Reddening of dune sands—evidence from southeast India

Thin section, SEM, and TEM analyses have indicated that the red ‘teri’ sands of southeast India have formed from weathering in situ of coastal dune sands. The data does not support a detrital origin for the red sands. C¹⁴ dates indicate that dune deposition and weathering, to a maximum depth of 10 m, leading to the formation of a hematite, koalinite and illite rich matrix has taken place rapidly over the past 25,000 years. It is postulated that garnet was a major source of hematite (ferric oxide).     

闽西晚白垩世红层的古环境探究

中国东南地区白垩纪红层通常被认为是陆相红色碎屑沉积物,是河流湖泊相沉积,但其古环境存在争论.本文以闽西晚白垩世红层为研究对象,利用环境磁学、粒度、地球化学、古土壤分析等方法,选取连城(LC)和冠豸山(GZS)两个剖面,分析探讨红层的古环境.结果显示:(1)闽西红层主要以细的粉砂颗粒为主,黏土和砂含量较少,表现为粉砂和砂互层,夹有薄层细粒砂砾层;样品磁化率偏低,主要载磁矿物为硬磁性矿物赤铁矿.(2)闽西红层有较高的风化程度,是暖湿气候下的中等风化程度;轻重稀土元素分异明显,Ce元素富集,Eu元素相对亏损,与上地壳(UCC)的分配模式相似,表明沉积物经历了充分混合,物质为混合沉积产物.(3)闽西红层虽然发育了一定的古土壤,但是成壤程度不强,没有明显的古土壤粘化层(Bt)和钙积层(Bk).由此推断,闽西红层沉积物在沉积前已在源区经过相当程度的风化过程,之后经过混合动力搬运沉积在盆地,沉积后风化成壤弱.可见,红层本身并不能直接反映沉积区环境,需结合古土壤发育特征判断沉积环境特征和变化.(4)闽西晚白垩世红层表现为相对干旱半干旱的古环境,红层中主要的着色矿物赤铁矿主要形成于源区,反映了地表透水性良好的干燥氧化条件,而不是"水成"环境.本文可为白垩纪红层古环境研究提供新的思路.     

Diagenetic development of unstable and stable magnetization in the St. Bees Sandstone (Triassic) of northern England

Thermal demagnetization of red and drab sandstones from the St. Bees Sandstone shows a wide range of directional stability. After the removal of a metastable secondary magnetization at temperatures up to 300°C red sandstones may show stable or unstable magnetization. Experiments indicate that both the stable and unstable magnetization is carried by coarse haematite particles (specularite).Drab sandstones, which have been subject to reduction and dissolution of haematite are generally unstable but specimens with a stable NRM occur and this must be carried by specularite because the pigment has been removed from these specimens.The stable magnetization is believed to have developed during deposition and early diagenesis by the oxidation of detrital iron oxides. Pole positions correspond to known Triassic poles and there are abundant normal and reversed zones typical of the Lower Triassic.The unstable magnetization of the red sandstones is apparently due to the development of authigenic overgrowths of haematite on the detrital specularites. This phase of authigenesis may have taken place over a long time, and after significant changes in the ambient geomagnetic field resulting in complex magnetizations in individual grains and hence whole rocks.     

Chemical remanent magnetization due to deep-burial diagenesis in oolitic hematite-bearing ironstones of Alabama

Oolitic hematite-bearing ironstones of the Silurian Red Mountain Formation of Alabama are shown to carry a single-component remanence stable enough to have survived major folding (of probable Permian age). Nevertheless, the remanence direction (ten sites yielding a paleopole at 38.0°N, 132.4°E with dm = 3.6°, dp = 1.9°), its reverse polarity and a negative intraformational conglomerate test show that the remanence was very likely acquired during the Pennsylvanian—some 130 Ma after deposition. This remanence is likely a chemical remanent magnetization (CRM) acquired during diagenesis induced by heating due to deep burial under a Pennsylvanian clastic wedge. Two possible mechanisms for acquisition of CRM during deep-burial diagenesis are considered. In hypothesis I, the oolitic hematite transformed from original geothite when heated to about 80°C, acquiring CRM. In hypothesis II, the oolitic hematite originated from ferrihydrite and was too fine-grained to acquire stable CRM until heat raised the solubility of hematite allowing grain growth. Hypothesis I explains the timing of remanence acquisition better, but there is some evidence that oolitic goethites may be stable to considerably more than 80°C. Hypothesis II has some difficulty explaining preliminary paleomagnetic results from oolitic hematite-bearing ironstones of the Silurian Clinton Group, New York State. We prefer hypothesis I but both hypotheses remain plausible. Both hypotheses warn that continental red beds may also acquire CRM during diagenesis induced by deep-burial heating, long after deposition but before folding.     

Magnetic properties of the Tertiary red clay from Gansu

The study on magnetic properties of the red clay indicates that the red clay and loesspaleosol sequence have a common magnetic mineralogy, with magnetite, maghemite, hematite (and possibly goethite) contributing to the magnetic behavior. The red clay magnetic susceptibility is also found to have a positive relation with extrafine superparamagnetic grains. This suggests that, like the Quaternary loess-paleosols, an ultrafine ferrimagnetic component produced during pedogenesis in the red clay under humid conditions also plays an important role in susceptibility enhancement in the soil units. This is supported by the correlation between Rb/Sr ratio and magnetic susceptibility. This signifies that, like the above loess-paleosol sequence, the magnetic susceptibility of the red clay can be used as a general proxy paleoclimatic indicator, although whether its susceptibility in the red clay is comparable to pedogenesis intensity and requires further investigation. Magnetic susceptibility variation in the red clay thus also provides an eolian/pedogenic record of paleoclimatic evolution. Study of the background susceptibility indicates that, on average, the absolute scale of the paleoclimatic shift from red clay development to Quaternary loess deposition is similar to the climatic shift from stage 5 (S1) to stage 2–4 (L1). This may suggest that during the Quaternary there is an evident strengthening of the absolute wind intensity to bring more (about double) coarser and less weathered (non-SP fraction) eolian magnetic input from the source regions to the Loess Plateau than during the Pliocene. The presence of eolian red clay since 7.5 Ma BP in central-northern China implies an important environmental change from the underlying Cretaceous red sandstone. The red clay development was closely related to global drying and climate cooling since the Cretaceous and closely associated with the abrupt uplift of the Qinghai-Xizang Plateau at about that time. This uplift of the plateau intensified the East Asia monsoon system and started red clay deposition.     

Magnetic properties of the Tertiary red clay from Gansu Province, China and its paleoclimatic significance

The study on magnetic properties of the red clay indicates that the red clay and loess- paleosol sequence have a common magnetic mineralogy, with magnetite, maghemite, hematite (and possibly goethite) contributing to the magnetic behavior. The red clay magnetic susceptibility is also found to have a positive relation with extrafine superparamagnetic grains. This suggests that, like the Quaternary loess-paleosols, an ultrafine ferrimagnetic component produced during pe-dogenesis in the red clay under humid conditions also plays an important role in susceptibility enhancement in the soil units. This is supported by the correlation between Rb/Sr ratio and magnetic susceptibility. This signifies that, like the above loess-paleosol sequence, the magnetic susceptibility of the red clay can be used as a general proxy paleoclimatic indicator, although whether its susceptibility in the red clay is comparable to pedogenesis intensity and requires further investigation. Magnetic susceptibility variation in the red clay thus also provides an eo-lian/pedogenic record of paleoclimatic evolution. Study of the background susceptibility indicates that, on average, the absolute scale of the paleoclimatic shift from red clay development to Quaternary loess deposition is similar to the climatic shift from stage 5 (S1) to stage 2-4 (L1). This may suggest that during the Quaternary there is an evident strengthening of the absolute wind intensity to bring more (about double) coarser and less weathered (non-SP fraction) eolian magnetic input from the source regions to the Loess Plateau than during the Pliocene. The presence of eolian red clay since 7.5 Ma BP in central-northern China implies an important envi-ronmental change from the underlying Cretaceous red sandstone. The red clay development was closely related to global drying and climate cooling since the Cretaceous and closely associated with the abrupt uplift of the Qinghai-Xizang Plateau at about that time. This uplift of the plateau intensified the East Asia monsoon system and started red clay deposition.     

Late Jurassic/Early Cretaceous magnetic stratigraphy from the sümeg section,Hungary

The pelagic limestones exposed at Sümeg appear to represent continuous deposition from Kimmeridgian through Berriasian. Detrital magnetite and haematite pigment are the carriers of remanence in the red and non-red limestones in the lower part, while magnetite becomes predominant in the upper half of the section. Thermal demagnetization has succesfully removed overprint magnetizations, and a well-defined magnetic stratigraphy has been obtained. The Late Jurassic/Early Cretaceous mixed polarity interval is correlated with the sequence of geomagnetic reversals derived from oceanic magnetic anomalies.     

三门峡盆地晚新生代沉积物磁性载体类型

对三门峡盆地晚新生代沉积岩样品进行岩石磁学研究,通过三轴饱和等温剩磁和剩磁矫顽力实验、交变退磁和热退磁实验及磁化率测定,发现黄土-古土壤、河湖相灰绿层和冲洪积层3种不同岩性的磁载体存在显著差异.即黄土-古土壤以磁铁矿为主,赤铁矿和磁赤铁矿很少;河湖相灰绿色沉积磁性矿物含量较低,主要为赤铁矿和磁铁矿,但磁铁矿较多,此外还有一些不稳定磁性矿物(如针铁矿、菱铁矿等);冲洪积物以磁铁矿和赤铁矿为主,磁铁矿相对较多.     

Environment and provenance in the development of recent alluvial deposits in epirus,nw greece

The valleys of Epirus, in NW Greece, are floored by alluvium laid down in historical times. In an attempt to evaluate the relative importance of diagenesis and of parent material in determining its local character, the alluvium was compared with the principal source deposits, namely the red beds of the late Quaternary Kokkinopilos Formation and the brown Mediterranean soils that have developed on flysch outcrops. Rehydration of the haematite pigment after deposition coupled with silt-clay depletion during redeposition of the red beds is responsible for the drab colour of the valley-floor deposits in limestone catchments. Where the alluvium was derived from brown soils, little mineralogical change has occurred. Some reduction and mobilization of iron has affected Kokkinopilos beds still in place, possibly during periods of seasonal waterlogging under oak forest, to produce a veining pattern akin to that found in pseudo-gley soils.     

Transformation relationship among different magnetic minerals within loess-paleosol sediments of the Chinese Loess Plateau

The dominant magnetic minerals and carriers of magnetic signals within the Chinese Loess Plateau are magnetite, maghemite, hematite, and goethite. In this study, we investigated the provenance and evolution of magnetic minerals during loess pedogenesis, using X-ray diffraction (XRD) and optical and electron microscopy, including field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). Our results reveal that single- and multiphase mineral assemblages among magnetic minerals in the loess-paleosol sequence have been formed. Partial oxidation of coarse eolian magnetite has occurred in the desert source area and the oxidation degree is enhanced after deposition of the dust upon the Chinese Loess Plateau. This mode of origin resulted in a microtexture consisting of an inner magnetite core surrounded by a hematite rim, and strongly affected the magnetic characteristics of the loess. Goethite coexists with hematite in the loess and paleosol, and nanometer-scale hematite is formed upon goethite rims via dehydration. Our study provides direct mineralogical evidence of the magnetic record and paleoclimatic implications of the loess-paleosol sequence of the Chinese Loess Plateau. Supported by National Natural Science Foundation of China (Grant Nos. 40772032 and 40573054) and National Basic Research Program (Grant No. 2007CB815603)     

Thermochemical remanent magnetization in Jurassic silicic volcanics from Nevada,U.S.A.

Characteristic magnetizations from Middle Jurassic dacitic to andesitic subaerial volcanics (the Fulstone and Artesia Formations) in the Buckskin Mountain Range, western central Basin and Range Province, are well-grouped, generally display univectorial decays to the origin in demagnetization and have hematite blocking temperatures restricted almost entirely to above 620°C. Petrographic, rock magnetic and electron microprobe investigations confirm that nearly pure hematite is the essential magnetic phase (up to about 10 vol. %) occurring as a replacement of coarse titaniferous magnetite phenocrysts and fine groundmass particles, as a secondary alteration product of ferromagnesian phenocrysts and as a mobilized phase filling cracks and other open spaces. The presence of antipodal directions in each flow unit and in interbedded volcanoclastic units (some having retained magnetite as a major magnetic phase) and magnetite-dominated remanences in time-equivalent intrusives cutting the flows indicates that the volcanics acquired their hematite remanence, a faithful record of the geomagnetic field, in high-temperature, deuteric oxidation during and following their emplacement, not during a later thermal event such as regional metamorphism. The remanence is probably a thermochemical remanent magnetization, although part may be of thermoremanent origin.     

基于剩磁各向异性方法对华北下三叠统红层磁倾角浅化效应的研究

本文报道利用岩石剩磁组构对华北下三叠统红层进行磁倾角浅化效应的进一步识别与校正研究结果.首先,采用45°等温剩磁各向异性方法,即通过沿与样品原始水平面(即层面)呈45°夹角方向施加磁化场获得等温剩磁,并进行逐步热退磁,获得平行于层面和垂直于层面的等温剩磁分量随外加磁场和热退磁温度的变化趋势,计算获得浅化因子f=0.70...     

Sedimentary rocks at Meridiani Planum: Origin, diagenesis, and implications for life on Mars

The MER rover Opportunity has carried out the first outcrop-scale investigation of ancient sedimentary rocks on Mars. The rocks, exposed in craters and along fissures in Meridiani Planum, are sandstones formed via the erosion and re-deposition of fine grained siliciclastics and evaporites derived from the chemical weathering of olivine basalts by acidic waters. A stratigraphic section more than seven meters thick measured in Endurance crater is dominated by eolian dune and sand sheet facies; the uppermost half meter, however, exhibits festoon cross lamination at a length scale that indicates subaqueous deposition, likely in a playa-like interdune setting. Silicates and sulfate minerals dominate outcrop geochemistry, but hematite and Fe3D3 (another ferric iron phase) make up as much as 11% of the rocks by weight. Jarosite in the outcrop matrix indicates precipitation at low pH. Cements, hematitic concretions, and crystal molds attest to a complex history of early diagenesis, mediated by ambient ground waters. The depositional and early diagenetic paleoenvironment at Meridiani was arid, acidic, and oxidizing, a characterization that places strong constraints on astrobiologial inference.     

亚热带地区发育于不同母岩风化壳上的红壤磁学特征对比及其环境意义

本研究对发育于亚热带地区花岗岩和变质岩风化壳之上的两个红壤剖面进行了系统的环境磁学测量及色度分析,探讨在同一地区不同母质上发育的红壤磁性差异的原因及其环境意义.研究区的两个剖面分别位于福建省南平市高铁北站和纺织厂附近,相距约15 km,气候条件基本相同.研究结果表明：（1）较强磁性的花岗岩母质层上发育的南平北站红壤（NPN）,在发育过程因母质层中多畴（MD）颗粒磁赤铁矿化的磁铁矿溶解,剖面上部的淋溶层和淀积层虽以较细的稳定单畴（SSD）颗粒和少量的假单畴（PSD）颗粒磁铁矿为主,但剖面磁性自下而上减弱.相较而言,南纺红壤（NF）剖面发育在磁性较弱的变质砂岩上,其过渡层和母质层以赤铁矿为主,因成壤过程中生成较细的超顺磁（SP）磁铁矿使得土壤淋溶层和淀积层磁性增强;说明母质不同是亚热带地区红壤磁性差异的主要原因.（2） NPN和NF两个剖面的气候条件基本相同,磁性差异比色度指标差异更为显著.亚热带地区因剖面受母质影响显著,整体磁性特征不能反映气候;黄度和红度的比值（b^*/a^*）远小于磁性的差异,说明针铁矿和赤铁矿的比值更能反映研究区的平均气候状况,即反映次生磁性矿物含量的参数为更适合的气候指标.     

Rock magnetic properties and palaeomagnetic results of sediments from a stone implement layer in the Bose Basin,Guangxi

Directional samples were taken to study rock magnetism and palaeomagnetic records from the Dong- sheng profile, which is 5 m thick and on the northwest edge of the Bose Basin. Mineralogy and rock magnetism of typical samples indicate that coarse granular titanomagnetite, and fine-grained hematite, superparamagnetic maghemite formed by pedogenesis are in the sediment, which has undergone many transformative processes during different stages of pedogenesis. Parallel samples were taken for thermal demagnetization (TH) (0 to 680℃) and alternating field (AF) demagnetization (0 to 80 mT) respectively. Experimental results of these two kinds of demagnetization illustrate that there are two or more magnetic components in the samples. Intensity of NRM decreases by almost 60% to 90% rapidly when the temperature ranges from 100℃ to 350℃, with a steady magnetic component. It is impossible to analyze the magnetic components at high temperature because those fluctuate widely when the temperature is higher than 400℃. Steady magnetic components from 100℃ to 350℃ indicate that the remanence was mainly carried by fine-grained hematite formed by pedogenesis, reflecting a change in the geomagnetic field while the magnetite was being oxidized into hematite by chemical weathering after deposition. The formative age of the sediments cannot be obtained by magnetic methods in this profile.     

The origin of the White Beds below the Cretaceous-Tertiary boundary in the Gubbio section, Italy

Immediately below the Cretaceous-Tertiary (K-T) boundary clay layer in Umbrian pelagic limestone sections is a 0.5 m thick interval of white limestone beds. Geochemical and rock magnetic studies have been carried out to investigate the origin of these beds. Fe/Si ratios suggest that the iron abundance is a constant proportion of the detrital component in the red marlstone above the boundary and the pink limestone below the white beds. The stratigraphic variations of initial susceptibility and the IRM intensities acquired in different fields behave similarly to the Fe/Si ratio, and reflect primarily the changing concentrations of the ferromagnetic minerals caused by sedimentary fluctuations. The Fe/Si ratio, overall Fe abundance and the intensities of the magnetic parameters are all anomalously low in the white beds. The differing magnetic properties of the samples are due mainly to differing proportions and grain-size distributions of pigmentary hematite and detrital magnetite. The coercivity spectra of samples from the white beds are very similar to those of the pink beds, but are clearly distinct from those of the red beds. The white beds were probably deposited under the same conditions as the underlying pink beds. The anomalously low intensities in the white beds result from reduction of hematite in originally pink beds and subsequent removal of the Fe²⁺ ions. The reduction may be a consequence of downwards infiltration of reducing waters resulting from the large quantity of organic matter produced by the extinctions at the K-T boundary.     

Magnetic Anisotropy as an Aid to Identifying CRM and DRM in Red Sedimentary Rocks

To further evaluate the potential of magnetic anisotropy techniques for determining the origin of the natural remanent magnetization (NRM) in sedimentary rocks, several new remanence anisotropy measurement techniques were explored. An accurate separation of the remanence anisotropy of magnetite and hematite in the same sedimentary rock sample was the goal.In one technique, Tertiary red and grey sedimentary rock samples from the Orera section (Spain) were exposed to 13 T fields in 9 different orientations. In each orientation, alternating field (af) demagnetization was used to separate the magnetite and hematite contributions of the high field isothermal remanent magnetization (IRM). Tensor subtraction was used to calculate the magnetite and hematite anisotropy tensors. Geologically interpretable fabrics did not result, probably because of the presence of goethite which contributes to the IRM. In the second technique, also applied to samples from Orera, an anisotropy of anhysteretic remanence (AAR) was applied in af fields up to 240 mT to directly measure the fabric of the magnetite in the sample. IRMs applied in 2 T fields followed by 240 mT af demagnetization, and thermal demagnetization at 90°C to remove the goethite contribution, were used to independently measure the hematite fabric in the same samples. This approach gave geologically interpretable results with minimum principal axes perpendicular to bedding, suggesting that the hematite and magnetite grains in the Orera samples both carry a depositional remanent magnetization (DRM). In a third experiment, IRMs applied in 13 T fields were used to measure the magnetic fabric of samples from the Dome de Barrot area (France). These samples had been demonstrated to have hematite as their only magnetic mineral. The fabrics that resulted were geologically interpretable, showing a strong NW-SE horizontal lineation consistent with AMS fabrics measured in the same samples. These fabrics suggest that the rock's remanence may have been affected by strain and could have originated as a DRM or a CRM.Our work shows that it is important to account for the presence of goethite when using high field IRMs to measure the remanence anisotropy of hematite-bearing sedimentary rocks. It also shows that very high magnetic fields (>10 T) may be used to measure the magnetic fabric of sedimentary rocks with highly coercive magnetic minerals without complete demagnetization between each position, provided that the field magnetically saturates the rock.     

一个变泥质岩包体样品的系统热磁试验及其矿物学意义

利用一件采自河北汉诺坝周坝地区变泥质岩包体样品,结合系统的低温和高温磁性测量结果,探讨了应用热磁实验鉴别样品中所含原生磁性矿物的多解性问题. 结果表明, 饱和等温剩余磁化强度（SIRM）在室温～250℃以及280℃～380℃的降低分别由高钛钛磁铁矿的剩磁解阻过程（一种物理过程）以及由磁赤铁矿转换成赤铁矿（一种矿物相变）引起.样品在500℃以后磁化率的升高则是由磁铁矿从钛磁赤铁矿中出溶所致.因此,κ T（即磁化率随温度变化）曲线中呈现约580℃居里点是由加热过程中次生的磁铁矿引起,而并非代表原始（即加热前）样品中的磁铁矿成分.     

Hysteresis effects of varying concentrations of magnetite,hematite, pyrrhotite,and greigite grains in a diamagnetic matrix

Summary The hysteresis properties of synthetic samples with very low contents of hematite, pyrrhotite, greigite and admixtures of magnetite and hematite in a diamagnetic matrix have been studied. The diamagnetic matrix used was sodium chloride (NaCl). The contents of the magnetic minerals varied for hematite from 0.5 to 6 wt%, for pyrrhotite from 0.02 to 0.2 wt% and for greigite from 0.02 to 0.6 wt%. Diamagnetic contributions to the magnetization curves can be distinguished in the measured samples. We observed a non-linear dependence of coercivity and saturation magnetization upon increasing contents of hematite as a result of effects of both the diamagnetic matrix and the hematite content. Only the saturation remanence which is measured in a zero magnetic field has a linear dependence on the hematite concentration. The shape of the hysteresis curves of admixtures of magnetite and hematite are probably caused by magnetostatic interactions.