Ammonite <Emphasis Type="Italic">Fauriella boissieri</Emphasis> (Pictet), the index species of the Berriasian upper zone from the Crimean Mountains

Ammonite Fauriella boissieri (Pictet), the index species of the Berriasian upper zone, is described for the first time as taxon occurring in the Crimean Mountains. In the Berriasian sections of the central Crimea and Chatyr-Dag massif, species F. boissieri are encountered only in association with upper Berriasian ammonites. The Berriasian-Valanginian boundary has not been identified based on ammonites in the Crimean Mountains. Consequently, there is no reason to include the otopeta Zone into the boissieri Zone in the rank of its upper subzone.     

Ammonite assemblages from basal layers of the Ryazanian Stage (Lower Cretaceous) of Central Russia

Five successive ammonite assemblages are distinguished in the basal part (Riasanites rjasanensis Zone s. l.) of the Ryazanian Stage of the East European platform. These are (from the base upward) (1) Hectoroceras tolijense; (2) Hectoroceras kochi; (3) Riasanites swistowianus; (4) Riasanites rjasanensis; and (5) Transcaspiites transfigurabilis assemblages. Two lower assemblages consist entirely of boreal taxa, which occur in association with diverse ammonites of the Tethyan origin higher in the section. The data obtained show that three upper assemblages are correlative with the Berriasian Dalmasiceras tauricum, Riasanites rjasanensis-Spiticeras cautleyi, and Euthymiceras euthymi subzones of the northern Caucasus. The succession of five–six ammonite assemblages established in the East European platform above the top of the Craspedites nodiger Zone may correspond to the same number of ammonite assemblages characterizing lower subzones of the standard Berriasian. Berriasella rulevae Mitta, sp. nov. from the upper part of the Riasanites rjasanensis Zone (transfigurabilis biohorizon) is described.     

Ammonites and Stratigraphy of the Terminal Part of the Middle Volgian Substage (Upper Jurassic; Epivirgatites nikitini Zone and Its Equivalents) of the Panboreal Realm: 2. <Emphasis Type="Italic">Titanites</Emphasis> and <Emphasis Type="Italic">Glaucolithites</Emphasis>

The genera Titanites and Glaucolithites, which were previously known only from the Portlandian of Northwestern Europe are now established in Epivirgatites nikitini Zone of European Russia. The Volgian species of Titanites are represented by both the endemic taxa Titanites (Paratitanites) manipulocostatus subgen. et sp. nov. and T. (Pseudogalbanites) triceps subgen. et sp. nov. and Titanites (Titanites) ex gr. titan Buckman of the Portland type. A new species Glaucolithites gardarikensis is described. It is likely that these ammonites migrated to the Central Russian Sea from northwestern Europe via the Norway-Greenland seaway and further to the Mezen-Pechora system of straits, which is supported by occurrences of Titanites in the north of Central Russia and Glaucolithites in East Greenland and on Spitsbergen. The direct and indirect correlations show that the middle part of the Nikitini Zone (Lahuseni Subzone) should at least partly be correlated with the Portlandian Kerbeus Zone.     

Detailed stratigraphy of the Jurassic-Cretaceous boundary beds of the Lena River lower reached based on ammonites and Buchiids

The Jurassic-Cretaceous (Volgian-Lower Valanginian) boundary deposits in the lower reaches of the Lena River (near the village of Chekurovka and on the Cape Chucha, North Yakutia) are described bed-by-bed. The taxonomic composition of ammonites and bivalves (mainly Buchia) is determined. The species assemblages are biostratigraphically analyzed and biostratigraphic units of the bed and zone ranks are recognized based on by Buchia and ammonites. Analogues of the Buchia Zones (buchiazones) Unschensis, Okensis, Tolmatschewi, Inflata and ammonite zones Exoticus, Okensis, Sibiricus, Analogus, Mesezhnikowi and ? Klimovskiensis are established in this region for the first time. A correlation of the distinguished buchiazones with the buchiazones of the Nordvik Peninsula, New Siberian Islands (Stolbovoy Island), the basin of the Anyuy River, and Northern California is proposed. The ammonite assemblages constantly contain phylloceratids; some stratigraphic intervals also contain lytoceratids; this is probably connected with a Paleo-Pacific influence. Unlike the ammonite assemblages of the same age of the Khatanga depression, the subzones cannot be distinguished in the Sibiricus and Kochi Zones of the Lower Lena due to differences in the stratigraphic ranges of some ammonite species. Hectoroceras in the Kochi zone is very rare and Praetollia predominates here.     

Stratigraphy of the Bathonian-Callovian boundary deposits in the Prosek section (Middle Volga Region). Article 1. Ammonites and infrazonal biostratigraphy

In European Russia, the most complete succession of Boreal sediments of the terminal Bathonian and lower Callovian is exposed near the Prosek Settlement. After its revision, the infrazonal division of the upper Bathonian and lower Callovian and position of the Bathonian-Callovian boundary are difined more carefully. The Calyx Zone and bodylevskyi Biohorizon are established in the upper Bathonian. The base of the lower Callovian is defined at the first occurrence level of Macrocephalites jacquoti. Based on four successive ammonite assemblages occurring in lower part of the Elatmae Zone, the breve, frearsi, quenstedti, and elatmae biohorizons are identified. The joint occurrence of Boreal, Subboreal, and Tethyan ammonites in the section facilitate its correlation with the other sections of the Panboreal paleobiogeographic superrealm.     

Systematic paleontology,biostratigraphy, paleobiogeography of <Emphasis Type="Italic">Loftusia</Emphasis> (foraminifera) and <Emphasis Type="Italic">Rudist</Emphasis> assemblages in a regressive sequence in the Hekimhan-Malatya area (Eastern Anatolia) Turkey

The Maastrichtian regressive sequence of the Hekimhan-Malatya area in Eastern Turkey consists of dolomitic limestones, limestones and calcareous mudstones which are dominated by rudists and Loftusia (foraminifera) assemblages. Several Loftusia species indicating middle to late Maastrichtian age such as Loftusia anatolica Meriç, L. baykali Meriç, L. coxi Henson, L. harrisoni Cox, L. minor Cox and L. morgani Douvillé have been recorded. Other benthic foraminifers present include Orbitoides medius d’ Archiac, Omphalocyclus macroporus (Lamarck), Laffitteina conica Drooger, Laffitteina mengaudi (Astre) and Laffitteina oeztuerki Inan. The rudists are abundant in the dolomitic limestones in the study area. The genus Miseia Patrulius is dominant and represented by Miseia bilacunosa Özer and Miseia hekimhanensis Karacabey-Öztemür. The Loftusia species and the Rudists assemblage indicates middle to late Maastrichtian age for the formation. The paleobiogeographic distribution of the assemblage has been discussed taking this find into account.     

<Emphasis Type="Italic">Suraqalatia brasieri</Emphasis> n.gen., n.sp. (larger foraminifera) from the Maastrichtian of Sulaimani area in northern Iraq

Suraqalatia brasieri n.gen., n.sp. from the family Dicyclinidae Loeblich and Tappan 1964 occurs on the Maastrichtian carbonate platform of northern Iraq. The new genus is recognizable by its large very compressed conical test, up to 55–70 mm in diameter, to 0.3–1.6 mm in thickness, planspiral cooling having very small proloculus in the initial part and later circular chambers including numerous chamberlets with an agglutinated wall. Suraqalatia brasieri n.gen., n.sp. is associated with textulariids, miliolids and rotaliids as Loftusia elongata Cox, L. morgani Douvillé, Orbitoides medius d’Archiac, O. megaloformis Papp & Kupper, O. gruenbachensis Papp, O. apiculatus Schlumberger, Omphalocyclus macroporus (Lamarck), Siderolites calcitrapoides Lamarck, Sirtina orbitoidiformis Brönnimann & Wirz. The associated macrofauna comprises large and rich giant rudists (Preradiolites sp.), other bivalves (Gryphaea sp. and Glycymeris sp.), gastropods (Acteonella sp.), echinoderms and corals. The fauna indicates shallow marine carbonate platform conditions within the Maastrichtian green house. It is also worth mentioning that the new genus has only been recorded from the Maastrichtian age.     

The upper Volgian Substage in Northeast Siberia (Nordvik Peninsula) and its Panboreal correlation based on ammonites

Section of the middle and upper Volgian substages and basal Boreal Berriasian in the Cape Urdyuk-Khaya (Nordvik Peninsula) is largely composed of dark argillites substantially enriched in C_org. Characteristic of the section is a continuous succession of ammonite, foraminiferal, ostracode, and dinocyst zones known also in the other Arctic areas. Boundaries of the upper Volgian Substage are recognizable only based on biostratigraphic criteria. The succession of the middle Volgian Taimyrosphinctes excentricus to basal Ryazanian Hectoroceras kochi zones is characterized. The range of the substage is revised. The lower Exoticus Zone, where ammonites characteristic of the Nikitini Zone upper part in the East European platform have been found, is referred to the middle Volgian Substage. Newly found ammonites are figured. Two possible positions of the Jurassic-Cretaceous boundary in the Arctic region, i.e., at the lower and upper boundaries of the Chetae Zone at the top of the upper Volgian Substage, are discussed.     

High-pressure thermo-elastic properties of beryl (Al<Subscript>4</Subscript>Be<Subscript>6</Subscript>Si<Subscript>12</Subscript>O<Subscript>36</Subscript>) from ab initio calculations,and observations about the source of thermal expansion

Ab initio calculations of thermo-elastic properties of beryl (Al₄Be₆Si₁₂O₃₆) have been carried out at the hybrid HF/DFT level by using the B3LYP and WC1LYP Hamiltonians. Static geometries and vibrational frequencies were calculated at different values of the unit cell volume to get static pressure and mode-γ Grüneisen’s parameters. Zero point and thermal pressures were calculated by following a standard statistical-thermodynamics approach, within the limit of the quasi-harmonic approximation, and added to the static pressure at each volume, to get the total pressure (P) as a function of both temperature (T) and cell volume (V). The resulting P(V, T) curves were fitted by appropriate EoS’, to get bulk modulus (K ₀) and its derivative (K′), at different temperatures. The calculation successfully reproduced the available experimental data concerning compressibility at room temperature (the WC1LYP Hamiltonian provided K ₀ and K′ values of 180.2 Gpa and 4.0, respectively) and the low values observed for the thermal expansion coefficient. A zone-centre soft mode \( P6/mcc \to P\bar{1} \) phase transition was predicted to occur at a pressure of about 14 GPa; the reduction of the frequency of the soft vibrational mode, as the pressure is increased, and the similar behaviour of the majority of the low-frequency modes, provided an explanation of the thermal behaviour of the crystal, which is consistent with the RUM model (Rigid Unit Model; Dove et al. in Miner Mag 59:629–639, 1995), where the negative contribution to thermal expansion is ascribed to a geometric effect connected to the tilting of rigid polyhedra in framework silicates.     

Representatives of genera <Emphasis Type="Italic">Malbosiceras</Emphasis> and <Emphasis Type="Italic">Pomeliceras</Emphasis> (Neocomitidae,Ammonoidea) from the Berriasian of the Crimean Mountains

The revised representatives of ammonite genera Malbosiceras and Pomeliceras from the Berriasian of the Crimean Mountains are classed with seven species, four of the first genus [M. malbosi (Pictet), M. chaperi (Pictet), M. broussei (Mazenot), M. pictetiforme Tavera] and three of the second one [P. aff. boisseti Nikolov, P. breveti (Pomel), P. (?) funduklense Lysenko et Arkadiev sp. nov.]. The identified species are described. The genus Mazenoticeras is considered as synonym of Malbosiceras. The above species prove that all the Berriasian zones (jacobi, occitanica and boissieri) are characteristic of corresponding deposits in the Crimean Mountains.     

Late Cretaceous (Cenomanian-Turonian) ammonites from southern Morocco and south western Algeria

On the basis of nine lithostratigraphical profiles, 23 cephalopods taxa (nautilus and ammonites) are described from the Preafrican Trough and the Kem Kem region. Among them, a new species is proposed: Spathites (Jeanrogericeras) asflaensis nov. sp. This fauna is placed in its biostratigraphical framework and correlated with the standard zonation of the late Cenomanian–early Turonian. Moreover, stratigraphic correlations are proposed for the whole Maghreb from the Tarfaya Basin in the west to central Tunisia in the east. Selected taxa reveal the paleogeographical context of the western Tethys; a complex distribution of emerged areas and epicontinental seas impacted by an important marine trangression that constantly modified the costaline.     

Optimal choice of the softening length and time step in <Emphasis Type="Italic">N</Emphasis>-body simulations

A criterion for the choice of optimal softening length ε for the potential and the choice of time step dt for N-body simulations of a collisionless stellar system is analyzed. Plummer and Hernquist spheres are used as models to analyze how changes in various parameters of an initially equilibrium stable model depend on ε and dt. These dependences are used to derive a criterion for choosing ε and dt. The resulting criterion is compared to Merritt’s criterion for choosing the softening length, which is based on minimizing the mean irregular force acting on a particle with unit mass. Our criterion for choosing ε and dt indicate that ε must be a factor of 1.5–2 smaller than the mean distance between particles in the densest regions to be resolved. The time step must always be adjusted to the chosen ε (the particle must, on average, travel a distance smaller than 0.5 ε during one time step). An algorithm for solving N-body problems with adaptive variations of the softening length is discussed in connection with the task of choosing ε, but is found not to be promising.     

<Emphasis Type="Italic">Salpingoporella</Emphasis> (dasycladalean algae) species from the Lower Cretaceous carbonate facies of Kopet Dagh basin (NE Iran)

Salpingoporella species from algal bearing of Barremian-Aptian limestones in the Kopet Dagh basin (NE of Iran) are described. Different species (S. cemi, S. hasi, S. heraldica, S. hispanica, S. milovanovici, S. muehlmbergi, S. parapiriniae, S. piriniae, S. cf. biokovensis, S. steinhauseri, S. polygonalis) are investigated from different biometrical aspects such as depositional environments and biogeographical distribution as well as their systematic palaeontology from two formations (the Tirgan and Sarcheshmeh formations) in nine stratigraphic sections.     

Sand-supported bio-adsorbent column of activated carbon for removal of coliform bacteria and <Emphasis Type="Italic">Escherichia coli</Emphasis> from water

New bio-adsorbent carbon materials were synthesized from the leaves and veins of Mucuna pruriens and Manihot esculenta plants, which are locally available in abundance. The synthesized carbons were activated using 0.01N HNO₃. Surface area of the activated carbons from M. pruriens and M. esculenta plants was found to be quite high, i.e., 918 and 865 m²/g, respectively. Scanning electron microscopy analysis of the carbons reflects complex disorganized surface structures of different open pore sizes, shapes and dimensions. These properties of the newly synthesized activated carbons led to the development of a sand-supported carbon column, for its possible use in the removal of coliform bacteria and Escherichia coli (E. Coli) from raw water samples. The removal percentage of E. coli was found to be 100% with both the types of carbon adsorbents, as confirmed from the McCardy most probable number table. Similarly, the removal percentage of coliform bacteria was found to be 99 and 98.7% by M. pruriens and M. esculenta carbon columns, respectively. These activated carbons synthesized from locally available plants possess the characteristics of good low-cost adsorbents which can be easily used for the removal of bacteria from water by adsorption method.     

Campanian-Lower Paleogene gastropods from the Kharga Oasis,south Western Desert,Egypt

The Campanian-Lower Paleogene successions exposed at the Kharga Oasis contain well-preserved gastropods. Nineteen gastropod species are identified and described in detail. Two new species are established: Gisortia khargaensis from the lower Eocene El Rufuf Formation and Ornopsis? barisensis from the lower Paleocene Kurkur Formation. In addition to, Turritella (Torquesia) derbesi Coquand is recorded herein for the first time from Egypt. The studied gastropods belonging to four clades: Sorbeoconcha (Metacerithium abictiforme (Wanner), Mesalia hofana Mayer-Eymar, Mesalia sp., Turritella (Torquesia) derbesi Coquand, Turritella (Torquesia) forgemoli Coquand, Turritella kaserensis Hewaidy and Azab, Turritella sp.), Littorinimorpha (Cypraedia bullina Oppenheim, Gisortia khargaensis nov. sp., Natica farafrensis Wanner, Aporrhais schweinfurthi (Quaas), Drepanocheilus bicarinatus Abbass, Drepanocheilus? sp., Anchura? unicarinatus (Abbass), Epitonium sp.), Neogastropoda (Ornopsis? barisensis nov. sp., Rostellana daniensis (Quaas), Vouta sp.), and Heterobranchia (Avellana cretacea Quaas).     

Smaller foraminifers from type sections of the Bolorian stage,the Lower Permian of Darvaz

Smaller foraminifers from Upper Yakhtashian and Bolorian deposits of the stratotype area (Pamir, Darvaz, Tajikistan) are investigated. Four assemblages are defined. The first assemblage is from Chalaroschwagerina vulgaris-Pamirina darvasica Zone. The second assemblage found in the transitional Yakhtashian-Bolorian beds includes Globivalvulina, Palaeotextulariidae, Hemigordiidae, and Glomospira, associated with the first Pachyphloia and Langella forms. Characteristic taxa of third assemblage from the Misellina (Brevaxina) dyhrenfurthi Zone are Geinitzinidae, Globivalvulina, Palaeotextulariidae, Glomospira, and rare Pachyphloia. The forth assemblage of Hemigordiidae, Pachyphloia, Palaeotextulariidae, Geinitzinidae, Pseudoagathammina is identified in the M. (Misellina) parvicostata Zone. The assemblages were compared with concurrent analogs from China, Japan, and Russia. New species and subspecies Glomospira paleograndis sp. nov., G. darvasica sp. nov., Agathammina darvasica sp. nov., Pachyphloia darvasica sp. nov., Nodosinelloides cubanicus elongatus subsp. nov., and Hemigordius saranensis darvasicus subsp. nov. are described.     

Elastic behavior of vanadinite,Pb<Subscript>10</Subscript>(VO<Subscript>4</Subscript>)<Subscript>6</Subscript>Cl<Subscript>2</Subscript>, a microporous non-zeolitic mineral

The high-pressure behavior of a vanadinite (Pb₁₀(VO₄)₆Cl₂, a = b = 10.3254(5), c = 7.3450(4) Å, space group P6₃/m), a natural microporous mineral, has been investigated using in-situ HP-synchrotron X-ray powder diffraction up to 7.67 GPa with a diamond anvil cell under hydrostatic conditions. No phase transition has been observed within the pressure range investigated. Axial and volume isothermal Equations of State (EoS) of vanadinite were determined. Fitting the P–V data with a third-order Birch-Murnaghan (BM) EoS, using the data weighted by the uncertainties in P and V, we obtained: V ₀ = 681(1) Å³, K ₀ = 41(5) GPa, and K′ = 12.5(2.5). The evolution of the lattice constants with P shows a strong anisotropic compression pattern. The axial bulk moduli were calculated with a third-order “linearized” BM-EoS. The EoS parameters are: a ₀ = 10.3302(2) Å, K ₀(a) = 35(2) GPa and K′(a) = 10(1) for the a-axis; c ₀ = 7.3520(3) Å, K ₀(c) = 98(4) GPa, and K′(c) = 9(2) for the c-axis (K ₀(a):K ₀(c) = 1:2.80). Axial and volume Eulerian-finite strain (fe) at different normalized stress (Fe) were calculated. The weighted linear regression through the data points yields the following intercept values: Fe _a (0) = 35(2) GPa for the a-axis, Fe _c (0) = 98(4) GPa for the c-axis and Fe _V (0) = 45(2) GPa for the unit-cell volume. The slope of the regression lines gives rise to K′ values of 10(1) for the a-axis, 9(2) for the c-axis and 11(1) for the unit cell-volume. A comparison between the HP-elastic response of vanadinite and the iso-structural apatite is carried out. The possible reasons of the elastic anisotropy are discussed.     

The use of ultrasonic frequencies to control the bloom formation,regrowth, and eco-toxicity in <Emphasis Type="Italic">Microcystis aeruginosa</Emphasis>

This study is focused on the use of ultrasound to disrupt Microcystis aeruginosa growth, with consideration for the gap between laboratory-scale experiment and field application. Laboratory-scale sonication systems with different frequencies (i.e., 20, 584, 869, and 1137 kHz) for 30 min at 10-min intervals were conducted to investigate their effectiveness at disrupting M. aeruginosa growth. The toxicological effect of sonicated M. aeruginosa including microcystin-LR was also evaluated using a Daphnia magna acute toxicity test. High frequencies, 869 and 1137 kHz, resulted in more than a 60% reduction of cells after 30 min of sonication. Low to middle frequencies, 20 and 584 kHz, only showed a 30% reduction of cells after 30 min of sonication. High frequencies also led to the inactivation of cell proliferation during M. aeruginosa regrowth, due to cellular destruction and finally cell death. However, the concentration of microcystin-LR and the potential adverse effects of M. aeruginosa on D. magna could not be controlled using ultrasonic frequencies. Therefore, our results suggest that ultrasonic frequencies between 869 and 1137 kHz are effective at controlling bloom formation in M. aeruginosa and the regrowth of M. aeruginosa after sonication, but not at controlling microcystin-LR concentrations and its adverse effects on D. magna. Consequently, a combined purification technology to reduce the cyanotoxins such as microcystin-LR, rather than ultrasonic frequency alone, will be needed to control M. aeruginosa growth and its toxicity levels in the aquatic environment.     

Barioferrite BaFe<Subscript>12</Subscript>O<Subscript>19</Subscript>: A new mineral species of the magnetoplumbite group from the Haturim Formation in Israel

A new mineral barioferrite—a natural analogue of synthetic barium ferrite Ba Fe ₁₂ ³⁺ O₁₉—has been identified in the central part of a metamorphosed barite nodule in the rock of the Haturim Formation (Mottled Zone) on the southern slope of Mount Ye’elim in Israel. The mineral is associated with barite, calcite, magnetite, and maghemite and occurs as tiny platy crystals up to 3 × 15 × 15 μm and their irregular aggregates. Barioferrite is black with streaks of brown, and its luster is submetallic. Its Calculated density is 5.31 g/cm³. The mineral is brittle; cleavage is absent. IR absorption bands (cm^?1) are observed at 635 (shoulder), 582, 544, 433, and 405 (shoulder). Barioferrite is characterized by ferrimagnetic behavior. Under a microscope in reflected light, barioferrite is grayish white with brownish red internal reflections, the pleochroism is weak (from gray-white on R _o to gray-white with a brown tint on R _e), and the bireflectance is weak with distinct anisotropy. The reflectance values of R _o/R _e, % (λ, nm) are 24.51/22.80 (470), 24.17/22.25 (546), 23.65/21.68 (589), and 22.67/20.85 (650). The chemical composition (electron microprobe, wt %; the ranges are given in parentheses) is BaO 13.13 (12.5–13.8), Fe₂O₃ 86.47 (85.5–87.5), and 99.60 in total. The empirical formula is Ba_0.95Fe _12.03 ³⁺ O₁₉. Barioferrite is hexagonal with space group P6₃/mmc, a = 5.875 (3) Å, c = 23.137 (19) Å, V = 691.6 (5) ų, and Z = 2. The strongest lines of the X-ray powder diffraction pattern [d, Å, (I, 5) (hkl)] are 2.938(46) (110), 2.770(100) (107), 2.624 (84) (114, 200), 2.420(44) (203), 2.225(40) (205), and 1.627(56) (304, 2.0.11). The holotype specimen of barioferrite is deposited at the Mineralogical Museum of St. Petersburg State University; its catalogue number is 1/19436.