尤碳钙铀矿在我国首次发现

尤碳钙铀矿是一种含钙的铀酰碳酸盐矿物,在我国湖南省首次发现。它产于湖南某花岗岩型热液铀矿床氧化带中,与红铀矿、橙黄铀矿、水丝铀矿、β-硅钙铀矿、纤碳铀矿等共生。矿物为黄色。比重D_(?)=4.0,D_(cal)=4.16。在长波紫外线照射下发污黄绿色弱荧光。二轴晶,负光性。折光率α=1.635,β=1.626,γ=1.505,2V=40°±。斜方晶系。X射线粉晶分析主要强线为8.10(9),7.20(10),3.51(8),3.15(9)。微量化学全分析结果CaO 4.08%,UO_3 74.44%,CO_2 4.29%,H_2O 13.27%。化学式为Ca (UO_2)_3[CO_3](OH)_6·5H_2O。     

我国首次发现的碳氢钠石

碳氢钠石是一种无水碱金属碳酸盐矿物,最初发现于美国的绿河盆地。一九八二年,在我国河南省泌阳凹陷首次发现。该矿物的化学成分是Na_2CO_3和NaHCO_3,分子式是:Na_2CO_3·3NaHCO_3。该矿物晶体呈板状,无色透明,主要产在重碳钠盐组成的碱矿层中。经测试确定,该矿物属二轴晶负光性,主折射率:Ng=1.531,Nm=1.524,Np=1.435,2V=31.45°;晶胞参数:a=10.046,b=15.633,c=3.492,a=92°8′,β=95。42′,γ=108°34′;最强的粉晶衍射线有:3.70(35),2.97(100),2.67(41),2.213(60);主要的红外光谱吸收带是:2616,1692,1662,1359,1048,1018,839,677cm_(-1)。据碳氢钠石的产状和共生组合特征,该矿物产于富钠,高P_(CO_2)的碳酸盐型内陆盐湖,是较高温度条件下快速蒸发的产物。     

萨碳硼镁钙石晶体结构的精确测定

本文对萨碳硼镁钙石(sakhaite)Ca_(48)Mg_(16)(BO_3)_(28)(CO_3)_(16)(Cl,F)_6(OH)_6·nH_2O的晶体结构进行了重新测定,求得晶胞参数:a=b=c=1.46151(9)nm。晶胞体积:V=3.1218(3)nm~3。单位晶胞中分子数Z=1,空间群为Fd3。结构测定的精度偏离因子R=0.0504。根据矿物化学成分及晶体结构特征,与前人报道的萨碳硼镁钙石及其人工合成矿物晶体结构特征进行了对比,指出本次测定的矿物与前人报道的天然萨碳硼镁钙石或人工合成矿物在矿物成分与结构上的差异,据此,讨论了我国产出的“萨碳硼镁钙石”有待重新命名的必要性。     

首次发现锰副硅灰石

锰副硅灰石是副硅灰石一个新变种矿物,为国内外首次发现。产于我国内蒙古矽卡岩型铅锌矿床中。矿物属于单斜晶系,空间群C_(2h)~5-P2_(1/c),晶胞参数a=1.47213,b=0.70489,c=0.69055nm,β=95.827°±0.03,V=0.71289nm~3,Z=12。化学分子式为(Ca_(0.75)Mn_(0.19)Fe_(0.068))_(1.00)Si_(1.00)O_3,属于硅灰石亚族矿物。     

盈江铀矿的新资料

本文第一次提供了由单晶X射线衍射分析测定的盈江铀矿的空间群和晶胞参数。该矿物产于广东省下庄铀矿田。斜方晶系,空间群Bmmb(63),a=15.707(3),b=17·424(3),c=13.692(2)?,V=3747?~3,Z=4。Dc=4.60g/cm~3,Dm=4.54g/cm~3。化学式:(K_2,Ca)(UO_2)_7(PO_4)_4(OH)_6·6H_2O。二轴晶,负光性。2Vc=36°,2Vm=36—38°。Ng=1.707(2),Nm=1.703(2),Np=1.666(1)。光性方位:Ng//Y,Nm//X,Np//Z。     

新的锂矿物——扎布耶石(Zabuyelite)

在西藏扎布耶盐湖中首次发现天然碳酸锂,呈细小棱柱状,单斜晶系,D=2.09±0.01(实测)。无色透明,β平行b轴,光轴面垂直(010),γ∧C=10°,沿(100)具双晶。γ=1.5743±0.001,β=1.5672±0.001,α=1.4285±0.001,2V(-)?25°。经化学全分析配算其化学式为Li_2CO_3。X射线特征线条:4.16(8)、2.92(8)、2.81(10)。α_0=0.835±0.0003nm,b_0=0.4964±0.001nm,c_0=0.6185±0.0009nm,     

新矿物——钓鱼岛石的研究

钓鱼岛石是在我国台湾省钓鱼岛附近海域海底表层沉积物中发现的一种新矿物。钓鱼岛石为无色淡绿色到,薄板状,一轴晶负光性,晶体很小,一般在0.4×0.2×0.03mm~3以下,D=3.30,H_(v15)=1392.8kg/mm~2。电子探针定量分析(以相应氧化物为标样)结果(％):Na_2O4.54、Al_2O_3 93.00、Cr_2O_31.95、MgO0.10、CaO 0.10、SiO_2 0.23、K_2O 0.12,总量100.04。以氧为17计算的化学式为(Na_(0.87) K_(0.02) Mg_(0.02) Ca_(0.01);)_(0.92)(Al_(10.84)Cr_(0.15)Si_(0.02))_(11.01)O_(17)。经四圆单晶衍射证明,该矿物为六方晶系,空间群为P6_3/mmc,a=b=5.602(1)Ac=22.626(5)A,α=β=90°,γ=120°。     

李时珍石—一种Zn硫酸盐新矿物

李时珍石是一种Zn硫酸盐新矿物,发现于我国青海省锡铁山铅锌矿床氧化带,化学分子式是ZnFe_2~(3+)(SO_4)_4·14H_2O。该矿物产于硬石膏裂隙或孔洞中,与粒铁矾、叶绿矾、自然硫、石膏、黄铁矿、石英等共生。晶体习性板状或板柱状。淡玫瑰紫色,玻璃光泽。硬度3.5,解理{010}近于完善。实测密度D_m=2.206(4)g/cm~3,计算密度D_c=2.201g/cm~3。偏光镜下无色,无多色性,2V(-)-47°;黄光中的折射率:α——1.522(2),β——1.568(1),γ——1.578(4)。空间群P(?),晶胞参数:a=6.477(1),b=15.298(3),c=6.309(1),α=90.20°(1),β=101.11°(1),γ=93.97°(1),V=611.9(1)(?)~3,Z=1。DTA曲线在119—156和740℃处有2个主要强吸热峰,在214,246,296和802℃处有4个弱吸热峰。TG曲线表明矿物在加热时,分阶段脱失结晶水,到310℃时,总失重量为30%。红外光谱在3351—3035和1131—997cm~(-1)处有2个主要吸收带;在1658—1651,667—537和484cm~(-1)处有3个次要吸收带。不同温度下测量的穆斯堡尔谱,由-Fe~(3+)离子的宽阔不对称单峰组成。     

柴达木石——一种锌和铁的硫酸盐新矿物

柴达木石是一种Zn和Fe~(3+)的硫酸盐新矿物,发现于我国青海省柴达木锡铁山铅锌矿氧化带。矿物属单斜晶系,空间群P2_1/m或P2_1,晶胞参数a=9.759(9)A,b=7.134(9)A,c=7.335(11)A,β=106.2(1)°,Z=2。化学分子式为ZnFe~(3+)(SO_4)_2(OH)·4H_2O。它是四水铜铁矾(guildite)的类似物。     

新的锂矿物——扎布耶石

在西藏扎布耶盐湖首次发现的天然碳酸锂呈细小棱柱状,单斜晶系,D=2.09±0.01(实测)。无色透明。解理沿 {100}完全,{011}中等,(011)与(011)的解理交角等于45°,具淡黄至浅棕色多色性。正交偏光下具高级干涉色。β平行b轴。光轴面垂直(010),Ng∧c=10°,沿(100)具双晶。Ng=1.5743±0.001,Nm=1.5672±0.001,Np=1.4285±0.001,2V(-)≈25°。化学式为Li_2CO_3。X射线特征线条:4.16(8),2.92(8),2.81(10)。α=0.835±0.0003nm,b=0.4964±0.001nm,c=0.6185±0.0009nm,β=114°36′±7′,V=0.233±0.1nm~3,Z=4。红外光谱特征峰有1473(s,sh),1430(v,s),1088(w),862(m),739(v,w),713(v,w),488(s),414(s),259(m)。     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861     

ENGINEERING GEOLOGY

正20141768 An Shaopeng(Institute of Rock and Soil Mechannics,Chinese Academy of Sciences,Wuhan 430071,China);Wei Lide Experimental Study on Mechanical Behavior of Xigeda Formation Siltstone and Structure Interface(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,21(5),2013,p.702-708,9illus.,1 table,16 refs.)     

HISTORICAL GEOLOGY & STRATIGRAPHY

正20140985Chen Liang(Post-Doctoral Research Station of Mining Engineering,School of Nuclear Resources and Nuclear Fuel Engineering,University of South China,Heng-yang 421001,China);Huang Wei Composition of Major and Correlated Elements with Organic Matters and Paleoclimatic Implication for Lower Paleogene Sediments in Sanshui Basin