Palaeontology and taphonomy of Late Quaternary fossil assemblages at Somersham,Cambridgeshire, England,and the problem of reworking

Assemblages of foraminifers, ostracods and molluscs from temperate Ipswichian Stage (last temperate stage) sediments and overlying cold Devensian Stage (last cold stage) sediments at Somersham in the southern Fenland of Cambridgeshire have been analysed. The Ipswichian sediments contain faunas consistent with temperate brackish water conditions under tidal influence. The Devensian assemblages were recovered from a series of sands and gravels laterally accreting in a channel cutting into Ipswichian sediments. In contrast to the Ipswichian faunas, the faunas of particular Devensian samples show a complex mixture of temperate freshwater, brackish and marine taxa. The molluscs are mainly freshwater, with few land snails; they occur together with foraminifers and ostracods. Freshwater, brackish water and marine ostracods are present with foraminifers. A sample of Devensian fine laminated sediment in the channel was analysed for pollen; only abundant pre-Quaternary spores were present, with abundant foraminifers in the same sample. The taphonomy of the assemblages and the difficulties of their interpretation in environmental terms are discussed. The importance of taphonomy in assessing environments, climate, range of taxa and dating is stressed.     

Late Pleistocene deposits at Block Fen,Cambridgeshire, England

Organic sediments in a gravel quarry at Block Fen, Cambridgeshire, form a sheet dividing lower from upper gravels. Analyses of pollen, macroscopic plant remains and molluscs from these organic sediments are presented. They indicate the presence of temperate freshwater and slightly brackish fine floodplain sediments, which, on the basis of the palaeobotany, are correlated with the temperate Ipswichian Stage. The freshwater sediments, ascribed to Ipswichian substage IIb, occur at ca. ?3 m OD. Marine-influenced tidal sediments, ascribed to Ipswichian substage III, occur at ca. ?6 m OD. No evidence was found for the presence of more than one temperate stage in the sequence. The lower gravels are then correlated with the cold Wolstonian Stage and the upper gravels with the cold Devensian Stage. In contrast to the woodland environments indicated by the palaeobotany of the Ipswichian organic sediments, post-Ipswichian pollen diagrams and macroscopic plant remains in the upper suite of sands and gravels indicate open tree-less vegetation typical of the cold Devensian Stage. They also contain a typical cold-stage mollusc fauna. The sediments containing these floras and faunas are associated with thermal contraction cracks, indicating the presence of permafrost. The final sand and gravel aggradation in the Devensian forms the Block Fen Terrace, near 0 m OD. The evidence indicates that it is younger than the lacustrine sediments resulting from the blocking of the Fenland at the Wash by Late Devensian ice at ca. 18.5 ka BP. The sequence at Block Fen is related to nearby Ipswichian and Devensian sediments at Chatteris, March, Wimblington and Mepal, and to deposits at Wretton on the east margin of Fenland. The correlation permits an outline reconstruction of the history of the valley carrying the River Great Ouse between the Isle of Ely and the Chatteris and March ‘islands’ from the time of a gravel aggradation before the Ipswichian to the Flandrian. The reconstruction shows the time and level of the Ipswichian marine incursion into the Middle Level of Fenland and the extent of aggradation and erosion in the Devensian.     

Ipswichian (Eemian) floodplain deposits and terrace stratigraphy in the lower Great Ouse and Cam valleys,southern England,UK

Gao, C. & Boreham, S. 2010: Ipswichian (Eemian) floodplain deposits and terrace stratigraphy in the lower Great Ouse and Cam valleys, southern England, UK. Boreas, 10.1111/j.1502‐3885.2010.00191.x. ISSN 0300‐9483. Thick argillaceous deposits named the Mannings Farm Beds recently uncovered in the third terrace at Mannings Farm near Willingham, Cambridgeshire contain a pollen sequence covering the transitions from Ipswichian/Eemian substages I to II and II to III, when oak and hornbeam expanded, respectively. This is the longest record hitherto obtained in Britain, providing important insight into the major forest successions in this temperate stage. The frequent occurrence of Ipswichian deposits in the third terrace suggests the development of an extensive floodplain on the valley bottom, similar to the case for the present‐day lower Great Ouse and Cam. The Mannings Farm Beds testify to a complete interglacial sequence emplaced between cold‐climate gravels that was directly associated with the terrace development. The third terrace developed during the Ipswichian and the preceding and succeeding cold stages. Major river downcutting, which shaped the third terrace, occurred during the Early Devensian/Weichselian. Previously reported interglacial fossils from this terrace that are inconsistent with an Ipswichian affinity are probably reworked material derived from pre‐Ipswichian interglacial deposits, or their significance as biostratigraphical indicators needs to be confirmed. The second and first terraces developed from the late Early Devensian onwards. Ipswichian deposits filling flood‐scoured deep channels in bedrock are preserved locally below these low terraces.     

Exploring former subglacial Hodgson Lake,Antarctica. Paper II: palaeolimnology

Direct exploration of subglacial lakes buried deep under the Antarctic Ice Sheet has yet to be achieved. However, at retreating margins of the ice sheet, there are a number of locations where former subglacial lakes are emerging from under the ice but remain perennially ice covered. One of these lakes, Hodgson Lake (72°00.549′S, 068°27.708′W) has emerged from under more than 297–465 m of glacial ice during the last few thousand years. This paper presents data from a multidisciplinary investigation of the palaeolimnology of this lake through a study of a 3.8 m sediment core extracted at a depth of 93.4 m below the ice surface. The core was dated using a combination of radiocarbon, optically stimulated luminescence, and relative palaeomagnetic intensity dating incorporated into a chronological model. Stratigraphic analyses included magnetic susceptibility, clast provenance, organic content, carbonate composition, siliceous microfossils, isotope and biogeochemical markers. Based on the chronological model we provisionally assign a well-defined magnetic polarity reversal event at ca 165 cm in the lake sediments to the Mono Lake excursion (ca 30–34 ka), whilst OSL measurements suggest that material incorporated into the basal sediments might date to 93 ± 9 ka. Four stratigraphic zones (A–D) were identified in the sedimentological data. The chronological model suggests that zones A–C were deposited between Marine Isotope Stages 5–2 and zone A during Stage 1, the Holocene. The palaeolimnological record tracks changes in the subglacial depositional environment linked principally to changing glacier dynamics and mass transport and indirectly to climate change. The sediment composition in zones A–C consists of fine-grained sediments together with sands, gravels and small clasts. There is no evidence of overriding glaciers being in contact with the bed reworking the stratigraphy or removing this sediment. This suggests that the lake existed in a subglacial cavity beneath overriding LGM ice. In zone D there is a transition to finer grained sediments characteristic of lower energy delivery coupled with a minor increase in the organic content attributed either to increases in allochthonous organic material being delivered from the deglaciating catchment, a minor increase in within-lake production or to an analytical artefact associated with an increase in the clay fraction. Evidence of biological activity is sparse. Total organic carbon varies from 0.2 to 0.6%, and cannot be unequivocally linked to in situ biological activity as comparisons of δ¹³C and C/N values with local reference data suggest that much of it is derived from the incorporation of carbon in catchment soils and gravels and possibly old CO₂ in meteoric ice. We use the data from this study to provide guidelines for the study of deep continental subglacial lakes including establishing sediment geochronologies, determining the extent to which subglacial sediments might provide a record of glaciological and environmental change and a brief review of methods to use in the search for life.     

Evolution of a periglacial landscape in the Late Devensian: environments and palaeobotany of the Mepal area,Cambridgeshire, England

The landscape evolution of the Mepal area from Late Devensian Block Fen Terrace times to the beginning of the Flandrian, a period of ca. 8000 radiocarbon years, is reconstructed. Stratigraphy is based on borehole transects and single boreholes, centred on a depression between the Block Fen Terrace and the Isle of Ely. Within the depression is a Devensian late‐glacial sequence, with the Windermere Interstadial represented by radiocarbon‐dated organic sediments. Pollen and plant macroscopic remains of the late‐glacial sediments are analysed. Plant communities with Betula developed in the interstadial. Before and after the interstadial there is much reworked pollen in the inorganic sediments, derived from local pre‐Devensian Pleistocene sediments, including temperate Ipswichian Stage sediments, and from mass‐wasting of the local Jurassic bedrock. Periods of such mass‐movement occur before and after the deposition of the late‐glacial lake sediments. Deposition of aeolian sediment occurs later than the main period of mass movement, but before the Windermere Interstadial. The relationship of the aeolian sediments in time and space to permafrost, indicated by local contraction polygons and cracks, is discussed. Solifluction diverted the flow of the River Great Ouse from a northeast direction in Block Fen Terrace times to a southwest direction as a channel developed to the west of the Chatteris–March ‘island’. This led to a drainage divide in Flandrian times. Copyright © 2002 John Wiley & Sons, Ltd.     

Paleoclimatic changes during the last 2.5 myr recorded in the Kathmandu Basin,Central Nepal Himalayas

Palynological and sedimentological studies of a series of slimes collected from a 284 m-long drill-well from the Kathmandu Basin reveal paleoclimatic records and environmental changes within the Kathmandu Valley during the last 2.5 myr. The slimes are composed of fluvio-deltaic and lacustrine sediments comprising sand beds of 66.3 m and mud beds of 218 m in length. Pollen analyses show Quercus and Cyclobalanopsis are predominant, with frequencies exceeding 70%. Pinus, Alnus and Gramineae are the next dominant taxa. Three fossil pollen zones were discriminated; each zone reflects major climatic change: Zone I, the oldest stage, indicates a cool and rather wet climate during 400 kyr from ca. 2.5 to 2.1 Ma; Zone II, the middle stage, reflects a warm and relatively dry climate without remarkable fluctuation; Zone III is characterized by seven cycles of warm-and-wet and cold-and-dry climate, which reflect the alternation of glacial and interglacial periods. The last cold maximum, 11 m deep, corresponds to the last glacial age around 20 kyr bp, judging from the ¹⁴C dating of the uppermost part of the lacustrine sediments.The Paleo-Kathmandu Lake is likely to have been initiated at around 2.1 Ma and to have been filled with black organic mud, the Kalimati Clay. The top of the Kalimati Clay is eroded and was overlain by fluvial sand after the last glacial age. The abrupt appearance of a 4 m-thick fossiliferous sand bed at the top of the middle member suggests a lowering of water level at around 1 Ma.     

Sedimentological characteristics of small rivers with loessic headwaters in the Chaco,South America

Some sedimentological characteristics of fluvial environments located in the northeastern region of the Chaco–Pampa plain were analysed in order to determine the possible influence of the loessic headwaters of local basins. Concentrations of suspended sediments, as well as grain size of the river beds, were compared. Unexpectedly, it was found that the suspended load has an inverse relationship with the hydrometric levels, with the exception of highly saline streams (conductivity values between 4300 and 11,000 μS cm⁻¹). The mean concentration of suspended sediments was 63.1 and 206.3 mg l⁻¹ in flood and low water periods, respectively. The grain size of bed sediments was relatively homogeneous along the whole hydrological cycle. Sandy–silty bottoms predominate in channels, followed by silty–sandy and clayey–silty bottom types. Sediment transport mainly occurs in accelerating flow suspension, overcoming the critical erosion velocity. During flood periods, some parameters exceeded by 70% the values recorded during the low water phase.     

Stratigraphy and origin of New Forest brickearths,England

The thin, loamy brickearth deposits overlying the flinty terrace gravels of the New Forest are divided into older and younger members. The Lower (older) Brickearth includes sediments thought to be mainly loess, with some aeolian sand and possible river floodloam (overbank sediment). These share the common feature of palaeo-argillic soil horizons in their upper layers. Two separate phases of pre-Holocene temperate pedogenesis often can be distinguished in the palaeo-argillic horizons. The Lower Brickearth is the most extensive pre-Devensian loess in Britain. The Upper (younger) Brickearth consists mainly of Late Devensian (Oxygen Isotope Stage 2) loess, but its lower layers also contain fine sand derived mainly from local Tertiary strata. Both brickearths occur on all the terrace surfaces of the New Forest and indicate that the terraces date from Oxygen Isotope Stage 6 or earlier.     

Mapping the sub-trappean Mesozoic sediments in the western part of Narmada–Tapti region of Deccan Volcanic Province,India

Deccan Traps spread over large parts of south, west and central India, possibly hiding underneath sediments with hydrocarbon potential. Here, we present the results of seismic refraction and wide-angle reflection experiments along three profiles, and analyze them together the results from all other refraction profiles executed earlier in the western part of Narmada–Tapti region of the Deccan Volcanic Province (DVP). We employ travel time modelling to derive the granitic basement configuration, including the overlying Trap and sub-trappean sediment thickness, if any. Travel time skips and amplitude decay in the first arrival refraction data are indicative of the presence of low velocity sediments (Mesozoic), which are the low velocity zones (LVZ) underneath the Traps. Reflection data from the top of LVZ and basement along with the basement refraction data have been used to derive the Mesozoic sediment thickness.In the middle and eastern parts of the study region between Narmada and Tapti, the Mesozoic sediment thickness varies between 0.5 and 2.0 km and reaches more than 2.5 km south of Sendhwa between Narmada and Tapti Rivers. Thick Mesozoic sediments in the eastern parts are also accompanied by thick Traps. The Mesozoic sediments along the present three profiles may not be much prospective in terms of its thickness, except inside the Cambay basin, where the subtrappean sediment thickness is about 1000–1500 m. In the eastern part of the study area, the deepest section (>4 km) has thick (∼2 km) Mesozoic sediments, but with almost equally thick Deccan Trap cover. Results of the present study provide important inputs for future planning for hydrocarbon exploration in this region.     

Partitioning and mobility of trace metals in the Blesbokspruit: Impact assessment of dewatering of mine waters in the East Rand,South Africa

A suite of trace metals was analyzed in water and sediment samples from the Blesbokspruit, a Ramsar certified riparian wetland, to assess the impact of mining on the sediment quality and the fate of trace metals in the environment. Limited mobility of trace metals was observed primarily because of their high partition coefficient in alkaline waters. Nickel was most mobile with a mean K_d of 10^3.28 L kg⁻¹ whereas Zr was least mobile with a mean K_d of 10^5.47 L kg⁻¹. The overall trace metal mobility sequence, derived for the Blesbokspruit, in increasing order, is: Zr < Cr < Pb < Ba < V < Cu < Zn < Sr < Mn < U < Mo < Co < Ni. Once removed from the solution, most trace metals were preferentially associated with the carbonate and Fe–Mn oxide fraction followed by the exchangeable fraction of the sediments. Organic C played a limited role in trace metal uptake. Only Cu was primarily associated with the organic fraction whereas Ti and Zr were mostly found in the residual fraction. Compared to their regional background, Au and Ag were most enriched, at times by a factor of 20–400, in the sediments. Significant enrichment of U, Hg, V, Cr, Co, Cu and Zn was also observed in the sediments.The calculated geoaccumulation indices suggest that the sediments are very lightly to lightly polluted with respect to most trace metals and highly polluted with respect to Au and Ag. The metal pollution index (MPI) for the 20 sampled sites varied between 2.9 and 45.7. The highest MPI values were found at sites that were close to tailings dams. Sediment eco-toxicity was quantified by calculating the sediment quality guideline index (SQG-I). The calculated SQG-I values (0.09–0.69) suggest that the sediments at the study area have low to moderate potential for eco-toxicity.     

Ethane- and propane-producing potential and molecular characterization of an ethanogenic enrichment in an anoxic estuarine sediment

Ethane and propane are low molecular weight hydrocarbons observed widely at trace levels in cold marine sediments where thermogenic sources are considered insignificant, but their biological sources remain poorly constrained. In this study, several C₂ and C₃ compounds including alkenes, alcohols, thiols and carboxylic acids with a C₂ or C₃ skeleton were tested for their relative alkane-producing potential in an anoxic estuary sediment. Maximum conversion efficiency of substrates to ethane or propane was observed in the sediment supplemented with ethylene (up to 38%), followed by additions with ethanethiol (0.01%) and propanethiol (0.003%). Experiments with sterilized sediment, 2-bromoethanesulfonic acid or NaNO₃ were negative for alkane production, suggesting that methanogens were involved in alkane generation. Detailed investigation on ethanogenesis from ethylene showed that this reaction required H₂ but at reasonably low concentration (< 120 nmol dissolved H₂ l⁻¹ slurry) and caused a slight stable carbon isotope effect (ε_{ethane/ethylene} = −8.6 ± 2.4‰). The high ethane-producing potential, reasonable H₂ requirement and extensive occurrence of ethylene make ethylene reduction a plausible explanation for ethane in cold marine sediment. Phylogenetic analysis was first carried out with an ethane-producing enrichment with ethylene as the substrate and showed a dominance of homoacetogenic bacteria and the methanogenic genus Methanocalculus. Although we cannot rule out the possibility that other methanogens in the gene libraries are responsible for ethanogenesis from ethylene, the dominance of Methanocalculus, with its hydrogenotrophic cultured representatives, is in accord with our biogeochemical observation that H₂ is required for this reaction.     

Mercury deposition and methylmercury formation in Narraguinnep Reservoir,southwestern Colorado,USA

Narraguinnep Reservoir in southwestern Colorado is one of several water bodies in Colorado with a mercury (Hg) advisory as Hg in fish tissue exceed the 0.3 μg/g guideline to protect human health recommended by the State of Colorado. Concentrations of Hg and methyl-Hg were measured in reservoir bottom sediment and pore water extracted from this sediment. Rates of Hg methylation and methyl-Hg demethylation were also measured in reservoir bottom sediment. The objective of this study was to evaluate potential sources of Hg in the region and evaluate the potential of reservoir sediment to generate methyl-Hg, a human neurotoxin and the dominant form of Hg in fish. Concentrations of Hg (ranged from 1.1 to 5.8 ng/L, n = 15) and methyl-Hg (ranged from 0.05 to 0.14 ng/L, n = 15) in pore water generally were highest at the sediment/water interface, and overall, Hg correlated with methyl-Hg in pore water (R² = 0.60, p = 0007, n = 15). Net Hg methylation flux in the top 3 cm of reservoir bottom sediment varied from 0.08 to 0.56 ng/m²/day (mean = 0.28 ng/m²/day, n = 5), which corresponded to an overall methyl-Hg production for the entire reservoir of 0.53 g/year. No significant point sources of Hg contamination are known to this reservoir or its supply waters, although several coal-fired power plants in the region emit Hg-bearing particulates. Narraguinnep Reservoir is located about 80 km downwind from two of the largest power plants, which together emit about 950 kg-Hg/year. Magnetic minerals separated from reservoir sediment contained spherical magnetite-bearing particles characteristic of coal-fired electric power plant fly ash. The presence of fly-ash magnetite in post-1970 sediment from Narraguinnep Reservoir indicates that the likely source of Hg to the catchment basin for this reservoir has been from airborne emissions from power plants, most of which began operation in the late-1960s and early 1970s in this region.     

Carbonate recrystallisation and organic matter maturation in heat-affected sediments from the Shaban Deep,Red Sea

Parasound profiles across the Shaban Deep in the Red Sea indicate turbiditic transport of surface sediments from the topographic height (basalt ridge) into the interior of the deep. This is supported by petrographical and (isotope-) geochemical evidence in the East Basin of the Shaban Deep where the presence of variable mixtures of authochtonous and allochthonous sediment compounds had been found.The uppermost 170 cm of both sediment cores 17008-1 and 17009-3 reveal “normal” stable oxygen isotope values for the planktonic foraminifera Globigerinoides ruber near ?1‰ which is indicative for carbonate formation in Red Sea surface water around 27 °C. However, below 182 cm in core 17008-1 highly variable δ ¹⁸O values for G. ruber between 0.26 and ?10.68‰ occur which are not the result of temperature-controlled oxygen isotope fractionation between foraminiferal carbonate and Red Sea surface water. The lowest δ¹⁸O values of ?10.68‰ measured for highly-altered foraminifera shells suggests carbonate precipitation higher than 90 °C.Organic petrographical observations show a great diversity of marine-derived macerals and terrigenous organic particles. Based on petrographical investigations sediment core 17008-1 can be subdivided in intervals predominantly of authochtonous character (i.e. 1, 3, 5 corresponding to core depths 0–170 cm, 370–415 cm, 69–136 cm), and allochthonous/thermally altered character (e.g. 2 and 4 corresponding to core depths 189–353 cm and 515–671 cm). Allochthonous/thermally altered material displays a wide to an extremely wide range of maturities (0.38–1.42% R_r) and also natural coke particles were found.Similarly, the organic geochemical and pyrolysis data indicate the predominance of well-preserved, immature algal and bacterial remains with a minor contribution of land plant material. Sediments below 170 cm (core 17008-1) contain contributions of re-sedimented pre-heated material most likely from the area of the basaltic ridge. This is documented by individual coke particles reduced hydrogen indices and elevated T_max values up to 440 °C.An “oil-type” contribution (evidenced by mature biomarkers, hopene/hopane ratios, elevated background fluorescence, n-alkane distribution) is also present in the sediments which most likely originated at greater depth and impregnated the surface sediments.The heat source responsible for recrystallisation of foraminiferal carbonate and maturation of organic particles in Shaban Deep sediments most likely is attributed to modern basalt extrusions which now separate the Shaban Deep subbasins.     

Evaluation of the anthropogenic influx of metallic pollutants into Puck Bay,southern Baltic

Distributions of 15 elements with depth in two sediment cores from Puck Bay in the Gulf of Gdansk show that Ag, Cd, Pb, Zn and possibly Cu and Ni are anthropogenically enriched in the sediments there. The concentrations of these elements decrease sharply with depth in the sediment column and the elements are preferentially enriched in the <2 μm size fraction of the sediment. The sequence of element enrichment depends on whether the enrichment factor (EF) and the anthropogenic factor (AF) are used to calculate the element enrichment. By contrast, the anthropogenic elements show no systematic decrease in concentration with depth in a sediment core taken from near the mouth of the Vistula River. This reflects the higher sedimentation rate there such that the entire upper 20 cm of the core was deposited during the major, post-war period of industrialization in Poland. In addition, these elements are enriched in the 2–63 μm fraction compared to the <2 μm fraction in these sediments. This suggests that the heavy metals are mainly adsorbed on Fe oxyhydroxide particles with diameters greater than 2 μm at the hydrological front where Vistula river water mixes with brackish Baltic water. It appears that heavy-metal pollution of sediments in parts of Puck Bay may be greater than that near the mouth of the Vistula River which may reflect, in part, the higher sedimentation rate near the mouth of the Vistula River. The mode of incorporation of heavy-metals into the sediments in the two areas may also be different.     

Preliminary optical and radiocarbon age determinations for Upper Pleistocene alluvial sediments in the southern Anti Atlas Mountains,MoroccoDatation des sédiments alluviaux du Pléistocène supérieur du versant sud de l'Anti-Atlas,Maroc

This paper presents the first results of a ¹⁴C and optical luminescence dating project on extensive alluvial silt formations in the southern Anti Atlas Mountains in southern Morocco. The silts comprise three members: basal silts, an inter-silt fluvial gravel member and a top silt member and are incised by the rivers. Top silt dates are: 11 340–11 940, 12 670–13 130 cal. yr BP, and 10.6±0.7 ka (OSL). OSL dates for the inter-silt gravels are 29.6±2.0 ka and for the bottom silts is 45.0±3.7 ka. The sediments correlate with Soltanian stratigraphies known elsewhere in Morocco. To cite this article: M. Thorp et al., C. R. Geoscience 334 (2002) 903–908.     

Quaternary fluvial, pedogenic and mass-movement processes at St George's Down, Newport, Isle of Wight

Recent geological mapping on the Isle of Wight by the British Geological Survey has shown the ‘Plateau Gravel’ to be a mixture of fluvial, solifluction, pedogenic and marine deposits ranging from pre-Anglian to Holocene age. As part of the resurvey of the island, several new exposures of the ‘Plateau Gravel’ between Newport and Downend were examined. A working gravel pit on St George's Down, near Newport, revealed a succession of flint gravels with an inter-bedded sequence of laminated silts. An upper in situ succession of pre-Anglian fluvial gravels caps the plateau, but a second, probably younger suite of gravel-rich sediments is exposed in a quarry on a topographically lower spur. These overlie in situ Clay-with-flints resting on Upper Cretaceous Chalk. These lower sediments are well exposed and display a complex stratigraphy. They consist predominantly of flint gravel, but include a dipping succession of laminated silts and palaeosols preserved in a hollow or small channel feature, intercalated between two distinct soliflucted cold-stage gravel sheets. Palynological and pedological evidence analysis suggests that these laminated silts and sands were deposited under a temperate climate but with frequent episodes of disruption caused by mass-movement and possibly freeze-thaw. The age of these laminated sediments are not known with any certainty but are likely to date to a temperate interval within the Late Pleistocene. The top of the laminated unit is cut by a heavily cryoturbated horizon presumed to be of Devensian age.     

Application of multifractal modeling technique in systematic geochemical stream sediment survey to identify copper anomalies: A case study from Ahar,Azarbaijan, Northwest Iran

This research is based on the application of stream sediments to mineral exploration. Identifying the geochemical anomalies from background is a fundamental task in exploration geochemistry. This paper applied the element concentration–area (C–A) model, to separating the geochemical anomalies from background based on a fractal approach and for the compilation of geochemical mapping from stream sediment samples (n = 620) of the Ahar region (Iran), where some Cu mineralization occurs. Comparisons of the known copper occurrences against the anomalous area created using thresholds from C–A method illustrate these hits. All of known Cu mineralizations and moreover defines two extra Cu anomaly districts. Additional sampling (n = 186) around new Cu anomaly confirms this anomaly within the district.     

Glacitectonic evidence of ice sheet interaction and retreat across the western part of Dogger Bank (North Sea) during the Last Glaciation

High-resolution 2D seismic data from the western side of Dogger Bank (North Sea) has revealed that the glacigenic sediments of the Dogger Bank Formation record a complex history of sedimentation and penecontemporaneous, large-scale, ice-marginal to proglacial glacitectonism. The resulting complex assemblage of glacial landforms and sediments record the interplay between two separate ice masses revealing that Late Devensian ice sheet dynamics across Dogger Bank were far more complex than previously thought, involving the North Sea lobe of the British and Irish Ice Sheet, advancing from the west, interacting with the Dogger Bank lobe which expanded from the north. The active northward retreat of the Dogger Bank lobe resulted in the development of a complex assemblage of arcuate thrust-block moraines (≤ 15 km wide, > 30 km long) composed of highly folded and thrust sediments, separated by sedimentary basins and meltwater channels filled by outwash. The impact of the North Sea lobe was restricted to the western margin of Dogger Bank and led to deep-seated (100–150 m thick) glacitectonism in response to ice-push from the west. During the earlier expansion of the North Sea lobe, this thrust and fold complex initially occupied a frontal marginal position changing to a more lateral ice-marginal position as the ice sheet continued to expand to the south. The complex structural relationships between the two glacitectonic complexes indicates that these ice masses interacted along the western side of Dogger Bank, with the inundation of this area by ice probably occurring during the last glaciation when the ice sheets attained their maximum extents.     

Elemental sulfur in drain sediments associated with acid sulfate soils

This paper reports the abundance of elemental S in drain sediments associated with acid sulfate soils. The sediments exhibited near-neutral pH (5.97–7.27), high concentrations of pore-water Fe²⁺ (1.37–15.9 mM) and abundant oxalate-extractable Fe (up to 4300 μmol g⁻¹). Maximum acid-volatile sulfide (AVS) concentrations in each sediment profile were high (118–1019 μmol g⁻¹), with AVS often exceeding pyrite-S. Elemental S occurred at concentrations of 13–396 μmol g⁻¹, with the higher concentrations exceeding previous concentrations reported for other sedimentary systems. Up to 62% of reduced inorganic S near the sediment/water interface was present as elemental S, due to reaction between AVS and oxidants such as O₂ and Fe(III). Significant correlation (r = 0.74; P < 0.05) between elemental S and oxalate-extractable Fe(III) is indicative of elemental S formation by in situ oxidation of AVS. The results indicate that AVS oxidation in near-surface sediments is dynamic in acidified coastal floodplain drains, causing elemental S to be a quantitatively important intermediate S fraction. Transformations of elemental S may therefore strongly influence water quality in ASS landscapes.     

Polycyclic aromatic hydrocarbon fingerprints in the Pichavaram mangrove–estuarine sediments,southeastern India

The sources and historical deposition of 16 polycyclic aromatic hydrocarbons (PAHs) were investigated in dated sediment cores from the Pichavaram mangrove–estuarine complex. The ΣPAH flux in mangrove and estuarine sediments was 0.064 ± 0.031 μg/cm²/yr and 0.043 ± 0.020 μg/cm²/yr, respectively. The PAH flux in sediments increased up-core, coinciding with rapid urbanization since the 1970s. The flux showed a decrease in recent years (since 1990), coinciding with less riverine discharge, and perhaps more effective implementation of environmental regulations. The sediments were dominated by low molecular weight PAHs, suggesting anthropogenic input. Ratios of specific PAH isomer pairs suggested a greater input of petrogenic vs. pyrogenic derived PAHs. Notably, the deposition of high molecular weight PAHs increase in mangrove surface sediments was due to lignite and firewood combustion. Because of their overall low concentration in sediments it is unlikely these PAHs pose an immediate ecological hazard.