Source Screening Module for Contaminant Transport Analysis Through Vadose and Saturated Zones

At complex sites there may be many potential sources of contaminants within the vadose zone. Screening‐level analyses are useful to identify which potential source areas should be the focus of detailed investigation and analysis. A source screening module (SSM) has been developed to support preliminary evaluation of the threat posed by vadose zone waste sites on groundwater quality. This tool implements analytical solutions to simulate contaminant transport through the unsaturated and saturated zones to predict time‐varying concentrations at potential groundwater receptors. The SSM integrates several transport processes in a single simulation that is implemented within a user‐friendly, Microsoft Excel? ‐ based interface.     

Monitoring in the Vadose and Saturated Zones Utilizing Fluoroplastic

A ground water monitoring program should include an investigation of all possible areas of concern. To be completely effective, the program should include soil sampling, soil analysis and water-quality examination of both the saturated and unsaturated zones. A well-tooled drill rig can take all the proper soil samples, perform all necessary tests and install a functional monitoring well. With the introduction of the fluoropolymer (Teflon(r)) sleeve lysimeter, a single monitoring well can be constructed to monitor both the saturated and unsaturated zones in one installation. The monitoring well screen and casing may also be completely constructed of fluoropolymer.
The sleeve lysimeter is designed with a threaded hollow inner diameter, allowing it to be attached between the joints of a casing string. This hollow I.D. acts as an extension of the casing; the lysimeter surrounds the casing. This creates an isolated vessel for sampling the vadose zone. Access to the screened monitoring well below is unaffected. Tests have shown that when properly installed, these porous fluoropolymer filter units can collect samples with no interaction between the filter and collected fluids.     

A Permanent Multilevel Monitoring and Sampling System in the Coastal Groundwater Mixing Zones

To study the spatial and temporal variability of water dynamics and chemical reactions within the coastal groundwater mixing zones (CGMZs), high‐resolution periodical and spatial groundwater sampling within CGMZs is needed. However, current samplers and sampling systems may require heavy driving machines to install. There is also possible contamination from the metal materials for current samplers and sampling systems. Here, a permanent multilevel sampling system is designed to sample coastal groundwater within CGMZs. This cost‐effective system consists of metal‐free materials and can be installed easily. The system is tested in Po Sam Pai and Tingkok, Tolo Harbor and Hong Kong. Major ions, nutrients, stable isotopes and radium and radon isotopes were analyzed and the data provided scientific information to study the fresh‐saltwater interface fluctuations, and temporal variations and spatial heterogeneity of geochemical processes occurred within CGMZs. The reliable spatial and temporal data from the sampling system demonstrate that the system functions well and can provide scientific data for coastal aquifer studies.     

The Suction Side Sample Catcher in Ground Water Quality Sampling

A suction side sample collector (SSSC) is a contrivance installed hydraulically ahead of the intake port of a pumping device. This paper describes construction and operational details of SSSCs fitted to a submersible pump with packer for use in a 6-inch cased borehole, an air lift pump with packer for use in a 1-inch or 2.5-inch cased borehole, a bladder pump for use in a casing of 2-inch or greater diameter, and a jet pump with packer for use in a 2-inch cased borehole.
Each form of SSSC has been thoroughly tested in ground water quality sampling for volatile organic chemicals. Comparative data for samples collected with the SSSCs and conventional sample collecting gear are presented. The SSSC is demonstrated to be superior to other methods of collecting volatile organic chemical samples owing to its freedom from contamination by the pump delivery line and to its mode of collecting the sample from a position in the well remote from disturbance by the pumping technique.
SSSCs are conveniently decontaminated, easily transported, and can be used to deliver samples to the laboratory while still at formation pressure. The air-lift pumps, described in this paper for use with SSSCs in 1- and 2.5-inch casings, have pumping capacities greater than obtained by other methods that can operate in these small casings. Discharge rates of up to 2 gpm are routinely achieved with the 1-inch model and higher rates are common With the 2.5-inch model. The use of packers with these pumps reduces the time needed to replace the water in the casing with fresh water from the formation.     

Geophysical Techniques to Delineate Saturated Alluvial Zones for the Siting of HVDC Power Transmission Return Electrodes

As high-voltage, direct-current (HVDC) electrical power transmission technology advances, the siting and design of the grounded return electrodes become critical factors. Electrode sites should be chosen where surrounding geologic conditions will not unfavorably channel large earth currents and harmfully affect nearby populations. An optimum site allows direct contact between the electrode and a large volume of a stable, low-resistivity material. A saturated alluvial zone between dry surface soils and an underlying crystalline bedrock is an ideal material for containing the current flow from the electrode.
A hydrogeologic investigation was conducted to delineate the saturated zone in several alluvial valleys in the southwestern desert region. Regional ground water flow directions, water quality, and seasonal fluctuations of the water table elevations were determined. The structural shape and topography of the crystalline basement beneath the valleys were interpreted from gravity data. Iterative forward-modeling of the data provided a low-cost means of deducing the volume of the lightweight alluvium. Electrical resistivity surveys were completed to measure the lateral and vertical variations in soil resistivities throughout the valleys. The geophysical data were used to extend the known hydrologic information into areas with no wells.
Composite models of the saturated zones in each valley were produced by integrating gravity interpretations with hydrologic and resistivity results. The composite models were used to predict current density in the ground that would be associated with a HVDC electrode. This methodology proved to be a cost-effective means of siting electrodes in a suitable geologic environment that would minimize their detrimental effects.     

Operational Ranges for Suction Lysimeters

Four questions relative to suction lysimeter performance have been raised by operators of land treatment systems. These questions deal with plugging of the porous segments of the lysimeters, soil suction operational ranges, adsorption onto and screening by the materials comprising the various lysimeter parts, and loss of volatile organics under negative pressures. This article first describes the physical operation of a lysimeter, the characteristics of the lysimeters tested (high- and low-flow lysimeters with porous ceramic cups and lysimeters with porous PTFE (polytetrafluo-roethylene) cups, and procedures followed in preparing them for testing. The results of experiments dealing with the first two questions plugging and operational ranges are then discussed. It was found that the intake rate of suction lysimeters placed in the vadose zone, in most types of soils, will initially drop off rapidly, but will stabilize after about 15 liters of moisture have been drawn through the porous cups. Packing a crystalline silica flour slurry around the cups of PTFE lysimeters negates most of the plugging associated with finer particles in soils. The effective operating range of ceramic lysimeters is between 0 and 60 centibars of suction independent of the use of silica flour. The operating range of PTFE lysimeters without silica flour is extremely narrow, but with the use of silica flour is extended to about 7 centibars of suction. The testing program indicates that all lysimeters should be checked for leaks using pressure techniques before field installation and that lysimeters have "dead" spaces, or reservoirs of from 34 to 80 mL of moisture that cannot be extracted from the cups, which must be taken into account when determining moisture collection rates. Information gathered in the test program is planned for inclusion in an EPA guidance document entitled "Unsaturated Zone Monitoring at Hazardous Waste Land Treatment Units."     

A Method for Installing Miniature Multilevel Sampling Wells

Abstract. A method has been developed to install miniature multilevel ground-water sampling wells in shallow, unconsoli-dated aquifers at sites without truck access. An advantage of these wells over the traditional bundle-type multilevel is that this type of installation causes minimal aquifer disturbance. Thus, miniature multilevels can be installed while a tracer test is in progress. Furthermore, only hand tools are needed in the field, and equipment and materials are easily obtained and inexpensive. The time required for installation is comparable to other methods.     

A Phenomenological Model for Particle Retention in Single,Saturated Fractures

Fractured aquifers are some of the most poorly characterized subsurface environments despite posing one of the highest risks to the protection of potable groundwater. This research was designed to improve the understanding of the factors affecting particle transport through fractures by developing a phenomenological model based on laboratory‐scale transport data. The model presented in this research employed data from over 70 particle tracer tests conducted in single, saturated, variable‐aperture fractures that were obtained from the natural environment and fractured in the laboratory or cast from epoxy in the laboratory. The particles employed were Escherichia coli RS2‐GFP and microspheres. The tracer experiments were conducted in natural (dolomitic limestone and granite) as well as epoxy replicas of the natural fractures. The multiple linear regression analysis revealed that the most important factors influencing particle retention in fractures are the ratio of the ionic strength of solution to collector charge, the ratio of particle to collector charge, and the ratio of advective to diffusive forces as described by the Peclet number. The model was able to reasonably (R² = 0.64) predict the fraction of particles retained; however, it is evident that some factors not accounted for in the model also contributed to retention. This research presents a novel approach to understanding particle transport in fractures, and illustrates the relative importance of various factors affecting the transport mechanisms. The utility of this model lies in the increased understanding of particle transport in fractures, which is extremely useful for directing future research.     

Capture Zones for Simple Aquifers

Abstract. The protection and cleanup of aquifers is a matter of high priority for all states and the federal government. One concept that is receiving increased attention is that of wellhead protection. Capture zones showing the area influenced by a well within a certain time are useful for both aquifer protection and cleanup. If hydrodynamic dispersion is neglected, a deterministic curve defines the capture zone. Analytical expressions for the capture zones can be derived for simple aquifers. However, the capture zone equations are transcendental and cannot be explicitly solved for the coordinates of the capture zone boundary. Fortunately, an iterative scheme allows the solution to proceed quickly and efficiently even on a modest personal computer. Three forms of the analytical solution must be used in an iterative scheme to cover the entire region of interest, after the extreme values of the x coordinate are determined by an iterative solution. The resulting solution is a discrete one, and usually 100-1000 intervals along the x-axis are necessary for a smooth definition of the capture zone. The presented program is written in FORTRAN and has been used in a variety of computing environments. No graphics capability is included with the program; it is assumed the user has access to a commercial package. The superposition of capture zones for multiple wells is expected to be satisfactory if the spacing is not too close. Because this program deals with simple aquifers, the results rarely will be the final word in a real application. However, the program is useful as a first phase in developing wellhead protection or aquifer cleanup schemes.     

A Low-Cost Programmable Reversing Flow Column Apparatus for Investigating Mixing Zones

This note describes the development and testing of a novel, programmable reversing flow 1D (R1D) experimental column apparatus designed to investigate reaction, sorption, and transport of solutes in aquifers within dynamic reversing flow zones where waters with different chemistries mix. The motivation for constructing this apparatus was to understand the roles of mixing and reaction on arsenic discharging through a tidally fluctuating riverbank. The apparatus can simulate complex transient flux schedules similar to natural flow regimes The apparatus uses an Arduino microcontroller to control flux magnitude through two peristaltic pumps. Solenoid valves control flow direction from two separate reservoirs. In-line probes continually measure effluent electrical conductance, pH, oxidation–reduction potential, and temperature. To understand how sensitive physical solute transport is to deviations from the real hydrograph of the tidally fluctuating river, two experiments were performed using: (1) a simpler constant magnitude, reversing flux direction schedule (RCF); and (2) a more environmentally relevant variable magnitude, reversing flux direction schedule (RVF). Wherein, flux magnitude was ramped up and down according to a sine wave. Modeled breakthrough curves of chloride yielded nearly identical dispersivities under both flow regimes. For the RVF experiment, Peclet numbers captured the transition between diffusion and dispersion dominated transport in the intertidal interval. Therefore, the apparatus accurately simulated conservative, environmentally relevant mixing under transient, variable flux flow regimes. Accurately generating variable flux reversing flow regimes is important to simulate the interaction between flow velocity and chemical reactions where Brownian diffusion of solutes to solid-phase reaction sites is kinetically limited.     

基于重塑饱和砂土模型的现场液化试验方法

基于现场开展土体液化问题研究势必成为今后土动力学中的一个重要发展方向。目前人工激振下的现场液化试验方法还不够成熟,尚需进一步探索和发展。本文从试验设备组成、场地地震动激励、试坑布置、饱和砂土模型制备、数据测量与采集等5个方面论述该方法中的主要技术问题。研究表明:动力加载系统激励产生的地震动在0~7m/s2;系统工作频率13~15Hz,饱和砂土模型与基础边缘的距离在0.5~2.5m范围内,更适合进行液化试验;应用水沉法现场制备饱和砂土模型,要重点注意试坑防水和尺寸定位的问题;数据测量与采集中要充分考虑对现场液化问题认识不够这一因素的影响,需对数据测量与采集提出附加要求;试验实例初步表明,该方法可行,适合开展液化问题研究。     

Sampling Plan Optimization: A Data Review and Sampling Frequency Evaluation Process

Lawrence Livermore National Laboratory (LLNL) uses a cost-effective sampling (CES) methodology to evaluate and review ground water contaminant data and optimize the site's ground water monitoring plan. The CES methodology is part of LLNL's regulatory approved compliance monitoring plan (Lamarre et al. 1996). It allows LLNL to adjust the ground water sampling plan every quarter in response to changing conditions at the site. Since the use of the CES methodology has been approved by the appropriate regulatory agencies, such adjustments do not need additional regulatory approval. This permits LLNL to respond more quickly to changing conditions. The CES methodology bases the sampling frequency for each location on trend, variability, and magnitude statistics describing the contaminants at that location, and on the input of the technical staff (hydrologists, chemists, statisticians, and project leaders). After initial setup is complete, each application of CES takes only a few days for as many as 400 wells. Effective use of the CES methodology requires sufficient data, an understanding of contaminant transport at the site, and an adequate number of monitoring wells downgradient of the contamination. The initial implementation of CES at LLNL in 1992 produced a 40% reduction in the required number of annual routine ground water samples at LLNL. This has saved LLNL $390,000 annually in sampling, analysis, and data management costs.     

A Simple Field Method for Assessing Near‐Surface Saturated Hydraulic Conductivity

This technical note describes an effective and inexpensive field technique for measuring the saturated hydraulic conductivity of both undisturbed cores and repacked soil samples. The method requires no specialized equipment; everything that is required can be obtained in a hardware store. The method is a straightforward field implementation of the widely used falling‐head laboratory analysis directly derived from Darcy's law. As such, it sidesteps the need for empirical assumptions about soil texture and the relationship between saturated and unsaturated flow components which many permeameter‐based methods rely upon. The method is shown to produce results that are consistent with K values obtained elsewhere in the same homogeneous sand formation. Furthermore, the proposed method is useful for measuring hydraulic conductivity in drill cuttings obtained from direct push or auguring drill techniques, which cannot be done with any other field method. The range of hydraulic conductivity values that this test is appropriate for is on the order of 1E ? 7 m/s to 1E ? 3 m/s.     

中国大陆强震轮回活动的计算机模型研究

通过对中国大陆7级以上强震的研究发现,地震活动呈现为时间上轮回和空间上迁移的动态图像。为探索这种图像的物理本质,本文应用非线性动力学模型来模拟在统一构造应力场作用下含有多个活动地震带的地震构造块体的地震活动。文中用若干列并联排列的基本元件(由Maxwell体和刚性滑块组成)来模拟地震活动带,并用耦合元件来模拟地震活动带之间和带内各段之间的相互耦合作用。本文的研究结果有助于理解强震的轮回活动以及高潮中成组强震间的相互影响特征。     

A Computer Model for Cyclic Activity of Strong Earthquakes in Continental Seismic Zones

Based on the study of activity of earthquakes with M**********>7.0 in mainland China,we have found a dynamic pattern,i.e.,the cyclic characteristics in time and migration from one seismic zone to another in space.In order to understand the physical mechanism of this pattern,we use a nonlinear dynamic model to simulate the seismic activity in fault zones under a unified tectonic stress field.The basic elements in our model consist of a Maxwell body and a rigid sliding block.Basic elements in a column represent a fault,and coupling elements connecting different columns simulate the interaction among faults and fault segments.The results provide insights to the cyclic activity of strong earthquakes and to the feature of mutual influence between strong earthquakes in groups in the climax of seismic activity.