry, it is well established that relationships can be found between the free energies of formation of aqueous or surface metal complexes and thermodynamic properties of the metal ions or ligands. Such systematic dependencies are commonly termed linear free energy relationships (LFER). A 2 site protolysis non-electrostatic surface complexation and cation exchange (2SPNE SC/CE) model has been used to model “in house” and literature sorption edge data for eleven elements: Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) to provide surface complexation constants for the strong sites on montmorillonite. Modelling a further 4 sets of sorption isotherms for Ni(II), Zn(II), Eu(III) and U(VI) provided complexation constants for the weak sites. The protolysis constants and site capacities derived for the 2SPNE SC/CE model in previous work were fixed in all of the calculations. Cation exchange was modelled simultaneously to provide selectivity coefficients. Good correlations between the logarithms of strong ^SK_x−1 and weak ^W1K_x−1 site binding constants on montmorillonite and the logarithm of the aqueous hydrolysis constants ^OHK_x were found which could be described by the following equations: Strong (≡S^SOH) sites:

SlogKX−1=8.1±0.3+(0.90±0.02)log^OHKX     

A Primary Observation on Palynofacies of the Chuangde Section (Late Jurassic-Cretaceous), Gyangzê, Southern Tibet

A primary study on palynofacies, which concerns the paleoenvironments from the sight of association of sedimentary organic matter preserved in sedimentary rocks, is conducted for a Late Jurassic-Cretaceous succession at Gyangzê, southern Tibet. Two palynofacies are recognized, which are formed in different sedimentary environments. The one in the pelagic is infertile in organic productivity and monotonous in component and is dominated by AOMA, while the other, being closely bound up with the slope, is characterized by abundant black phytoclasts that are possibly of algal origin and contains much AOM. The influence of terrestrial input is clear in the latter, for particles generated from terrestrial plants are common. A number of fossil spores and pollen together with some dinocysts are discovered, but they are normally in a bad condition of preservation. Nevertheless, this convinces us that the late Jurassic-Cretaceous succession in the Gyangzê area has a potential for palynological stratigraphy. We have also proved that the volume of PM can achieve similar results in presenting the productivity of organic matter as the weight of TOC does. This technique is much easier in the laboratory than that we do with TOC.     

Fish remains from Arbreda Cave (Serinyà, Girona), northeast Spain,and their palaeoecological significance

This paper presents the study and palaeoecological analysis of fossil fish vertebrae of the Arbreda Cave (Serinyà, Girona), probably the most significant Catalan palaeolithic site. Morphological and radiographical studies were used to identify vertebrae to genus and, whenever possible, to species level. The taxa identified are: Anguilla anguilla, Barbussp., Leuciscussp., Rutilus sp., Salmo salar, Salmo trutta and Salmo sp. Species distribution at various archaeological levels provided palaeoecological data. There is a high proportion of Salmo trutta remains in the Upper Gravettian level and a sudden decrease of fossil fish bones in the Solutrean level with shouldered points. This decrease coincides with the period of lower temperatures of the Late Pleniglacial. Finally, the post-glacial terra rossa level is characterised by the absence of Salmo trutta remains. The presence of Salmo salar in Mediterranean sites has often been discussed. However, the dating of remains of this Atlantic species found in the Arbreda Cave makes it likely that these specimens were caught in Atlantic rivers on the northern Pyrennean slope and then transported to the area studied. © 1997 John Wiley and Sons, Ltd.     

Roamerella,a new name for the genus Roemerella Akopyan in (Mollusca,Gastropoda; Upper Cretaceous), preoccupied by Roemerella (Brachiopoda,Lingulata; Devonian)

The Late Cretaceous (Turonian–Campanian) turritellid gastropod Roemerella Akopyan in Akopyan et al., 1990, is a junior homonym of the Devonian inarticulate brachiopod Roemerella Hall and Clarke, 1890. The generic name Roamerella nom. nov. is proposed for the homonymous gastropod.     

Petrogenesis of extension-related alkaline volcanism in Karaburhan (Sivrihisar–Eskisehir), NW Anatolia, Turkey

Alkaline lavas were erupted as phonolites and trachytes around Karaburhan (Sivrihisar–Eskisehir, NW Anatolia) within the Izmir–Ankara–Erzincan suture zone. These volcanic rocks were emplaced as domes, close and parallel to the ophiolite thrust line. According to ⁴⁰Ar/³⁹Ar geochronological analyses of sanidine crystals from the phonolites, the age of the alkaline volcanics is 25 Ma (Late Oligocene–Early Miocene).The flow-textured phonolites are porphyritic and consist mainly of sanidine, clinopyroxene, and feldspathoid crystals. The clinopyroxenes show compositional zoning, with aegirine (Na_0.82–0.96Fe⁺³_0.68–0.83) rims and aegirine–augite cores (containing calcium, magnesium, and Fe⁺²). Some aegirine–augites are replaced with sodium-, calcium-, and magnesium-rich amphibole (hastingsite). Feldspathoid (hauyne) crystals enriched with elemental Na and Ca have been almost completely altered to zeolite and carbonate minerals. The fine-grained trachytes with a trachytic texture consist of feldspar (oligoclase and sanidine) phenocrystals and clinopyroxene microphenocrystals within a groundmass made up largely of alkali feldspar microlites.Although there are some differences in their element patterns, the phonolites and trachytes exhibit enrichment in LILEs (Sr, K, Rb, Ba, Th) and LREEs (La, Ce, Pr, Nd) and negative anomalies in Nb and Ta. These geochemical characteristics indicate a lithospheric mantle enriched by fluids extracted from the subduction component. In addition, the high ⁸⁷Sr/⁸⁶Sr (0.706358–0.708052) and low ¹⁴³Nd/¹⁴⁴Nd (0.512546–0.512646) isotope concentrations of the alkaline lavas reflect a mantle source that has undergone metasomatism by subduction-derived fluids. Petrogenetic modeling indicates that the alkaline lavas generated from the subduction-modified lithospheric mantle have undergone assimilation, fractional crystallization, and crustal contamination, acquiring high Pb, Ba, Rb, and Sr contents and Pb isotopic compositions during their ascent through the thickened crust in an extensional setting.     

Origin of post‐Minoan caves and volcaniclastic cave fill,Thera (Santorini), Greece

The Aegean island of Thera (Santorini) was covered by tephra from its cataclysmic Late Bronze Age (ca. 3600 yr B.P.) eruption. Vertical exposures of the eruptive sequence show secondary, nonvolcanic, circular (in cross section) features composed of stratified sediment. Many are inaccessible from the floors of modern quarries and appear to be caves filled with younger sediment, but show no connection to the land surface. A filled cave was found in the wall of a modern gully outside the modern quarries, and a filled cave was found in a terrace scarp, well above the modern gully. Natural (and probably rapid) incision by gullies into the thick tephra deposit left many locations with lateral access to tephra. Inhabitants from post‐Minoan to recent times excavated tephra for materials and buildings, and caves were subsequently filled by sporadic (possibly seasonal) flood events that deposited sediment. These gullies may have provided access for modern tephra removal that isolated the filled caves high on the modern quarry walls. © 2003 Wiley Periodicals, Inc.     

Composition and origin of stromatactis‐bearing mud‐mounds (Upper Devonian,Frasnian), southern Rocky Mountains,western Canada

Stromatactis‐bearing mud‐mounds remain an enigmatic reef type despite being common in Palaeozoic ramp settings. Two well preserved Upper Devonian (Frasnian) mud‐mounds in the Mount Hawk Formation crop out side by side in the southern Rocky Mountains of west‐central Alberta and provide an opportunity to develop a new case study that can be compared with the other coeval examples, such as those well‐known ones in southern Belgium, as well as evaluate competing hypotheses for mud‐mound formation. The southern mud‐mound is 46·2 m thick and 38·6 m wide at the base, whilst the northern one is 53·3 m thick and 72·2 m wide at the base, and they exhibit three or four growth stages indicated by interfingering and onlapping geometries with flanking strata. The biota is diverse, but fossils only occupy 10·7% by volume, among which sponge spicules, echinoderms, ostracods, brachiopods and calcimicrobes belonging to Girvanella and Rothpletzella are the most common. Five microfacies are discriminated in the mud‐mounds: biomicrite, clotted micrite, spiculite, stromatolite and laminite, with clotted micrite comprising the largest proportion. There is no internal vertical or lateral palaeoecological zonation, and the presence of calcimicrobes and calcareous algae throughout indicates accretion entirely within the photic zone, in a deeper ramp setting seaward of a large carbonate platform to the east. Stromatactis is abundant and the cavities were mostly due to excavation by currents rather than physical collapse of spiculate siliceous sponges. Formation of lime mud involved a combination of multiple organisms, mechanisms and processes. Cyanobacteria were integral to mud‐mound frame‐building and accretion because they stabilized the surface, often permineralized to form Girvanella and provided organic matter that was decomposed by bacteria. This induced precipitation of micrite, forming early indurated rigid masses, evidenced by the presence of intraclasts, stromatactis cavities, isopachous marine cements, absence of bioturbation and rare synsedimentary brittle deformation. The same microbial components, invertebrate biota and clotted micrite occur in underlying strata, suggesting that there was a protracted period of potential mud‐mound initiation before the exact conditions arose to trigger it. The ramp setting, antecedent sea floor topography and relative sea‐level likely contributed together to control this. This study indicates that mud‐mound formation was controlled by a combination of processes, but they are essentially a microbial buildup.     

Controls on synorogenic alluvial-fan architecture, Beartooth Conglomerate (Palaeocene), Wyoming and Montana

Late Palaeocene uplift of the Beartooth Range in northwestern Wyoming and southwestern Montana generated the Beartooth Conglomerate along the eastern and northeastern flanks of the range. Systematic unroofing sequences and intraformational unconformities, folds, and faults in the conglomerate attest to deposition during uplift. Along the eastern flank, at least three ancient alluvial-fan systems and a braidplain system can be distinguished on the bases of petrofacies and lithofacies. The two southern fans consist of 700+ m of sedimentary-clast conglomerate and subordinate sandstone, dominated by hyperconcentrated-flow and stream-flow facies. The next fan to the north is dominated by plutonic and metamorphic clasts and contains abundant mud-matrix-supported debris-flow facies, as well as stream-flow facies. The northernmost depositional system consists of arkosic, channellized fluvial conglomerate and sandstone, overbank mudstone, and crevasse-splay sandstone units. Palaeocurrent data indicate eastward dispersal, away from the Beartooth Range. Outstanding exposure of the Beartooth Conglomerate allows facies to be mapped on lateral photographic mosaics. A seven-fold hierarchy of bounding surfaces and enclosed lithosomes exists in the Beartooth Conglomerate. First- through fourth-order surfaces are analogous to first- through fourth-order surfaces that recently have been documented in sandy fluvial facies, with one exception: sediment gravity flows are bounded by first-order surfaces. Fifth-order surfaces are either erosional (e.g. lateral migration of fanhead trench) or accretionary (e.g. aggradation of fan surface during backfilling of trench, and construction of lobes on lower fan during entrenchment on upper fan). Some fifth-order surfaces coincide with intraformational angular unconformities and are thus the result of long-term fanhead entrenchment following uplift of the upper part of the fan. Sixth-order surfaces bound individual fan packages that are several hundred metres thick and ～ 10 km² in area. The enclosed sixth-order lithosomes are distinguishable in terms of petrofacies and lithofacies. A single seventh-order surface bounds the entire Beartooth Conglomerate. Lower-order lithosomes are produced by intrinsic processes of fan construction. Fifth-order lithosomes can be attributed to both extrinsic and intrinsic controls. Sixth- and seventh-order lithosomes are generated by extrinsic controls.     

Euthecosomatous gastropods (Mollusca: Heterobranchia) from Buton (SE Sulawesi,Indonesia), with notes on species from Viti Levu,Fiji; systematics,biostratigraphy

Geologie en Mijnbouw - Pteropoda (Mollusca, Gastropoda, Euthecosomata) described by Beets (1943, 1950, 1953) from the alleged Late Miocene/Early Pliocene asphaltic deposits of Buton (SE Sulawesi,...     

Mineral chemistry,crystallization conditions and magma mixing‐mingling at Orduzu volcano (Malatya), Eastern Anatolia,Turkey

The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd.