The tritium and carbon-14 profiles at the Geosecs I (1969) and GOGO I (1971) North Pacific stations

Tritium and¹⁴C data of the “GOGO I” station at 28.5°N, 121.6°W in November 1971 are reported. The tritium decline between 150 and 350 m depth is as pronounced as was observed on a previous occupation of the same position, station “Geosecs I” in September 1969, and the tritium concentrations below 200 m are unchanged.¹⁴C data from the depth range of tritium decline are corrected for fallout¹⁴C contribution. The correcting procedure requires simultaneous measurements of¹⁴C, ΣCO₂, and tritium. It is concluded that the natural absolute¹⁴C concentration attains a maximum near 400 m depth, of 7.5% excess over that of surface water.     

Reduction of thermohaline circulation during deglaciation: the effect on atmospheric radiocarbon and CO2

A two-? ocean reservoir model is employed to examine the combined effects of vertical ocean circulation, organic matter extraction and cosmic ray production on the¹⁴C/¹²C in the atmosphere, ocean and sediment. In this model, dissolution of deep-sea calcium carbonate sediment is assumed to respond to the supply of particulate carbonate from the surface ocean and to the dissolved carbonate-ion concentration of the deep-sea.If the vertical ocean circulation decreased by 50% during the maximum rate of deglaciation, the atmospheric¹⁴C/¹²C would have increased concurrently by 10% relative to the pre-bomb present. Further, if cosmic ray production of¹⁴C was 50% greater than present at about 7800 years B.P. as suggested by archeomagnetic measurements, a double maximum of 10% occurs. The first is at about 10.5 ka and the second at 6.5 ka. This result is similar to the variation of¹⁴C/¹²C over the last 10,000 years calculated from the¹⁴C dates measured by Stuiver on the varved Lake of the Clouds. The result is not sensibly altered if 10¹⁷ moles of organic carbon is extracted from the ocean during sea-level rise.Reduction of the thermohaline ocean circulation by 50% over a one- to two-thousand-year interval would not be sensibly detected in the dating of deep-sea sediment. If Broecker's organic nutrient extraction occurs in conjunction with reduction of vertical circulation, a decrease in the atmospheric P_CO2 will precede the eventual rise.     

Atmospheric14C changes resulting from fossil fuel CO2 release and cosmic ray flux variability

A high-precision tree-ring record of the atmospheric¹⁴C levels between 1820 and 1954 is presented. Good agreement is obtained between measured and model calculated 19th and 20th century atmospheric Δ¹⁴C levels when both fossil fuel CO₂ release and predicted natural variations in¹⁴C production are taken into account. The best fit is obtained by using a ?-diffusion model with an oceanic eddy diffusion coefficient of 3 cm²/s, a CO₂ atmosphere-ocean gas exchange rate of 21 moles m^?2 yr^?1 and biospheric residence time of 60 years.For trees in the state of Washington the measured 1949–1951 atmospheric Δ¹⁴C level was20.0±1.2%. below the 1855–1864 level. Model calculations indicate that in 1950 industrial CO₂ emissions are responsible for at least 85% of the Δ¹⁴C decline, whereas natural variability accounts for the remaining 15%.     

Turnover of Eastern Caribbean deep water from 14C measurements

A¹⁴C balance for the Eastern Caribbean deep water indicates the average inflow of Atlantic water into the basin to be 2.3 × 10⁵ m³/sec (±30%), or about 2–4 times the values estimated previously. The balance uses a model representation of the deep-water turnover, and is based on¹⁴C concentrations at a station in the Venezuelan Basin which average Δ¹⁴C= 89‰ below 800 m depth with a total range of only 9‰, as well as on a¹⁴C concentration of the Atlantic inflow of Δ¹⁴C= ?71%. as obtained from measurements outside the Antilles Arch. The turnover time of the basin water below 2500 m depth is 55 years, which corresponds to an average upwelling velocity at this depth of about 35 m/year. With such upwelling, the temperature profile below 1800 m (the depth of the sill determining the inflow of new water) requires a vertical eddy diffusivity of about 5 cm²/sec. The oxygen consumption, and silica and CO₂ regeneration, rates below 2500 m depth are obtained as ?0.18, + 0.08, and + 0.2 μmole kg^?1 yr^?1, respectively. The CO₂ regeneration has but a negligible effect on the¹⁴C balance.     

The half life of32Si determined from a varved Gulf of California sediment core

Excess²¹⁰Pb measurements and varve chronology were used to establish a sediment accumulation rate of 0.19 cm/yr in a 95-cm-long box core raised from the Gulf of California. Varve thickness is unchanged over the entire length of the core, indicating a constant rate of sediment accumulation. The³²Si specific activity of biogenic silica shows an exponential decrease with depth in this core. The half life of³²Si, calculated from these data and the 0.19-cm/yr sediment accumulation rate, is276 ± 32 years. As most of the silica and³²Si supplied to the Gulf of California is a result of upwelling of deep ocean water, this half life determination should be relatively insensitive to secular variations in the atmospheric supply of³²Si.     

Reconstructions of the <Superscript>14</Superscript>С cosmogenic isotope content from natural archives after the last glacial termination

Data on the content of the ¹⁴C cosmogenic isotope in tree rings, which were obtained as a result of laboratory measurements, are often used when solar activity (SA) is reconstructed for previous epochs, in which direct observations are absent. However, these data contain information not only about SA variations but also about changes in the Earth climatic parameters, such as the global temperature and the CO₂ content in the Earth’s atmosphere. The effect of these variations on the ¹⁴C isotope content in different natural reservoirs after the last glacial termination to the middle of the Holocene is considered. The global temperature and the CO₂ content increased on this time interval. In this case the ¹⁴C absolute content in the atmosphere increased on this time interval, even though the ¹⁴С to ¹²С isotope concentration ratio (as described by the Δ¹⁴С parameter) decreased. These variations in the radiocarbon absolute content can be caused by its redistribution between natural reservoirs. It has been indicated that such a redistribution is possible only when the rate of carbon exchange between the ocean and atmosphere depends on temperature. The values of the corresponding temperature coefficient for the 17–10 ka BC time interval, which make it possible to describe the carbon redistribution between the ocean and atmosphere, have been obtained.     

Tritium and90Sr in North Atlantic surface water

Areal distributions and complete time histories since 1952 are presented of the tritium and⁹⁰Sr concentrations in North Atlantic surface water. The distributions are based on a compilation of measured North Atlantic surface water tritium concentrations which is part of this paper and includes hitherto unpublished measurements, and on available⁹⁰Sr compilations. To reconstruct the insufficiently represented early concentrations, a two-box North Atlantic mixing model with tropospheric input is employed, for which the input is specified (on relative scales), and which is fitted to the available surface water observations. This procedure gives a natural tritium concentration of 0.2 TU (±30%), and furthermore suggests that part of the old oceanic tritium and⁹⁰Sr measurements are high. The fit requires characteristic model mixing times of 2.5 years (exchange with an intermediate-depth reservoir about three times the size of the surface box) and 30 years (loss into the deep ocean), and a tritium/⁹⁰Sr input ratio of 310 Ci/Ci. The areal distributions and time histories can serve as boundary value data for evaluations of subsurface tritium and⁹⁰Sr measurements.     

The radiocarbon budget for Mono Lake: an unsolved mystery

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.     

Carbon monoxide on the primitive earth

The reaction of CO + OH^? in aqueous solution to give formate was studied as a carbon monoxide sink on the primitive earth and in the present ocean. The reaction is first order in OH^? and first order in the molar CO concentration. The second order rate constant is given by log k(M^?1hr^?1) = 15.83?4886/T between 25°C and 60°C. Using the solubility of CO in sea water, and assuming a pH of 8 for a primitive ocean of the present size, the halflife of CO in the atmosphere is calculated to be 12 × 10⁶ yr at 0°C and 5.5 × 10⁴ yr at 25°C.Three other CO sinks would have been important in the primitive atmosphere: CO + H₂ → H₂CO driven by various energy sources, CO + OH → CO₂ + H, and the Fischer-Tropsch reaction of CO + H₂ → hydrocarbons, etc. It is concluded that the lifetime of a CO atmosphere would have been very short on the geological time scale although the relative importance of these four CO sinks is difficult to estimate.The CO + OH^? reaction to give formate is a very minor CO sink on the earth at the present time.     

Major ion chemistry of two cratonic rivers in the tropics: Weathering rates and their controlling factors

Continental weathering plays a dominant role in regulating the global carbon cycle, soil chemistry and nutrient supply to oceans. The CO₂-mediated silicate weathering acts as a major CO₂ sink, whereas sulphuric acid-mediated carbonate dissolution releases CO₂ to the atmosphere–ocean system. In this study, dissolved major ions and silica concentrations of two tropical (Damodar and Subarnarekha) river systems from India have been measured to constrain the type and rate of chemical weathering for these basins. The total dissolved solids (TDS) of these rivers, a measure of total solute supply from all possible sources, are about 2–3 times higher than that of the global average for rivers. Mass balance calculations involving inverse modelling estimate that 63 ± 11% of total cations are derived from rock weathering, of which 27 ± 7% of cations are supplied through silicate weathering. The sulphide-S concentrations are estimated by comparing the water chemistry of these two rivers with that of a nearby river (Brahmani) with similar lithology but no signatures of sulphide oxidation. The outflows of Damodar and Subarnarekha rivers receive 17% and 55% of SO₄ through sulphide oxidation, respectively. The sulphide oxidation fluxes from the ore mining areas, such as upper Damodar (0.52 × 10⁹ mol/yr) and lower Subarnarekha (0.66 × 10⁹ mol/yr) basins, are disproportionally (~9 times) higher compared to their fractional areal coverage to the global drainage area. The corresponding CO₂ release rate (2.84 × 10⁴ mol/km²/yr) for the Damodar basin is lower by five times than its CO₂ uptake rate (1.38 × 10⁵ mol/km²/yr). The outcomes of this study underscore the dominance of sulphide oxidation in controlling the dissolved chemical (cationic and sulphur) fluxes.     

New insights into the spatial variability of the surface water carbon dioxide in varying sea ice conditions in the Arctic Ocean

In the summer of 2005, continuous surface water measurements of fugacity of CO₂ (fCO₂^sw), salinity and temperature were performed onboard the IB Oden along the Northwest Passage from Cape Farwell (South Greenland) to the Chukchi Sea. The aim was to investigate the importance of sea ice and river runoff on the spatial variability of fCO₂ and the sea–air CO₂ fluxes in the Arctic Ocean. Additional data was obtained from measurements of total alkalinity (A_T) by discrete surface water and water column sampling in the Canadian Arctic Archipelago (CAA), on the Mackenzie shelf, and in the Bering Strait. The linear relationship between A_T and salinity was used to evaluate and calculate the relative fractions of sea ice melt water and river runoff along the cruise track. High-frequency fCO₂^sw data showed rapid changes, due to variable sea ice conditions, freshwater addition, physical upwelling and biological processes. The fCO₂^sw varied between 102 and 678 μatm. Under the sea ice in the CAA and the northern Chukchi Sea, fCO₂^sw were largely CO₂ undersaturated of approximately 100 μatm lower than the atmospheric level. This suggested CO₂ uptake by biological production and limited sea–air CO₂ gas exchange due to the ice cover. In open areas, such as the relatively fresh water of the Mackenzie shelf and the Bering Strait, the fCO₂^sw values were close to the atmospheric CO₂ level. Upwelling of saline and relatively warm water at the Cape Bathurst caused a dramatic fCO₂^sw increase of about 100 μatm relative to the values in the CAA. At the southern part of the Chukchi Peninsula we found the highest fCO₂^sw values and the water was CO₂ supersaturated, likely due to upwelling. In the study area, the calculated sea–air CO₂ flux varied between an oceanic CO₂ sink of 140 mmol m⁻² d⁻¹ and an oceanic source of 18 mmol m⁻² d⁻¹. However, in the CAA and the northern Chukchi Sea, the sea ice cover prevented gas exchange, and the CO₂ fluxes were probably negligible at this time of the year. Assuming that the water was exposed to the atmosphere by total melting and gas exchange would be the only process, the CO₂ undersaturated water in the ice-covered areas will not have the time to reach the atmospheric CO₂ value, before the formation of new sea ice. This study highlights the value of using high-frequency measurements to gain increased insight into the variable and complex conditions, encountered on the shelves in the Arctic Ocean.     

Interannual variations of bomb radiocarbon during 1977– 1998 recorded in coral from Daya Bay,South China Sea

22 annual layered samples of coral from 1977 to 1998 were collected from Daya Bay, South China Sea, their bomb-¹⁴C (nuclear weapons testing¹⁴C) concentrations were determined and studied, and the atmosphere-sea exchange rate and diffusion thickness were estimated and found to be 17 mol · m⁻² · a⁻¹ and 32 μm, respectively. The interannual variation of coral Δ¹⁴C is mainly controlled by oceanic factors. In ENSO years, the coastwise upwelling current of South China Sea gets intensified, hence the coral Δ¹⁴C displays its bottom value. The coral Δ¹⁴C does no respond vividly to the variation of the solar radiation energy. In the past 20 years or so, the genera situation and the oceanic thermal structure of South China Sea are still stable even though inter annual variation occurs in the atmosphere-sea interaction and the upwelling current driven by the tropical energy.     

Correlations between13C and ΣCO2 in surface waters and atmospheric CO2

¹³C and ΣCO₂ data from the North and South Atlantic, the Antarctic, and the North and South Pacific are given. The δ¹³C of the ΣCO₂ in the deep water (～3000m) decreases from 1.7‰ in the North Atlantic to ?0.10‰ in the North Pacific. This change is attributed to the addition of about 158 μmoles of CO₂ per kg of seawater. The in-situ oxidation of organic matter accounts for 83% of this increase in ΣCO₂, while the remainder is attributed to dissolution of calcium carbonate.The δ¹³C of the dissolved CO₂ in mid-latitude surface water samples is controlled by a quasi-steady-state equilibrium with atmospheric CO₂ at a mean temperature of 16°C. The δ¹³C and ΣCO₂ values of Antarctic surface water samples suggest that these waters are derived from a mixture of North Atlantic deep water and equilibrated surface water.     

Meridional distribution of226Ra in the eastern Pacific along GEOSECS cruise tracks

We present the distribution of²²⁶Ra in eight vertical profiles from the eastern Pacific. The profiles are located along a meridional trend near 125°W, from 43°S to 29°N. Surface²²⁶Ra concentrations are about 7 dpm/100 kg, except for the two stations south of 30°S where the higher values are due to the Antarctic influence. Deep waters show a distinctive south-to-north increase in the²²⁶Ra content, from about 26 to 41 dpm/100 kg near the bottom. Unlike in the Atlantic and Antarctic Oceans, the effect of²²⁶Ra injection from bottom sediments is clearly discernible in the area. The presence of this primary²²⁶Ra can be traced up to at least 1–1.5 km above the ocean floor, making this part of the sea bed among the strongest source regions for the oceanic²²⁶Ra. Numerical solutions of a two-dimensional vertical advection-diffusion model applied to the deep (1.2–4 km)²²⁶Ra data give the following set of best fits: upwelling velocity(V_z) = 3.5m/yr, vertical eddy diffusivity(K_z) = 0.6cm²/s, horizontal (north-south) eddy diffusivity(K_y) = 1 × 10⁷cm²/s, and water-column regeneration flux of²²⁶Ra(J) = 3.3 × 10^?5dpmkg^?1yr^?1 as an upper limit. These parametric values are in general agreement with one-dimensional (vertical) model fits for the Ra-Ba system. However, consideration of²²⁶Ra balance leads us to suspect the appropriateness of describing the vertical exchange processes in the eastern Pacific with constantV_z and K_z. If future modeling is attempted, it may be preferable to treat the area as a diffusion-dominant mixing regime with depth-dependent diffusivities.     

Inorganic carbon dynamics during northern California coastal upwelling

Coastal upwelling events in the California Current System can transport subsurface waters with high levels of carbon dioxide (CO₂) to the sea surface near shore. As these waters age and are advected offshore, CO₂ levels decrease dramatically, falling well below the atmospheric concentration beyond the continental shelf break. In May 2007 we observed an upwelling event off the coast of northern California. During the upwelling event subsurface respiration along the upwelling path added ∼35 μmol kg⁻¹ of dissolved inorganic carbon (DIC) to the water as it transited toward shore causing the waters to become undersaturated with respect to Aragonite. Within the mixed layer, pCO₂ levels were reduced by the biological uptake of DIC (up to 70%), gas exchange (up to 44%), and the addition of total alkalinity through CaCO₃ dissolution in the undersaturated waters (up to 23%). The percentage contribution of each of these processes was dependent on distance from shore. At the time of measurement, a phytoplankton bloom was just beginning to develop over the continental shelf. A box model was used to project the evolution of the water chemistry as the bloom developed. The biological utilization of available nitrate resulted in a DIC decrease of ∼200 μmol kg⁻¹, sea surface pCO₂ near ∼200 ppm, and an aragonite saturation state of ∼3. These results suggest that respiration processes along the upwelling path generally increase the acidification of the waters that are being upwelled, but once the waters reach the surface biological productivity and gas exchange reduce that acidification over time.     

Estimate of productivity in ecosystem of the broad-leaved Korean pine mixed forest in Changbai Mountain

We measured soil, stem and branch respiration of trees and shrubs, foliage photosynthesis and respiration in ecosystem of the needle and broad-leaved Korean pine forest in Changbai Mountain by LI-6400 CO₂ analysis system. Measurement of forest microclimate was conducted simultaneously and a model was found for the relationship of soil, stem, leaf and climate factors. CO₂ flux of different components in ecosystem of the broad-leaved Korean pine forest was estimated based on vegetation characteristics. The net ecosystem exchange was measured by eddy covariance technique. And we studied the effect of temperature and photosynthetic active radiation on ecosystem CO₂ flux. Through analysis we found that the net ecosystem exchange was affected mainly by soil respiration and leaf photosynthesis. Annual net ecosystem exchange ranged from a minimum of about ?4.671 μmol·m^?2·s^?1 to a maximum of 13.80 μmol·m^?2·s^?1, mean net ecosystem exchange of CO₂ flux was ?2.0 μmol·m^?2·s^?1 and 3.9 μmol·m^?2·s^?1 in winter and summer respectively (mean value during 24 h). Primary productivity of tree, shrub and herbage contributed about 89.7%, 3.5% and 6.8% to the gross primary productivity of the broad-leaved Korean pine forest respectively. Soil respiration contributed about 69.7% CO₂ to the broad-leaved Korean pine forest ecosystem, comprising about 15.2% from tree leaves and 15.1% from branches. The net ecosystem exchange in growing season and non-growing season contributed 56.8% and 43.2% to the annual CO₂ efflux respectively. The ratio of autotrophic respiration to gross primary productivity (R _a:GPP) was 0.52 (NPP:GPP=0.48). Annual carbon accumulation underground accounted for 52% of the gross primary productivity, and soil respiration contributed 60% to gross primary productivity. The NPP of the needle and broad-leaved Korean pine forest was 769.3 gC·m^?2·a^?1. The net ecosystem exchange of this forest ecosystem (NEE) was 229.51 gC·m^?2·a^?1. The NEE of this forest ecosystem acquired by eddy covariance technique was lower than chamber estimates by 19.8%.     

Restrictions on Deep Flow Across the Shelf-break and the Role of Submarine Canyons in Facilitating such Flow

The shelf-break acts as a separator between the coastal ocean and the open ocean. Circulation (particularly deep near-bottom flow) is restricted from crossing the bathymetry. Eddies become elongated in the region of the shelf-break restricting exchange. An estimate of the horizontal eddy diffusivity over the shelf-break of less than 10m²s^-1 is found from a numerical model. Various mechanisms are responsible for the weak cross-isobath flow that does occur. One is the increase of the Rossby number over small-scale topography such as submarine canyons. Along-shore flow (in the direction opposite to Kelvin wave propagation) generates upwelling through submarine canyons. A review of upwelling through submarine canyons is given. The deep cross-shelf flow generated by the canyons is shown to be as significant as the wind-driven upwelling in some regions. Examples for the reduction of flow across the shelf-break and for upwelling through canyons are taken from the West Coast of Vancouver Island.     

The effect of light on the release of organic compounds by the cyanobacteriumOscillatoria rubescens

The effect of light intensity on the release of dissolved organic carbon during photosynthesis on NaH¹⁴CO₃ was investigated using the phytoplanktonic CyanobacteriumOscillatoria rubescens. The released products were fractionated by molecular size and chemical identifications attempted using combined thin-layer electrophoresis and chromatography, and high pressure liquid chromatography.Within the range of irradiances tested (from 6 to 60 µmole m^–2 sec^–1), though the upper one inhibited photosynthesis ofO. rubescens, light had little effect on the quantity and composition of the excreted products. The released carbon was always lower than 3% of the incorporated carbon, and mainly composed (62 to 86%) by small molecular weight compounds. The prevailing identified compounds were amino acids which represented more than 20% of the excreted carbon. Among organic acids, glycolic acid accounted for less than 2% of the recovered radioactivity. Glucose was the only identified sugar.Abbreviations EOC excreted organic carbon - DOC dissolved organic carbon - PER percent extracellular release - LMW low molecular weight - HMW high molecular weight - AA amino acids - µmoles m^–2 sec^–1 = µEinsteins m^–2 sec^–1     

Seasonal variation in carbon exchange and its ecological analysis over Leymus chinensis steppe in Inner Mongolia

Eddy covariance technique was used to measure carbon flux during two growing seasons in 2003 and 2004 over typical steppe in the Inner Mongolia Plateau, China. The results showed that there were two different CO₂ flux diurnal patterns at the grassland ecosystem. One had a dual peak in diurnal course of CO₂ fluxes with a depression of CO₂ flux after noon, and the other had a single peak. In 2003, the maximum diurnal uptake and emitting value of CO₂ were −7.4 and 5.4 g·m⁻²·d⁻¹ respectively and both occurred in July. While in 2004, the maximum diurnal uptake and release of CO₂ were −12.8 and 5.8 g·m⁻²·d⁻¹ and occurred both in August. The grassland fixed 294.66 and 467.46 g CO₂·m⁻² in 2003 and 2004, and released 333.14 and 437.17 g CO₂·m⁻² in 2003 and 2004, respectively from May to September. Water availability and photosynthetic active radiation (PAR) are two important factors of controlling CO₂ flux. Consecutive precipitation can cause reduction in the ability of ecosystem carbon exchange. Under favorable soil water conditions, daytime CO₂ flux is dependent on PAR. CO₂ flux, under soil water stress conditions, is obviously less than those under favorable soil water conditions, and there is a light saturation phenomena at PAR=1200 μmol·m⁻²·s⁻¹. Soil respiration was temperature dependent when there was no soil water stress; otherwise, this response became accumulatively decoupled from soil temperature.

     

Seasonal variations in pCO2 and its controlling factors in surface seawater of the northern East China Sea

Surface partial pressure of CO₂ (pCO₂), temperature, salinity, nutrients, and chlorophyll a were measured in the East China Sea (ECS; 31°30′–34°00′N to 124°00′–127°30′E) in August 2003 (summer), May 2004 (spring), October 2004 (early fall), and November 2005 (fall). The warm and saline Tsushima Warm Current was observed in the eastern part of the survey area during four cruises, and relatively low salinity waters due to outflow from the Changjiang (Yangtze River) were observed over the western part of the survey area. Surface pCO₂ ranged from 236 to 445 μatm in spring and summer, and from 326 to 517 μatm in fall. Large pCO₂ (values >400 μatm) occurred in the western part of the study area in spring and fall, and in the eastern part in summer. A positive linear correlation existed between surface pCO₂ and temperature in the eastern part of the study area, where the Tsushima Warm Current dominates; this correlation suggests that temperature is the major factor controlling surface pCO₂ distribution in that area. In the western part of the study area, however, the main controlling factor is different and seasonally complex. There is large transport in this region of Changjiang Diluted Water in summer, causing low salinity and low pCO₂ values. The relationship between surface pCO₂ and water stability suggests that the amount of mixing and/or upwelling of CO₂-rich water might be the important process controlling surface pCO₂ levels during spring and fall in this shallow region. Sea–air CO₂ flux, based on the application of a Wanninkhof [1992. Relationship between wind speed and gas exchange over the ocean. Journal of Geophysical Research 97, 7373–7382] formula for gas transfer velocity and a set of monthly averaged satellite wind data, were −5.04±1.59, −2.52±1.81, 1.71±2.87, and 0.39±0.18 mmol m⁻² d⁻¹ in spring, summer, early fall, and fall, respectively, in the northern ECS. The ocean in this study area is therefore a carbon sink in spring and summer, but a weak source or in equilibrium with the atmosphere in fall. If the winter flux value is assumed to have been the mean of autumnal and vernal values, then the northern ECS absorbs about 0.013 Pg C annually. That result suggests that the northern ECS is a net sink for atmospheric CO₂, a result consistent with previous studies.