Deep-water circulation in the Northeast Atlantic and climatic changes during the Late Neogene (DSDP Site 141)

Oxygen and carbon stable isotope data of Pyrgo murrhina and flux rates of calcium carbonate in the bio- and magnetostratigraphically dated sediment sequence at DSDP Site 141 were used for a reconstruction of the deep-water circulation in the Northeast Atlantic during Late Miocene and Pliocene times. A distinct change towards reduced advection of deep water recorded near 5.4 Ma is contemporaneous with the cessation of the outflow of the saline Mediterranean water into the Atlantic. During the Pliocene, between 4.5 and 2.75 Ma and between 2.1 and 1.8 Ma, North Atlantic Deep Water (NADW) circulation was sluggish and Site 141 possibly influenced by Antarctic Bottom Water (AABW). Near 2.75 Ma, the advection of well-oxidized NADW was strongly intensified. This change is related to an onset of major Arctic ice growth and/or a major cooling of NADW.     

Clay mineral assemblages,siliciclastic input and paleoproductivity at ODP Site 1085 off Southwest Africa: A late Miocene–early Pliocene history of Orange river discharges and Benguela current activity,and their relation to global sea level change

A late Miocene to early Pliocene sequence drilled on the continental slope of southwest Africa off the Orange river mouth (ODP Site 1085) has been investigated. Clay mineral assemblages, coarse siliciclastics and benthic foraminifer accumulation rates (BFAR) unravel a step by step evolution of marine and continental environments closely related to sea level variations, ocean circulation and global climate: (1) smectite is a typical tracer of the Orange river load, whereas illite is mostly transported by the Benguela current (like chlorite) and winds, and kaolinite is derived from low latitudes by the poleward undercurrent and the North Atlantic Deep Water (NADW); (2) increased erosion and influence of the Orange river after 9.6 Ma is linked to a sea level drop at a time of Antarctic ice-growth. This has been followed by an increased seasonality of precipitation and high productivity, but low oxygen content and associated dissolution of carbonates; (3) increased productivity and dissolution of carbonates, and coeval increase of continental aridity after 8.9 Ma express a further development of the Benguela current and upwelling; (4) better preservation of carbonates and increased contribution of terrigenous material from northern sources at 6.9 Ma are related to increased circulation of NADW after an early stage of northern hemisphere glaciation; (5) increased erosion and contribution from the Orange river and westward shift of the area of higher productivity from 5.9–5.8 Ma to 5.3–5.2 Ma are related to a significant fall of sea level, and encompass the time of the entire Mediterranean salinity crisis; (6) short-term variations of the smectite/illite ratio (S/I) and BFAR suggest a major control of productivity by wind and current activities (and related upwelling), but may express brief variations of sea level in specific intervals before 8.9 Ma and during the late Messinian especially.     

Paleoclimatic changes in southern Africa during the intensification of Northern Hemisphere glaciation: evidence from ODP Leg 175 Site 1085

Pliocene age sediments from Ocean Drilling Program Leg 175, Site 1085-A and B in the Cape Basin were analyzed to investigate the impact of the intensification of Northern Hemisphere glaciation (INHG) on the South Atlantic Benguela Current system from 4 to 2 Ma. Proxies for productivity (concentrations and mass accumulation rates of total organic carbon, carbon to nitrogen ratios, percent calcium carbonate, and percent biogenic silica) as well as weight percent sand (a proxy for preservation or winnowing) peak at 3.2, 3.0, 2.4, and 2.25 Ma. Normative calculations of allied trace and major elemental determinations indicate synchronous increases in productivity peaks, as well as high concentrations and accumulations of terrigenous sediments. Coeval increases in hemipelagic sedimentation and productivity indicators could be the result of enhanced eolian sedimentation resulting from strengthened winds, leading to elevated rates of upwelling and enhanced productivity. However, rapid burial, as indicated by high sedimentation rates, could also enhance preservation. The very high concentrations (>30%) and accumulations (up to 60 g/cm²/kyr) limit the likelihood that eolian sedimentation was the only transport mechanism, invoking an additional fluvial source. Rapid burial by either eolian or fluvial transport links these intervals of enhanced preservation and productivity with continental climate changes resulting from (1) increased winds and/or dust availability due to higher aridity in the Namibia/northern South Africa region; (2) lowered sea-level related to increased ice volume; (3) increased sediment load due to wetter conditions in the continental interior; or (4) some combination. Peaks at 3.2, 2.4 and 2.25 Ma are coincident with maximum precession, suggesting a link between hemipelagic sedimentation and enhanced monsoonal circulation over southern Africa. The Site 1085 sedimentary record during the INHG seems to be controlled by low-latitude processes linked to precession rather than hig-latitude processes.     

Benthic foraminifera and sediment grain size variability at intermediate water depths in the Northeast Atlantic during the late Pliocene–early Pleistocene

Sedimentological and faunal records from the transitional period marking the onset of widespread northern hemisphere glaciation have been investigated at Ocean Drilling Program Site 984. The late Pliocene interglacial sediments of the northeast Atlantic are carbonate rich and show evidence of vigorous bottom water circulation at intermediate water depths. Contrasting this, the late Pliocene glacial sediments are characterised by carbonate dissolution and slower bottom current velocities. Weak or “leaky” Norwegian Sea overflows, undersaturated with respect to carbonate, influenced this region during the late Pliocene glacials. The early Pleistocene pattern of intermediate water circulation appears to have changed radically in the northeast Atlantic. At this time, interglacial carbonate values and inferred bottom current velocities are low. This suggests slow-flowing, undersaturated Norwegian Sea water bathing the site. The overflow increased during the early Pleistocene interglacials as the exchange between the Atlantic and Norwegian-Greenland Seas improved. The most significant feature of the early Pleistocene glacials is the increase in inferred bottom current velocity. These changes reflect a switch in deep North Atlantic convection to shallower depths during glacial periods, possibly in a manner similar to the increasing contribution of glacial intermediate water to the North Atlantic during the late Pleistocene glacials. Our results suggest that the late Pleistocene climate variability of the North Atlantic is a pervasive feature of the late Pliocene–early Pleistocene record.     

The early Matuyama Diatom Maximum off SW Africa: a conceptual model

An important discovery during Ocean Drilling Program Leg 175, when investigating the record of upwelling off Namibia, was the finding of a distinct Late Pliocene diatom maximum spanning the lower half of the Matuyama reversed polarity chron (MDM, Matuyama Diatom Maximum) and centered around 2.6–2.0 Ma. This maximum was observed at all sites off southwestern Africa between 20°S and 30°S, and is most strongly represented in sediments of Site 1084, off Lüderitz, Namibia. The MDM is characterized by high biogenic opal content, high numbers of diatom valves, and a diatom flora rich in Southern Ocean representatives (with Thalassiothrix antarctica forming diatom mats) as well as coastal upwelling components. Before MDM time, diatoms are rare until ca. 3.6 Ma. After the MDM, in the Pleistocene, the composition of the diatom flora points to increased importance of coastal upwelling toward the present, but is accompanied by a general decrease in opal and diatom deposition. Here we present a simple conceptual model as a first step in formalizing a possible forcing mechanism responsible for the record of opal deposition in the upwelling system off Namibia. The model takes into account Southern Ocean oceanography, and a link with deepwater circulation and deepwater nutrient chemistry which, in turn, are coupled to the evolution of North Atlantic Deep Water (NADW). The model proposes that between the MDM and the Mid-Pleistocene climate revolution, opal deposition off Namibia is not directly tied to glacial–interglacial fluctuations (as seen in the global δ¹⁸O record), but that, instead, a strong deepwater link exists with increased NADW production (as seen in the deepwater δ¹³C record) accounting for higher supply of silicate to the thermocline waters that feed the upwelling process. The opal record of Site 1084 shows affinity to eccentricity on the 400-kyr scale but not for the 100-kyr scale. This points toward long-term geologic processes for delivery of silica to the ocean.     

The late Miocene onset of high productivity in the Benguela Current upwelling system as part of a global pattern

We have examined the history of the elevated primary productivity associated with the Benguela Current upwelling system off southwest Africa using sediments from 7.5 to 4.8 Ma at Ocean Drilling Program Site 1085 in the middle Cape Basin. Sedimentation rates are low until 6.9 Ma. Low accumulation rates of benthic foraminifers and organic carbon indicate that biological productivity was also low. Paleoproductivity dramatically increased at 6.7–6.5 Ma and was highly variable until 4.8 Ma with productivity maxima during cooler periods. The presence of radiolarian opal only between 5.8 and 5.2 Ma suggests an interlude of silica-rich intermediate water in the Cape Basin. The onset of heightened productivity under the Benguela Current is mirrored by similar increases reported between 6.9 and 6.7 Ma in the tropical eastern Pacific, the western and northern Pacific, and the Indian Ocean. The similarity between the patterns at Site 1085 and in the Pacific and Indian Oceans suggests that the dramatic productivity increase off southwest Africa is part of a global response to paleoceanographic changes.     

Late Quaternary siliciclastic/carbonate sedimentation model for the Capricorn Channel,southern Great Barrier Reef province,Australia

A model is presented for hemipelagic siliciclastic and carbonate sedimentation during the last glacial–interglacial cycle in the Capricorn Channel, southern Great Barrier Reef (GBR). Stable isotope ratios, grainsize, carbonate content and mineralogy were analysed for seven cores in a depth transect from 166 to 2892 m below sea level (mbsl). Results show variations in the flux of terrigenous, neritic and pelagic sediments to the continental slope over the last sea level cycle.During the glacial lowstand terrigenous sediment influenced all the cores down to 2000 mbsl. The percentages of quartz and feldspar in the cores decreased with water depth, while the percentage of clay increased. X-ray diffraction analysis of the glacial lowstand clay mineralogy suggests that the siliciclastic sediment was primarily sourced from the Fitzroy River, which debouched directly into the northwest sector of the Capricorn Channel at this time. The cores also show a decrease in pelagic calcite and an increase in aragonite and high magnesium calcite (HMC) during the glacial. The influx of HMC and aragonite is most likely from reworking of coral reefs exposed on the continental shelf during the glacial, and also from HMC ooids precipitated at the head of the Capricorn Channel at this time. Mass accumulation rates (MARs) are high (13.5 g cm^? 3 kyr^? 1) during the glacial and peak at ~ 20 g cm^? 3 kyr^? 1 in the early transgression (16–14 ka BP). MARs then decline with further sea level rise as the Fitzroy River mouth retreats from the edge of the continental shelf after 13.5 ka BP. MARs remain low (4 cm^? 3 kyr^? 1) throughout the Holocene highstand.Data for the Holocene highstand indicate there is a reduction in siliciclastic influx to the Capricorn Channel with little quartz and feldspar below 350 mbsl. However, fine-grained fluvial sediments, presumably from the Fitzroy River, were still accumulating on the mid slope down to 2000 mbsl. The proportion of pelagic calcite in the core tops increases with water depth, while HMC decreases, and is present only in trace amounts in cores below 1500 mbsl. The difference in the percentage of HMC in the deeper cores between the glacial and Holocene may reflect differences in supply or deepening of the HMC lysocline during the glacial.Sediment accumulation rates also vary between cores in the Capricorn Channel and do not show the expected exponential decrease with depth. This may be due to intermediate or deep water currents reworking the sediments. It is also possible that present bathymetry data are too sparse to detect the potential role that submarine channels may play in the distribution and accumulation of sediments.Comparison of the Capricorn Channel MARs with those for other mixed carbonate/siliciclastic provinces from the northeast margin of Australia indicates that peak MARs in the early transgression in the Capricorn Channel precede those from the central GBR and south of Fraser Island. The difference in the timing of the carbonate and siliciclastic MAR peaks along the northeast margin is primarily related to differences in the physiography and climate of the provinces. The only common trend in the MARs from the northeast margin of Australia is the near synchronicity of the carbonate and siliciclastic MAR peaks in individual sediment cores, which supports a coeval sedimentation model.     

Neogene oceanographic variations recorded in manganese nodules from the Somali Basin

A detailed study of a nodule from the Somali Basin dated by ²³⁰Th_excess was correlated with the paleoceanographic events recorded in Site 236 (Leg 24) Deep Sea Drilling Project (DSDP) cores. Tentative indications are that the phase of nodule accretion starting with the development of pillar structure at a depth of 20 mm in the nodule around 13 Ma coincides with increased Antarctic Bottom Water (AABW) flow and an elevated calciumcarbonate compensation depth (CCD).

The Late Miocene lowering of the CCD is represented by the mottled zones between 8 and 18 mm in the nodule is characterised by an abundant silicate component (>20%) of aeolian origin. The Miocene/Pliocene boundary (5 Ma) occurs at a depth of about 8 mm and is represented by the development of pillar structure and a minimum of aeolian dust (10.3%).

The increased biological productivity of the Somali surface water since the Middle Miocene is demonstrated by the increasing C_org content of the nodule (from 0.11 to 0.19%) towards its surface.     

南沙海区更新世以来的放射虫丰度低值事件及其古海洋学意义

根据南沙海区17957－2柱1．34Ma以来的放射虫定量研究发现,在0．88－0．91Ma和1．14－1．16Ma两个时期放射虫堆积率和丰度突然降到最低值,造成两次丰度低值事件。第一次丰度低值事件与0．9Ma发生的“中更新世革命”事件有关。这两次丰度低值事件可能是由于高的放射虫碎壳率所反映的强硅质溶解作用、含量较高的碳酸盐和火山灰的稀释作用以及较低的表层初级生产力三者的共同作用所造成的,反映了硅质生物沉积过程的复杂性。     

Cyclic variations in the chemical composition of eastern Mediterranean Pliocene sediments: a key for understanding sapropel formation

Two Pliocene Mediterranean sediment cores from Ocean Drilling Program (ODP) Leg 160, Sites 964 (Pisano Plateau, Ionian Basin) and 967 (lower northern slope of Eratosthenes Seamount, south of Cyprus) have been analyzed for major and minor elements (Si, Ti, Al, Fe, Mg, Ca, K, Ba, Cr, Ni, V, Zn, Zr) by X-ray fluorescence analysis at a depth resolution of 3 to 4 cm (a total of 430 samples). Core 964C-9H comprises five sapropels with up to 9.7% total organic-carbon (TOC), one 2.5-m-thick turbidite, and a 50-cm segment of a second turbidite, whereas Core 967B-9H contains eight sapropels with TOC contents of up to 6.7%. Cyclic variations in carbonate content and detrital-matter composition are evident at both sites. At Site 964 (Pisano Plateau) terrigenous detrital-matter chemistry reflects periods of stronger Saharan dust input (higher Si/Al and Zr/Al ratios) alternating with fluvial input from the northern borderlands (higher Mg/Al ratios). Cyclicity is not well-expressed at this location because turbidites and winnowing occur. Site 967 (Eratosthenes Seamount) sediments are strongly influenced by discharge from the Nile River during humid periods (low K/Al and Mg/Al ratios). At Site 967 sapropels occur only during periods of enhanced Nile discharge with correspondingly lower Si/Al, Ti/Al, Mg/Al, K/Al, and Zr/Al ratios. Accumulation rates of carbonate and terrigenous detrital matter were 30% lower during such episodes because of the reduction in eolian input and carbonate production and/or carbonate dissolution. Periodical Ba enrichments, which are not only seen in the sapropels, but in every K/Al minimum, document the association of enhanced bioproductivity and sapropel formation. As calculated from excess Ba concentrations, productivity increased by up to a factor of five during intervals of intensified Nile runoff. Fluviatile discharge seems to be responsible for an enhanced input of nutrients and suspended matter containing low Mg/Al and K/Al ratios. Based on organic-carbon concentrations, episodes of sapropel formation lasted at least from 1000 to 4000 years at Site 964, and from 2000 to 6000 years at Site 967. Periods of enhanced bio-productivity, as defined by Ba enrichments, lasted from 8000 to 12,000 years at Site 967. Episodes of high river discharge and corresponding nutrient input, as well as conditions of sapropel formation, seem to have lasted longer in the eastern part of the basin (Site 967) than at the Pisano Plateau (Site 964).     

Mud waves at Deep Sea Drilling Project Site 603, US Atlantic lower continental rise

An extensive field of mud waves occupies the Lower Continental Rise, east of Cape Hatteras, USA. Seismic profiles at Deep Sea Drilling Project Site 603 show that they have migrated upcurrent at a steadily decreasing rate, until a standing wave phase was established in the Quaternary. The growth of the waves was terminated between the early Pleistocene and Holocene by an erosional event(s). Erosion was greatest on the downcurrent sides of the waves causing an apparent upcurrent migration at the surface. It is suggested that erosion may have played a significant part in the migration of the deeper waves at Site 603.     

Accumulation of organic and inorganic carbon in Pliocene–Pleistocene sediments along the SW African margin

The Ocean Drilling Program Leg 175 recovered a unique series of stratigraphically continuous sedimentary sections along the SW African margin, an area which is presently affected by active coastal upwelling. The accumulation rates of organic and inorganic carbon are a major component of this record. Four Leg 175 sites (1082, 1084, 1085, 1087) are chosen as part of a latitudinal transect from the present northern to southern boundaries of the Benguela Current upwelling system, to decipher the Pliocene–Pleistocene history of biogenic production and its relationship with global and local changes in oceanic circulation and climate. The pattern of CaCO₃ and C_org mass accumulation rates (MARs) over 0.25-Myr intervals indicates that the evolution of carbon burial is highly variable between the northern and the southern Benguela regions, as well as between sites that have similar hydrological conditions. This, as well as the presence over most locations of high-amplitude, rapid changes of carbon burial, reflect the partitioning of biogenic production and patterns of sedimentation into local compartments over the Benguela margin. The combined mapping of CaCO₃ and C_org MARs at the study locations suggests four distinct evolutionary periods, which are essentially linked with major steps in global climate change: the early Pliocene, the mid-Pliocene warm event, a late Pliocene intensification of northern hemisphere glaciation and the Pleistocene. The early Pliocene spatially heterogeneous patterns of carbon burial are thought to reflect the occurrence of mass-gravitational movements over the Benguela slope which resulted in disruption of the recorded biogenic production. This was followed (3.5–3 Ma) by an episode of peak carbonate accumulation over the whole margin and, subsequently, by the onset of Benguela provincialism into a northern and a southern sedimentary regime near 2 Ma. This mid and late Pliocene evolution is interpreted as a direct response to changes in the ventilation of bottom and intermediate waters, as well as to dynamics of the subtropical gyral circulation and associated wind stress.     

南海北部晚渐新世与早中新世之交T60构造运动的古水深响应

本文采用国际大洋发现计划(IODP)第368航次U1501站位井深264.0～331.1 m的样品,通过有孔虫壳体氧同位素地层和锶同位素定年,得出该段井深年龄为晚渐新世?早中新世20.3～32.0 Ma(地震反射不整合面T60的底部年龄在28～30.5 Ma左右)。T60构造运动之后,岩芯沉积物中有机碳含量、底栖有孔虫壳体稳定碳同位素δ13C、浮游与底栖有孔虫碳同位素差值Δδ13C_P-B指示海水表层生产力的降低;碳酸钙含量、有机碳/氮比值反映了陆源物质输入的减少;结合浮游有孔虫相对丰度以及底栖有孔虫的属种组合变化,共同揭示了南海北部在晚渐新世?早中新世时期,区域构造沉降运动导致了U1501站位在T60之后古水深逐步加深、离岸距离变远,相关结论从微体古生物学角度为认识T60构造事件及其沉积环境变化提供了科学证据。     

渤海中部海域海底热扩散率及恒温层深度研究

利用渤海中部海域泥温实测资料，计算出该海域海底热扩散率及恒温层深度。结果表明，８＃平台处的热扩散率为０．００１～０．００５ｃｍ２ｓ－１，Ａ（Ｂ）平台处为０．００２～０．０１０ｃｍ２ｓ－１。恒温层深度８＃平台处为８ｍ，Ａ（Ｂ）平台处１０ｍ，也有差异。与陆地比较，海底恒温层深度较浅，且水深越深恒温层深度越浅。     

Determination of sediment volumes, accumulation rates and turbidite emplacement frequencies on the Madeira Abyssal Plain (NE Atlantic): a correlation between seismic and borehole data

The sedimentary infill history of the Madeira Abyssal Plain (MAP) is established from correlation of ODP Leg 157 drillsites (Sites 950–952) with an almost regular grid of 7000 km of intermediate-resolution seismic reflection profiles covering the central part of the abyssal plain. The most conspicuous seismic reflectors bounding the seismostratigraphic units have been identified and mapped. Correlation between seismic and borehole data using synthetic seismograms allows the lithological attribution and dating of the reflectors and seismostratigraphic units. Lateral mapping and correlation of seismic units also allows both the volumes and rates of accumulation of sediments within each seismostratigraphic unit and equivalent time periods of deposition to be determined. These calculations have been corrected for the effect of compaction, calculated at around 40% at the base of the drillholes. Three main turbidite types have been identified at the drillsites and their emplacement frequency has been calculated for each site and time period. Our results show that Cretaceous oceanic crust was draped with red pelagic clays, and the fracture-zone valleys were completely infilled and levelled in a geologically rather short time, probably during the latest Oligocene and Early Miocene, by organic-rich turbidites derived from the NW African continental margin. At 16 Ma, the topography was levelled enough to allow large turbidity current flows to cover the entire plain. During the Middle and Late Miocene (16–5.9 Ma), organic-rich turbidites were emplaced on the abyssal plain at a low rate of accumulation (12 m/my). In the uppermost Miocene–Early Pliocene (5.9–3.6 Ma), turbidite emplacement increased markedly in both frequency and accumulation rate (e.g., 26 m/my for organic-rich turbidites). During this time, period emplacement of volcanic-rich turbidites also increased in volume and frequency, a trend that continued into the Pliocene. Increased volcanic-rich turbidite emplacement correlates well with increased volcanic activity on the Canary Islands, and increased organic-rich turbidite emplacement may correlate with periods of erosion on the NW African continental margin. These erosional periods may be related to global cooling and falling sea level, intensification of bottom-water currents, and enhanced upwelling on the margin.     

Siliciclastic influx and burial of the Cenozoic carbonate system in the Gulf of Papua

An extensive carbonate system in the Gulf of Papua (GoP), developed in the late Oligocene–middle Miocene, was buried by huge influx of siliciclastics originated from Papua New Guinea. Major episodes of siliciclastic influx in the carbonate system are related to tectonic activity in the fold and thrust belt during the Oligocene Peninsular Orogeny, late Miocene Central Range Orogeny, and late Pliocene renewed uplift and exhumation of peninsular region. Siliciclastics did not influence the carbonate deposition during the late Oligocene–middle Miocene, since they were accumulated in the Aure Trough, proximal foreland basin protecting the carbonate system. The most significant burial of the carbonate system started during the late Miocene–early Pliocene in the result of the Central Range Orogeny. However, the largest influx was related to the renewed uplift of the Papuan Peninsula during the early late Pliocene. The shelf edge prograded ∼150 km and formed more than 80% of the modern shelf. This high siliciclastic influx was also enhanced by the “mid” Pliocene global warmth period and intensified East Asian monsoons at 3.6–2.9 Ma. Although many publications exist on carbonate–siliciclastic mixing in different depositional environments, this study helps understand the carbonate–siliciclastic interactions in space and time, especially at basinal scale, and during different intervals of the carbonate system burial by siliciclastic sediments.     

南海IODP 349航次基底玄武岩中碳酸盐岩脉的岩石学特征*

国际大洋发现计划(International Ocean Discovery Program, IODP)349航次在南海东部次海盆和西南次海盆残留扩张脊附近的U1431和U1433站位首次钻取基底玄武岩, 通过对16块基底玄武岩内的碳酸盐岩脉薄片镜下观察以及激光拉曼光谱分析, 揭示碳酸盐矿物为方解石和文石, 为典型的洋壳低温热液蚀变次生矿物。U1431站位碳酸盐岩脉为独立的方解石脉、文石脉交替出现; 而U1433站位则存在方解石脉、文石脉和方解石-文石共生脉三种情况。此外, U1431站位在基底~42.1m处出现了平行的方解石脉和文石脉, 揭示U1431存在不同来源热液的多期活动, 即可能存在多次或多阶段不同的热液注入。U1431和U1433站位的碳酸岩脉中, 文石的矿物集合体形状基本一致, 呈块状、纤维状和放射纤维状; 而方解石存在差异, U1431的方解石以斑块状、块状、粒状和纤维状出现, 而U1433的方解石仅出现块状。U1431站位的碳酸盐岩脉的丰度明显高于U1433站位。这些均揭示U1431站位的低温热液活动强, 而U1433站位则相对弱。两个站位的热液活动不同很可能是由于区域地质环境的差异造成——U1431附近的巨大海山为其提供了热液补给, 而U1433远离热液的补给/渗漏点。     

Pliocene export production and terrigenous provenance of the Southern Cape Basin, southwest African margin

We have analyzed 33 Pliocene bulk sediment samples from Ocean Drilling Program Site 1085 in the Cape Basin, located offshore of western Africa in the Angola–Benguela Current system, for 17 major and trace elements, and interpreted their associations and temporal variations in the context of an allied data set of CaCO₃, opal, and C_org. We base our interpretations on elemental ratios, accumulation rates, inter-element correlations, and several multi-element statistical techniques. On the basis of qualitative assessment of downhole changes in the distributions of P and Ba, utilized as proxies of export production, we conclude that highs in bulk and biogenic accumulation that occur at 3.2 Ma, 3.0 Ma, 2.4 Ma, and 2.25 Ma were caused by increases in export production as well as terrigenous flux, and record a greater sequestering of organic matter during these time periods. Studies of refractory elements and other indicator proxies (SiO₂, Al₂O₃, TiO₂, Fe₂O₃, MgO, V, Cr, Sr, and Zr) strongly suggest that the terrigenous component of the bulk sediment is composed of two compositional end-members, one being ‘basaltic’ in composition and the other similar to an ‘average shale’. The basaltic end-member comprises approximately 10–15% of the total bulk sediment and its presence is consistent with the local geology of source material in the drainage basin of the nearby Orange River. The increase in bulk accumulation at 2.4 Ma appears to reflect a greater relative increase in basaltic input than the relative increase in shale-type input. Although studies such as this cannot precisely identify the transport mechanisms of the different terrigenous components, these results are most consistent with variations in sea level (and associated changes in shelf geometry and fluvial input) being responsible for the changing depositional conditions along the Angolan Margin during this time period.     

沉积环境对雅浦海沟沉积颗粒物组成和分布的影响

通过对西太平洋雅浦海沟不同水深沉积物中总有机碳（TOC）、总氮（TN）、碳稳定同位素（δ13C）、粒度组成和比表面积（SSA）等参数的分析,探讨了雅浦海沟不同水深沉积颗粒物来源、分布及其影响因素的异同。结果表明,雅浦海沟沉积物TOC含量和δ13C平均值分别为（0.34%±0.14%）和（-20.8‰±0.7‰）,其中海洋浮游植物、陆源土壤和维管植物来源有机碳（OC）的贡献分别为（70%±3%）、（22%±3%）和（8%±2%）,且不同水深差异不大,海沟内沉积物的横向输运可能是深部沉积OC的重要输入途径。由于水深更深站位沉积颗粒物中具有更强的微生物活动和在水柱中更长的保留时间,导致其TOC和TN含量较低,但δ13C无明显差异。水深较浅站位TN含量、SSA、粒径组成和中值粒径等参数垂向变化波动较更深站位更为显著,表明海沟沟壁水深较浅处物源输入和沉积环境的不稳定。同时,由于低OC含量、低SSA以及高密度的海底火山喷出岩在海沟水深较浅的沟壁坡折处的广泛分布,导致该区域粒径组成与TOC含量无显著相关性,而较深站位中TOC含量与粉砂呈正相关,与砂和黏土含量呈负相关。整体而言,雅浦海沟沉积物中粉砂粒级颗粒物是OC的主要载体,而SSA是影响海沟沉积OC剖面分布的最重要因素。     

Seasonal and vertical variations of sinking particle fluxes in the West Caroline Basin

A sediment trap experiment was carried out in the West Caroline Basin, located in the equatorial western Pacific between influences of the Asian monsoon and the open ocean. Annual mass flux at the shallow trap at Site 1 was 57.10 g m^-2 yr^-1. Generally, the higher flux of organic matter was associated with higher activities of biogenic opal-producing and carbonate-producing plankton communities. In addition, as the organic matter content increases, the organic carbon/carbonate carbon ratio shows a tendency to increase. Carbonate-producing plankton was predominant during periods 1 and 3 (May to July and November to the beginning of December), which could be due to limited silica supply to the euphotic zone. On the other hand, surface sea water was more nutrient-rich during periods 2 and 4 (August to October and the end of December to April) at Site 1. These high total mass fluxes could be stimulated by wind.The amount of biogenic components collected in the sediment traps and the accumulation in surface sediments at Site 1 could be compared with primary productivity values. Carbonate and biogenic opal fluxes were 99% and 90% less, respectively, in the surface sediments compared to those in the shallow sediment trap. This could be due to the reaction of sinking particles with undersaturated deep sea water just above the sea floor, rather than with the water column during sinking. About 20% of the organic matter was decomposed between the shallow and deep sediment traps and more than 98% between the deep sediment trap and final burial in the surface sediments. The relative amount of organic carbon preserved in surface sediments was about 0.10% of annual primary productivity.