Discussion on origin of clay minerals in outcropped sandstone from Lower Cretaceous Chengzihe Formation and Muling Formation in Jixi Basin

Clay minerals in the outcropped sandstone from Lower Cretaceous Chengzihe Formation and Muling Formation in Jixi Basin were analyzed by X-ray diffraction. The results show that the clay minerals mainly consist of illite, kaollinite and illite/smectite, which can be divided into two types: kaolinite- and illite/smectite types. The outcropped sandstone occurred in middle diagenetic stage-A on the basis of the clay mineral composition. The development factor of the formation of kaolinite type clay mineral is caused mainly by the organic acid from the coal-bearing formation and mudstone during the diagenesis process in Lower Cretaceous Chengzihe Formation and Muling Formation in the Jixi Basin. The weak hydrodynamic force of sedimentary facies made the sandstone leaching condition poor, which is the reason forming the aggregation of clay minerals of the illite/smectite-and illite types.     

Discussion on origin of clay minerals in outcropped sandstone from Lower Cretaceous Chengzihe Formation and Muling Formation in Jixi Basin

Clay minerals in the outcropped sandstone from Lower Cretaceous Chengzihe Formation and Muling Formation in Jixi Basin were analyzed by X-ray diffraction. The results show that the clay minerals mainly consist of illite, kaollinite and illite/smectite, which can be divided into two types： kaolinite- and illite/smectite types. The outcropped sandstone occurred in middle diagenetic stage-A on the basis of the clay mineral composition. The development factor of the formation of kaolinite type clay mineral is caused mainly by the organic acid from the coal-bearing formation and nmdstone during the diagenesis process in Lower Cretaceous Chengzihe Formation and Muling Formation in the Jixi Basin. The weak hydrodynamic force of sedimentary facies made the sandstone leaching condition poor, which is the reason forming the aggregation of clay minerals of the illite/ smectite-and illite types.     

乌石东区成岩演化数值模拟与孔隙度预测

乌石东区已发现的商业性油田主要形成于复杂陆相沉积环境, 受构造、沉积和成岩作用综合影响, 储层非均质性强, 油藏渗流特征复杂, 直接影响着油田的开发方案制定。因此, 有必要开展储层物性主控因素分析, 从理论上和技术上实现甜点区预测。研究采用成岩数值模拟的方法, 基于成岩环境参数, 应用化学动力学模型, 通过对镜质组反射率、古地温、伊/蒙混层中蒙皂石层含量和石英自生加大的模拟, 加权平均得到成岩指数。根据成岩指数的变化对储层成岩阶段及孔隙度横向展布规律进行预测。模拟结果表明, 乌石东区成岩阶段主要为中成岩A1-A2期, 凹陷中心成岩作用较强, 向北逐渐减弱。综合沉积、成岩等认识, 建立孔隙度预测模型, 对孔隙度进行平面预测, 预测结果表明: 顺物源方向, 随埋深增大, 储层物性变差, 同成岩作用变化趋势一致。      

基岩区断层泥的物质组成、定年方法与地震断层弱化机制研究进展

断层泥作为脆性断层活动的产物,是厘定断层的变形特征、形成时代与弱化机制的重要研究对象,在构造地质和地震地质等研究中具有重要意义。因此,全面了解断层泥的研究与进展,有助于基岩区古地震的研究。在系统收集和分析国内外相关资料的基础上,全面介绍了断层泥的矿物组成、石英形貌特征、定年方法与地震断层弱化机制等方面的研究进展,以及断层泥在基岩区地震断层研究中的应用。断层泥主要由黏土矿物(蒙脱石、伊利石、高岭石以及绿泥石等)与围岩矿物的碎粉和碎砾(石英、长石、云母、方解石、白云石等)组成。断层泥中的石英、伊利石与方解石是限定断层活动期次和形成时代的主要测试对象。目前断层泥定年方法主要包括石英微形貌特征分析法、石英ESR和OSL定年法、伊利石K-Ar或40Ar/39Ar定年法和方解石U-Pb定年法。地震断层的弱化机制研究主要涉及断层泥中矿物细粒化与新矿物形成、岩石组构的发育、断层摩擦生热、熔体形成与热增压等方面。      

The Sources and Transport Patterns of Modern Sediments in Hangzhou Bay: Evidence from Clay Minerals

Clay mineral compositions of 199 offshore surface sediment samples collected from the Hangzhou Bay have been analyzed. The clay minerals in the sediments from the Hangzhou Bay are dominated by illite(58.7%, on average), followed by chlorite(20.3%), kaolinite(16.9%) and smectite(4.1%). Two provinces were classified by Q-mode cluster analysis. Class Ⅰ with relatively low amounts of illite and smectite is widely distributed in the Hangzhou Bay, especially concentrated in the top and mouth of the bay, and the northern and southern nearshore areas. Class Ⅱ with comparatively high amounts of illite and smectite is mainly concentrated in the central part of the bay with the water depth of 8–10 m. By comparing clay mineral compositions with the neighbouring regions, we can find that the sediments in the Hangzhou Bay are mainly influenced by the resuspension and repeated deposition of particles from the Yangtze River due to the strong dynamic environment. In particular, the clay fraction of Class Ⅰ is mainly supplied by the Yangtze River, while the sediments of Class Ⅱ are mixture of the clay minerals carried by the Yangtze River and Qiantang River. In general, the distributions of clay minerals in the northern bay are affected by Yangtze River runoff, coastal current and flood tide together, and in the southern they are mainly affected by the Qiantang River runoff and ebb tide.     

鄂尔多斯盆地中部延长组下组合流体包裹体特征和油气充注期次

通过对储层成岩作用、流体包裹体岩相学和孔隙沥青特征的分析,在烃包裹体期次划分的基础上,结合流体包裹体均一温度特征、烃源岩热演化史、地层埋藏史和储层成岩史,确定了鄂尔多斯盆地中部延长组下组合油气充注期次。结果表明:鄂尔多斯盆地中部延长组长8段和长9段致密储层主要发育压实、胶结、交代和溶解4种成岩作用,自生矿物主要为绿泥石、石英胶结物、长石胶结物和方解石胶结物。根据包裹体宿主矿物形成序列,识别出3期烃包裹体。第一期烃包裹体分布在石英愈合缝、石英次生加大边和充填孔隙的石英胶结物中,少数低成熟的黄色荧光烃包裹体及黑色荧光沥青包裹体代表了烃源岩进入生烃门限后排出的少量烃类充注,多数成熟度较高的蓝色、蓝白色荧光烃包裹体代表了生烃高峰期大量烃类充注;第二期烃包裹体分布在长石胶结物中,数量较少,显示蓝色和蓝白色荧光,在溶蚀孔隙周围或沿解理分布,呈短柱状,边界平直;第三期烃包裹体分布在方解石胶结物中,呈孤立或零星分布,形状近六边形;后两期烃包裹体均是在烃类充注结束后捕获孔隙中烃类形成的。研究区延长组长8段和长9段经历了晚侏罗世末期至早白垩世末期的一期烃类持续充注。     

Features of clay minerals in the YSDP102 core on the continental shelf of the southeast Yellow Sea

Ninety-eight clay mineral samples from the YSDP102 core were analyzed by x-ray diffractometer to study the four clay minerals: illite, chlorite, kaolinite and smectite. Twenty-eight samples had been analyzed on the laser particle-siz eanalyzer to reveal the particle features of the sediments. Distribution of the clay minerals and the particle characteristics in the YSDP102 core show that the core experienced three different depositional periods and formed three different sedimentary intervals due to different sediment sources and different depositional environments. Features of the clay minerals and the heavy minerals in the YSDP102 core indicate that coarse-grained sediments and fine-grained sediments result from different sources. The Yellow Sea Warm Current has greatly influenced the sedimentary framework of this region since the current‘s formation.     

The Mineral Composition and Sources of the Fine-Grained Sediments from the 49.6°E Hydrothermal Field at the SWIR

We used the X-ray diffraction method to determine systematically the mineral phases in bulk sediment samples and acid undissolved residuals of the fine-grained fraction of the surface sediments from the 49.6°E hydrothermal field at the Southwest Indian Ridge(SWIR)and discussed the mineral sources of the surface sediments.The results showed that the surface sediments in this region were composed of calcareous ooze,and calcite was the dominant mineral.The sediments also contained quartz,feldspar,clay minerals,pyroxene,sphalerite,barite,serpentine,and magnetite.The quartz,feldspar,and clay minerals were exogenous minerals that mainly originated from the Namib and Kalahari deserts in southern Africa.The pyroxene,serpentine,magnetite,sphalerite,calcite,and barite were endogenous minerals from weathering of seafloor basement rocks and seafloor hydrothermal activities.The sulfide particles in the sediments were mainly deposited from upwelling plumes.     

Diagenetic Sequences Analysis of Fuyu Reservoir in

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Diagenetic Sequences Analysis of Fuyu Reservoir in Qijia - Gulong Depression, Northern Songliao Basin

Five paragenetic associations are recognized in Fuyu reservoir of Qijia - gulong depression of Daqing oil field: 1 )detrital illite permeation, glauconite and pyrite precipitation; 2 ) feldspar dissolution, kaolinite precipitation and the incipient quartz overgrowths; 3 ) early calcite cements; 4 ) postdate quartz overgrowths and pore - filling quartz, authigenetic illite and chlorite formation, feldspar overgrowths, petroleum injections, K - feldspar and calcite cement dissolution; 5) pore - filling calcite and calcite replacement.     

Diagenetic Sequences Analysis of Fuyu Reservoir in Qijia-Gulong Depression,Northern Songliao Basin

Five paragenetic associations are recognized in Fuyu reservoir of Qijia - gulong depression of Daqing oil field: 1) detrital illite permeation, glauconite and pyrite precipitation; 2) feldspar dissolution, kaolinite precipitation and the incipient quartz overgrowths; 3) early calcite cements; 4) postdate quartz overgrowths and pore - filling quartz, authigenetic illite and chlorite formation, feldspar overgrowths, petroleum injections, K - feldspar and calcite cement dissolution; 5) pore - filling calcite and calcite replacement.     

Assemblage characteristics of clay minerals and its implications to evolution of eolian dust input to the Parece Vela Basin since 1.95 Ma

To understand the provenance and evolution of eolian input in the last 1.95 Ma in the Parece Vela Basin in the eastern Philippine Sea, the clay mineral assemblage of a gravity core PV090510 from the basin was investigated using paleogeomagnetic dating and X-ray diffraction. The assemblage of the core mainly consisted of smectite （-46%） and illite （-40%）, with some chlorite （-10%） and kaolinite （-4%）. Analysis of the provenance of these minerals suggested that smectite was mainly derived from volcanic rocks of the Mariana Arc, while illite, chlorite, and kaolinite were mainly transported as eolian dust by the East Asian monsoon from central Asia. We used the ratio of （illite＋chlorite＋kaolinite）/smectite as a proxy for Asian eolian input to the Parece Vela Basin since 1.95 Ma. This ratio followed glacial and interglacial cycles and was consistent with the intensity of the East Asian monsoon and aridity of central Asia since 1.95 Ma. The changes of the ratio reflected three different stages of the East Asian monsoon and provenance climate.     

Clay mineral distribution in surface sediments of the South China Sea and its significance for in sediment sources and transport

Clay minerals of surface sediments in the South China Sea (SCS) are analyzed with X-ray diffraction, and their transport is explored with a grain size trend analysis (GSTA) model. Results show that clay mineral types in various sedimentary environments have different sediment sources and transport routes. Sediments in the northern SCS (north of 20°N) between the southwest of Taiwan Island and the outer mouth of the Pearl River have high contents of illite and chlorite, which are derived mainly from sediments on Taiwan Island and/or the Yangtze River. Sediments from the Pearl River are characterized by high kaolinite and low smectite content, and most are distributed in the area between the mouth of the Pearl River and northeast of Hainan Island and transported vertically from the continental shelf to the slope. Characterized by high illite content, sediments from Kalimantan Island are transported toward the Nansha Trough. Sediments from Luzon Island are related with volcanic materials, and are transported westwards according to smectite distribution. On the Sunda Shelf, sediments from the Mekong River are transported southeast in the north while sediments from the Indonesian islands are transported northward in the south. Ascertaining surface sediment sources and their transport routes will not only improve understanding of modern transportation and depositional processes, but also aid paleoenvironmental and paleoclimatic analysis of the SCS.     

青藏高原东北缘尖扎盆地沉积物矿物特征及其古环境意义

应用X射线衍射对青藏髙原东北缘尖扎盆地加让剖面11.8~5.8 Ma的地层沉积物进行矿物分析,结果表明加让剖面沉积物矿物组分主要包括碎屑矿物、碳酸盐矿物和黏土矿物。其中,以碎屑矿物居多,主要是石英、斜长石、云母类矿物(白云母、黑云母),及少量尖晶石、辉石类矿物(普通辉石、锰钙辉石及顽火辉石等)、金红石、刚玉、磁铁矿、钛磁铁矿、榍石、霞石,偶见锆石、石榴子石、锐钛矿;碳酸盐矿物以方解石居为主,白云石占比较少;黏土矿物中,绿泥石占比最高,还有少量赤铁矿、蛭石和沸石。以全岩矿物指标研究为主,结合加让剖面沉积相演化特点,并以磁化率变化为参考,进行系统的矿物学研究,获得了尖扎盆地在11.8~5.8 Ma蕴含的古气候环境演化大致可分为4个阶段:11.8~10.0 Ma,气候干冷期;10.0~8.6 Ma,气候暖湿波动期;8.6~6.2 Ma,气候温暖湿润期;6.2~5.8 Ma,气候干冷期。在约10.0、8.6、7.2 Ma附近,主要矿物占比及组合特征有明显改变,当时的古环境状况发生急剧变化,可能揭示青藏高原东北缘在10~8 Ma期间广泛发生了一系列较强烈的构造运动,来源于周边山脉的剥蚀使得研究区沉积的近源物质增多,约7.2 Ma之后的古环境演化过程主要受青藏高原构造隆升以及全球气候变冷协同影响。     

Provenance of Sediments Filling a Paleo-Channel that Formed on the Western Yellow Sea Continental Shelf During the Last Glacial Period

Several buried paleo-channels are located on the continental shelf of the western Yellow Sea. Research on the paleochannels is significant for both theoretical studies and practical applications. In this paper, we analyse and discuss the mineralogy of sediments in a core (SYS-0803) recovered from a buried paleo-channel on the continental shelf of the western Yellow Sea. The aim is to determine the provenance of sediments that fill the paleo-channel. The heavy mineral assemblage of sediments in the core consists of schistose minerals, common hornblende, epidote, and ilmenite. The light mineral assemblage consists of plagioclase, quartz, lithic fragments, and K-feldspar. Analysis of the compositional maturity of the sand fraction revealed a quartz/feldspar ratio of < 1. A relatively high percentage of smectite is recorded throughout the entire paleo-channel fill, with the greatest percentage in the middle to lower parts. The detrital mineral assemblage and clay mineral content indicate that the paleo-channel sediments were sourced mainly from the Huanghe River during the last glacial period.     

湘中涟源凹陷下石炭统天鹅坪组页岩气成藏条件及主控因素

下石炭统天鹅坪组页岩是湘中地区页岩气勘探的新层系。基于野外地质调查、页岩气钻井的样品采集和分析测试等对湘中涟源凹陷石炭系天鹅坪组泥页岩的发育特征、有机地球化学特征、储层特征和含气性等页岩气成藏地质条件进行了分析。结果表明:涟源凹陷石炭系天鹅坪组有机质丰度较高,w（TOC）分布在0.78%~2.84%之间,有机质类型以Ⅱ₁型为主,有机质成熟度R_o分布在1.48%~2.09%之间,处于高成熟演化阶段;泥页岩矿物成分以石英和黏土矿物为主,黏土矿物主要由伊蒙混层、伊利石和绿泥石组成;泥页岩有机质孔较发育,孔隙度平均为1.97%,渗透率平均为0.847×10-3 μm2,但大多小于0.1×10-3 μm2;湘新地4井天鹅坪组泥页岩含气量分布在1.64~4.29 m3/t,平均2.69 m3/t（不含残余气）。结合区域构造-沉积演化背景的分析表明,涟源凹陷下石炭统天鹅坪组页岩气成藏条件的主控因素为沉积环境、构造保存条件,其中深水陆棚相是页岩气有利相带,复杂构造背景下由对冲式构造样式形成的向斜对页岩气保存条件最为有利,是研究区页岩气勘探的"甜点区"。研究成果可以为该区后续油气勘探提供参考。      

鄂尔多斯盆地中部马五~4亚段成岩作用及储集性能

鄂尔多斯盆地中部下奥陶统马家沟组第五段第四亚段（马五４亚段）储层经历了成岩环境为海底、早期大气淡水、浅埋、表生大气淡水和埋藏环境．控制孔隙演化的主要成岩作用是准同生白云石化、溶解、破裂和充填作用。储层孔隙类型多样，非均质性强，受控于岩相和成岩作用，尤其是表生溶解作用．     

CO2基增强型地热系统中流体-花岗岩相互作用研究进展及展望

CO₂与水相比,膨胀性大、黏度低、与岩石反应程度低,并且在作为增强型地热系统（EGS）渗流传热流体时,比水具有更高的换热效率。对CO₂-EGS生产过程中储层岩石物性变化的研究具有重要意义,从理论研究、实验研究、数值模拟3个方面,对CO₂基增强型地热系统CO₂-EGS中流体-岩石相互作用的研究现状进行了总结,并且从矿物成分、微观孔结构和力学性质3个方面对储层岩石性质的变化进行了评价。结果表明,CO₂-水-岩石相互作用参与反应的矿物主要为石英、长石类;而沉淀的矿物为蒙脱石、伊利石及方解石等。CO₂-水-岩石相互作用会导致储层岩石的力学性质下降,孔隙结构特征改变。最后,讨论了CO₂作为EGS渗流传热流体仍需攻克的难点问题,包括:CO₂的热动力学特征、换热效率,CO₂-水-岩石的相互作用及其对储层性质的改变,影响CO₂-EGS经济性的因素,以及CO₂-EGS数值模型的研究等。针对这些方面的研究可为今后CO₂-EGS的开发奠定基础。      

渝东石柱地区龙马溪组页岩纤维状脉体成因

渝东石柱地区志留系龙马溪组页岩地层发育特殊的纤维状方解石脉体。为揭示其流体来源及形成机理，结合岩石学及地球化学特征等开展系统分析。研究表明，纤维状方解石脉（FCV）以顺层或近平行层面充填于黑色粉砂质页岩和泥质粉砂岩微裂缝中，脉体宽0.1~4.0 cm、横向延伸一般为0.5~8.0 m。纤维状方解石晶体以柱状、纤维状垂直裂缝壁生长为主，多与石英共生产出。晶体表面洁净，局部见方解石压力影、机械双晶及晶体间锯齿状晶界。阴极发光下纤维状方解石呈暗红色-橘红色；碳-氧同位素分析表明δ13C_PDB略偏负、δ18O_PDB负异常明显（δ13C_PDB、δ18O_PDB平均值分别为-1.549‰及-12.654‰），指示其形成过程中受温度升高影响明显；流体包裹体均一温度平均值为159.5℃。结合区域构造-热演化史分析，结果表明石柱地区龙马溪组FCV形成流体具造山带同构造期超高压有机流体性质特征，为中-晚三叠世印支期同构造作用驱动深部流体叠加生烃超高压释放导致水力压裂所致，裂缝的开启导致孔隙流体的过饱和及纤维状方解石的快速沉淀。      

歧口凹陷沙一下亚段页岩形成环境及页岩油潜力综合评价

渤海湾盆地是目前我国主要的陆相页岩油资源开采区,歧口凹陷位于盆地腹地,是渤海湾盆地内典型的富油气凹陷之一,但长期以来缺少对不同层位页岩形成环境及页岩油潜力的综合评价。选取歧口凹陷沙一下亚段富有机质页岩为研究对象,综合运用地化录井技术和生排烃模拟技术,进行歧口凹陷沙一下亚段页岩沉积特征的描述和页岩油潜力的综合评价。研究结果显示,①歧口凹陷沙一下亚段沉积于水体盐度较高的还原-强还原环境,营养物质丰富,气候炎热湿润,适宜生物大量繁殖,生产力水平高;②结合生排烃模拟实验结果,研究区沙一下亚段页岩生烃能力强、生烃效率高、排油率较低,生成的原油仍大部分残留在页岩中,具有良好的勘探潜力;③研究区沙一下亚段页岩中含有适量碳酸盐矿物,在成岩过程中改善了储集条件,为页岩油提供了良好的储集场所。歧口凹陷西南缘海侵的发生从沉积环境、古生产力及对成岩作用影响等方面促进了沙一下亚段有机质的富集,而有机质富集、生烃强度高以及良好的储集条件共同控制了沙一下亚段页岩油的大面积分布。研究区沙一下亚段页岩油储层可分为碳酸盐岩和混合沉积岩2种类型,综合2种储层的含油性特征后发现,碳酸盐岩矿物含量和脆性指数对页岩含油性有着极大影响。有利勘探区域为构造裂缝发育的宽缓斜坡区和白云岩化程度较高的地区; 有利勘探层段为孔隙和微裂缝发育的白云岩、白云质页岩和灰质页岩层段。该研究成果可为歧口凹陷页岩油的勘探开发提供指导。