The chemical composition of the Sun

We present a redetermination of the solar abundances of all available elements. The new results have very recently been published by Asplund et al. (Annu. Rev. Astron. Astrophys. 47:481, 2009). The basic ingredients of this work, the main results and some of their implications are summarized hereafter.     

The chemical composition and structure of the moon

Three types of igneous rocks, all ultimately related to basaltic liquids, appear to be common on the lunar surface. They are: (1) iron-rich mare basalts, (2) U-, REE-, and Al-rich basalts (KREEP), and (3) plagioclase-rich or anorthositic rocks. All three rock types are depleted in elements more volatile than sodium and in the siderophile elements when relative element abundances are compared with those of carbonaceous chondrites. The chemistry and age relationships of these rocks suggest that they are derived from a feldspathic, refractory element-rich interior that becomes more pyroxenitic; that is, iron/magnesium-rich; with depth.It is suggested that the deeper parts of the lunar interior tend toward chondritic element abundances. The radial variation in mineralogy and bulk chemical composition inferred from the surface chemistry is probably a primitive feature of the Moon that reflects the accretion of refractory elementenriched materials late in the formation of the body.     

Two-stage model for chemical evolution of galactic halo

We propose a model of chemical evolution of the galactic halo which consists of a succession of two different evolutionary stages; each stage is characterized by different outflow rate of gas from the star-forming region so that different metal-enrichment rate is resulted. The low-metal stars with [Fe/H]<–0.8 are formed mainly during the first 3×10⁸ yr, and most of the high-metal stars with [Fe/H]–0.8 are formed during the succeeding 2×10⁹ yr. This model naturally explains the metallicity distribution of globular clusters in the galactic halo including both the metal-rich and the metal-poor clusters. We also discuss the implications of the present model on the formation and evolution of the galactic halo.     

Photoionization models and chemical abundances of three halo planetary nebulae

Abtracts Photoionization models have been constructed to explain the line emission of the three halo planetary nebulae: K 648, 49+88°.1 and 108–76°.1. The charge transfer reactions between neutral hydrogen and different ions were taken into account in ionization equations. Due to lack of observational information, radiation-bounded as well as matter-bounded models have been considered. Both these models indicate that He and C abundances are close to solar values whereas the heavier elements are depleted.Partially supported by the Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brazil.This paper was entirely written when I received a preprint of Peimbert and Torres-Peimbert (1979) whose results confirm a high abundance of carbon in the planetary nebula 49+88°.1.     

The chemical composition of the Small Magellanic Cloud

The Small Magellanic Cloud is a close, irregular galaxy that has experienced a complex star formation history due to the strong interactions occurred both with the Large Magellanic Cloud and the Galaxy. Despite its importance, the chemical composition of its stellar populations older than ∼ 1–2 Gyr is still poorly investigated. I present the first results of a spectroscopic survey of ∼ 200 Small Magellanic Cloud giant stars performed with FLAMES@VLT. The derived metallicity distribution peaks at [Fe/H] ∼ –0.9/–1.0 dex, with a secondary peak at [Fe/H] ∼ –0.6 dex. All these stars show [α /Fe] abundance ratios that are solar or mildly enhanced (∼+0.1 dex). Also, three metal‐poor stars (with [Fe/H] ∼ –2.5 dex and enhanced [α /Fe] ratios compatible with those of the Galactic Halo) have been detected in the outskirts of the SMC: These giants are the most metal‐poor stars discovered so far in the Magellanic Clouds. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The chemical atmospheric composition of the giant planets

For a long time it was believed that the atmospheres of the giant planets, dominated by molecular hydrogen and helium, were similar in composition to the primordial nebula from which they formed. However, this image has strongly evolved over the past twenty years, due to new developments of ground-based infrared spectroscopy, coupled with the success of the Voyager space mission.Significant differences were measured in the abundances of helium, deuterium and carbon of the four giant planets. The variations in the C/H and D/H ratios have given support to the "nucleation" formation scenario, in which the four giant planets first accreted a nucleus of about ten terrestrial masses, big enough to bind gravitationally the surrounding gaseous nebula; the helium depletion in Saturn has been interpreted as a differentiation effect in Saturn's interior; the apparent helium excess in Neptune, coupled with the recent unexpected detection of CO and HCN in this planet, might imply the presence of molecular nitrogen. In the case of Jupiter and Saturn, disequilibrium species have been detected (CO, PH₃, GeH₄, AsH₃), which are tracers of vertical dynamical motions.In the future, significant progress in our knowledge of the Jovian composition, including the noble gases, should be obtained with the mass spectrometer of the Galileo probe. The ISO mission is expected to provide new far-infrared spectroscopic data which should lead to the detection of new minor species and a better determination of the D/H ratio.     

The chemical composition and structure of 30 Doradus

Spectrophotometry of many regions within 30 Doradus in the Large Magellanic Cloud provides chemical abundances and densities for this nebular complex. The helium to hydrogen abundance ratio is about one-tenth by number and the heavier elements are underabundant compared to Orion, with nitrogen showing the greatest deficit. The forbidden lines of singly-ionized sulphur show wide density variations across this object. The distribution of the intensities in these sulphur lines suggests that supernova shocks may have played an important role in producing the composite appearance of this giant HII region.     

The age of the halo as determined from halo field stars

The age of the Galactic halo is a critical parameter that can constrain the origin of the stellar halo.In general, the Galactic stellar halo is believed to be very old. However, different independent measurements and techniques based on various types of stars are required so that the age estimates of the Galactic halo are accurate, robust, and reliable. In this work, we provide a novel approach to determine the age of the halo with turn-off stars. We first carefully select 63 field halo turn-off stars from the literature. Then, we compare them with the GARSTEC model, which takes the process of atomic diffusion into account in the B- V vs. metallicity plane. Finally, we run Monte Carlo simulations to consider the uncertainty of the color index and obtain the age of 10.5 ± 1.5 Gyr. This result is in agreement with previous studies. Future works are needed to collect more turn-off samples with more accurate photometry to reduce the uncertainty of the age.     

The chemical composition of matter in the early universe

The results of the computations of the chemical evolution for a galaxy cluster are presented. The matter exchange between galaxies and intergalactic medium is taken into account. Two dependences of star formation rate on time are considered: (i) monotonously decreasing dependence characteristic of elliptical galaxies, (ii) dependence having two peaks associated with creation of spiral galaxy subsystems, with suppression of star formation at the period between maxima. It is assumed that galactic ejection is due to explosions of II-type supernova with massesm5M , and that the accretion on to a galaxy depends but weakly on the time. By comparing the obtained results with total combination of available observations, it is established that the rate of gaseous exchange between a galaxy and intergalactic medium should be rather large: 0.03M _gal Gyr^–1. Besides, the activity of each type of galaxy leads to an approximately equal enrichment of intergalactic gas by new elements synthesized in the stars. The existence of a large accretion on to the Galaxy leads to the decrease of primordial deuterium abundance by a factor of no more than 2 during the galaxy evolution time. It enables us to assume that the standard Big Bang model with baryon density parameter _b 0.1 may be considered as true.     

The stellar halo of the Galaxy

Stellar halos may hold some of the best preserved fossils of the formation history of galaxies. They are a natural product of the merging processes that probably take place during the assembly of a galaxy, and hence may well be the most ubiquitous component of galaxies, independently of their Hubble type. This review focuses on our current understanding of the spatial structure, the kinematics and chemistry of halo stars in the Milky Way. In recent years, we have experienced a change in paradigm thanks to the discovery of large amounts of substructure, especially in the outer halo. I discuss the implications of the currently available observational constraints and fold them into several possible formation scenarios. Unraveling the formation of the Galactic halo will be possible in the near future through a combination of large wide field photometric and spectroscopic surveys, and especially in the era of Gaia.     

Chemical composition and evolutionary status of the Ap star HD 138633

We present the results of our study of the atmospheric chemical composition and evolutionary status for the chemically peculiar Ap star HD 138633. In contrast to ordinary Ap stars that exhibit strong lines of rare-earth elements in their spectra, these elements are represented very poorly in the spectrum of HD 138633. The magnetic field is estimated to be less than 700 G, which is also atypical of peculiar Ap stars. We have detected a stratification of such elements as Fe, Si, Ca, and Y in the atmosphere of HD 138633 whose pattern agrees qualitatively with the predictions of the theory of diffusive separation of elements under the joint action of gravity and radiation pressure forces. The nonuniform distribution obtained by assuming a stepwise distribution of elements in depth agrees qualitatively with the stratification distribution for β CrB. The search for pulsations points to the possible existence of lowamplitude pulsations with a period of about 17 min.     

The asymmetric structure of the Galactic halo

Using the stellar photometry catalogue based on the latest data release (DR4) of the Sloan Digital Sky Survey (SDSS), a study of the Galactic structure using star counts is carried out for selected areas of the sky. The sample areas are selected along a circle at a Galactic latitude of +60°, and 10 strips of high Galactic latitude along different longitudes. Direct statistics of the data show that the surface densities of ℓ from 180° to 360° are systematically higher than those of ℓ from 0° to 180°, defining a region of overdensity (in the direction of Virgo) and another one of underdensity (in the direction of Ursa Major) with respect to an axisymmetric model. It is shown by comparing the results from star counts in the ( g − r ) colour that the density deviations are due to an asymmetry of the stellar density in the halo. Theoretical models for the surface density profile are built and star counts are performed using a triaxial halo of which the parameters are constrained by observational data. Two possible reasons for the asymmetric structure are discussed.     

The physics of the galactic halo gas

The available data speak in favour of space and time inhomogeneity of gaseous corona of our Galaxy. The observedCIV and SiIV ions are formed mainly by fast photons and localized inHII-clouds of the galactic halo. On the other hand, theNV ions are thermally ionized and localized in the gas corresponding to a transformation of hot intercloud coronal gas in theHII-clouds. TheHII-clouds exhibit downward the gas flow. The galactic fountain can eject the interstellar matter up to height of 1 kpc. Such ejections may be also displayed inCIV, SiIV, and partiallyNV, and partiallyNV absorptions. But large gaseous corona extending up to 3–5 kpc proves to be mass-unbalanced. It is possible that the existence of corona is evidence for violent star formation in the galactic disc in the recent past.     

Average chemical composition of the lunar surface

The available data on the chemical composition of the lunar surface at eleven sites (3 Surveyor, 5 Apollo and 3 Luna) are used to estimate the amounts of principal chemical elements (those present in more than about 0.5% by atom) in average lunar surface material. The terrae of the Moon differ from the maria in having much less iron and titanium and appreciably more aluminum and calcium.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

On the chemical composition of pregalactic matter

Rostov State University. Translated from Astrofizika, Vol. 30, No. 2, pp. 437–448, March–April, 1989.     

The chemical composition of stars with extrasolar planetary systems

Spectroscopic studies of stars with and without planetary systems have concluded that planet hosts are more metal‐rich. This enrichment is also seen in the other chemical elements studied and is likely to be primordial in nature. Interesting trends of different chemical elements begin to appear as the number of extrasolar planets continues to grow. I present our current knowledge concerning the observed abundance trends of chemical elements in planet hosts and their possible implications. In most cases the abundance trends of planet host stars are identical to those of the comparison sample. However, some exceptions (such as Li) have been reported too. No clear correlation was found between orbital parameters of planets and host star metallicity. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The main sequence location as function of chemical composition

Available data for computed zero-age lines are analyzed, and empirical formulae giving the luminosity as function of the chemical composition are derived. Mass-luminosity relations are also presented for a very wide range of the chemical composition parameters (X, Y, Z). Comparison with the observed zero-age lines are discussed.