A comparative study of the ARM and Isr of some natural magnetites of MD and PSD grain size

Summary. ARM and I _sr stability with respect to alternating field and low-temperature treatment were measured for a set of artificial rock specimens. Each of the specimens contained a known amount of a natural magnetic mineral of a known grain size. The following minerals were used: a homogeneous natural magnetite, a natural titanomagnetite with submicroscopic Fe-rich inclusions, and a natural titanomagnetite and a natural titano-maghemite that both show exsolution phenomena. The grain size of the fractions varied from < 5 to 250 μm. It is found that the stability of ARM and I _rs of multi-domain grains with respect to alternating fields and low-temperature treatment is similar, whereas for the smallest grains studied (< 5 μm) ARM is more stable than I _sr. Multi-domain ARM data from this study are in agreement with current multi-domain ARM theory. Low-temperature behaviour of ARM and I _sr can be explained either in terms of a model in which stable moments in the bulk of the grains are screened by the surrounding matrix or in terms of a model in which regeneration of the bulk remanence plays a role and in which stable moments are situated on the surfaces of the grains.     

Grain-size dependence of initial susceptibility and saturation magnetization-related parameters of four natural magnetites in the PSD—MD range

Summary. Initial susceptibility, coercive force and several types of remanent coercive forces were measured on a set of artificial rock specimens containing grain-size fractions of a natural magnetite and titanomagnetite, both of which are optically homogeneous and a natural titanomagnetite and titanomaghemite, both of which show exsolution phenomena. It was found subsequently that the optically homogeneous titanomagnetite contains some submicroscopic Fe-rich inclusions. These inclusions are magnetically screened in coarse grains; only for the lower grain sizes studied they have an appreciable influence on the data. The size of the fractions varied from < 5 to 250 μm. The parameters and several parameter ratios are plotted as a function of grain size. Several of these parameters can be used as mineralogical and grain-size indicators. The varying degree of exsolution of the minerals is reflected in the gradients of the plots. From plots of initial susceptibility versus grain size it is concluded that the shape of the grains does not play a dominant role in determining the change of this parameter with grain size. Variation of the various parameters with grain size is explained in terms of a gradual transition from large PSD grains to MD grains without there being any sharp transition. For titanomagnetite ( x = 0.55) the transition takes place at grain sizes that are about 15 μm larger than for magnetite.     

High-temperature characteristics of a natural titanomagnetite

Summary. Continuous recordings were made of thermal demagnetizations of Isr, ARM and TRM induced in artificial rock specimens. The artificial rock specimens contained well-defined grain-size fractions of a natural titanomagnetite, which under an optical microscope was homogeneous. Using a Transmission Electron Microscope it was shown that submicroscopic inclusions exist within the titanomagnetite. Screening of the remanence of these inclusions by the surrounding titanomagnetite is thought to be responsible for the occurrence of 'peaks' in the continuous thermal decay curves of Isr and ARM; higher 'peaks' observed in the case of TRM are thought to be caused by the combined effects of screening and an anti-parallel remanence in the titanomagnetite. Further submicroscopic exsolution processes, which occur in the titanomagnetite as a result of repeated heating, can be deduced from the development of new 'peaks', from changes in the temperature at which the 'peak(s)'occur, their shape and their relative height. The use of stepwise demagnetization techniques on the titanomagnetite yielded erroneous directional results due to the screening in the titanomagnetite; the biasing effects due to screening could be avoided by using continuous thermal demagnetization techniques.     

Reliability of palaeointensity methods using alternating field demagnetization and anhysteretic remanence

Summary. Using natural volcanic rocks which acquired thermoremanence (TRM) in known fields, reliability of various palaeointensity methods using alternating field (AF) demagnetization were evaluated. Natural remanence (NRM), TRM and anhysteretic remanences (ARM's) before and after heating were stepwisely AF demagnetized following Shaw's method.
It was found that the coercivity spectra of TRM and ARM in these samples are very similar, and that even when changes occurred during heating, the changes for two remanences are quite similar in many samples. Therefore, Shaw's method of palaeointensity determination, which incorporates ARM checks to the conventional comparison of NRM and TRM coercivity spectra, gives results as reliable as those obtained by the Thellier method. Many examples were demonstrated in which TRM and ARM intensities changed substantially by heating, but without changes in the shape of their coercivity spectra. Such changes cannot normally be detected and erroneous palaeointensities with apparent internal consistency would be obtained by usual AF demagnetization methods.
Although ARM is quite similar to TRM, the rate of acquisition of ARM and TRM in weak fields varies by a factor of five among the present samples. To determine palaeointensities from the linear relation between ARM and TRM, it is necessary to determine experimentally the relative acquisition rate of these remanences. Therefore, methods based only on NRM-ARM relations would not give palaeointensities with acceptable errors.     

Relationship between median destructive field and remanent coercive forces for dispersed natural magnetite, titanomagnetite and hematite

Summary. Remanent acquisition curves, remanent hysteresis curves and alternating field demagnetization curves were determined for a number of artificial rock specimens containing well-defined grain-size fractions between 5 and 250 μm of natural magnetite, titanomagnetite and hematite. From these curves, the remanent acquisition coercive force H '_cr, the remanent coercive force H _cr and the median destructive field of IRM H _½I were determined. Theoretically these parameters should be the same for an assembly of non-interacting, homogeneously distributed, randomly oriented single-domain grains. For a given hematite specimen H '_cr, H _cr and H _½I have about the same value in spite of the strong grain-size dependence of these parameters. For each specimen of magnetite and titanomagnetite the value of H '_cr is larger than H _cr which again is larger than H _½I. However, the ratios H '_cr/ H _cr and H _½I/ H _cr appear to have a (different) constant value. An interesting relationship which appears to hold for dispersed magnetite, titanomagnetite or hematite grains between 5 and 250 μm, independently of grain-size, quantity and packing density of the magnetic material, is:      

Grain-size dependence of two-dimensional micromagnetic structures for pseudo-single-domain magnetite (0.2–2.5 μm)

Micromagnetic modelling with a Monte Carlo method was performed to obtain 2-D micromagnetic structures of pseudo-single-domain (PSD) magnetite (0.2–2.5  μm). Cubic model grains were subdivided into a 2-D array with a maximum of 100×100 cells. In order to find an appropriate cell size, the variation of the self-consistency parameter ( S ) with cell size was examined. We regard solutions with S >0.95, which corresponds to cell sizes ≤0.03  μm, as representing realistic micromagnetic structures. For saturation remanence states, we found vortex structures for small PSD grains (≤0.25  μm) and closure domain structures for larger PSD grains (0.6–2.5  μm). Between 0.25 and 0.6  μm, structures remained chaotic even after a very large number of Monte Carlo steps. In grains with a closure domain structure, domain walls were usually subdivided into several segments with opposite polarities of magnetization rotation.     

Coercive force of single crystals of magnetite at low temperatures

The temperature dependence of coercive force H _c was studied on well-characterized and stoichiometric millimetre-sized single crystals of magnetite at a series of 16 temperatures from 300 to 10 K using a SQUID magnetometer. H _c decreases gradually with cooling to the isotropic temperature, T _i = 130 K, where the first magnetocrystalline anisotropy constant K ₁ becomes zero. H _c exhibits a sharp increase at the Verwey transition, T _v = 120 K, where the structure changes from cubic to monoclinic. In crossing the Verwey transition, H _c increases by more than two orders of magnitude, from 20 μT to 2.4 mT, and the shape of the hysteresis loops becomes wasp-waisted.
Observed coercivity between 300 K and 170 K varies with temperature as λ _s / M _s , where λ _s is the magnetostriction constant and M _s is the saturation magnetization, indicating that the coercivity in MD magnetite is controlled mainly by internal stress associated with dislocations or other crystal defects. It seems likely that the stable single-domain-like magnetic memory observed in large MD magnetite crystals is due to magnetoelastically pinned domain walls. The discontinuous change in H _c at the Verwey transition is controlled by abrupt changes in magnetocrystalline and magnetostriction constants due to crystal deformation from cubic to monoclinic structure.     

The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

Palaeointensity determination and K—Ar dating of the Tertiary north-east Jalisco volcanics (Mexico)

b
Sixteen samples representing eight Tertiary volcanic units from north-east Jalisco, Mexico were studied in an attempt to estimate the palaeointensity of the Earth's magnetic field. The experimental technique used was similar to that proposed by Shaw (1974) and an attempt was made to incorporate further criteria using the directional behaviour of the NRM, TRM and two ARMs during the af treatment and measuring the rate of ARM acquisition before and after heating. The directional information was used for checking the stability of all remanent magnetizations involved and for correcting the ARM test values. In addition the TRM directional behaviour could be a valuable yet simple test to detect the problem of insufficient heating. The use of the ARM acquisition test in the palaeointensity determination permits the full investigation of the coercive force spectrum and could lead to a more reliable palaeointensity method. This combined ARM method was applied to one sample. Further work is needed to understand the NRM—ARM1 and TRM—ARM2 relationships if the ARM tests are to be used for correcting TRM alteration effects. Whole rock K—Ar age determinations were carried out on samples from four selected units. Ten samples, representing six of the units, are considered to yield reliable palaeointensity values. Mean values were computed for each unit and reduced to the palaeoequator. The mean palaeoequatorial values and K—Ar ages determined are: I (13 |Mp 2 Myr), 0.504 Oe; II, 0.453 Oe; III, 0.439 Oe; VI (52 |Mp 10 Myr), 0.074 Oe; VII (14 |Mp 2 Myr), 0.187 Oe and VIII (12 |Mp 2 Myr), 0.251 Oe. These results agree reasonably well with those from previous studies. A large number of palaeointensity estimations, many more than currently available, are required to obtain an average estimate of the behaviour of the Earth's magnetic field during the Tertiary.     

Rotational remanent magnetization (RRM) and its high temporal and thermal stability

The time and temperature stability of various types of magnetic remanence has been measured in pottery samples containing magnetite and in a clay sample containing manganese ferrite. The time decay of rotational remanent magnetization (RRM), anhysteretic remanent magnetization (ARM) and a low-field isothermal remanent magnetization (IRM) has been measured. While the decay of the last two remanences is easily measurable at about 2 and 19 per cent per decade of time, respectively, the decay of RRM is too small to be measured, being less than about 0.1 per cent per decade of time. Thermal demagnetization of thermoremanent magnetization (TRM), ARM and RRM indicates that RRM is also the most thermally stable. The implications of these experiments are that rocks which exhibit gyromagnetic effects such as RRM contain highly stable particles and therefore are likely to be most suitable for palaeomagnetism.     

红黏土磁化率增强机制

对于黄土-古土壤序列,磁化率增强机制已经被大家认可,并且磁化率被广泛作为古夏季风强弱变化的代用指标。红黏土伏于第四纪黄土之下,同为风成沉积物,对红黏土磁化率增强机制的研究程度不高,且对强发育红黏土获得比较低的磁化率值的原因不清楚。本文通过对佳县红黏土进行系统岩石磁学分析得出：(1) 红黏土磁性矿物种类以磁铁矿为主,同时含有一定量磁赤铁矿、赤铁矿;磁性矿物平均粒径为PSD颗粒;强发育层含有较多的软磁性矿物,弱发育层含有较多的硬磁性矿物。(2) χ、χfd和χARM两两之间表现出很好线性正相关关系,说明红黏土中含有大量SP和SD颗粒亚铁磁性矿物,这些细小磁颗粒是在成壤过程中产生,成壤作用导致古土壤层磁化率升高。(3) 红黏土χfd、χfd%值较高,说明经历较强的成壤过程,成壤环境与黄土高原黄土-古土壤序列类似,与阿拉斯加、西伯利亚黄土-古土壤明显不同。     

干旱区泥炭样品加热过程中磁学特征的变化研究

利用采自干旱区高山～新疆阿尔泰山的表层泥炭样品,以K-T曲线为主,结合J-T曲线、磁滞参数以及XRD等相关实验,探讨了应用热磁实验鉴别富含有机质的弱磁性物质磁性特征.结果表明:样品中磁化率的主要贡献者为低矫顽力的强磁性矿物-磁铁矿,磁铁矿的粒径为PSD(准单畴).加热过程中,含铁粘土矿物绿泥石分解生成新的磁铁矿,磁畴转变成MD(多畴),逐步加热的K-T曲线表明,利用K-T曲线分析含有大量有机质成分弱磁性物质的磁性特征具有一定的指导作用,泥炭样品受热生成的磁性矿物的类型与数量不仅受加热的最高温度控制,同时在加热到不同温度时由于有机质对磁性矿物的还原作用表现出差异性,使得泥炭样品加热到不同温度后的转化、改造及最终生成物亦变得异常复杂.     

The rock magnetic signal of climate change in the maar lake sequence of Lac St Front (France)

Rock magnetic properties of the maar lake sediments of Lac St Front (Massif Central, France) reflect environmental changes during the last climatic cycle. High magnetic concentrations are measured in the sediments deposited under glacial climatic conditions, while lower concentrations correspond with more temperate climatic periods. Low- and high-temperature measurements indicate that the remanence is carried by (titanium-poor) magnetite. However, some maghemite and haematite is present in sediments deposited under temperate conditions.
Normalized intensities and coercivities of the anhysteretic remanent magnetization (ARM) are clearly higher for the sediments deposited during the temperate climatic periods of the Eemian, St Germain I, II and Mid-glacial than for glacial sediments, but other magnetic parameters hardly differ between these groups. Due to slight differences in magnetic composition and possible effects of grain interactions, it is not straightforward to relate this different ARM behaviour to magnetic grain-size variations. For the Holocene sediments, rock magnetic parameters indicate a larger grain size. This trend is also suggested by granulometric experiments with an optical laser granulometer. Dissolution of smaller grains is the most likely explanation for this larger grain size.
Changes in magnetic composition and grain size are extremely limited for the glacial sediments, but magnetic concentration varies considerably. Magnetic concentration maxima in the glacial sediments of Lac St Front correlate with those of the nearby Lac du Bouchet (Thouveny et al. 1994). Correlating the susceptibility records of these sequences with the δ¹⁸O record of the GRIP ice cores (Thouveny et al. 1994) suggests that magnetic concentration maxima may correspond with short cold climatic episodes, associated with Heinrich events.     

A theoretical and experimental comparison of the anisotropies of magnetic susceptibility and remanence in rocks and minerals

Summary. Susceptibility, thermo-remanent magnetization (TRM) and isothermal remanent magnetization (IRM) anisotropy ellipsoids have been determined for several rock samples. The results indicate that the ellipsoid of initial susceptibility is less anisotropic than the TRM and low field IRM ellipsoids which are found experimentally to be of identical shape. This suggests that palaeomagnetic data for anisotropic rocks may be corrected by using the anisotropy ellipsoid determined from magnetically non-destructive low field IRM measurements. Such IRM measurements can also be used to obtain anisotropy axes of samples which are inherently anisotropic but which have a susceptibility which is too weak to be accurately measured. The results for a series of artificial anisotropic samples containing magnetite particles of different sizes (in the range 0.2–90 μm) were very similar to those for the rocks. In contrast, a comparison of the susceptibility and IRM ellipsoids for anisotropic samples containing particles from a magnetic tape gave very different results in accordance with theory. Such results imply that susceptibility and IRM ellipsoids could be used to determine whether anisotropic rocks contain uniaxial single-domain particles (magnetization confined to the easy axis) or whether the particles are essentially multidomain.     

The relationship between the magnetic properties of terrestrial igneous rocks and the composition and internal structure of their component Fe-oxide grains

Summary. Hysteresis loops and the demagnetization of saturation remanence (SIRM), before and after heating, are used to determine the high field magnetic behaviour and the coercivity spectra for common igneous rock types containing discrete types of magnetic carriers. These incude homogeneous to highly exsolved titanomagnetite grains, oxidized titanomagnetite grains (martite), exsolved hemo-ilmenite grains, and oxidized ilmenite grains. Specific internal structures and changes in composition due to oxidation are found to have characteristic effects on both high and low field magnetic properties.     

Changes in direction of the remanence of rocks produced by stationary alternating field demagnetization

Summary. A theoretical investigation of the way in which an isotropic rock containing single-domain particles acquires both IRM and ARM (or TRM) has indicated that stationary single-axis alternating field (af) demagnetization with the af axis at an angle to the remanence vector should produce progressive angular changes in a single-component remanence as demagnetization proceeds. Just before the remanence is completely removed it should lie at 90° to the af axis irrespective of the original orientation of the remanence (apart from 0°). Experimental observations on a rock sample support these deductions.
This analysis has been extended to investigate the way in which ARM (or TRM) and IRM are demagnetized by static three-axis demagnetization methods which are used by some workers in palaeomagnetism. Theory, in conjunction with the use of a numerical model, predicts that an ARM or TRM should not undergo significant direction changes when these methods are applied but an IRM should undergo progressive direction changes as demagnetization proceeds, usually moving until it makes an angle of cos⁻¹ (1/3) with each of the three af axes just before it is removed. Confirmation that such changes do occur have been obtained by experiments on a rock sample. The relative merits of static and tumbling af demagnetization methods are also discussed.     

Effects of weathering on single-domain magnetite in Early Pliocene marine marls

Rock magnetic parameters are often used to recognize variations in the original magnetic mineralogy and for normalizing purposes in palaeointensity studies. Incipient weathering, however, is shown to have a profound but partly reversible influence on the rock magnetic properties of the marls of the Early Pliocene Trubi formation in southern Sicily (Italy). The remanence in the marls resides in single-domain (SD) magnetite grains, but the remanent coercive force (H_cr) shows a strong variation and most values observed are anomalously high ( H_cr) range 36–188 mT).
The enhanced coercivities are attributed to stress in the magnetite grains induced by surface oxidation at low temperature. Upon heating to 150 °C a reduction of coercivities occurs that can be explained by a stress reduction as a result of a reduction of Fe^2- gradient due to a higher diffusion rate at elevated temperature. After heating to 150 °C, coercivities are quite uniform throughout the outcrop and the values are characteristic of SD magnetite (H_cr range 30–38 mT). The bulk susceptibility increases by 4–24 per cent, and the isothermal remanent magnetization (IRM) decreases by 5–11 per cent. The increase in anhysteretic remanent magnetization (ARM) is large: 20–242 per cent. The magnitude of the changes is related to the degree of weathering.
Another effect of heating the marl samples to 150 °C is a substantial reduction of the coercivities of the secondary overprint in the natural remanent magnetization. After heating. separation of the secondary and primary components by alternating-field demagnetization is more efficient. The usual difficulties of thermal demagnetization above 300 °C may thus be avoided by a combination of moderate heating to 150 °C and subsequent alternating-field demagnetization.     

Frequency dependence of magnetic susceptibility for populations of single-domain grains

A recent paper (Dearing et al . 1996) on the use of frequency dependence of magnetic susceptibility (Xfd) in magnetic grain-size investigations of environmental materic has proposed a fundamentally new model for the magnetic susceptibility of single-domain (SD) grains measured at different frequencies, and is divergent from the no well-established theory of SD behaviour. This new model appears to be founded on a confusion about the behaviour of SD grains, as predicted by theory, and magnetic measurements of real materials, which naturally have a distribution of magnetic grain sizes. Here I try to clear up this confusion by showing how different log-normal distributions of magnetic grain sizes affect the frequency dependence of magnetic susceptibility measurement. This analysis highlights that the limiting maximum Xfd value of ˜ 15 per cent obtained for environmental materials can be explained simply as a constraint imposed by the magnetic grain-size distribution having a finite minimum width (˜1.0 on a natural log scale). There is no reason to suppose that if the grain-size dispersion was narrower higher Xfd values could not be observed. Furthermore, the Xfd value is non-unique and so cannot be used quantitatively to determine the amount or grain-size distribution of SD grains in a sample     

Comparison of two classification methods to identify grain size fractions of aeolian sediment

Grain-size class-Std(GSCStd) and Grain-size class-dD(GSCdD) methods are simple statistical approaches for classifying bulk grain-size distributions(GSDs) into grain-size fractions. Although these two methods were developed based on similar statistical principles, the classification difference between these two methods has not been analyzed. In this study, GSCStd and GSCdD methods are conducted in thirteen grain-size data sequences to examine the applicability for identifying grain size fractions. Results show that, application of the GSCStd method is equivalent to that of the GSCdD method in identifying finer grain-size fractions, and the difference between the two methods mainly comes from the identification of coarse grain-size fractions. Thus, finer grain-size fractions are recommended for use in research of surface aeolian and paleo-aeolian sediments. In addition, our results do not completely agree with previous studies, coarser grain-size fractions in our case suggest that the GSCdD method may not be more applicable than the GSCStd method.     

A comparison of archaeointensity results from Chinese ceramics using microwave and conventional Thellier's and Shaw's methods

Palaeo- and archaeointensity determinations of the geomagnetic field are limited by mineralogical alteration that may occur when samples are heated in the laboratory to produce a TRM ( Thellier & Thellier 1959 ; Shaw 1974 ). By using microwave excitation of the magnetic grains we have been able to create a TRM without significantly heating the bulk samples, thereby avoiding thermal alteration ( Walton et al . 1993 ; Shaw et al . 1996 ). When applied to Peruvian ceramics in a manner analogous to the standard Thellier method, the microwave technique was found to reduce the scatter dramatically in the archaeointensity results ( Shaw et al . 1996 ). In the present study we apply this microwave technique to a collection of Chinese ceramics covering the time interval 2700–7500  yr BP. These ceramics have already been investigated using adaptations of both Thellier's ( Coe 1967 ) and Shaw's ( Rolph & Shaw 1985 ) palaeointensity methods ( Yang et al . 1993a ). Although an acceptable agreement was found between those two methods, the equivalent virtual axial dipole moments (VADMs) were significantly lower than for the global model of McElhinny & Senanayake (1982 ). The present study, using the microwave technique with cooling-rate correction, has provided more consistent VADMs, and is much closer to the global model.