The palaeoposition of Madagascar: Remanence and magnetic properties of late Palaeozoic sediments

Palaeomagnetic results are reported from the predominantly green sediments of the Upper Permian to Lower Triassic Sakamena Group and the Upper Carboniferous to Lower Permian Sakoa Group of Madagascar. Secondary magnetizations could only be removed successfully through thermal demagnetization procedures and then only if the cleaning process was completed by 450°C. Heating in air caused extensive magnetochemical changes to occur above this temperature. Coercivity spectrum analysis and low-temperature characteristics of the heated and unheated green sediments indicate that considerable amounts of fine-grained single-domain magnetite are formed at 500°C or more from some non-magnetic mineral, probably the iron silicates. For this reason consistent palaeomagnetic data could only be obtained from about half the samples collected. Results from 4 sites (19 samples) of the Lower Sakamena Group give a palaeomagnetic pole at 64.9S, 113.9E (A₉₅ = 5.6°) and 3 sites (16 samples) from the Glacial Series of the Sakoa Group give a pole at 47.9S, 84.1E (A₉₅ = 8.1°). When compared with corresponding data from Africa these results confirm and strengthen our previous conclusions from the Triassic-Jurassic Isalo Group regarding the palaeoposition of Madagascar. All three poles are only consistent with the Smith and Hallam reconstruction which places Madagascar off the eastern coast of Africa adjacent to Kenya and Tanzania.     

Palaeomagnetic study of late precambrian rocks of the midland craton of England and Wales

The Precambrian basement of the British region south of the Caledonian orogenic belt is only observed in a few small inliers; this paper reports a detailed paleomagnetic study of four of these inliers. The Stanner-Hanter amphibolitised gabbro-dolerite complex of uncertain age yields a mean direction of magnetisation D = 282°, I = 51° (15 sites,α₉₅ = 11.4°) after AF and thermal cleaning. Uriconian lavas and tuffs (～700-600 m.y.) of the Pontesford and Wrekin inliers require both thermal and AF cleaning for complete analysis of NRM. The former region (Western Uriconian) yields a mean of D = 136°, I = ?25° (6 sites,α₉₅ = 15.3°) and the latter region (Eastern Uriconian) a mean of D = 78°, I = 17° (9 sites, α₉₅ = 12.8°); the Eastern Uriconian shows a marked improvement in precision after a two-stage fold test, and the palaeomagnetic data suggest that some apparent polar movement took place between eruption of the two sequences. The Uriconian rocks in both areas were intruded by dolerites which yield a mean direction of magnetisation D = 72°, I = 54° (11 sites,α₉₅ = 13.2°).The collective data give palaeomagnetic poles related to Upper Proterozoic metamorphic episodes (Stanner-Hanter Complex and Rushton Schist) which are in close agreement with earlier studies of the Malvernian metamorphic rocks, and to the late Precambrian Uriconian volcanic/hypabyssal igneous episode. All of these magnetisations are probably confined to the interval 700-600 m.y., and are indicative of appreciable polar movement during this interval. The palaeomagnetic poles define an apparent polar wander path for this crustal block between Late Precambrian and Lower Cambrian times and show that cratonic Britain south of the Caledonian suture is unrelated to the Baltic Shield.     

Palaeomagnetism of Upper Cretaceous volcanic rocks from Cabo de Sto. Agostinho,Brazil

One hundred samples from nine sites in Upper Cretaceous volcanics (K/Ar age 85–99 m.y.) of the magmatic province of Cabo de Santo Agostinho, Pernambuco (8.4°S, 35.0°W) yield a mean direction of magnetizationD = 0.4°, I = ?20.6°withα₉₅ = 4.8°, k = 114 after AF cleaning. All sites have normal polarity with a mean pole, named SAK₁₀, at 87.6°N, 135°E withA₉₅ = 4.5° which is close to other Upper Cretaceous poles for South America. These poles are compared with Upper Cretaceous poles of Africa for various reconstructions of the two continents.     

Geochemistry of Devonian–Carboniferous clastic sediments of the Tsetserleg terrane,Hangay Basin,Central Mongolia: Provenance,source weathering,and tectonic setting

The Devonian–Carboniferous Tsetserleg terrane of Mongolia forms part of the complex Central Asian Orogenic Belt (CAOB). The Tsetserleg terrane consists mainly of clastic sediments, and is situated in the southern Hangay–Hentey Basin. Internally the terrane is divided into the Erdenetsogt (Middle Devonian), Tsetserleg (Middle‐Upper Devonian) and Jargalant (Lower Carboniferous) Formations. Provenance and tectonic setting of the Hangay–Hentey Basin remains controversial, with proposals ranging from passive margin through to island‐arc. A suite of 94 Tsetserleg sandstones and mudrocks was collected with the aim of constraining provenance, source weathering, and depositional setting, using established petrographic and whole‐rock geochemical parameters. Petrographically the sandstones are immature, with average compositions of Q₂₂F₁₄L₆₄, Q₁₄F₁₇L₆₉, and Q₁₈F₁₂L₇₀ in the Erdenetsogt, Tsetserleg, and Jargalant Formations, respectively. Lv/L ratios range from 0.81 to 1.00 (average 0.95), and P/F from 0.68 to 0.93 (average 0.83). Framework compositions indicate deposition in an undissected or transitional arc. Geochemically, the sandstones are classified as greywackes. Geochemical contrasts between sandstone and mudrock averages in each formation are small, with lithotype means for SiO₂ ranging only from 65.54 to 68.62 wt.%. These features and weak trends on variation diagrams reflect the immaturity of the sediments. Comparison of elemental abundances with average upper continental crust, major element discriminant scores, and immobile element ratios indicate a uniform average source composition between dacite and rhyolite. The maximum value for the Chemical Index of Alteration in the Erdenetsogt Formation is about 78 after correction for K‐metasomatism, indicating moderate source weathering. Lower maximum values (61 and 63, respectively) in the Tsetserleg and Jargalant Formations indicate they were derived from a virtually unweathered and tectonically active source. Tectonic setting discrimination parameters indicate a continental island‐arc environment, similar to several other CAOB suites of similar age. This arc source may have been built on a continental fragment situated within the Mongol–Okhotsk Ocean during Middle Devonian‐Lower Carboniferous time.     

Paleomagnetic evidence for the relative positions of Timor and Australia in the Permian

An Upper Permian paleomagnetic pole has been determined for the Cribas Formation in eastern Timor. The co-ordinates for the mean pole are 159.8°E and 56.6°S,α₉₅ = 9.0. The reliability of the pole is ascertained through thermal demagnetization, a fold test, comparison between red beds and a lava flow, and the presence of normal and reversed polarities. The Timor pole is in excellent agreement with the Australian Upper Permian and Triassic poles. From this it is inferred that autochthonous Timor formed part of the Australian continental margin at least since the Upper Permian.     

Geomagnetic field paleointensity in the cretaceous from Upper Cretaceous rocks of Georgia

A representative collection of Upper Cretaceous rocks of Georgia (530 samples from 24 sites) is used for the study of magnetic properties of the rocks and the determination of the paleodirection and paleointensity (H _an) of the geomagnetic field. Titanomagnetites with Curie points of 200–350°C are shown to be carriers of natural remanent magnetization (NRM) preserving primary paleomagnetic information during heatings to 300–350°C. The characteristic NRM component of the samples is identified in the interval 120–350°C. The Thellier and Thellier-Coe methods are used for the determination of H _an meeting modern requirements on the reliability of such results. New paleointensity determinations are obtained and virtual dipole magnetic moment (VDM) values are calculated for four sites whose stratigraphic age is the Upper Cretaceous (Cenomanian-Campanian). It is shown that, in the interval 99.6–70.6 Ma, the VDM value was two or more times smaller than the present value, which agrees with the majority of H _an data available for this time period. According to our results, the H _an value did not change at the boundary of the Cretaceous normal superchron.     

Palaeomagnetism of middle Ordovician volcanic rocks from Quebec

This palaeomagnetic study is centered on agglomerates and volcanic rocks from the western margin of the Appalachian belt in the Drummondville-Actonvale-Granby area, Quebec (long.: 72°30′W, lat.: 46°00′N). It involves a total of 36 oriented samples (111 speciments) distributed over eleven sites. Both thermal and AF cleaning techniques were used to isolate residual remanent components. The dispersion of the directions is slightly reduced after AF cleaning and thermal treatment.The palaeopole position obtained is 191°E, 6°N (d_m = 14°, d_p = 7°) after thermal treatment and 164°E, 19°N (d_m = 11°, d_p = 6°) after AF cleaning. The polarity of most of the sites (two exceptions) are reversed. The thermal-treated data appear to be relatively stable and an approximate value of the primary magnetization is extracted from them. The palaeopole obtained does not lie close to the tentatively defined position of the Cambrian and Ordovician poles from rocks of the North American plate; it is located near the Upper Cambrian and Lower Ordovician poles from eastern Newfoundland and the Lower Ordovician pole from the Caledonides in Europe.     

Paleomagnetism and ore mineralogy of some basalts of the Geirud Formation of Late Devonian - Early Carboniferous age from the southern Alborz,Iran

Basaltic lavas from the southern Alborz, an area about 40 km northeast of Tehran, Iran, have been paleomagnetically investigated. The lavas are of Late Devonian-Early Carboniferous age, and belong to the basal member of the Geirud Formation. At 11 sites a total of 80 cores was drilled.Detailed analyses by means of progressive demagnetization of the natural remanent magnetization (NRM) were made both by the application of alternating magnetic fields and by heating. Also, on a number of specimens a study was done both with thin sections and with polished sections. There proved to be general agreement between the properties of the characteristic NRM and the kind of Fe-Ti oxides in the lavas. In the case of specimens containing magnetite only the characteristic NRM was entirely removed at temperatures just below 600°C, or in alternating fields up to 1500/2000 Oe peak value; on the other hand, in specimens containing both magnetite and a substantial part of hematite (martite) the final part of the characteristic remanence was removed at temperatures above 600°C, and this remanence resisted alternating fields above 2000 Oe peak value. From the characteristic site-mean directions of 5 sites an average paleomagnetic direction is computed withD = 210.8°,I = 66.9°, and α₉₅ = 3.9°.This result might be taken as an indication that at the Devono-Carboniferous transition the southern part of the Alborz was located in the present Indian Ocean off the Arabian coast.     

Paleomagnetism of Lower Devonian volcanics and Devonian dykes from northcentral New Brunswick,Canada

Some 50 oriented samples (120 specimens) have been collected on eight sites of volcanic rocks from the Lower Devonian Dalhousie Group of northern New Brunswick and Devonian andesitic to basic dykes from central New Brunswick. Univectorial and occasional multivectorial components were extracted from the various samples. Results after AF and thermal demagnetization compare relatively well. In the volcanics and tuffs, two components of magnetization have been isolated: A (D = 33°, I = ?58°, α₉₅ = 7.3°, K = 236) for four sites and B (D = 66°, I = +53°) for three sites. The grouping of component A is improved after tilt correction but the fold test is not significantly positive at the 95% confidence level. Component A is interpreted as being primary while component B is unresolved and appears to be the resultant magnetization of a Late Paleozoic and a recent component. The pole position obtained for tilt corrected component A is 268°E, 1°S, d_p = 6.5°, d_m = 8.8°. The paleolatitude calculated for component A is 39°S. The paleopole of in situ component A is located close to those of the Early-Middle Devonian formations from Quebec, New Brunswick and New England states while the paleopole of tilt-corrected component A is similar to Lower Devonian poles of rock units from the Canadian Arctic Archipelago. If component A is primary (as we believe it to be), then the western half of the northern Appalachians had already docked onto the North American Craton by Early Devonian time. Alternatively, if component A is secondary the same conclusion applies but the juxtaposition took place in Middle Devonian time.     

Palaeomagnetism of the Early Carboniferous Deer Lake Group,western Newfoundland: no evidence for mid-Carboniferous displacement of “Acadia”

Early Carboniferous (Viséan to possibly earliest Namurian) sedimentary rocks of the Deer Lake Group of western Newfoundland rest unconformably on Grenvillian basement rocks of the Canadian Shield which form the western border of the Early Palaeozoic Appalachian orogen. In addition to magnetically soft magnetizations directed along the present field, three families of magnetization directions are found. Two of them (referred to as N (north) and S (south)) are antiparallel and prefolding, and were probably acquired during the depositional process. N and S are roughly of equal frequency. They have a mean direction irrespective of sign of 0.7°, ?35.2°, k = 40, α₉₅ = 8.9°, and a palaeopole 21.5°N, 121.8°E (10.3°, 6.0°) corresponding to a palaeolatitude of 20 ± 6°S. This agrees with the palaeolatitude (17 ± 5°S) determined from the somewhat older Early Carboniferous (Tournaisian) Terenceville Formation of the Avalon Platform on the eastern side of the Appalachian orogen in Newfoundland. The third magnetization, referred to as H (roughly horizontal), has a mean direction 156.8°, ?13.3°, k = 37, α₉₅ = 10.1°, and a palaeopole 45.4°N, 140.3°E (10.3°, 5.3°) corresponding to a palaeolatitude of 7 ± 4°N; we interpret this to be an early Kiaman (latest Carboniferous to early Permian) overprint probably acquired chemically. The palaeolatitude determined from the H overprint agrees with that determined from Early Carboniferous rocks of cratonic North America west of the Appalachians. Therefore, we argue, Early Carboniferous palaeofield determinations for cratonic North America have been strongly biased by unremoved Kiaman overprints. Because of this, and because of the good agreement between Early Carboniferous palaeolatitudes obtained from opposite margins of the Appalachian orogen, we suggest that there is, at present, no palaeomagnetic evidence for the previously proposed 1500 km displacement from the south of an eastern portion of the Appalachians (“Acadia”) relative to cratonic North America during the Carboniferous.     

Paleomagnetism of certain constituents of the Bay St. George sub-basin,western Newfoundland

Paleomagnetic studies have been made of certain constituents of the Bay St. George sub-basin. Specifically, results are reported from the Spout Falls Formation (Tournaisian), the Jeffreys Village Member of the Robinsons River Formation (Visean), and the Searston Formation (Namurian-Westphalian). The following magnetizations have been isolated: Spout Falls A (Tournaisian) with D = 343.5°, I = ?22.7°, k = 61.2, α₉₅ = 7.1° and the corresponding pole at 28.6°N, 139.5°E (4.5°, 8.5°); Spout Falls B (Kiaman) with D = 166.7°, I = 12.2°, k = 51.7, α₉₅ = 10.7° and the corresponding pole at 34.5°S, 42.7°W (5.5°, 10.9°); Jeffreys Village A (Visean) with D = 351.2°, I = ?27.3°, k = 54.0, α₉₅ = 7.6° and the corresponding pole at 26.5°N, 130.7°E (4.5°, 8.3°); Searston A (Namurian) with D = 161.7°, I = 11.7°, k = 107, α₉₅ = 7.4° and the corresponding pole at 33.9°S, 37.2°W (3.8°, 7.5°); and Searston C with D = 111.6°, I = ?13.8°, k = 28.8, α₉₅ = 14.5° and the corresponding pole at 19.6°S, 19.0°E (7.6°, 14.8°). After comparison with paleopoles of similar ages derived from eastern and western Newfoundland rocks, from constituents of the east coast basin and for interior North America, it is concluded that: (1) it is unlikely that any large scale relative motion took place since the Early Carboniferous between eastern and western Newfoundland; (2) it is unlikely that any north-south relative motion took place between the east coast basin and the Bay St. George sub-basin; and (3) the Bay St. George sub-basin results do not support the earlier proposed displaced terrane hypothesis of the northern Appalachians in as much as the motions during the Carboniferous are not supported. There is evidence of the northward motion of the Appalachians and North America as a whole during the Carboniferous. The magnetostratigraphic horizon marker in the Carboniferous separating a dominant normal and reversed magnetization on the older side and an entirely reversed (Kiaman) magnetization on the younger side may be placed in the Bay St. George sub-basin at the base of the Searston Formation.     

Palaeomagnetism of Mesozoic igneous rocks from the Maranha˜o Basin,Brazil, and the time of opening of the South Atlantic

From Middle-Upper Jurassic volcanics at the western margin of the Maranha?o Basin (6.4°S, 47.4°W) 15 sites (121 samples) have a mean magnetization directionD = 3.9°,I = ?17.9° withα₉₅ = 9.3°,k = 17.9 after AF cleaning (all sites have normal polarity). This yields a pole (named SAJ₂) at 85.3°N, 82.5°E (A₉₅ = 6.9°) which is near to the other known Middle Jurassic South American pole. For 21 sites (190 samples) from Lower Cretaceous basalt intrusions from the eastern part of the Maranha?o Basin (6.5°S, 42°W) the mean direction isD = 174.7°,I = +6.0° withα₉₅ = 2.8°,k = 122 (all sites have reversed polarity) yielding a pole (SAK₉) at 83.6°N, 261°E (A₉₅ = 1.9°) in agreement with other Lower Cretaceous pole positions for South America. Comparing Mesozoic pole positions for South America and Africa in the pre-drift configuration after Bullard et al. [13] one finds a significant difference (with more than 95% probability) for the Lower Cretaceous and Middle Jurassic poles and also a probable difference for the mean Triassic poles indicating a small but probably stationary separation of the two continents from the predrift position in the Mesozoic until Lower Cretaceous time which may be due to an early rifting event.     

Aspects of Caledonian palaeomagnetism and their tectonic implications

Palaeomagnetic results from the Lower Palaeozoic inliers of northern England cover the upper part of the (Middle Ordovician) Borrowdale Volcanic Series (palaeomagnetic pole 208°E, 18°S, A₉₅ = 9.4°), minor extrusive units relating to the Caradoc and Ashgill stages of Ordovician times, intrusive episodes of Middle Ordovician and Middle Silurian to Late Devonian age, and the Shap Granite of Devonian (393 m.y.) age (palaeomagnetic pole 313°E, 33°S, A₉₅ = 5.6°).A complete assessment of Ordovician to Devonian palaeomagnetic data for the British region shows that the pole was nearly static relative to this region for long intervals which were separated by shifts occupying no more than a few millions of years. The mean palaeomagnetic poles are: Ordovician (6°E, 16°S), Lower Silurian (58°E, 16°N), Middle Silurian/Lower Devonian (318°E, 6°N) and Middle/Upper Devonian (338°E, 26°S); the first two shifts separating these mean poles can be explained predominantly in terms of rotational movements of the crustal plate but the last involved appreciable movement in palaeolatitude.Comparison of Lower Palaeozoic palaeomagnetic data from the British region with contemporaneous data from continental Europe/North America on the Pangaean reconstruction reveals a systematic discrepancy in palaeolatitude between the two regions prior to Middle Devonian times. This discrepancy was eliminated during a few millions of years of Lower/Middle Devonian times (ca. 395 m.y.) and can be explained in terms of ca. 3500 km of sinistral strike-slip movement close to the line of the orthotectonic Caledonides. This motion is linked both in time and place to the impingement of the Gondwanaland and Laurentian supercontinents during the Acadian orogeny; this appears to have displaced the British sub-plate until it became effectively locked between the Baltic and Laurentian regions. Although movement of the dipole field relative to the British region in Lower Palaeozoic times is now well defined, nearly one fifth of the total data show that the geomagnetic field was more complex than dipolar during this interval. Until the significance of these anomalies is fully resolved, the tectonic model derived from the palaeomagnetic data cannot be regarded as unambiguous.     

Paleomagnetic evidence for Jurassic deformation of the McCoy Mountains Formation,southeastern California and southwestern Arizona

The Mesozoic McCoy Mountains Formation is a 7.3-km-thick deformed clastic sequence exposed in six mountain ranges in southeastern California and southwestern Arizona. Interbedded with Jurassic volcanic rocks at its base, the McCoy Mountains Formation had been assigned a Cretaceous age based upon fossil angiosperm wood found in the upper third of the section. Characteristic natural remanent magnetism (NRM) from 145 oriented samples from 18 sites within the sedimentary terrane yield an in situ mean direction:I = 20.6°, D = 335.1°, α₉₅ = 7.7° (uncorrected for structural tilting). Opaque mineralogy and a failed fold test indicate that the NRM is a chemical remanence acquired post-folding. The paleomagnetic pole position calculated from the in situ mean direction falls adjacent to poles from the Summerville Formation and Canelo Hills Volcanics. We interpret these data to indicate that deformation, mild metamorphism, and resultant magnetization of the McCoy Mountains Formation occurred during Jurassic time. It is suggested that the McCoy Mountains Formation and underlying Jurassic volcanics were deposited adjacent to, and then deformed between, the North American craton and an outlying allochthonous terrane during Jurassic time.     

The Early Carboniferous paleomagnetic field of North America and its bearing on tectonics of the Northern Appalachians

We have obtained additional evidence for the Early Carboniferous paleomagnetic field for cratonic North America from study of the Barnett Formation of central Texas. A characteristic magnetization of this unit was isolated after thermal demagnetization at four sites (36 samples) out of eight sites (65 samples) collected. The mean direction of declination = 156.3°, inclination = 5.8° (N = 4 ,k = 905 , α₉₅ = 3.0°), corresponds to a paleomagnetic pole position at lat. = 49.1°N,long. = 119.3°E (dp = 1.5° , dm = 3.0°). Field evidence suggests that characteristic magnetization was acquired very early in the history of the rock unit whereas the rejected sites are comprised of weakly magnetized limestones dominated by secondary components near the present-day field direction. Comparison of the Barnett pole with other Early Carboniferous (Mississippian) paleopoles from North America shows that it lies close to the apparent polar wander path for stable North America and that the divergence of paleopoles from the Northern Appalachians noted previously for the Devonian persisted into the Early Carboniferous. We interpret this difference in paleopoles as further evidence for the Northern Appalachian displaced terrain which we refer to here as Acadia, and the apparent coherence of Late Carboniferous paleopoles as indicating a large (～1500 km) motion of Acadia with respect to stable North America over a rather short time interval in the Carboniferous.     

The territory of Georgia and surrounding countries in the Upper Cretaceous: paleomagnetic data

Paleomagnetic researches of the Upper Cretaceous rocks, collected from 24 cross-sections (530 samples) of Georgia have shown that only nine samples are suitable for the paleotectonic problem to be solved. The method of thermomagnetic cleaning was used for the paleomagnetic directions of these rocks to be determined. Magnetic-mineralogical data and the tests of paleomagnetic accuracy have proved the ancient age of the stable part of the natural remnant magnetization (NRM) that is close to the initial one. The study results have demonstrated that the position of the areas studied in the Upper Cretaceous time was located 11°–18° southward from their modern latitudinal position; the distance between structures of the Great Caucasus and Trans-Caucasus was 10°–14°. The wide variations of the paleoinclinations are connected with the local turns of tectonic blocks     

Palaeomagnetism of the Msissi norite (Morocco) and the Palaeozoic reconstruction of Gondwanaland

Palaeomagnetic results are reported from eight sites in an Upper Devonian basic intrusion (the Msissi norite) in southeast Morocco. Specimens from one site are suspected of having been affected by lightning, but results from the other seven sites indicate the presence of a less-stable component, probably of viscous origin. The pole position corresponding to the stable component(0.5°S, 25°E, A₉₅ = 16.5) is interposed between the Middle Cambrian/Ordovician pole and the Lower Carboniferous pole on the African polar wander curve. When the southern continents are reassembled on the Smith/Hallam reconstruction of Gondwanaland the new Moroccan Devoniån pole is in excellent agreement with the corresponding portion of the main Australian polar-wander curve. This places additional constraints on the possible date of fusion of the separate Southeast Australian plate with the rest of Gondwanaland, postulated recently on palaeomagnetic grounds by M.W. McElhinny and B.J.J. Embleton (1974). The combined African/Australian polar-wander curve is compared with the South American curve, and two possible interpretations of available data are discussed, one involving possible relative tectonic motion between South America and the rest of Gondwanaland during the Lower and Middle Palaeozoic, and the other, favoured here, requiring a reassessment of the ages of several South American pole determinations.     

Superimposed Recent,Permo-Carboniferous and Ordovician palaeomagnetic remanence in the Builth Volcanic Series,Wales

The Builth Volcanic Series of Llanvirnian age in Llanelwedd Quarries, mid-Wales, carries three components of natural remanent magnetisation. Component P, regarded as primary, is a thermochemical remanence directed at D = 181.7°, I = +54.5°, α₉₅ = 4.4° relative to bedding. Component S is a secondary component with in situ D = 178.7°, I = ?6.7°, α₉₅ = 5.4° and is believed to be a low-temperature chemical remanence (CRM) of Permo-Carboniferous age. Component R is directed close to the present geomagnetic field and is believed to be a recent viscous remanence (VRM).The results are of interest for three reasons. First, they are an unusually good example of multi-component NRM analysis, the three components being so clearly discriminated by thermal demagnetisation because they have almost completely separate blocking temperature ranges. Second, they provide evidence of a Permo-Carboniferous event (possibly a mild thermal or hydrothermal pulse promoting CRM acquisition) some 40 km north of the Hercynian orogenic front. Third, they illustrate very clearly the importance of detailed demagnetisation: this work revises the pole position for these rocks by ～ 10° and removes an obstacle to the palaeomagnetic recognition of the ～ 1000 km wide Iapetus Ocean cutting Britain in Ordovician time.     

Geochemistry of volcanic and hydrothermal gases of Mutnovsky volcano,Kamchatka: evidence for mantle,slab and atmosphere contributions to fluids of a typical arc volcano

We report chemical compositions (major and trace components including light hydrocarbons), hydrogen, oxygen, helium and nitrogen isotope ratios of volcanic and geothermal fluids of Mutnovsky volcano, Kamchatka. Several aspects of the geochemistry of fluids are discussed: chemical equilibria, mixing of fluids from different sources, evaluation of the parent magmatic gas composition and contributions to magmatic vapors of fluids from different reservoirs of the Kamchatkan subduction zone. Among reactive species, hydrogen and carbon monoxide in volcanic vapors are chemically equilibrated at temperatures >300°C with the SO₂-H₂S redox-pair. A metastable equilibrium between saturated and unsaturated light hydrocarbons is attained at close to discharge temperatures. Methane is disequilibrated. Three different sources of fluids from three fumarolic fields in the Mutnovsky craters can be distinguished: (1) magmatic gas from a large convecting magma body discharging through Active Funnel, a young crater with the hottest fumaroles (up to 620°C) contributing ~80% to the total volcanic gas output; (2) volcanic fluid from a separate shallow magma body beneath the Bottom Field of the main crater (96–280°C fumaroles); and (3) hydrothermal fluid with a high relative and absolute concentrations of CH₄ from the Upper Field in the main crater (96–285°C fumaroles). The composition of the parent magmatic gas is estimated using water isotopes and correlations between He and other components in the Active Funnel gases. The He-Ar-N₂ systematics of volcanic and hydrothermal fluids of Mutnovsky are consistent with a large slab-derived sedimentary nitrogen input for the nitrogen inventory, and we calculate that only ~1% of the magmatic N₂ has a mantle origin and <<1% is derived from the arc crust.     

Sulitjelma Gabbro,northern Norway: A palaeomagnetic result

The Sulitjelma Gabbro situated at 67.2°N, 15.4°E was intruded close to the Late Ordovician climax of regional metamorphism in the northern Scandinavian Caledonides. Magnetic properties have been examined from samples collected at seven localities in the south western part of this body. Total NRM directions show a tendency to be aligned near the present earth's magnetic field direction in this region. Stability to a.f. demagnetisation is low and commensurate with low Koenigsberger ratios (0.001–0.16) and the presence of unoxidised magnetite as the principal remanence carrier. After cleaning the site mean directions no longer show an alignment near the present earth's field and of six statistically significant sites three are approximately reversed with respect to remainder. The combined mean direction after cleaning isD = 195°,I = 15° (precision parameterk = 6) and the derived virtual geomagnetic pole is at 0°E, 14°S (α₉₅ = 23°). This pole is close to poles of comparable age from the British Isles and suggests that Britain and Norway were part of the same crustal plate in Ordovician times. Discrepancies between Siluro-Devonian results from the two regions may be due to inadequate age coverage of present results.