SR isotope geochemistry of voluminous rhyolite of the Tamagawa Welded Tuffs, related rocks and andesite of the young volcanics, in Hachimantai geothermal area, Northeast Japan

The volcanic rocks from the Hachimantai geothermal area, Northeast Japan, are divided into the following five groups: (1) rhyolite of the Tamagawa Welded Tuffs (about 500 km³, 2.0–1.4 Ma); (2) andesite related to the Tamagawa Welded Tuffs (about 10 km³, 1.5 Ma); (3) andesite of the Matsukawa Andesite (about 100 km³, 1.8-1.2 Ma); (4) dacite of the Kashinai Formation (about 100 km³, 1.1 Ma); and (5) andesite of the Young Volcanics (about 300 km³, younger than 1 Ma). ratios of less-altered samples of the five groups range from 0.7038 to 0.7046. There is no significant difference in ratios among the five groups in spite of differences in age and chemical composition. Therefore, fusion of or contamination by old acidic crust can be ruled out for the genesis of the voluminous acidic magma which produced the rhyolite of the Tamagawa Welded Tuffs and the dacite of the Kashinai Formation.The low ratios and the chemistry suggest two possibilities for the genesis of the acidic rocks. One is a low degree of partial melting of the basic crust, which has a low ratio, under high temperature. Another is a high degree of fractional crystallization from basic magma derived from the mantle.     

Mineralogy and stable isotope geochemistry of hydrothermally altered oceanic rocks

Data for the diffusion of cations in pyroxenes are relevant to a variety of sub-solidus processes including order-disorder and exsolution. Similar data must also be available if the reliability of geobarometers and geothermometers involving pyroxenes is to be assessed. Two types of diffusion experiment have been performed to determine cation diffusion rates in pyroxenes: (1) interdiffusion between single crystals of diopside and polycrystalline sinters enriched in Al and Fe, and (2) interdiffusion between single crystals of diopside and a glass of the same composition which was isotopically enriched in²⁶Mg and⁴³Ca. Following high-temperature annealing for periods up to several hundred hours, analysis of the diffusion couples, using an electron microprobe and an ion microprobe respectively, failed to show any measurable diffusion profiles. From these “null result” experiments the diffusion coefficients (D) for Al and Fe in diopside are estimated to be less than4×10^?14cm²s^?1 at 1200°C, and values ofD for Ca and Mg in diopside are estimated to be less than7 × 10^?14cm²s^?1 at 1250°C. These rates are significantly slower than published tracer-type diffusion data for Ca and Al.A review of studies of order-disorder, microstructural coarsening, and diffusion in pyroxenes suggest that activation energies for cation exchange are typically in excess of 60 kcal mol^?1. Transport rates will be assisted, and activation energies lowered by sample non-stoichiometry, inhomogeneities, high dislocation densities and the presence of water.The collective data for Al, Mg and Ca diffusion in diopside indicate diffusion coefficients? 10^?15cm²s^?1 at 1200°C. A comparison with data for diffusion in garnet, olivine and spinel suggests that pyroxenes may have the highest blocking temperatures.     

Mineralogy,chemistry and crystallization sequence of clay minerals in altered tholeiitic basalts from the Peru Trench

Petrographic examination of amygdules and veins associated with moderately altered pillow basalts dredged from the Peru Trench has revealed that a consistent pattern of mineral crystallization has occurred. This sequence is: (1) green, weakly pleochroic clay (R.I. > 1.56); (2) dark yellowish brown, non-pleochroic clay (R.I. > 1.56); (3) light yellowish brown to colorless, fibrous, weakly pleochroic clay (R.I. < 1.56); and (4) calcite or celadonite. Chemical and X-ray diffraction analyses suggest that all clay mineral amygdule and vein fillings are dominated by intimate mixtures of an Fe-rich saponite and nontronite with very small admixtures of serpentine and illite. It is argued that sequential mineral fillings of fractures and vesicles may provide significant information about the chemistry of circulating interstitial fluids. For the pillow basalts studied the first-formed clays were enriched in nontronite, thereby suggesting Fe-rich fluids. These in turn were followed by saponite-rich clays and calcite. The change from Fe-and Mg-rich fluids to dominantly Ca-rich fluids is thought to correspond to a change from mafic mineral alteration to plagioclase alteration in the pillow basalts. An increase in the Fe³⁺/Fe²⁺ ratio of clays toward the centers of vesicles may indicate a change toward a more oxidizing environment of alteration.     

Rb-Sr isotope geochemistry of lherzolites and their constituent minerals from Victoria,Australia

Major element data and Rb, Sr and⁸⁷Sr/⁸⁶Sr analyses for seven spinel lherzolite xenoliths and their Recent host basalt from Victoria, Australia, are presented. The exotic nature of the xenoliths is indicated by a wide spread in⁸⁷Sr/⁸⁶Sr values (0.7035–0.7076) compared with the basalt (0.7041). Five of the lherzolites provide evidence of a thermal event in the mantle 650 m.y. ago. Equilibration temperatures calculated from the compositions of the lherzolite phases (ca. 1050°C) apparently relate to this event. Estimates of the local geothermal gradient suggest temperatures of less than 700°C in the source region before eruption of the lherzolites.Isotopic analyses of the lherzolite minerals show that orthopyroxene contains more radiogenic Sr than coexisting olivine and clinopyroxene in three of the xenoliths. The⁸⁷Sr/⁸⁶Sr relationships between clinopyroxene and orthopyroxene suggest that internal isotopic disequilibrium has existed in the source region for up to 550 m.y.     

Geology, water geochemistry and geothermal potential of the jemez springs area, Canon de San Diego, new Mexico

Studies of the geology, geochemistry of thermal waters, and of one exploratory geothermal well show that two related hot spring systems discharge in Canõn de San Diego at Soda Dam (48°C) and Jemez Springs (72°C). The hot springs discharge from separate strands of the Jemez fault zone which trends northeastward towards the center of Valles Caldera. Exploration drilling to Precambrian basement beneath Jemez Springs encountered a hot aquifer (68°C) at the top of Paleozoic limestone of appropriate temperature and composition to be the local source of the fluids in the surface hot springs at Jemez Springs. Comparisons of the soluble elements Na, Li, Cl, and B, arguments based on isotopic evidence, and chemical geothermometry indicate that the hot spring fluids are derivatives of the deep geothermal fluid within Valles Caldera. No hot aquifer was discovered in or on top of Precambrian basement. It appears that low- to moderate-temperature geothermal reservoirs (< 100°C) of small volume are localized along the Jemez fault zone between Jemez Springs and the margin of Valles Caldera.     

Mineralogy and physical nature of clay gouge

Fault gouges have been observed in the surface outcrops, in shallow excavations, and in deep (300 meters below the surface) tunnels and mines in fault zones. The 2-microns fractions in these fault gouges may compose a few percent to more than fifty percent of the total mass in the outcrops, and the mineralogy of the 2-microns fractions consists of a variety of clays (the common ones are montmorillonite, illite, kaolinite, chlorite, vermiculite and mixed-layer clays) and some quartz, feldspars, etc.Although we cannot yet conclude directly from the studies of gouges that similar gouges exist at depths where many large shallow earthquakes are generated, there is a strong possibility that they do, based on (1) available equilibrium data on various clays — for example, kaolinite has been found to exist at 4 kb and 375°C (±15°C) (Thompson, 1970) and montmorillonite + kaolite has been found to exist at 450°C and 4 kb (Velde, 1969); (2) the compatibility of laboratory velocity data in gouge (Wang et al., 1977) with those in a model for central California (Healy andPeake, 1975); (3) the capability of clays to undergo sudden earthquake-like displacements (Summers andByerlee, 1977); (4) the petrology of intrafault cataclastic rocks in old fault zones (Kasza, 1977); and (5) the compatibility of gouge mineralogy with the mineralogy of hydrothermal clay deposits.If clay gouges are indeed significant components of the fault zone at depth, then the mechanical properties of clays under confining pressures up to 4 kb are important in the behavior of faults. Very few experiments have been performed under such high pressures. But from the physical makeup of clays, we can infer that (1) the range of possible behavior includes stable sliding with vermiculite and montmorillonite (asByerlee andSummers, 1977, have proven) to stick-slip-like behavior with kaolinite, chlorite, etc.; (2) the absence or presence of water will greatly affect the strengths of gouges — it is possible that water may reduce the strength of gouge to a fairly small value.     

Coseismic changes in the chemical composition of volcanic gases from the Owakudani geothermal area on Hakone volcano,Japan

The chemical and isotopic compositions of volcanic gases at a borehole and a natural fumarole in the Owakudani geothermal area, Hakone volcano, Japan, have been repeatedly measured since 2001, when a seismic swarm occurred in the area. The CO₂/H₂O and CO₂/H₂S ratios were high in 2001. It increased in 2006 and again in 2008 when seismic swarms occurred beneath the geothermal area. The observed increases suggest the injection of CO₂- and SO₂-rich magmatic gas into the underlying hydrothermal reservoir, implying that the magmatic gas was episodically supplied to the hydrothermal system in 2006 and 2008. The earthquake swarms probably resulted from the injection of gas through the shallow crust accompanying the break of the sealing zone.     

Strontium, oxygen, and hydrogen isotope geochemistry of hydrothermally altered and weathered rocks in DSDP Hole 504B, Costa Rica Rift

DSDP Hole 504B was drilled into 6 Ma crust, about 200 km south of the Costa Rica Rift, Galapagos Spreading Center, penetrating 1.35 km into a section that can be divided into four zones—Zone I: oxic submarine weathering; Zone II: anoxic alteration; Zones III and IV: hydrothermal alteration to greenschist facies. In Zone III there is intense veining of pillow basalts. Zone IV consists of altered sheeted dikes. Isotopic geochemical signatures in relation to the alteration zones are recorded in Hole 504B, as follows:

Zone	Depth(m)	Average87Sr/86Sr	Average δ18O (%o)	Average δD (%o)
I	275–550	0.7032	7.3	−63
II	550–890	0.7029	6.5	−45
III	890–1050	0.7035	5.6	−31
IV	1050–1350	0.7032	5.5	−36

Full-size table

Alteration temperatures are as low as 10°C in Zones I and II based on oxygen isotope fractionation. Strontium isotopic data indicate that a circulation of seawater is much more restricted in Zone II than in Zone I. Fluid inclusion measurements of vein quartz indicate the alteration temperature was mainly 300 ± 20°C in Zones III and IV, which is consistent with secondary mineral assemblages.The strontium, oxygen, and hydrogen isotopic compositions of hydrothermal fluids which were responsible for the greenschist facies alteration in Zones III and IV are estimated to be 0.7037, 2‰, and 3‰, respectively. Strontium and oxygen isotope data indicate that completely altered portions of greenstones and vein minerals were in equilibrium with modified seawater under low water/rock ratios (in weight) of about 1.6. This value is close to that of the end-member hydrothermal fluids issuing at 21°N EPR.Basement rocks are not completely hydrothermally altered. About 32% of the greenstones in Zones III and IV have escaped alteration. Thus 1 g of fresh basalt including the 32% unaltered portion are required in order to make 1 g of end-member solution from fresh seawater in water-rock reactions.     

Major active faults determine the location of the Tongonan geothermal field: Evidence provided by rock alteration and stable isotope geochemistry

Abstract The influence of major active faults on rock alteration and stable isotope geochemistry is described for the Tongonan geothermal field, Leyte, the Philippines. In the Pliocene, acid alteration with characteristic iron enrichment (3 g/100 g) and calcium depletion (2 g/100 g) occurred along a Riedel shear fault in the Malitbog sector, and initial minor acid alteration also occurred along a similar shear in the Mahiao sector. Later, sodium metasomatism (5 g/100 g) coincided with the highest aquifer chloride (10 000 mg/kg) as a result of dissociation of saline magmatic fluids discharging through the reservoir rocks in the Upper Mahiao. The incursion of magmatic fluids (possibly δD 35‰, δ¹⁸O +7‰) set up a vigorous convection cell of meteoric water, which focused around low‐angle (L) shears centered in the Sambaloran sector. Meteoric water (δD ?35 to ?40‰, δ¹⁸O ?6 ± 1‰) depleted the reservoir in silica (6 g/100 g) and potassium (1–2 g/100 g). It also completely exchanged oxygen isotopes rapidly (within months) at high temperatures (300–400°C), and now does so continuously with fractured isotopically fresh or incompletely altered rock at small scales (centimeters or less) exposed by a 2 cm/year creep around the L shears to form a new component called geothermal water. Geothermal water mixes with meteoric water at lower temperatures (<300°C) to create the characteristic shift in δ¹⁸O of 6‰ at near constant δD (?35 ± 5‰). The 10‰ variation in δD is due to groundwater recharge derived from rain falling on steep terrain (5‰) and to enrichment of deuterium in boiling saline solutions (5‰); it is not due to two‐component mixing of meteoric with magmatic water. The low (～1) isotopic water/rock (W/R) ratios calculated from oxygen isotopes in previously published reports are meaningless, because the water contains four components (predominantly geothermal and meteoric water; <10% magmatic and rock water). W/R ratios of up to 1500 calculated from spring and rock chemistry are more realistic and, with a flow rate of approximately 50 L/s through a 30 km³ reservoir, can account for the estimated 3 My age of the system.     

Isotope geochemistry of minerals and fluids from Newberry volcano, Oregon

Isotopic compositions were determined for hydrothermal quartz, calcite, and siderite from core samples of the Newberry 2 drill hole, Oregon. The δ¹⁵O values for these minerals decrease with increasing temperatures. The values indicate that these hydrothermal minerals precipitated in isotopic equilibrium with water currently present in the reservoirs. The δ¹⁸O values of quartz and calcite from the andesite and basalt flows (700–932 m) have isotopic values which require that the equilibrated water δ¹⁸O values increase slightly (− 11.3 to −9.2‰) with increasing measured temperatures (150–265°C). The lithic tuffs and brecciated lava flows (300–700 m) contain widespread siderite. Calculated oxygen isotopic compositions of waters in equilibrium with siderite generally increase with increasing temperatures (76–100°C). The δ¹⁸O values of siderite probably result from precipitation in water produced by mixing various amounts of the deep hydrothermal water (− 10.5 ‰) with meteoric water (− 15.5 ‰) recharged within the caldera. The δ¹³C values of calcite and siderite decrease with increasing temperatures and show that these minerals precipitated in isotopic equilibrium with CO₂ of about −8 ‰.The δ¹⁸O values of weakly altered (<5% alteration of plagioclase) whole-rock samples decrease with increasing temperatures above 100°C, indicating that exchange between water and rock is kinetically controlled. The water/rock mass ratios decrease with decreasing temperatures. The δ¹⁸O values of rocks from the bottom of Newberry 2 show about 40% isotopic exchange with the reservoir water.The calculated δ¹⁸O and δD values of bottom hole water determined from the fluid produced during the 20 hour flow test are −10.2 and −109‰, respectively. The δD value of the hydrothermal water indicates recharge from outside the caldera.     

Opaque minerals in geothermal well no. 7, Krafla, Northern Iceland

Study of the opaque minerals from well No. 7, Krafla, indicates two mineral assemblages: (1) hydrothermally altered igneous minerals and (2) secondary minerals that have precipitated from the geothermal fluid at depths down to 2140 m, and at temperatures up to more than 340°C. Chief amongst the chemically precipitated minerals are pyrite, pyrrhotite and goethite, which is described here for the first time in an Icelandic geothermal drill hole.The geothermal system at Krafla has been periodically disturbed by the influx of volcanic emanations; this article attempts to interpret, by use of thermochemical calculations, the processes affecting the precipitated mineral assemblage.     

Osmium isotope geochemistry in the Mackenzie River basin

The Cenozoic marine osmium isotope record is largely driven by changes in the continental input. We aid its interpretation by supplying direct measurements of present day riverine Os in known geological and environmental settings. We analyzed Os concentrations and isotopic ratios in the dissolved, suspended, and bed materials of the Mackenzie River in Canada and smaller rivers draining the Western Cordillera into the Pacific Ocean. Rhenium content was measured for suspended and bed materials to provide further constraint. Dissolved ¹⁸⁷Os/¹⁸⁸Os ratios range from 0.74 to 4.5 and are controlled to first order by age and lithology of the bedrock. The rivers draining Jurassic volcanic rocks are unradiogenic, as low as 0.74, and those draining the Precambrian Canadian Shield are radiogenic, as high as 3.5. The headwaters of the Mackenzie left bank tributaries draining metamorphic carbonates in the Eastern Cordillera and Paleozoic black and gray shales in the Transition zone and the Interior Platform are especially radiogenic (3.0-4.5) with relatively high concentrations of Os. These latter rivers are responsible for the Mackenzie being above world average in Os concentration and yield (mol Os/km²/year) as well as in ¹⁸⁷Os/¹⁸⁸Os. The dissolved load is more radiogenic than the suspended or bed loads and constitutes a significant fraction of total fluvial Os.     

The impact of different clay minerals on the anisotropy of clay matrix in shale

Although clay is composed of disconnected anisotropic clay platelets, many rock physics models treat the clay platelets in shale as interconnected. However, the clay matrix in shales can be modelled as anisotropic clay platelets embedded within a soft isotropic interplatelet region, allowing the influence of disconnected clay platelets on the elastic properties of the clay matrix to be analysed. In this model, properties of the interplatelet region are governed by its effective bulk and shear moduli, whereas the effective properties of the clay platelets are governed by their volume fraction, aspect ratio and elastic stiffness tensor. Together, these parameters implicitly account for variations in clay and fluid properties, as well as fluid saturation. Elastic stiffnesses of clay platelets are obtained from the literature, including both experimental measurements and first-principles calculations of the full anisotropic (monoclinic or triclinic) elastic stiffness tensors of layered silicates. These published elastic stiffness tensors are used to compile a database of equivalent transverse isotropic elastic stiffness tensors, and other physical properties, for eight common varieties of layered silicates. Clay matrix anisotropy is then investigated by examining the influence of these different elastic stiffnesses, and of varying model parameters, upon the effective transverse isotropic elastic stiffness tensor of the clay matrix. The relationship between the different clay minerals and their associated anisotropy parameters is studied, and their impact on the resulting anisotropy of the clay matrix is analysed.     

Ore-forming mechanism for the Xiaoxinancha Au-rich Cu deposit in Yanbian,Jilin Province,China: Evidence from noble gas isotope geochemistry of fluid inclusions in minerals

The Xiaoxinancha Au-rich copper deposit is one of important Au-Cu deposits along the continental margin in Eastern China. The deposit consists of two sections: the Beishan mine (North), composed of altered rocks with veinlet-dissemination sulfides and melnicovite-dominated sulfide-quartz veins, and the Nanshan mine (South), composed of pyrrhotite-dominated sulfide-quartz veins and pure sulfide veins. The isotope compositions of noble gases extracted from fluid inclusions in ore minerals, i.e. ratios of 3He/4He, 20Ne/22Ne and40Ar/36Ar are in the ranges of 4.45―0.08 Ra, 10.2―8.8 and 306―430, respectively. Fluid inclusions in minerals from the Nanshan mine have higher 3He/4He and 20Ne/22Ne ratios whereas those from the Beishan mine have lower 3He/4He ratios. The analysis of origin, and evolution of the ore fluids and its relations with the ore-forming stages and the ages of mineralization suggests that the initial hydrothermal fluids probably come from the melts generated by partial melting of oceanic crust with the participation of fluids from the mantle (mantle-plume type)/aesthenosphere. This also corresponds to the continental margin settings during the subduction of Izanagi ocaneic plate towards the palaeo-Asian continent (123―102 Ma). The veinlet-dissemination ore bodies of the Beishan mine were formed through replacement and crystallization of the mixed fluids generated by mixing of the ascending high-temperature boiling fluid with young crustal fluid whereas the melnicovite-dominated sulfide-quartz veins were formed subsequently by filling of the high-temperature ore fluid in fissures. Pyrrhotite-dominated sulfide-quartz veins in the Nanshan mine were formed by filling-deposition-crystallization of the moderate-temperature ore fluids and the pure sulfide veins were formed later by filling-deposition-crystallization of ore substance-rich fluids after boiling of the moderate-temperature ore fluids. The metallogenic dynamic processes can be summarized as: (1) formation of fluidand ore substance-bearing Adakitic magma by degassing, dewatering and partial melting during subduction of the Izanagi plate; (2) separation and formation of ore fluids from the Adakitic magma; and (3) success-sive ascending of the ore fluids and final formation of the Au-rich Cu deposit of veinlet-dissemination and vein types by secondary boiling.     

Compositions of heavy minerals in Northeastern China sandlands and provenance analysis

Sand samples deposited since the Last Glacial Maximum (LGM) from the Hulun Buir, Horqin and Otin-dag sandlands were measured for their assemblages of heavy minerals and chemical compositions of detrital garnets and tourmalines. Heavy mineral assemblages of these three sandlands consist mainly of garnet, ilmenite, epidote and minor amphibole and magnetite. Garnets consist mainly of high Mg type-A ones (58% on average), and minor type-B ones. Toumalines are mainly composed of Mg-rich and minor Fe-rich ones. Compared with those of central-southern Mongolia and central Tarim, these three sandlands are derived from the Phanerozoic rocks of the Central Asian Orogenic Belt and the Archean and Paleoprotorozoic basement rocks of the North China Craton. Our results provide direct evidence that the present-day sands may be reworked from LGM ones. Differences of heavy mineral composi-tions occur between the samples of the three sandlands and Taklimakan Desert, indicating that the material of the western arid regions contributes little to the eastern sandlands.     

Volcanism in the Sumisu Rift, I. Major element, volatile, and stable isotope geochemistry

A bimodal volcanic suite with KAr ages of 0.05–1.40 Ma was collected from the Sumisu Rift using alvin. These rocks are contemporaneous with island arc tholeiite lavas of the Izu-Ogasawara arc 20 km to the east, and provide a present day example of volcanism associated with arc rifting and back-arc basin initiation. Major element geochemistry of the basalts is most similar to that of basalts found in other, more mature back-arc basins, which indicates that back-arc basins need not begin their magmatic evolution with lavas bearing strong arc signatures.Volatile concentrations distinguish Sumisu Rift basalts from island arc basalts and MORB. H₂O contents, which are at least four times greater than in MORB, suppress plagioclase crystallization. This suppression results in a more mafic fractionating assemblage, which prevents Al₂O₃ depletion and delays the initiation of Fe₂O_3^(tot) and TiO₂ enrichment. However, unlike arc basalts,Fe^3+/ΣFe ratios are only slightly higher than in MORB and are insufficient to cause magnetite saturation early enough to suppress Fe₂O_3^(tot) and TiO₂ enrichment. Thus, major element trends are more similar to those of MORB than arcs.H₂O, CO₂ and S are undersaturated relative to pure phase solubility curves, indicating exsolution of an H₂O-rich mixed gas phase. HighH₂O/S, highδD, and low (MORB-like)δ³⁴S ratios are considered primary and distinctive of the back-arc basin setting.     

Helium isotope characteristics of Andean geothermal fluids and lavas

The first comprehensive helium isotope survey of the Andes is reported here. We have sampled geothermal fluids and phyric lava flows from the Southern (svz) and Central (cvz) Volcanic Zones, the volcanically active Pun˜a region and the Precordillera, Salta Basin, Longitudinal Valley and the aseismic region between the two volcanic zones. Although the active areas are characterised by significant differences in crustal age and thickness, the svz, cvz and Pun˜a are characterised by a wide and overlapping range in ³He/⁴He ratios (for fluids and phenocrysts) from predominantly radiogenic values to close to the MORB ratio. The measured ranges in ³He/⁴He ratios (R) (reported normalised to the air ³He/⁴He—R_A) are: svz (0.18 < R/R_A< 6.9); cvz (0.82 < R/R_A< 6.0); and Pun˜a (1.8 < R/R_A< 5.4). Modification of magmatic ³He/⁴He ratios by water/rock interactions (fluids) or post-eruptive grow-in of radiogenic ⁴He or preferential diffusive loss of ³He (phenocrysts) is considered unlikely; this means that the wide range reflects the helium isotope characteristics of magma bodies in the Andean crust. The mechanism controlling the ³He/⁴He ratios appears to be a mixing between mantle (MORB-like) helium and a radiogenic helium component derived from radioactive decay within the magma (magma aging) and/or interaction with ⁴He-rich country rock: a process expected to be influenced by pre-eruptive degassing of the mantle component. Assimilation of lower crust is also capable of modifying ³He/⁴He ratios, albeit to a much lesser extent. However, it is possible that the highest measured values in each zone were established by the addition of lower crustal radiogenic helium to MORB helium. In this case, the higher ‘base level’ ratios of the svz would reflect the younger crustal structure of this region. In contrast to helium, there is no overlap in the Sr or Pb isotope characteristics of lavas from the active zones: in all areas, therefore, ³He/⁴He ratios appear to vary independently of Sr and Pb isotope variations. This decoupling between the lithophile tracers and helium reflects the different processes controlling their isotopic characteristics: crust-mantle interactions, alone, for Sr and Pb but for helium the effects of pre-eruptive degassing and possibly magma aging are possibly superimposed. The presence of mantle helium in the Pun˜a region, and to a lesser extent in the Salta Basin, gives an across-arc perspective to the helium isotope distribution and shows mantle melting to occur significantly to the east of the active arc: this is most probably a consequence of lithospheric delamination. The Precordillera hot spring water has the only pure radiogenic helium signal of the entire sample suite and thus marks the western limit of asthenospheric mantle under the Andes.     

腾格里沙漠盐湖氯同位素地球化学特征

δ~(37)Cl值可以用来指示盐湖演化过程中卤水的蒸发浓缩程度、可能的补给来源和控制因素,本文对腾格里沙漠地区12个代表性盐湖卤水样品开展了氯同位素组成研究.结果表明,研究区内沙漠盐湖卤水的δ~(37)Cl值变化范围为-0.10‰~1.36‰,平均值为0.55‰;其中,硫酸钠亚型卤水的δ~(37)Cl值范围为-0.10‰~1.36‰(平均值为0.56‰),硫酸镁亚型卤水的δ~(37)Cl值范围为0.14‰~0.82‰(平均值为0.48‰).对比柴达木盆地现代盐湖分析数据,发现区内沙漠盐湖的δ~(37)Cl平均值明显大于柴达木盆地盐湖的δ~(37)Cl平均值,并且,硫酸钠亚型卤水δ~(37)Cl最高,硫酸镁亚型卤水次之,氯化物型卤水最小.基于不同盐湖地下水咸化程度以及盐湖卤水中δ~(37)Cl值与Br/Cl系数关系的研究,揭示了研究区东部和东北部盐湖可能受到第三系地层咸水的补给,而其他盐湖主要受蒸发浓缩作用影响.δ~(37)Cl值分布特征则显示,腾格里沙漠地区部分盐湖在形成过程中可能受到区域构造活动诱发的第三系深部水补给及水-岩作用等多重因素的影响.