A 3-D coastal tidal rectification process: observations, theory and experiments

In homogeneous rotating fluid, when there is an oscillating forcing in the interior fluid with a period long enough for an Ekman layer to develop, there is an interaction between the oscillatory Ekman layer and the vertical wall, since the latter imposes an alternating adjustment flow confined near the wall. As a result, this coastal rectification process leads to a Lagrangian transport along the coast. The Ekman number, the Rossby number and the temporal Rossby number of the forcing flow are the governing parameters of that mechanism which can be described by a simplified analytical model taking into account both the vertical time-dependent structure of the current and the presence of the wall. The model shows that the residual (rectified) current flowing with the coast to its right results from the strong nonlinear interaction between along- and cross-shore tidal currents leading to asymmetrical momentum exchanges between the Ekman bottom layer and the coastal boundary layer. The model provides simple scaling laws for the maximum intensity and width of the residual current. The latter is significantly larger than the friction (Stokes) lateral boundary layer of the forcing flow. A comprehensive set of experiments is performed in the 13 m diameter rotating tank by oscillating an 8 m×2 m horizontal plate and vertical wall in a homogeneous fluid at rest in solid-body rotation and measuring the two horizontal components of the current at several locations and depths above the central part of the plate. The predicted and experimentally measured maximum intensity and width of the residual current are in very good agreement, within the range of validity of the model, i.e. when the Ekman number is sufficiently small. However experiments also show that the residual current still occurs when the Ekman layer thickness is of the same order as the fluid depth, but it is then confined to a narrower band along the vertical wall. The flow structure found experimentally is also correctly described by a numerical model developed by Zhang et al. (1994). Current measurements in the Eastern part of the English Channel near the French coast reveal a significant coastal residual current flowing Northward and the coastal rectification process described here may account for part of it.     

UV camera measurements of fumarole field degassing (La Fossa crater,Vulcano Island)

The UV camera is becoming an important new tool in the armory of volcano geochemists to derive high time resolution SO₂ flux measurements. Furthermore, the high camera spatial resolution is particularly useful for exploring multiple-source SO₂ gas emissions, for instance the composite fumarolic systems topping most quiescent volcanoes. Here, we report on the first SO₂ flux measurements from individual fumaroles of the fumarolic field of La Fossa crater (Vulcano Island, Aeolian Island), which we performed using a UV camera in two field campaigns: in November 12, 2009 and February 4, 2010. We derived ~ 0.5 Hz SO₂ flux time-series finding fluxes from individual fumaroles, ranging from 2 to 8.7 t d^?1, with a total emission from the entire system of ~ 20 t d^?1 and ~ 13 t d^?1, in November 2009 and February 2010 respectively. These data were augmented with molar H₂S/SO₂, CO₂/SO₂ and H₂O/SO₂ ratios, measured using a portable MultiGAS analyzer, for the individual fumaroles. Using the SO₂ flux data in tandem with the molar ratios, we calculated the flux of volcanic species from individual fumaroles, and the crater as a whole: CO₂ (684 t d^?1 and 293 t d^?1), H₂S (8 t d^?1 and 7.5 t d^?1) and H₂O (580 t d^?1 and 225 t d^?1).     

Optical dating of a hyperconcentrated flow deposit on a Yellow River terrace in Hukou,Shaanxi, China

A sand layer, interpreted as a hyperconcentrated flow deposit, was found interbedded between loess on a Yellow River terrace in Hukou, Shaanxi, China. The site is known as the Longwangchan Palaeolithic site. The deposits from the terrace were dated using optically stimulated luminescence (OSL). Two samples from the sand layer were dated to 30 ± 2 and 33 ± 3 ka using coarse-grained (CG) quartz, and to 82 ± 7 and 94 ± 5 ka using fine-grained (FG) quartz, respectively. The CG quartz OSL ages are believed to be reliable on the basis of the OSL ages of the bracketing loess samples. The overestimation of the FG quartz OSL ages of the sand samples is explained in terms of hyperconcentrated flow processes during sediment transport and deposition. The large difference between the CG and FG quartz OSL ages of the sand samples helps to better understand the formation of the hyperconcentrated flow deposit. The hyperconcentrated flow deposit in this study indicates an extreme river flood occurring at ～30 ka in this area. In addition, the stone artifacts found in the lower loess layer overlying the bedrock of the terrace were dated to ～47 ka.     

Re–Os geochronology of a Mesoproterozoic sedimentary succession,Taoudeni basin,Mauritania: Implications for basin-wide correlations and Re–Os organic-rich sediments systematics

The exceptionally well-preserved sedimentary rocks of the Taoudeni basin, NW Africa represent one of the world's most widespread (> 1 M km²) Proterozoic successions. Hitherto, the sedimentary rocks were considered to be Mid Tonian based on Rb–Sr illite and glauconite geochronology of the Atar Group. However, new Re–Os organic-rich sediment (ORS) geochronology from two drill cores indicates that the Proterozoic Atar Group is ～ 200 Ma older (1107 ± 12 Ma, 1109 ± 22 Ma and 1105 ± 37 Ma). The Re–Os geochronology suggests that the Rb–Sr geochronology records the age of diagenetic events possibly associated with the Pan African collision.The new Re–Os geochronology data provide absolute age constraints for recent carbon isotope chemostratigraphy which suggests that the Atar Group is Mesoproterozoic and not Neoproterozoic.The new Re–Os ORS geochronology supports previous studies that suggest that rapid hydrocarbon generation (flash pyrolysis) from contact metamorphism of a dolerite sill does not significantly disturb the Re–Os ORS systematics. Modelled contact conditions suggest that the Re–Os ORS systematics remain undisturbed at ～ 650 °C at the sill/shale contact and ≥ 280 °C 20 m from the sill/shale contact.Moreover, the Re–Os geochronology indicates that the West African craton has a depositional history that predates 1100 Ma and that ORS can be correlated on a basin-wide scale. In addition, the Re–Os depositional ages for the ORS of the Taoudeni basin are comparable to those of ORS from the São Francisco craton, suggesting that these cratons are correlatable. This postulate is further supported by identical Os_i values for the Atar Group and the Vazante Group of the São Francisco craton.     

Crustal seismic structure and depth distribution of earthquakes in the Archean Kuusamo region,Fennoscandian Shield

Two-dimensional crustal velocity models are derived from passive seismic observations for the Archean Karelian bedrock of north-eastern Finland. In addition, an updated Moho depth map is constructed by integrating the results of this study with previous data sets. The structural models image a typical three-layer Archean crust, with thickness varying between 40 and 52 km. P wave velocities within the 12–20 km thick upper crust range from 6.1 to 6.4 km/s. The relatively high velocities are related to layered mafic intrusive and volcanic rocks. The middle crust is a fairly homogeneous layer associated with velocities of 6.5–6.8 km/s. The boundary between middle and lower crust is located at depths between 28 and 38 km. The thickness of the lower crust increases from 5–15 km in the Archean part to 15–22 km in the Archean–Proterozoic transition zone. In the lower crust and uppermost mantle, P wave velocities vary between 6.9–7.3 km/s and 7.9–8.2 km/s. The average V_p/V_s ratio increases from 1.71 in the upper crust to 1.76 in the lower crust.The crust attains its maximum thickness in the south-east, where the Archean crust is both over- and underthrust by the Proterozoic crust. A crustal depression bulging out from that zone to the N–NE towards Kuusamo is linked to a collision between major Archean blocks. Further north, crustal thickening under the Salla and Kittilä greenstone belts is tentatively associated with a NW–SE-oriented collision zone or major shear zone. Elevated Moho beneath the Pudasjärvi block is primarily explained with rift-related extension and crustal thinning at ∼2.4–2.1 Ga.The new crustal velocity models and synthetic waveform modelling are used to outline the thickness of the seismogenic layer beneath the temporary Kuusamo seismic network. Lack of seismic activity within the mafic high-velocity body in the uppermost 8 km of crust and relative abundance of mid-crustal, i.e., 14–30 km deep earthquakes are characteristic features of the Kuusamo seismicity. The upper limit of seismicity is attributed to the excess of strong mafic material in the uppermost crust. Comparison with the rheological profiles of the lithosphere, calculated at nearby locations, indicates that the base of the seismogenic layer correlates best with the onset of brittle to ductile transition at about 30 km depth.We found no evidence on microearthquake activity in the lower crust beneath the Archean Karelian craton. However, a data set of relatively well-constrained events extracted from the regional earthquake catalogue implies a deeper cut-off depth for earthquakes in the Norrbotten tectonic province of northern Sweden.     

Visualization and modeling of the colonization dynamics of a bioluminescent bacterium in variably saturated,translucent quartz sand

An experimental and numerical investigation was conducted to study the colonization dynamics of a bioluminescent bacterium, Pseudomonas fluorescens HK44, during growth in a porous medium under steady, variably saturated flow conditions. Experiments were conducted in a thin-slab light transmission chamber filled with uniform, translucent quartz sand. Steady, variably saturated flow conditions were established using drip emitters mounted on the top of the chamber, with glucose applied through a central dripper located directly above an inoculated region of the chamber. Periodic pulses of salicylate and a dye tracer were applied to induce bioluminescence of the bacterium to monitor colony expansion and to track changes in the hydraulic and transport properties of the sand. Changes in the apparent water saturation of the sand were quantified by monitoring light transmission through the chamber with a CCD camera. The colonized region expanded laterally by about 15 cm, and upward against the flow by 7–8 cm during the 6-day experiment while apparent saturations in the colonized region decreased by 7–9% and the capillary fringe dropped by ∼5 cm. The observed data were reproduced approximately using a numerical model that accounted for the processes of water flow, solute and bacterial transport, cell growth and accumulation, glucose and oxygen consumption, and gas diffusion and exchange. The results of this study illustrate some of the complexities associated with coupled flow, reactive transport, and biological processes in variably saturated porous media, such as localized desaturation, capillary fringe lowering effects, and upstream movement of bacterial colonization, that may not readily observable using other experimental techniques.     

Importance of reversible attachment in predicting E. coli transport in saturated aquifers from column experiments

Drinking water wells indiscriminatingly placed adjacent to fecal contaminated surface water represents a significant but difficult to quantify health risk. Here we seek to understand mechanisms that limit the contamination extent by scaling up bacterial transport results from the laboratory to the field in a well constrained setting. Three pulses of Escherichia coli originating during the early monsoon from a freshly excavated pond receiving latrine effluent in Bangladesh were monitored in 6 wells and modeled with a two-dimensional (2-D) flow and transport model conditioned with measured hydraulic heads. The modeling was performed assuming three different modes of interaction of E. coli with aquifer sands: (1) irreversible attachment only (best-fit k_i = 7.6 day⁻¹); (2) reversible attachment only (k_a = 10.5 and k_d = 0.2 day⁻¹); and (3) a combination of reversible and irreversible modes of attachment (k_a = 60, k_d = 7.6, k_i = 5.2 day⁻¹). Only the third approach adequately reproduced the observed temporal and spatial distribution of E. coli, including a 4-log₁₀ lateral removal distance of ∼9 m. In saturated column experiments, carried out using aquifer sand from the field site, a combination of reversible and irreversible attachment was also required to reproduce the observed breakthrough curves and E. coli retention profiles within the laboratory columns. Applying the laboratory-measured kinetic parameters to the 2-D calibrated flow model of the field site underestimates the observed 4-log₁₀ lateral removal distance by less than a factor of two. This is promising for predicting field scale transport from laboratory experiments.     

Density and flow structure in the Clyde Sea front

A well-defined front in temperature and salinity separates the stratified Clyde Sea water from the vertically well mixed water of the North Channel. The detailed structure of the front was observed in autumn 1990 by a combination of, repeated crossings of the front using a ship-borne ADCP and a towed undulating CTD system, and the deployment of a fixed mooring system with temperature, salinity and velocity sensors for a period of 12 days. The results show that the front was situated on the Great Plateau near a contour of log₁₀(H/U³₂)=2.7∼3.7 where H is the water depth and U₂ the amplitude of M₂ tidal velocity. The temperature structure in the Clyde Sea was inverted and the Clyde Sea surface temperature was lower than that of the vertically well mixed water in the North Channel. Since the salinity gradient was stronger than the temperature gradient with fresher water on the surface, the density structure was predominantly controlled by salinity. There were indications of warm and saline bottom water upwelling on the mixed side of the front during spring tides. This upwelling disappeared and the salinity and temperature structure at the front was more diffuse during the neap tide period. A jet-like along-front residual current was observed flowing to the northwest in the surface layer with a counter flow to the southeast in the bottom layer. The vertical difference in velocity was about 9 cm s⁻¹ and was approximately consistent with the shear determined from the thermal wind relation. Both cross- and along-front components of the current observed at the mooring station varied in response to the advection of the front, although both components had large variations with periods of less than one day and several days. The front was advected past the mooring system by a mean flow from the North Channel to the inner basin, while oscillating 3–5 km back and forth with the tidal currents. From the velocity at a current meter mooring and CTD data, the front was estimated to have moved up to 20 km during the observational period and the cross frontal velocity was inferred to be 3–4 cm s⁻¹.     

Coda-Q and its lapse time dependence analysis in the interaction zone of the Dinarides,the Alps and the Pannonian basin

The single backscattering model was used to estimate total attenuation of coda waves (Q_c) of local earthquakes recorded on eight seismological stations in the complex area of the western continental Croatia. We estimated Q₀ and n, parameters of the frequency dependent coda-Q using the relation Q_c = Q₀fⁿ. Lapse time dependence of these parameters was studied using a constant 30 s long time window that was slid along the coda of seismograms. Obtained Q_c were distributed into classes according to their lapse time, t_L. For t_L = 20–50 s we estimated Q₀ = 45–184 and n = 0.49–0.94, and for t_L = 60–100 s we obtained Q₀ = 119–316 and n = 0.37–0.82. There is a tendency of decrease of parameter n with increasing Q₀, and vice versa. The rates of change of both Q₀ and n seem to decrease for lapse times larger than 50–80 s, indicating an alteration in rock properties controlling coda attenuation at depths of about 100–160 km. A very good correlation was found between the frequency dependence parameter n and the Moho depths for lapse times of 50, 60 and 70 s.     

Analytical solution for enhanced recharge around a bedrock exposure caused by deep-aquifer dewatering through a variable thickness aquitard

In this study an analytical solution was developed to predict steady radially-symmetric percolation rates from an aquifer underlain by a variable thickness aquitard. The solutions consider an aquitard with constant thickness and with radial-symmetrically increasing thickness outward from the center. The solution was used to predict the percolation rate from a peat layer around a bedrock outcrop in the James Bay Lowland near the De Beers Victor diamond mine. In this case the marine sediment layer limited the direct connection between the peat layer and the bedrock as an aquitard. Our zero order solution with constant marine sediment thickness showed the best fit to the steady state water level data of June 2012. It was found that the enhanced recharge around bioherms (i.e., at rates greater than the regional average of 0.7 mm/day) will only occur in marine sediments less than 4.3 m thick, for extreme depressurization of 30 m.     

Degassing of stratified magma by compositional convection

A new model is proposed for passive degassing from sub-volcanic magma chambers. The water content in stably stratified shallow magma chamber will be equated to its solubility at the upper boundary by convection. Water from a lower layer high in water content can enrich the contact zone of the upper layer and lead to further convective overturn of this boundary layer. A complete set of equations describing convection with bubble formation and dissolution is reduced to a simplified form by assuming a small bubble content. The development and pattern of flow driven by vesiculation is modeled numerically in a 2D magma chamber for relatively low Raleigh numbers (5×10⁵). Bubbles rising from the magma will collect near the roof in a layer of 8–10 vol% and then escape upward to fumaroles. The Stokes flux of bubbles escaping from an andesitic magma with viscosity 10⁴ P and a top surface of about 500×500 m corresponds with observed total magmatic water fluxes of 35 kg/s. Pressure within the chamber is buffered by elastic (and local visco-elastic) deformations in the solid rocks bounding the chamber to the range between ambient and close to lithostatic values. In a chamber closed to fresh magma inputs, the decrease in volume due to such gentle volatile escape lowers the reference pressure. Bubbles flux from the lower layer induced by variation of the saturation level around stratification boundary may be efficient mechanism for the water transport between layers.     

Bioremediation of surface water co-contaminated with zinc (II) and linear alkylbenzene sulfonates by Spirulina platensis

Potential remediation of surface water contaminated with linear alkylbenzene sulfonates (LAS) and zinc (Zn (II)) by sorption on Spirulina platensis was studied using batch techniques. Results show that LAS can be biodegraded by Spirulina platensis, and its biodegradation rate after 5 days was 87%, 80%, and 70.5% when its initial concentration was 0.5, 1, and 2 mg/L, respectively. The maximum Zn (II) uptake capacity of Spirulina platensis was found to be 30.96 mg/g. LAS may enhance the maximum Zn (II) uptake capacity of Spirulina platensis, which can be attributed to an increase in bioavailability due to the presence of LAS. The biodegradation rates of LAS by Spirulina platensis increased with Zn (II) and reached the maximum when Zn (II) was 4 mg/L. The joint toxicity test showed that the combined effect of LAS and Zn (II) was Synergistic. LAS can enhance the biosorption of Zn (II), and reciprocally, Zn (II) can enhance LAS biodegradation.     

Magnetic susceptibility and Cs-137 inventory variability as influenced by land use change and slope positions in a hilly,semiarid region of west-central Iran

The objective of this study was to explore the slope position and land use change effects on the variability in magnetic susceptibility and ¹³⁷Cs inventory as the soil redistribution indicators in a hilly semiarid calcareous area in Iran. The selected study area is located in a hilly region with pasture and cultivation land use of Fereydunshahr, Isfahan Province in west-central Iran. In the two mentioned dominant ecosystems, four slope positions including summit, shoulder, backslope and footslope were identified and in each land use and slope position, three cores were selected to collect 72 soil samples from three depths (0–10, 10–20, 20–30 cm) in an area of 15 × 15 cm. Additional 28 soil samples were collected from the reference site for soil loss and deposition calculations by using the Cs-137 measurement. The results of the study with the use of the Cs-137 technique showed that the average soil loss in the pasture land (46.4 t ha^− 1 yr^− 1) was significantly (p < 0.05) lower than the average soil loss in the cultivated land (80.4 t ha^− 1 yr^− 1). The highest soil loss in both land uses was obtained in the shoulder position, 60.1 and 84.4 t ha^− 1 yr^− 1, respectively, for the pasture and cultivated lands. Moreover, the highest rates of soil deposition was observed in a footslope position in both land uses and they were 34 and 32.4 t ha^− 1 yr^− 1 for the pasture and cultivated lands, respectively. Magnetic susceptibility was significantly (p < 0.05) greater in pasture (χ_lf = 41.51 × 10^− 8 m³/kg) than in the cultivated land (χ_lf = 34.90 × 10^− 8 m³/kg). The pasture land with a lower soil loss rate, indicated significantly higher magnetic susceptibility in all landform positions as compared to that in the cultivated land. The results of the correlation analysis showed that among the studied soil physico-chemical properties, χ_lf (r = 0.83, p < 0.01) in the pasture land had the highest correlation with the Cs-137 inventory. Throughout the non-linear regression analysis, χ_lf was introduced for relating soil parameters and the cesium inventory explained 68% and 79% of the total variability of ¹³⁷Cs in the pasture and cultivated lands, respectively. The results implied that the variability in the magnetic susceptibility within the hillslope is consistent with the variation of the Cs-inventory; and the results thus demonstrate the slope and land use effects on soil redistribution.     

An evaluation of the toxicity and bioaccumulation of thallium in the coastal marine environment using the macroalga,Ulva lactuca

Thallium(I) has been added to cultures of the marine macroalga, Ulva lactuca, for a period of 48 h and the accumulation of the metal and its effects on the photochemical efficiency of photosystem II (PS II) measured. Thallium elicited a measurable toxic response above concentrations of 10 μg L⁻¹ in both coastal seawater (salinity 33) and estuarine water (salinity 20). The accumulation of Tl was defined by a linear relationship with aqueous Tl and accumulation factors of about 900 mL g⁻¹ in both media. Thallium accumulated by U. lactuca that was resistant to an EDTA extraction and, by operational definition, internalised, exceeded 90% in both cases. Accumulation and toxicity of Tl in the presence of a ∼10⁵-fold excess of its biogeochemical analogue, potassium, suggests that Tl has a high intrinsic phytotoxicity and that its mode of action involves permeation of the cell membrane as Tl⁺ through NaCl–KCl co-transporter sites rather than (or in addition to) transport through K⁺ ion channels.     

Forecasting the ionospheric f0F2 parameter one hour ahead using a support vector machine technique

This paper proposes a method for forecasting the ionospheric critical frequency, f₀F₂, 1 h in advance, using the support vector machine (SVM) approach. The inputs to the SVM network are the time of day, seasonal information, 2 month running mean sunspot number (R2), 3 day running mean of the 3 h planetary magnetic ap index, the solar zenith angle, the present value f₀F₂(t) and its first and second increments, the observation of f₀F₂ at t?23 h, the 30-day mean value at time, t, f_mF₂ (t) and the previous 30 day running mean of f₀F₂ at t?23 h f_mF₂(t?23). The output is the predicted f₀F₂ 1 h ahead. The network is trained to use the ionospheric sounding data at Haikou, Guangzhou, Chongqing, Lanzhou, Beijing, Changchun and Manzhouli stations at high and low solar activities. The performance of the SVM model was verified with observed data. It is shown that the predicted f₀F₂ has good agreement with the observed f₀F₂. The performance of the SVM model is superior to that of the autocorrelation and persistence models, and that it is comparable to that of the neural network model.     

Short- and long-time behavior of aquifer drainage after slow and sudden recharge according to the linearized Laplace equation

During the last 25 years there has been a great interest in deriving aquifer characteristics from outflow data. This analysis has been mainly based of the drainage of a horizontal aquifer after sudden drawdown, using the Boussinesq approximation. Following the general approach of Brutsaert and Lopez [Brutsaert W, Lopez, JP. Basin-scale geohydrologic drought flow features of riparian aquifers in the southern Great Plains. Water Resour Res 1998;34(2):233–40], it was determined that for this geometry the aquifer behavior could be characterized by dQ/dt ∝ Q³ for small t and by dQ/dt ∝ Q^3/2 for large t. It was remarked that dQ/dt ∝ Q for large t is often observed. In practice, it is also difficult to determine if dQ/dt ∝ Q³ for small t because this behavior can only be observed over a very short period.Here, we present a similar analysis of aquifer behavior based on the more fundamental Laplace solution for penetrated aquifers. It has been shown that also when the drain does not fully penetrate the aquifer, the solution still produces good results [Szilagyi, J. Sensitivity analysis of aquifer parameter estimations based on the Laplace equation with linearized boundary conditions. Water Resour Res 2003;39(6)]. The Laplace solution quickly shows that dQ/dt ∝ Q for t → ∞ and dQ/dt ∝ Q^∞ for t → 0, after sudden drawdown. This analysis reconfirms previous findings concerning long-time behavior. More importantly, the analysis shows that the exponent B in dQ/dt ∝ Q^B does not have a fixed limited value for short times for the given geometry. Further analysis, however, shows that under certain conditions the relation dQ/dt ∝ Q³ is retained for 0 ≪ t < 1. Detailed examination of the Laplace solution also shows under which types of recharge dynamics a well-identifiable transition takes place between short- and long-term behavior. As long as such a clear transition exists, the aquifer characterization method proposed earlier by Brutsaert and Lopez [Brutsaert W, Lopez, JP. Basin-scale geohydrologic drought flow features of riparian aquifers in the southern Great Plains. Water Resour Res 1998;34(2):233–40] can be applied. It is shown that for a sharp pulse input, the Laplace solution gives similar results as presented by Brutsaert and Lopez [Brutsaert W, Lopez, JP. Basin-scale geohydrologic drought flow features of riparian aquifers in the southern Great Plains. Water Resour Res 1998;34(2):233–40]. For a smooth pulse, the transition becomes unclear. What is “smooth” and “sharp” depends on input and aquifer characteristics, whereby shallow aquifers give clearer transitions than deep aquifers for the same input. The analysis shows that when rain ceases suddenly after the aquifer has come into equilibrium with a steady rain input, a usable transition in the relation between dQ/dt and Q can be found as well. Researchers can use the present analysis to assess whether specific aquifers and recharge events can be used for the previously suggested characterization method.     

Estimation of Shallow S-Wave Velocity Structure in Damascus City,Syria, Using Microtremor Exploration

Array measurements of microtremors were carried out at thirty sites in Damascus city, Syria to estimate S-wave velocity structures of shallow soil formations for site effect analysis. The microtremor data were recorded by 6 vertical-component seismometers distributed along the circumferences of two circles as well as a 3-component seismometer deployed in the center. The phase velocities were estimated at each site from the vertical components of recorded microtremor data by using the Spatial Autocorrelation method. Then, Genetic Simulated Annealing Algorithm technique was applied for inversion of the phase velocities to estimate 1-D S-wave velocity structures beneath the sites. The inverted Vs profiles are not uniform in Damascus city and the results show that a shallow soft layer (∼200 m/s) appears in the eastern part of the city as well as the central part along Barada River. This layer controls the amplification distribution in the city with a high amplification mainly observed at the locations having this layer. The inversion results also show that the depth to the engineering bedrock (∼750 m/s) is very shallow along the foothills of Mt. Qasyoun in the north-west. Then the depth increases towards the east and the south. The maximum depth to the engineering bedrock (∼80 m) was observed in the southern part of Damascus. To validate the results of the inversions, the spectral ratios between the horizontal and vertical components (H/V) of the recorded microtremor data at the central seismometer were compared with the computed ellipticities of the fundamental-mode Rayleigh-waves based on the respective Vs structure. The results show a good agreement in a period range of 0.05 s to 0.5 s. In this period range, the dominant peaks of the H/V ratios are due to the overall effect of the velocity contrasts between the shallow layers representing the subsurface S-wave velocity structure. Moreover, the average S-wave velocity for the top 10 m of soils (V_S10) shows a better correlation with the averaged site amplification in a period range of 0.05 s to 0.5 s than V_S30 which indicates that V_S10 can be a better proxy for high-frequency site amplification in the case of Damascus city.     

Taiwan strait current in winter

Four bottom-mounted current profilers were deployed across the Taiwan Strait from September 28 to December 14 of 1999 to monitor the current velocity when the northeast monsoon was strong. Results indicate both diurnal and semidiurnal tidal currents were primarily barotropic. The barotropic diurnal tide might be explained by a single Kelvin wave propagating along the Mainland China coast from north to south. However, the barotropic semidiurnal tide manifested as a more complicated form in the Taiwan Strait.The subtidal current generally fluctuated with the northeast winds. When the northeast wind was weak, the along- and cross-strait subtidal current flowed primarily against the wind and toward Taiwan, respectively. As the northeast wind intensified, the along-strait current flowed downwind, brought the cold China coastal water southward, and formed a baroclinic velocity front in the western portion of the Taiwan Strait. The Ekman effect forced the cross-strait current toward Mainland China in the upper water column and toward Taiwan in the lower water column, respectively. The along-strait volume transport, estimated from interpolated current velocity, varied from −5 to 2 Sv with a mean value of 0.12±0.33 Sv. Similar transport was also estimated from the sea level difference across the Taiwan Strait.Although the local wind played a dominant role for the fluctuations of current velocity and transport in the Taiwan Strait, it could be not the only important factor. The current or transport directed frequently against the wind could be related to the northward current, which was consistently observed in the Penghu Channel.     

Co-sequestration of SO2 with supercritical CO2 in carbonates: An experimental study of capillary trapping,relative permeability,and capillary pressure

In this study we performed three categories of steady- and unsteady-state core-flooding experiments to investigate capillary trapping, relative permeability, and capillary pressure, in a scCO₂ + SO₂/brine/limestone system at elevated temperature and pressure conditions, i.e., 60 °C and 19.16 MPa. We used a Madison limestone core sample acquired from the Rock Springs Uplift in southwest Wyoming. We carried out two sets of steady-state drainage-imbibition relative permeability experiments with different initial brine saturations to study hysteresis. We found that the final scCO₂ + SO₂ drainage relative permeability was very low, i.e., 0.04. We also observed a rapid reduction in the scCO₂-rich phase imbibition relative permeability curve, which resulted in a high residual trapping. The results showed that between 62.8% and more than 76% of the initial scCO₂ + SO₂ at the end of drainage was trapped by capillary trapping mechanism (trapping efficiency). We found that at higher initial brine saturations, the trapping efficiency was higher. The maximum initial and residual scCO₂-rich phase saturations at the end of primary drainage and imbibition were 0.525 and 0.329, respectively. Each drainage-imbibition cycle was followed by a dissolution process to re-establish S_w = 1. The dissolution brine relative permeabilities for both cycles were also obtained. We characterized the scCO₂ + SO₂/brine capillary pressure hysteresis behavior through unsteady-state primary drainage, imbibition, and secondary drainage experiments. We observed negative imbibition capillary pressure curve indicative of possible wettability alteration throughout the experiments due to contact with scCO₂ + SO₂/brine fluid system. The trapping results were compared to those reported in literature for other carbonate core samples. We noticed slightly more residual trapping in our sample, which might be attributed to heterogeneity, different viscosity ratio, and pore-space topologies. The impact of dynamic effects, i.e., high brine flow rate imbibition tests, on trapping of the scCO₂-rich phase was also explored. We performed two imbibition experiments with relatively high brine flow rates. The residual scCO₂ saturation dropped to 0.291 and 0.262 at the end of the first and second imbibition tests, i.e., 11.5% and 20.4%, respectively, compared to 0.329 under capillary-dominated regime.     

Fine-sediment transport associated with cold-front passages on the shallow shelf,Gulf of Mexico

The eastern part of the chenier plain of the Louisiana coast has been prograding seaward over the last few decades while much of the rest of the Louisiana coast is experiencing high erosion rates. The source of sediment is the Atchafalaya River, which has been delivering sediment to the coastal ocean since the 1940s. Researchers have suggested that the repeated passage of cold fronts during winter and early spring plays an important role in delivering sediment to the coast. A sediment-transport study on the Atchafalaya coast was conducted between October 1997 and March 2001, which included several field experiments in early March, the period of high discharge from the Atchafalaya and frequent cold-front activity. A combination of shipboard profiling and time-series measurements from a bottom tripod and array of wave sensors on the inner shelf has resulted in a data set that illustrates the mechanism of onshore transport. For a cold-front passage sampled in 2001, during pre-front conditions, sediment is resuspended and mixed throughout the water column, with transport rates onshore and to the west of 53 and 184 g s⁻¹ m⁻¹, respectively. Post-front conditions also result in onshore transport due to onshore flow (upwelling) in the lower meter of the water column and formation of a high-concentration bottom layer. Post-front onshore transport rates are 32 g s⁻¹ m⁻¹ and most of the transport occurs in the bottom meter of the water column. The repeated cycling of cold-front passages leads to a positive feedback with transport onshore during both pre- and post-front conditions, and effective attenuation of wave energy over the muddy inner shelf inhibits erosion at the coast. Thus, the chenier-plain coast is experiencing high progradation rates (up to 29 m yr⁻¹), while most of the Gulf coast is eroding.