Non-point pollution of groundwater from agricultural activities in Mediterranean Spain: the Balearic Islands case study

Mediterranean Spain is a region with intensive agricultural production combined with an important seasonal water demand for water supply. High application rates of inorganic nitrogen fertiliser, input of plant protection products and intensive irrigation, sometimes with treated wastewater, is a common practice. As a result, most aquifers show nitrate contamination problems of agricultural origin. Data on pesticide residues is scarce, as systematic monitoring is not currently done. In Majorca Island, values up to 700 mg/l of nitrate in groundwater have been observed. To analyse the current situation derived from non-point pollution, several actions have been taken at different scales: declaration of a nitrate vulnerable zone, field experiments to evaluate nitrogen transport to the aquifer and the development of a GIS-simulation model to generate nitrate risk maps.     

The innovation of greenhouse crops in the Mediterranean area: The Turkish case

The cultivation of early vegetables has altered the agrarian regions of the Mediterranean coast. Even if this restructuring process has already been completed in many countries, it can still be observed in Turkey. The development on the S coast of Turkey, where in 1985 a total of 113 villages with winter vegetable cultivation were studied, serves as an example. Hot-house cultivation was introduced here in glass greenhouses near Antalya around 1940 and spread only slowly along the S coast. An accelerated increase in the land used for early season vegetables was triggered off by the technical innovation of under-plastic cultivation (plastic greenhouses, plastic tunnels) around 1965. The partial innovations glass greenhouse — plastic greenhouse — plastic tunnel were, because of their different capital intensity, adopted by different agrarian social groups. Today glass greenhouse-, plastic greenhouse-and plastic tunnel-regions have formed which have recently undergone a considerable degree of intermingling. The diffusion process of early vegetables in total, like that of the partial innovations, did not happen continuously, rather the changes were carried erratically over wide distances; the process of intermingling also showed such a form of spreading. A sociopsychological motive can be offered as a basis for this type of spreading, for which the term spasmodic diffusion is suggested: the comparatively high degree of isolation of the Turkish village communities from the outside world and their strong orientation inwards lead inevitably to isolation of innovations. Derived from this is the thesis that other spontaneous innovations in similarly structured agrarian regions also always spread erratically (spasmodic).     

Oxygen isotopes from Chinese caves: records not of monsoon rainfall but of circulation regime

Oxygen isotope variations in Chinese stalagmites have been widely interpreted as a record of the amount of East Asian summer monsoonal rainfall. This interpretation infers decreasing monsoonal rainfall from the mid‐Holocene and large, dipolar rainfall oscillations within glaciations. However, the speleothem δ¹⁸O variations conflict with independent palaeoclimate proxies (cave δ¹³C, loess/palaeosol magnetic properties, δ¹³C alkanes), which indicate no systematic decline in rainfall from the mid‐Holocene, and no glacial rainfall maxima. Using mass balance calculations (which incorporate seasonality effects in both δ¹⁸O concentration and amount of precipitation), we demonstrate that the cave δ¹⁸O variations cannot be accounted for by summer rainfall changes, or rainfall seasonality or winter cooling, but instead reflect changes in moisture source. A possible driver of the δ¹⁸O variations in Chinese stalagmites is precessional forcing of inter‐hemispheric temperature gradients, and resultant shifts in the position and intensity of the subtropical pressure cells. Through such forcing, Indian monsoon‐sourced δ¹⁸O may have dominated at times of high boreal summer insolation, and local Pacific‐sourced moisture at low insolation. Suppression of summer monsoonal rainfall during glacial stages may reflect diminished sea and land surface temperatures and the radiative impacts of increased regional dust fluxes. Copyright © 2012 John Wiley & Sons, Ltd.     

Th-and U-bearing minerals in the SE Mediterranean margin of Spain

This paper presents the first specific study of the Th-and U-bearing minerals, which were recently found in the SE Mediterranean margin of Spain (El Hoyazo area,Almeria province). These minerals are REE phosphates (mainly monazite) which occur as amoeboidal-to-elongate inclusions,from around 10 120μm to 120μm, hosted in single garnet crystals from dacite lavas and metamorphic rocks from the El Hoyazo Volcanic Complex. Th and U contents are higher than 1 wt%, with 3.04 to 5.62wt% for Th02, and 0.7 to 1.75 wt% for UO2. Both elements are also found in xenotime (ThO2:0.24,UO2:0.27wt%). Given that the erosion of the volcanic source rocks has generated a “placer-type” deposit of monazite sands and that garnets (main carriers of monazite) are being commercialised, an environmental monitoring and management plan should be urgently executed in the area.     

The end of the Messinian Salinity Crisis in the western Mediterranean: Insights from the carbonate platforms of south-eastern Spain

How the Messinian Salinity Crisis (MSC) ended is still a matter of intense debate. The Terminal Carbonate Complex (TCC) is a late Messinian carbonate platform system that recorded western Mediterranean hydrological changes from the final stages of evaporite deposition till the advent of Lago-Mare fresh- to brackish water conditions at the very end of Messinian times. A multidisciplinary study has been carried out in three localities in south-eastern Spain to reconstruct the history of TCC platforms and elucidate their significance in the MSC. Overall, this study provides evidence that the TCC formed following a regional 4th order water level rise and fall concomitant with an opening-restriction trend. It can be subdivided into four 5th order depositional sequences (DS1 to DS4) recording two phases: (1) from DS1 to DS3, a tide-dominated ooidic to oobioclastic system with stenohaline faunas developed as a result of a 70 m water level rise. During this period, the TCC developed in a shallow sea with close to normal marine salinity; (2) in depositional sequence 4, a microbialite-dominated platform system developed. This is indicative of a significant environmental change and is attributed to a 30 to 40 m water level fall in the basins under study. These restricted conditions were coeval with intense evaporite deformation and brine recycling. The syn-sedimentary deformation of evaporites had a major impact on platform architecture and carbonate production, affecting the Messinian series throughout south-eastern Spain at the end of the TCC history. At that time, the TCC developed in a lake with fluctuating, brackish- to hypersaline water. These findings suggest a temporary restoration of marine conditions in the western Mediterranean marginal basins due to Atlantic water influxes prompted by a global sea level rise around 5.6 Ma. Whether marine conditions extended to the entire western Mediterranean still needs to be investigated.     

Lignin and fatty acid records in Lake Baikal sediments over the last 130 kyr: A comparison with pollen records

A 10 m sediment core from Academician Ridge in Lake Baikal was analyzed for its molecular composition using on-line TMAH (tetramethylammomium hydroxide) thermochemolysis. Major products are lignin phenols, n-C₁₄ to C₃₀ fatty acids (alkanoic acids), cutin acids, hydroxy acids and aliphatic dicarboxylic acids. Lignin phenols are abundant in warmer periods (the interglacial: marine isotope stage (MIS) 5e and MIS 1), but extremely low in the other (colder) periods. This result coincides well with pollen records reported for a core near the present site, where an expansion of coniferous forests in sub-stage 5e and MIS 1 was implied. Normal C₂₄–C₃₀ alkanoic acids, important components of plant wax esters, are abundant in 5e and MIS 1 and are present in significant amounts in the other (colder) periods, unlike the lignin phenols. A high abundance of n-C₂₄ to C₃₀ alkanoic acids relative to lignin phenols in the Bølling–Allerød warm period suggests an enhanced development of herbs.It is implied from comparison of the sedimentary lignin phenol record with fossil pollen records and lignin phenol analysis of modern pollen that the ratio of cinnamyl phenols to vanillyl phenols may serve as an indicator of pollen contribution to sedimentary organic matter.     

Lateglacial and Holocene palaeohydrology in the western Mediterranean region: The Lake Estanya record (NE Spain)

The multi-proxy analysis of sediment cores recovered in karstic Lake Estanya (42°02′ N, 0°32′ E; 670 m a. s. l., NE Spain), located in the transitional area between the humid Pyrenees and the semi-arid Central Ebro Basin, provides the first high-resolution, continuous sedimentary record in the region, extending back the last 21 000 years. The integration of sedimentary facies, elemental and isotopical geochemistry and biogenic silica, together with a robust age model based on 17 AMS radiocarbon dates, enables precise reconstruction of the main hydrological and environmental changes in the region during the last deglaciation.Arid conditions, represented by shallow lake levels, predominantly saline waters and reduced organic productivity occurred throughout the last glacial maximum (21–18 cal kyrs BP) and the lateglacial, reaching their maximum intensity during the period 18–14.5 cal kyrs BP (including Heinrich event 1) and the Younger Dryas (12.9–11.6 cal kyrs BP). Less saline conditions characterized the 14.5–12.6 cal kyrs BP period, suggesting higher effective moisture during the Bölling/Allerød. The onset of more humid conditions started at 9.4 cal kyrs, indicating a delayed hydrological response to the onset of the Holocene which is also documented in several sites of the Mediterranean Basin. Higher, although fluctuating, Holocene lake levels were punctuated by a mid Holocene arid period between 4.8 and 4.0 cal kyrs BP. A major lake-level rise occurred at 1.2 cal kyrs BP, conducive to the establishment of conditions similar to the present and interrupted by a last major water level drop, occurring around 800 cal yrs BP, which coincides with the Medieval Climate Anomaly.The main hydrological stages in Lake Estanya are in phase with most Western Mediterranean and North Atlantic continental and marine records, but our results also show similarities with other Iberian and northern African reconstructions, emphasizing peculiarities of palaeohydrological evolution of the Iberian Peninsula during the last deglaciation.     

Terrestrial stable isotope records of Late Quaternary paleoclimates in the eastern Mediterranean region

Terrestrial stable isotope records (¹³C/¹²C, ¹⁸O/¹⁶O, and D/H ratios) of late Quaternary paleoclimates in the eastern Mediterranean region are reviewed. Significant paleoclimatic reconstructions come from a variety of isotopic studies. Paleogroundwaters, although they cannot be accurately dated, show oxygen and hydrogen isotopic compositions highly depleted in heavier isotopes compared to modern meteoric waters in arid regions of southern Israel, Sinai and northeastern Africa and attest to a major difference in climatic regime some time in the Pleistocene. Th-U dating of land snails showing a similar ¹⁸O depletion indicates ages of 100,000 yr and ≥300,000 yr for this climatic regime in the Negev Desert of southern Israel. Carbon isotope records of organic matter have not been studied extensively in the region, except for the record of Holocene land snails in the Negev. These document a southward shift in pure C₃ plant communities in the middle and early Holocene relative to their present distribution and indicate wetter conditions at those times. An oxygen isotope curve for the Holocene, reflecting changes in the isotopic composition of precipitation, has been established from analysis of carbonate materials—land snail shells and speleothems. The curve indicates a depletion of ca. 2‰ in ¹⁸O centered around 7000 cal yr bp, with modern levels being reached by 5000 cal yr bp. Carbon isotope analysis of soil carbonates in paleosols developed in loess in the Negev show the existence of dramatic north–south climatic gradients at the times of formation of the soils (ca. 13,000, 28,000, and ≥37,000 ¹⁴C yr bp), as occur also today due to the waning influence of Mediterranean to the south. Some isotopic methods, widely used in other regions, have received little or no attention in the eastern Mediterranean region. These include oxygen and hydrogen isotopes in wood, phosphate oxygen and organic carbon in bones and teeth, and carbon in soil organic matter.     

Coastal state sovereignty in the Mediterranean sea: the case of Malta

The Mediterranean is one of the worlds most intensively used seas being a global highway for shipping and having considerable strategic, economic and cultural significance for its 21 coastal states. While most coastal states are eager to exercise their offshore sovereignties as recognised by the 1982 UN Law of the Sea Convention, there are a number of problems associated with reaching formal maritime boundary delimitations, and in the exercise of rights particularly those associated with territorial waters. Malta also claims a contiguous zone, continental shelf, and an exclusive fishing zone. Each of these is considered in turn, comparing Maltas claims and policies with those of other Mediterranean states. Maltas straight baselines are discussed, together with the 1985 boundary agreement with Libya, and the working arrangement with Italy in the Malta Channel. As with the Mediterranean as a whole Maltas maritime boundary system is only partially delimited, and minor problems remain in the exercise of offshore rights.     

Speleogenesis: the evolution of the Castleton caves

Castleton, in North Derbyshire, is unique in Britain in having four caves open to tourists, as well as several ‘mid’ caves, most of which are only accessible to potholers and speleologists. Together, the tourist and wild caves tell a fascinating story of speleogenesis — the growth and development of a cave system. Both geologists and geomorphologists often ignore cave systems, but such systems play an important part in the evolution of the landscape as we see it today.     

Dolomite in caves: Recent dolomite formation in oxic, non-sulfate environments. Castañar Cave, Spain

Dolomite is a common mineral in the rock record but rare in recent superficial environments. Where it does occur, it is related to anoxic, sulfate-rich environments and microbial activity. The occurrence of some dolomite deposits in caves, however, indicates that dolomite formation is also possible in oxic, non-sulfate settings. Dolomite is forming at 17 °C and in oxic-vadose conditions on the host rocks and aragonite speleothems of the Castañar Cave, Cáceres, Spain. It appears as spheroids and dumbbells 50–300 μm in diameter that internally consist of micron-sized rhombic to rounded crystals. Initially this dolomite is Ca-rich, non-stoichiometric and poorly ordered. Mg-rich solutions allow the precipitation of metastable Mg-rich carbonates, such as huntite. This soon transforms into this Ca-rich dolomite, which later “ages” to form a more stoichiometric dolomite. These dolomites show similarities to those grown under anoxic, sulfate-rich conditions and their presence in caves provides a different setting that may contribute to the understanding of the “dolomite problem”, including their initial formation and later recrystallization processes.     

Coastal erosion in the south-eastern Mediterranean: case of beaches in North Tunisia

This research is conducted as part of a Spanish International Cooperation Agency project with the aim to investigate the sustainable protection of Tunisian coastal zones, as in the case of Beni Khiar and Dar Chaabane coasts (Hammamet Gulf) separated by Oued El Kebir river. The sedimentary dynamic of these beaches is studied in order to identify the main causes responsible for their erosion by the use of different approaches of in situ measurements and numerical methods. Geophysical surveys and sedimentary analyses have demonstrated that sediments are finer and less carbonated from Beni Khiar to Dar Chaabane. Then, the shoreline mapping of several missions of aerial photos has illustrated a mean shoreline retreat between 3 and 4 m/year. In terms of sand volume, a sediment loss more than 30,000 m³/year at Dar Chaabane has been observed since the hill lake structures were built within Oued El Kebir river in 1996. Finally, modelled hydrodynamic and sedimentary patterns have illustrated the refraction of waves in deep water close to shoals and a high-energy concentration along Dar Chaabane coast. The sediment transport direction is mainly of NE-SW induced by ESE-SE wave-driven alongshore current. Results provided by these approaches have shown the importance of Oued El Kebir sediment yield in supplying the neighbouring beaches. Changes in sedimentary dynamics are affected by the modification of hydrodynamic patters caused by the presence of hydrological dams and the implementations of hotels close to the shoreline. This finding underlines the key role of Oued El Kebir fluvial activity in controlling the equilibrium of beaches and their sensitivity to coastal managements induced by man activities, as in the case of the most Mediterranean beaches.     

Collapse of caves at shallow depth in Gaziantep city center,Turkey: a case study

This paper focuses on an investigation of the possible causes for the collapse of limestone caves in Gaziantep, Turkey. The city contains a lot of man-made caves, at a shallow depth, of various width and length. These caves were mainly excavated to provide work or storage space. As the city has been growing fast with increased population, many structures were constructed over these caves. Recently, two caves collapsed and five houses were damaged. These caves are all made of limestone and it was observed after the collapse that the limestone was saturated with water due to sewer pipe leakage and surface water. Tests were carried out on the limestone and it was determined that the compressive strength of limestone decreases by about 50% and the tensile strength decreased by about 80% when saturated with water. It was concluded that the reduced strength of the limestone combined with additional loads due to the factors mentioned above seem to be the main reason for these collapses.     

The problem of sustainable groundwater management: the case of La Mancha aquifers, Spain

Gisser and Sánchez (Water Resour Res 16(4):638–642, 1980) compared two different strategies to manage aquifers: “free market” and policy regulation. They stated that the outcome of both is practically the same, and that policy regulation could not improve social welfare. This study challenges this argument by analyzing the management strategies in two large aquifers located in southern Spain, the Eastern La Mancha and the Western La Mancha aquifers. The appeal of this case stems from the fact that management of the Eastern La Mancha aquifer is almost sustainable. In stark contrast, its neighboring Western La Mancha aquifer is being grossly mismanaged. The results engage two major questions from previous groundwater literature. The first question is whether or not aquifer management requires policy intervention. The answer depends upon the consideration and magnitude of environmental damages in the model. The second question addresses the nature of groundwater policies. The contrast in management outcomes between the Western and the Eastern La Mancha aquifers is related to the different types of policy instruments implemented for each aquifer. The results of these policies underline the importance of nurturing the stakeholders’ collective action under the appropriate institutional setting.     

末次冰消期滇西地区气候突变事件:湖泊孢粉记录

在末次冰消期总体持续增温的过程中,全球气候经历了一系列以"快速增温/降温"为主要特征的千-数十年尺度的突变事件。由于这些气候突变事件具有明显的高频特性,需要在全球范围不同地区开展更多高分辨率的古气候研究,用于进行突变事件的对比和机制的探讨。本研究对比滇西南腾冲青海湖、滇西北泸沽湖和高山湖泊天才湖约2万以来的孢粉、炭屑记录,揭示了中国滇西地区末次冰消期的植被演替与气候变化历史,探讨了末次冰消期存在的气候突变事件。结果表明,滇西地区末次冰消期开始转暖发生在约19 ka（1 ka=1000 cal.a B.P.）;冰消期开始以后,滇西地区气候普遍依次在17.5±0.5~15.2±0.1 ka期间、15.2±0.1~14.3±0.1 ka期间、14.3±0.1~12.9±0.1 ka期间和12.9±0.1~11.7±0.2 ka期间存在冷干-逐渐变暖变湿-明显更暖湿-温度湿度略有下降等这几个突变事件,它们在时间上分别对应于H1冷事件、波令前增暖期、B/A暖期和YD冷事件;滇西地区比较一致地在11.7±0.2 ka进入全新世。除此之外,滇西北地区在约17.7~17.0 ka期间可能还存在一次短暂的较明显的暖湿期。对末次冰消期气候变化机制的探讨认为,末次冰消期开始转暖及以后逐渐增温的趋势主要受夏季太阳辐射量从约20 ka逐渐增加,到11 ka左右达到峰值的控制;而末次冰消期发生的气候突变事件如H1冷事件、波令前增暖期、B/A暖期和YD冷事件主要是受大西洋温盐环流的影响,同时温室气体浓度的变化也起了重要的调制作用。     

The setting of the Mt. Carmel caves reassessed

Four caves on the SW flank of Mt. Carmel, es Skhul, el Wad, el Jaml and et Tabun, were first excavated in the 1930s by a team led by Dorothy Garrod. They yielded human remains whose age and evolutionary status remain controversial partly because the complexity of the cave deposits invites conflicting interpretations. The abrasion of artefacts and pebbles in el Wad and es Skhul, which was originally ascribed to spring flow within the caves, is explained here by wave action, with the implication that during part of the Middle Palaeolithic the caves were on the shoreline rather than being separated from it—as they now are—by several kilometres of coastal plain and a height difference of some 45 m. U-series, thermoluminescence (TL) and electron spin resonance (ESR) dating suggests that this occurred about 120,000 years ago, when sea level in the eastern Mediterranean stood 5–6 m above its present position. It follows that Mt. Carmel has subsequently undergone some 40 m of uplift. During the period of maximum submergence, the coastal route between Africa and the northern Mediterranean would have been partly blocked, but the loss of the coastal plain for transit and as a source of animal food was offset by easier access from the caves to marine resources.     

Provincial disparities in levels of living: The case of Spain, 1970–1981

Regional inequalities in economic development in Spain are widely recognised, but similar patterns of levels of living have been less studied. Some of the general factors which might contribute to regional inequalities are discussed. Although it is difficult to identify their precise role, it is argued that the pattern of economic growth, the character of regional economic structures, population distribution and urbanisation, return migration, and the nature of Spanish regional and local government all contribute in varying ways to inequalities in levels of living in different regions. Furthermore, they suggest that such inequalities have persisted throughout the 1970's. The regional patterns are then described and trends of change between 1970 and 1981 examined. The evidence suggests that the decade saw a widening dichotomy in levels of living in Spain with the south and west showing deterioration and the N and E showing relative improvement.     

Late Miocene Mediterranean desiccation: topography and significance of the `Salinity Crisis' erosion surface on-land in southeast Spain

The result of sea level fall at the margins of the Mediterranean during the Late Miocene `Salinity Crisis' was the creation of an extensive erosion surface. However, the shape of this `Salinity Crisis' unconformity reflects local factors and in turn significantly determined local conditions during subsequent reflooding. At Sorbas, in southeast Spain, erosional overdeepening of a pre-existing basin during drawdown created a depression over 200 m deep with an incised floor patterned by 30-m-deep gullies. During reflooding this semi-enclosed palaeovalley temporarily became a barred basin in which gypsum was deposited. These Sorbas evaporites thus resulted from local basin sculpture. Diverse local effects elsewhere during drawdown and reflooding account for marked stratigraphic variations that continue to complicate recognition and correlation of the `Salinity Crisis' in marginal successions. The drawdown erosion surface is itself the key indicator of this important event in marginal Mediterranean basins.