Empirical Equations of P-Wave Velocity in the Shallow and Semi-Deep Sea Sediments from the South China Sea

Three-hundred and thirty-one sediment cores, including six sediment types(clayey-and sandy-silt, silty-and sandy-clay, clayey-and silty-sand) were collected from the shallow and semi-deep seas of the South China Sea, and the P-wave velocities and physical properties of core sediments were measured under standard laboratory conditions. To eliminate the influence of environmental factors, the empirical sound speed ratio equations were established. Compared with several equations from literature, the porosity and wet bulk density empirical equations established in this paper agree well with Richardson and Briggs(2004)'s in-situ equations, which implies that our empirical equations can be used in the similar region of world's oceans under certain conditions and will be useful in areas lacking first-hand P-wave speed data. However, the mean grain size equations established in this study, similar to the previous studies, have low accuracy, which may be due to the different particle arrangements and degrees of compaction in sediments. The results also show that for different sediment types, the equation based on all sediment data is in good agreement with the measured data in the study area, as there are both siliciclastic and carbonate sediments on the studied seabed. It is suggested that appropriate empirical equations should be selected according to sediment types and sedimentary environment in future works, and the empirical equation of porosity or the two-parameter equation of porosity and grain size should be preferred.     

南海北部渔场表层沉积物中的硫化物

为了给南海北部渔场的资源和环境保护提供基础数据,用碘量法测定了南海北部陆架区表层沉积物中硫化物含量.结果表明,全部28份样品中硫化物含量为3.3～42.2mg/kg(干重,下同),平均为12.1mg/kg,符合外海含量低的一般规律,明显低于沿岸海湾的含量,远低于日本渔业环境质量标准(200mg/kg)和安全下限值(400mg/kg).硫化物含量在测站间和不同区域间存在一定差异,南北方向呈近岸(13.1mg/kg)略高于离岸(12.1mg/kg)、离岸略高于远岸(11.1mg/kg)的梯度分布,但梯度差异不显著(p＞0.10);东西方向的分布特点是粤西海域(23.7mg/kg)＞海南岛以东(15.3mg/kg)＞台湾浅滩(9.4mg/kg)≈粤东海域(8.7mg/kg)≈珠江口外海域(8.6mg/kg).空间分布不太均匀主要是受沉积物类型的影响,与陆源硫化物输入的关系不大.     

Linking Monsoon Activity with River-Derived Sediments Deposition in the Northern South China Sea

The history of the East Asian monsoon(EAM) since Last Glacial Maximum is reconstructed based on records in a sediment core retrieved from the northern South China Sea. The provenance of organic carbon and the EAM's evolution are investigated using combined organic carbon, grain size, and AMS 14 C dating analysis. Responding to the strong winter monsoon, the marine organic matter was dominated in the sediments, and δ13 C of organic matter was high during the last glacial period. During the Holocene, the primary productivity decreased and the dilution effect of riverine inorganic clastics strengthened. Accordingly, the total organic carbon contents and δ13 C values decreased, and terrestrial organic matter content increased in the core sediments. The 4 μm grain size fraction, as the environmental sensitive grain size component, is determined to reconstruct the paleoclimatic records. During the last glacial period, the contents of 4 μm grain size component were mainly controlled by the sea level changes. Upon the Holocene, the influence of the sea level changes weakened and the roles of current system and provenance strengthened. The correlation between the EAM and solar insolation forcing is also discussed in this paper.     

Shear Wave Speed Dispersion Characteristics of Seafloor Sediments in the Northern South China Sea

To accurately characterize the shear wave speed dispersion of seafloor sediments in the northern South China Sea,five types of sediments including silty clay,clayey silt,sandy silt,silty sand,and clayey sand were selected,on which the measurements of the shear wave speed at 0.5-2.0 kHz and related physical properties were performed.Results reveal that the shear wave speed of sediments increases as the frequency increases,and the dispersion enhanced in the sediments in the order of silty clay,clayey silt,sandy silt,silty sand,and clayey sand,at a linear change rate of 0.727,0.787,3.32,4.893,and 6.967 m s?1 kHz?1,respectively.Through regression analysis,linear and logarithmic regression equations for the correlation between shear wave speed and frequency were established for each sediment type and the determination coefficients of regression equations indicate that the correlation is closer to a logarithmic relationship.The Grain-Shearing(GS)and Biot-Stoll models were used to calculate the shear wave speed dispersion of the five sediment types,and the comparison between theoretical prediction and measured results of shear wave speeds shows that the GS model can more accurately describe the shear wave speed dispersion characteristics of these sediments in the frequency band of 0.5-2.0 kHz.In the same band,the predictions obtained by using the Biot-Stoll model are significantly different from the measured data.     

南海北部近海柱状沉积物多环芳烃组成及来源分析

【目的】研究南海北部近海区域柱状沉积物多环芳烃组成及分布特征,讨论全新世早期火历史及气候变化。【方法】利用AMS ¹⁴C定年技术结合有机地球化学分析手段对全新世早期南海北部近海沉积物柱状样品中多环芳烃(PAHs)分布特征进行研究。【结果】南海北部近海沉积物中16种PAHs总浓度范围为8.58~17.48 ng/g,在约10000 a B.P.的全新世早期呈现先增大后减小波动变化,与TOC变化基本同步。【结论】沉积物中多环芳烃主要来源于南海北部近海陆源区域自然火灾产生的焦炭残渣。PAHs的沉积浓度变化间接指示了全新世早期东亚季风的强度变化。     

Dimethylsulfide in the South China Sea

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Geochemistry and Petrogenesis of Volcanic Rocks from the Continent-Ocean Transition Zone in Northern South China Sea and Their Tectonic Implications

Miocene–Pliocene(22–5 Myr) volcanism and associated seamounts are abundant in the continent-ocean transition(COT) zone in the margin of the north South China Sea(SCS). The petrogenesis of volcanic rocks from these seamounts and regional tectonic evolution of COT zone are poorly known. In this paper, we obtained whole-rock major and trace element compositions and Sr-Nd-Pb isotopic data for these volcanic rocks from the Puyuan and Beipo seamounts within COT zone, in northeastern SCS. Based on the geochemical analyses, the volcanic rocks are classified as alkaline ocean island basalts(OIB) and enriched mid-ocean ridge basalts(E-MORB). The OIBs from the Puyuan seamount are alkaline trachybasalts and tephrites that show enrichment of the light rare earth elements(LREE) relative to heavy rare earth elements(HREE) and more radiogenic Sr-Nd isotopic compositions, and have significant ‘Dupal isotopic anomaly'. In contrast, the E-MORBs from the Beipo seamount are tholeiitic basalts that have less enrichment in LREE and less radiogenic Sr-Nd isotopic compositions than the counterparts from the Puyuan seamount. Petrological and geochemical differences between the OIBs and MORBs from these two seamounts can be explained by different mantle sources and tectonic evolution stages of the COT zone. Syn-spreading OIB type basalts from the Puyuan seamount were derived from an isotopically ‘enriched', and garnet facies-dominated pyroxenitic mantle transferred by the Hainan mantle plume. In contrast, post-spreading E-MORB type basalts from the Beipo seamount are considered to be derived from the melting of isotopically ‘depleted' pyroxenite mantle triggered by lithosphere bending and subsequent post-rifting at the lower continental slope of the northern margin.     

Purification and Characterization of an Alkaline Protease from Micrococcus sp.Isolated from the South China Sea

Protease is wildly used in various fields,such as food,medicine,washing,leather,cosmetics and other industrial fields.In this study,an alkaline protease secreted by Micrococcus NH54PC02 isolated from the South China Sea was purified and characterized.The growth curve and enzyme activity curve indicated that the cell reached a maximum concentration at the 30 th hour and the enzyme activity reached the maximum value at the 36 th hour.The protease was purified with 3 steps involving ammonium sulfate precipitation,ion-exchange chromatography and hydrophobic chromatography with 8.22-fold increase in specific activity and 23.68% increase in the recovery.The molecular mass of the protease was estimated to be 25 k Da by SDS-PAGE analysis.The optimum temperature and p H for the protease activity were 50℃ and pH 10.0,respectively.The protease showed a strong stability in a wide range of pH values ranging from 6.0–11.0,and maintained 90% enzyme activity in strong alkaline environment with p H 11.0.Inhibitor trials indicated that the protease might be serine protease.But it also possessed the characteristic of metalloprotease as it could be strongly inhibited by EDTA and strongly stimulated by Mn~(2+).Evaluation of matrix-assisted laser desorption ionization/time-of-flight MS(MALDI-TOF-TOF/MS) showed that the protease might belong to the peptidase S8 family.     

Deep-sea geohazards in the South China Sea

Various geological processes and features that might inflict hazards identified in the South China Sea by using new technologies and methods.These features include submarine landslides,pockmark fields,shallow free gas,gas hydrates,mud diapirs and earthquake tsunami,which are widely distributed in the continental slope and reefal islands of the South China Sea.Although the study and assessment of geohazards in the South China Sea came into operation only recently,advances in various aspects are evolving at full speed to comply with National Marine Strategy and‘the Belt and Road’Policy.The characteristics of geohazards in deep-water seafloor of the South China Sea are summarized based on new scientific advances.This progress is aimed to aid ongoing deep-water drilling activities and decrease geological risks in ocean development.     

Water masses in the South China Sea and water exchange between the Pacific and the South China Sea

Water masses in the South China Sea (SCS) were identified and analyzed with the data collected in the summer and winter of 1998. The distributions of temperature and salinity near the Bashi Channel (the Luzon Strait) were analyzed by using the data obtained in July and December of 1997. Based on the results from the data collected in the winter of 1998, waters in the open sea areas of the SCS were divided into six water masses: the Surface Water Mass of the SCS (S), the Subsurface Water Mass of the SCS (U), the Subsurface-Intermediate Water Mass of the SCS (UI), the Intermediate Water Mass of the SCS (I), the Deep Water Mass of the SCS (D) and the Bottom Water Mass of the SCS(B). For the summer of 1998, the Kuroshio Surface Water Mass (KS) and the Kuroshio Subsurface Water Mass (KU) were also identified in the SCS. But no Kuroshio water was found to pass the 119.5°E meridian and enter the SCS in the time of winter observations. The Sulu Sea Water (SSW) intruded into the SCS through the Mindoro Channel between 50–75 m in the summer of 1998. However, the data obtained in the summer and winter of 1997 indicated that water from the Pacific had entered the SCS through the northern part of the Luzon Strait in these seasons, but water from the SCS had entered the Pacific through the southern part of the Strait. These phenomena might correlate with the 1998 El-Niño event.     

Some new species of radiolaria from surface sediments of the East China Sea and the South China Sea

Fourteen species of Radiolaria described in this paper were discovered from surface sediments of the East China Sea, the South China Sea and the cores of the Okinawa Trough. Type specimens are deposited in the Second Institute of Oceanography, SOA.     

SEAWATER FLUX OF THE SOUTH CHINA SEA

The South China Sea water can be divided according to depth into three boxes by the pycnoclineand a sill.Using a box model with matter balance,the net seawater fluxes were calculated to be317.9×10~4 m~3/s in box Ⅰ for the upper homogeneous layer outflowing to the adjoining oceans;67×10~4 m~3/s in box Ⅲ for the water entering the basin;240×10~4 m~3/s in box Ⅱ for water entering theSouth China Sea.The upward speed of basin water was calculated to be 8.4×10~(-5) cm/s and that ofseawater flowing up along the pycnocline was calculated to be 8.9×10~(-5) cm/s.     

Kuroshio Intrusion Combined with Coastal Currents Affects Phytoplankton in the Northern South China Sea Revealed by Lipid Biomarkers

The northern South China Sea(NSCS) is significantly influenced by the Kuroshio intrusion and the coastal currents. Our knowledge on the roles of both currents on phytoplankton spatial variations is still inadequate. Here, we investigated the concentrations of phytoplankton biomarkers and their proportions in surface suspended particles from 47 sites of the NSCS during summer of 2017 and 2019. Brassicasterol/epi-brassicasterol, dinosterol, and C37 alkenones were used as proxies of biomass for dia...     

Planaxidae (Mollusca,Gastropoda) from the South China Sea

Planaxidae is a family of tropical and subtropical marine gastropods that are adapted to an intertidal, rocky environment. The present study deals with three species in the family Planaxidae from the South China Sea: P lanaxis sulcatus(von Born, 1778), Angiola longispira(Smith, 1872), and S upplanaxis niger(Quoy and Gaimard, 1833), based on specimens deposited in the Marine Biodiversity Collections of the South China Sea, Chinese Academy of Sciences. The taxonomic status, main morphological characteristics of the shell and radula, distribution, and habitat of these three planaxid species are presented. We also briefly discuss their morphological dif ferences and the biogeographic distribution.     

THE NOMENCLATURE OF THE SOUTH CHINA SEA ISLANDS IN ANCIENT CHINA

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On the sources of the Taiwan Warm Current from the South China Sea

Historical hydrographic data across several sections in the South China Sea (SCS) and Taiwan Strait have been reconsidered. The year-around existence of the South China Sea Warm Current (SCSWC) along the shelf break off the Guangdong coast and the seemingly year-around southwestward current to the east of SCSWC are both evident in the data. The data also showed that the northward current in the Taiwan Strait seemed to be the extension of SCSWC. A barotropic numerical model is employed to explain some of the observed features. Reasonable simulation of the circulation in the northeast part of SCS has been found.     

Pathways of mesoscale variability in the South China Sea

The propagation of oceanic mesoscale signals in the South China Sea (SCS) is mapped from satellite altimetric observations and an eddy-resolving global ocean model by using the maximum cross-correlation (MCC) method. Significant mesoscale signals propagate along two major bands of high variability. The northern band is located west of the Luzon Strait, characterized by southwestward eddy propagation. Although eddies are the most active in winter, their southwestward migrations, steered by bathymetry, occur throughout the year. Advection by the mean flow plays a secondary role in modulating the propagating speed. The southern eddy band lies in the southwest part of the SCS deep basin and is oriented in an approximately meridional direction. Mesoscale variability propagates southward along the band in autumn. This southward eddy pathway could not be explained by mean flow advection and is likely related to eddy detachments from the western boundary current due to nonlinear effects. Our mapping of eddy propagation velocities provides important information for further understanding eddy dynamics in the SCS.     

CHARACTERIZATION OF FINE-GRAINED TURBIDITE DEPOSITS FROM THE SOUTH CHINA SEA SEDIMENT CORES

Two depositional processes controlled the muddy sediments in the South China Sea Basin. Bathyal sediments depositional rate was 7.66 cm/la in the northern continental slope of the Basin where turbidity current was almost nonexistent. In the northern margin of the Basin, abyssal sediment depositional rate was 5.05cm/ka and turbidity current occurrence averaged 0.22 per 1000 years. Turbidite was found in the middle of the Basin. Over half of the muddy sediments in the deep sea basin were deposited by turbidity currents, and had typically graded bedding, and contents of organic matter, calcareous material and micropaleontologic species inconsistent with the environment.     

Diatom assemblages in surface sediments from the South China Sea as environmental indicators

We studied diatom distribution from 62 samples from the uppermost 1 cm of sediment in the South China Sea (SCS), using grabs or box corers in three cruises between 2001–2007. Fifty six genera, 256 species and their varieties were identified. Dominating species included Coscinodiscus africanus, Coscinodiscus nodulifer, Cyclotella stylorum, Hemidiscus cuneiformis, Melosira sulcata, Nitzschia marina, Roperia tesselata, Thalassionema nitzschioides, Thalassiosira excentrica, and Thalassiothrix longissima. Most surface sediments in the SCS were rich in diatoms, except for a few coarse samples. Average diatom abundance in the study area was 104 607 valve/g. In terms of the abundance, ecology, and spatial distribution, seven diatom zones (Zones 1–7) were recognized. Zone 1 (northern continental shelf) is affected by warm currents, SCS northern branch of the Kuroshio, and northern coastal currents; Zone 2 (northwestern continental shelf) is affected by intense coastal currents; Zone 3 (Xisha Islands sea area) is a bathyal environment with transitional water masses; Zone 4 (sea basin) is a bathyal-to-deep sea with stable and uniform central water masses in a semi-enclosed marginal sea; Zone 5 (Nansha Islands marine area) is a pelagic environment with relatively high surface temperature; Zone 6 (northern Sunda Shelf) is a tropical shelf environment; and Zone 7 (northern Kalimantan Island shelf area) is affected by warm waters from the Indian Ocean and coastal waters. The data indicate that these diatom zones are closely related to topography, hydrodynamics, temperature, nutrients and especially the salinity. Better understanding of the relationship between diatom distribution and the oceanographic factors would help in the reconstruction of the SCS in the past.