Dynamics of oil product distributions in water and bottom sediments of the sea of Azov and the Black Sea after ship accidents in the Kerch Strait

The dynamics of concentrations of oil products spilled into the aquatic ecosystem as a result of accidents in the Kerch Strait is discussed. Provision is made for the analysis of the results of long-term monitoring and for the revealing of differences in concentrations and distribution of oil hydrocarbons in the Sea of Azov and in the Black Sea after emergency spills. The available information was used to outline the course of events that led to such redistribution of spilled mazut in marine ecosystems.     

Cascading ocean basins: numerical simulations of the circulation and interbasin exchange in the Azov-Black-Marmara-Mediterranean Seas system

In this paper, we use the unstructured grid model SCHISM to simulate the thermohydrodynamics in a chain of baroclinic, interconnected basins. The model shows a good skill in simulating the horizontal circulation and vertical profiles of temperature, salinity, and currents. The magnitude and phases of the seasonal changes of circulation are consistent with earlier observations. Among the mesoscale and subbasin-scale circulation features that are realistically simulated are the anticyclonic coastal eddies, the Sebastopol and Batumi eddies, the Marmara Sea outflow around the southern coast of the Limnos Island, and the pathway of the cold water originating from the shelf. The superiority of the simulations compared to earlier numerical studies is demonstrated with the example of model capabilities to resolve the strait dynamics, gravity currents originating from the straits, high-salinity bottom layer on the shallow shelf, as well as the multiple intrusions from the Bosporus Strait down to 700 m depth. The warm temperature intrusions from the strait produce the warm water mass in the intermediate layers of the Black Sea. One novel result is that the seasonal intensification of circulation affects the interbasin exchange, thus allowing us to formulate the concept of circulation-controlled interbasin exchange. To the best of our knowledge, the present numerical simulations, for the first time, suggest that the sea level in the interior part of the Black Sea can be lower than the sea level in the Marmara Sea and even in some parts of the Aegean Sea. The comparison with observations shows that the timings and magnitude of exchange flows are also realistically simulated, along with the blocking events. The short-term variability of the strait transports is largely controlled by the anomalies of wind. The simulations demonstrate the crucial role of the narrow and shallow strait of Bosporus in separating the two pairs of basins: Aegean-Marmara Seas from one side and Azov-Black Seas from the other side. The straits of Kerch and Dardanelles provide sufficient interbasin connectivity that prevents large phase lags of the sea levels in the neighboring basins. The two-layer flows in the three straits considered here show different dependencies upon the net transport, and the spatial variability of this dependence is also quite pronounced. We show that the blocking of the surface flow can occur at different net transports, thus casting doubt on a previous approach of using simple relationships to prescribe (steady) outflow and inflow. Specific attention is paid to the role of synoptic atmospheric forcing for the basin-wide circulation and redistribution of mass in the Black Sea. An important controlling process is the propagation of coastal waves. One major conclusion from this research is that modeling the individual basins separately could result in large inaccuracies because of the critical importance of the cascading character of these interconnected basins.     

Global geoenvironmental problems: Black Sea basin

The issue of the geoenvironmental state of Black Sea basin, the final basin receiving the runoff of many large rivers of the European continent (Danube, Dnieper, Don, etc.) and considerable runoff from the nearby watersheds, including Turkish, is considered. The extent and geoenvironmental consequences of the large-scale changes in the hydrology, water balance, and hydrochemistry of the sea basin under the effect hydrotechnical interception and industrial pollution of river runoff are discussed. The genetic role of Black Sea rifting in one of the world’s largest oil-and-gas-bearing basins with its inherent thermal and geochemical processes, geoenvironmental conditions, and risks is emphasized. Improved information is given about the genesis of hydrogen sulfide dissolved in seawater and related to the processes of geochemical sulfate reduction of silt water sulfates under the effect of hydrocarbon gases, which mostly form in zones of deep catagenesis of sedimentary formations and lower crust rock metamorphism. It is emphasized that the ecological stability of a sea basin showing such complex and contradictory relationships with natural and technogenic objects and processes can be ensured only by joint and well coordinated efforts of the countries of the Black Sea and nearby regions aimed on rational nature and water management, including when laying pipelines on Black Sea bed and developing the power resources of the Black Sea oil-and-gas-bearing basin.     

The environmental and biotic impact of the oil spill in Kerch Strait in November 2007

The effect of an emergency oil spill in Kerch Strait in November 2007 on the environment and biota in the southern Sea of Azov is analyzed based on the material of integrated expedition studies carried out by the Southern Scientific Center, RAS, before and after shipwrecks and during monitoring within a year after the emergency.     

Environmental challenges in Polish agriculture covering a main area of the Baltic Sea Basin

Poland largely encompases the estuary of the Vistula and Odra rivers, which drain into the Baltic Sea. Only a very small area of the south-east part of the country is within the Black Sea Basin. Poland contributes significantly to the pollution of the Baltic Sea, with biogenic nutrients and organic substances. Poland includes more than half the coastal inhabitants of the Baltic Sea, and they use 40% of the arable land situated there. The contribution to the pollution of this sea with nitrogen, phosphorus and organic substances is approximately 30, 40 and 22%, respectively. The main sources of nutrients are untreated sewage and the runoff and leakage of fertilizers from agricultural land. The natural conditions in Poland are poorer than in Western Europe due to the prevalence of light soils and a short growing period with frequent droughts. After correcting the synthetic index for soil and climate, it was estimated that for each inhabitant of Poland there are 0.3 ha of farmland, which is comparable to that of Western Europe. For the maintenance of the population, intensive agricultural production must be accompanied by environmental protection regulations. Polish agriculture is not only a polluter but also a recipient of pollution, especially the deposits of sulphur and heavy metals emitted by industry and municipal areas. The estimated annual emission of sulphur dioxide is about 4 million t, which equals an average deposit of about 90 kg of sulphur per hectare of farmland. The pedological processes and acid deposits cause more than 60% of agricultural land in Poland to be acidic. The contamination of soils with heavy metals in general is lower than in Western Europe, but in some areas (e.g. Upper Silesia) it exceeds the safe limits.     

Assessment of potential transport of pollutants into the Barents Sea via sea ice--an observational approach

The present estimates of ice drift in the Arctic include utilization of satellite imagery data (special sensor microwave/imager) and a reconstruction of air pressure for the period 1899-1998. A significant part of the sea ice in the Arctic Ocean has its origin in the Kara Sea and melts in the Greenland and the Barents Sea (BS). Consequently there may be a particular risk of pollutants in the Kara Sea entering the food webs of the Greenland and BS. The ice export from the Kara Sea between 1988 and 1994 was about 208,000 km2 (154 km3) per year. The import of ice into the BS was during the same period 161,000 km2 (183 km3) per year while the ice drift through the Fram Strait into the Greenland Sea was 583,000 km2 (1859 km3) per year. Ice which formed adjacent to the Ob and Yenisey rivers in early January, drifted into the BS within two years (with a probability of about 50%.     

Biochemical Study of Brackish-Water Marine Ecosystems

The concentrations and the elemental and biochemical composition of dissolved and particulate organic matter (OM) characteristic of southern and Arctic seas are presented. The rate of OM transformation in the production–decomposition cycle and that of the phosphate cycle are estimated from the activity of the redox enzymes of the electron-transport system and that of phosphatase. Carbohydrates and protein are shown to be the main biochemical components in the water of all the seas under study in dissolved and particulate OM, respectively. The contribution of carbohydrates to particulate OM under the conditions of intense primary production is demonstrated to be comparable to that of protein. High concentrations of lipids are shown to be characteristic of the coastal ecosystems in the middle Caspian Sea and northwestern shelf of the Black Sea because of severe pollution in these areas. It is noted that at higher trophic levels, the ecosystem of the Caspian Sea intensely assimilates allochthonous OM, and that the Black Sea ecosystem transfers considerable amounts of OM to the hydrogen sulfide zone.     

Satellite-derived variability of the Aegean Sea ecohydrodynamics

Eight years of AVHRR-derived sea surface temperature (SST) and SeaWiFS-derived surface chlorophyll (Chl) data (1998–2005) are used to investigate key processes affecting the spatial and temporal variability of the two parameters in the Aegean Sea. Seasonal mean SST and Chl maps are constructed using daily data to study seasonal dynamics whereas empirical orthogonal function (EOF) and correlational analysis is applied to the 8-day composite SST and Chl anomaly time-series in order to study the variability and co-variability of the two parameters from subseasonal to interannual time-scales. The seasonal mean fields show that Black Sea cold and chlorophyll-rich waters enter through the Dardanelles Strait and they are accumulated in the north-eastern part of the Aegean Sea, steered by the Samothraki anticyclone. Large chlorophyll concentrations are encountered in the hydrological front off the Dardanelles Strait as well as in coastal areas affected by large riverine/anthropogenic nutrient loads. The SST seasonal mean patterns reveal strong cooling that is associated with upwelling along the eastern boundary of the basin during summer due to strong northerly winds, a process which is not present in the surface chlorophyll climatology. The Chl dataset presents much stronger sub-seasonal variability than SST, with large variations in the phase and strength of the phytoplankton seasonal cycles. EOF analysis of the anomaly time-series shows that SST non-seasonal variability is controlled by synoptic weather variations and anomalies in the north–south wind-stress component regulating the summer coastal upwelling regime. Mean SST and Chl patterns, and their associated variations, are not closely linked implying that Black Sea and riverine inputs mainly control the intra-annual and interannual variability of the surface chlorophyll in the Aegean Sea rather than mixing and/or upwelling processes.     

Formation and Evolution of the Anaerobic Zone in the Black Sea from the Most Recent Salinization to the Present State: Retrospective Estimation Based on Mathematical Modeling

It is established that the formation and evolution of the anaerobic zone of the Black Sea are associated with the beginning and development of the most recent salinization of the sea and the formation of pycnocline at intermediate depths; a deterioration of deep-water aeration and the formation of anaerobic conditions in deeper layers; the rate of sulfate-reduction first in the near-bed layer and later, as oxygen is depleted, in the water mass. Formalization of these processes based on refined present-day data on water balance enabled the reproduction of profiles of water salinity and vertical-exchange coefficient for different formation stages of salinity regime in the Black Sea. The vertical distribution of oxygen and hydrogen sulfide is reconstructed, and the rates of oxygen consumption in water column and sulfate reduction in the near-bed layer and at the upper boundary of the anaerobic zone are evaluated in numerical experiments. The obtained data show the transformation of the vertical distribution of oxygen and hydrogen sulfide in the Black Sea from the beginning of its most recent salinization to the present-day state. It is shown that the anaerobic zone rises from 2000 to 200 m within 500–600 years (in the period 3.9–4.5 Ka from the beginning of water exchange through the Bosphorus), and next the upper boundary of the anaerobic zone slowly ascends up to its present-day position (130–180 m). Mathematical modeling was used to evaluate the fluxes of oxygen and hydrogen sulfide at different formation stages of the anaerobic zone in the sea.__________Translated from Vodnye Resursy, Vol. 32, No. 3, 2005, pp. 307–321.Original Russian Text Copyright © 2005 by Leonov, Shaporenko.     

Ecogeographical assessment of the possible impact of mariculture on coastal waters in the Eastern Black Sea

Trends in mariculture development in Russia are studied. Global experience in controlling the after-effects of fish farm operation for the marine environment are analyzed. Statistical procesing of the data of field oceanographic surveys, carried out in 1957–1989 in a one-mile coastal zone in the Eastern Black Sea, was implemented. Results of studying natural factors determining the input of organic pollutants and the rate of their biogeochemical transformation, as well as the conditions of sediment accumulation and water aeration in the Russian part of the Black Sea coast were systematized. It was found that powerful natural self-purification mechanisms of aquatic environment act along the North Caucasian coast of the Black Sea. The conclusion on almost complete environmental safety of a marine underwater fish farm, which is under construction in the Sochi Region (Khosta Settl.) was made. Attention is attracted to the need to take into account the high hydrodynamic activity in the investigated region in the process of fixing keepnets on anchors while anchoring the fish farm.     

中国海域地震区划及关键问题研究

国家重点研发计划项目《海域地震区划关键技术研究》已实施3年,进入项目结题阶段,已形成海域地震区划方法与技术体系,研究成果为即将开展的中国海域地震区划图编制工作提供技术支撑.项目组分析和探讨了海域地震区划研究基础与存在的问题,结合所关注的关键科学和技术问题,介绍和分析了主要研究成果和进展,包括海域断裂活动性探测和地震构造...     

Solomon Sea circulation and water mass modifications: response at ENSO timescales

The South Pacific low latitude western boundary currents (LLWBCs) carry waters of subtropical origin through the Solomon Sea before joining the equatorial Pacific. Changes in their properties or transport are assumed to impact El Niño Southern Oscillation (ENSO) dynamics. At ENSO timescales, the LLWBCs transport tends to counterbalance the interior geostrophic one. When transiting through the complex geography of the Solomon Sea, the main LLWBC, the New Guinea Coastal Undercurrent, cannot follow a unique simple route to the equator. Instead, its routes and water mass properties are influenced by the circulation occurring in the Solomon Sea. In this study, the response of the Solomon Sea circulation to ENSO is investigated based on a numerical simulation. The transport anomalies entering the Solomon Sea from the south are confined to the top 250 m of the water column, where they represent 7.5 Sv (based on ENSO composites) for a mean transport of 10 Sv. The induced circulation anomalies in the Solomon Sea are not symmetric between the two ENSO states because of (1) a bathymetric control at Vitiaz Strait, which plays a stronger role during El Niño, and (2) an additional inflow through Solomon Strait during La Niña events. In terms of temperature and salinity, modifications are particularly notable for the thermocline water during El Niño conditions, with cooler and fresher waters compared to the climatological mean. The surface water at Vitiaz Strait and the upper thermocline water at Solomon Strait, feeding respectively the equatorial Pacific warm pool and the Equatorial Undercurrent, particularly affect the heat and salt fluxes. These fluxes can change by up to a factor of 2 between extreme El Niño and La Niña conditions.     

Mathematical modeling of marine environment pollution processes by petroleum hydrocarbons and their degradation in Caspian Sea ecosystem

The available observational data on the pollution of tributaries and areas of the Caspian Sea by petroleum hydrocarbons and products are examined. The possible petroleum input from sources in the sea is assessed using up-to-date data of satellite observations of sea surface pollution by oil films. The hydroecological CNPSi-model is applied to studying water pollution processes by petroleum hydrocarbons in ten areas chosen in the Caspian Sea and the subsequent biodegradation of those pollutants. The model calculations of the within-year dynamics of petroleum hydrocarbon concentrations use mean annual observational data on within-year variations in water mediium characteristics (water temperature, light intensity, and transparency), as well as the morphometric parameters of sea areas (the area, mean depth, and water volumes). The characteristics of water exchange between the areas were evaluated using a hydrodynamic model. The model calculations were used to characterize the within-year variations in petroleum hydrocarbon concentrations, the biomasses of petroleum-oxidizing bacteria, the characteristics of their oxidation activity and bioproduction, and the internal fluxes of petroleum hydrocarbons (their input from various sources, horizontal and vertical transport, and biotransformation) in different sea areas. Calculation results were used to compile annual balances for the processes of input and consumption of petroleum hydrocarbons in the chosen and aggregated sea areas.     

ENAA Studies of pollution in anoxic Black Sea sediments

The vertical distributions of five potential pollutants - Zn, As, Br, Sn, and Sb - were determined via epithermal neutron activation in the upper 50 cm of unconsolidated sediments from the Black Sea, which were collected 600 m below sea surface. This analysis demonstrated increasing concentrations towards the upper limits of sediments, which were greater than alert concentrations in the case of As and Br, and in accordance with Romanian Environment Regulations. The utilization of Chernobyl ¹³⁷Cs as a time marker allowed for dating of this region to the last 100 years.     

Hydrocarbons in the modern sediments of the Caspian Sea

The presented results have been obtained in a study of the concentrations and composition of aliphatic and polycyclic hydrocarbons in bottom sediments of Volga delta branches and in its shallow zone (2009–2010), as well as the Caspian Sea proper (2010–2013). Oil hydrocarbon pollution has been found to manifest itself mostly in Volga delta branches, which, despite the low concentrations (up to 54.5 μg/g), showed higher hydrocarbons share in C_org (up to 33.8%), while the composition of alkanes suggested their oil genesis. The geochemical barrier the Volga–the Caspian Sea prevents anthropogenic hydrocarbons from entering the open parts of the Caspian. Bottom sediments in the shallow zone of the Northern Caspian, represented by coarse-grained material, are now polluted by oil hydrocarbons to a lesser extent compared with other areas. The highest concentrations of aliphatic hydrocarbons (up to 178 μg/g) were recorded in the deepsea bottom sediments of Derbent Depression and in depressions of the Middle and Southern Caspian. These areas show a higher concentration of C_org (up to 9.884%) and a low concentration of hydrocarbons in C_org (up to 0.16%), while odd high-molecular homologues (n-C₂₅–C₃₁) dominate in the composition of alkanes.     

Geochronological reconstruction of Cs transport from the Coruh river to the SE Black Sea: comparative assessment of radionuclide retention in the mountainous catchment area

The deposition record of ¹³⁷Cs was traced in the SE Black Sea sediments adjacent to the Coruh river mouth in comparison with the earlier studied chronology of ¹³⁷Cs deposition in front of the Danube delta (NW Black Sea). In both cases, the ¹³⁷Cs profiles showed two subsurface peaks attributable to maximum fallout of ‘bomb’ and Chernobyl radionuclides. The Coruh profile revealed a larger contribution of ‘bomb’ ¹³⁷Cs in comparison with the Chernobyl input, suggesting different coverage of NW and SE Black Sea regions with the Chernobyl fallout. The ¹³⁷Cs-derived dating showed that maximum deposition of particulate bound ¹³⁷Cs in sediments adjacent to the Coruh river mouth was delayed for 14 yr relative to date of Chernobyl accident, reflecting a buffer effect of the watershed soils. This transit time is 3 times longer than in the Danube catchment area, indicating a difference in retention processes in these mountainous (Coruh) and lowland (Danube) river basins. The ¹³⁷Cs profile in Coruh sediments showed penetration of ¹³⁷Cs to much greater depth than would be expected from ¹³⁷Cs fallout chronology, suggesting the sediment mixing rate of 1.3 cm² yr⁻¹. This value was used to evaluate deposition chronology of ¹³⁷Cs, applying the model developed for pulse fallout case. Comparing the measured and modelled data has allowed differentiation of the flood-induced discharge of the ¹³⁷Cs-containing suspended matter and the slower transit of eroded soil particles from the contaminated catchment areas. The obtained results may be used for the prediction of period when the pollutants, deposited over the river basins, can reach the Black Sea.     

Focal Depths of Earthquakes in the Crimea–Black Sea Region

The problem of determining focal depths of earthquakes in the Crimea–Black Sea region is considered. Based on the results of interannual studies, it is found that the focal depths of Crimean earthquakes are mainly crustal, with maximum values of up to 60 km. Some recent publications, however, have described deep-focus earthquakes with depths of up to 300 km which were “revealed” in the Crimean region. In this respect, there arose the need to study such a large difference in estimated focal depths. Convincing examples show that the sensational “revelation” of deep earthquakes in Crimea was caused by incorrect processing of the experimental data, in particular, due to (1) a sharp distortion in the recorded arrival times of body waves, (2) exclusion of data from stations nearest to a source, (3) unreasonable arbitrary selection of data from seismic stations, and (4) dropping of data from the worldwide seismological network, including those on deep seismic phases. Thus, the conclusions about the presence of deep mantle earthquakes in Crimea are erroneous. We have redetermined the parameters of hypocenters and verified that the focal depths of earthquakes in the Crimea–Black Sea region are no more than 60 km. Based on these data, we analyze the features of the spatial distribution of focal depths to show that earthquake sources are grouped along conduits that dip southeastward, from the continental part of Crimea toward the Black Sea Basin, in the case of grouping of sources in the Alushta–Yalta and Sevastopol areas. The seismic focal layer of the Kerch–Anapa area dips northeastward, from the Black Sea beneath the North Caucasus.     

Variations in the Black Sea water salinity from its latest salinization to the present state: Estimation based on mathematical modeling

The available published data were used to reveal the principal conditions and factors that control the formation and evolution of the Black Sea water salinity. Formalization of the major processes that contribute to the formation of sea salinity structure enabled, based on the present-day data on water balance, the reproduction of profiles of water salinity and the coefficient of vertical water exchange K _Z after 2, 4, 6, 8, and 10 ka since the beginning of water exchange with the Sea of Marmara through the Bosphorus. The time during which the present-day profile of the Black Sea water salinity had formed was evaluated. The results of simulation for different formation stages of the Black Sea salinity structure were used to determine the major ways of salt input into the sea (with river runoff and waters of the Lower Bosphorus Current) and its removal from the sea (the Upper Bosphorus Current). It was established that the Black Sea water salinity regime has virtually attained a stationary state.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 154–164.Original Russian Text Copyright © 2005 by Leonov.     

Variability in Solomon Sea circulation derived from altimeter sea level data

The Solomon Sea is a key region in the Pacific Ocean where equatorial and subtropical circulations are connected. The region exhibits the highest levels in sea level variability in the entire south tropical Pacific Ocean. Altimeter data was utilized to explore sea level and western boundary currents in this poorly understood portion of the ocean. Since the geography of the region is extremely intricate, with numerous islands and complex bathymetry, specifically reprocessed along-track data in addition to standard gridded data were utilized in this study. Sea level anomalies (SLA) in the Solomon Sea principally evolve at seasonal and interannual time scales. The annual cycle is phased by Rossby waves arriving in the Solomon Strait, whereas the interannual signature corresponds to the basin-scale ENSO mode. The highest SLA variability are concentrated in the eastern Solomon Sea, particularly at the mouth of the Solomon Strait, where they are associated with a high eddy kinetic energy signal that was particularly active during the phase transition during the 1997–1998 ENSO event. Track data appear especially helpful for documenting the fine structure of surface coastal currents. The annual variability of the boundary currents that emerged from altimetry compared quite well with the variability seen at the thermocline level, as based on numerical simulations. At interannual time scales, western boundary current transport anomalies counterbalance changes in western equatorial Pacific warm water volume, confirming the phasing of South Pacific western boundary currents to ENSO. Altimetry appears to be a valuable source of information for variability in low latitude western boundary currents and their associated transport in the South Pacific.     

Spatial distribution of water mass pollution characteristics in the Barents Sea

Digital databases on 444 stations were used to carry out statistical analysis of regularities in the spatial distribution of Barents Sea water pollution. The analysis was focused on the concentrations in water of heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) and toxic organic compounds: hexachlorocyclohexanes, hexachlorobenzene, chlordans, DDT, polychlorbiphenyls, polycyclic aromatic hydrocarbons, and normal paraffins. The statistical analysis of data on pollutants was carried out along two major directions in their distribution: the vertical—in the surface and bottom water layers; and the horizontal—over water masses. Reliable differences were identified in the pollution level of different water masses of the Barents Sea. The frontal zone was found to concentrate pollution.