贵州草海近21ka以来有机地球化学记录反映的古环境变化

草海位于黔滇交界,主要受印度夏季风的影响,其湖沼沉积物记录了中—晚第四纪的环境变化历史,是研究第四纪环境和季风演变的良好载体。本研究选取的南屯NT03钻孔,岩心长405 cm,在放射性碳同位素(AMS14C)测年基础上建立了年代序列,并进行了沉积物的色差值(L*)、烧失量(LOI550)、总有机碳(TOC)、碳氮比(C/N)和有机稳定碳同位素(δ13Corg)等古环境替代指标的测试。实验结果显示,L*、LOI550和TOC等3个有机碳含量指标同步变化,共同指示该钻孔序列经历了3个沉积环境演变阶段,即末次盛冰期晚期(21—15 cal ka BP)河流—冲积相沉积阶段、冰消期至早中全新世(15—4 cal ka BP)高湖面湖泊—沼泽相沉积阶段和晚全新世(4 cal ka BP以来)洪冲积相沉积阶段。近2万年以来草海湖沼面积经历的收缩→扩张→收缩演变过程与石笋氧同位素变化基本吻合,表明季风降雨是引起草海湖泊水体和周边生态系统变化的主要因素。δ13Corg指标变化范围为-29. 28‰～-24. 19‰,表明草海盆地周围植被组成在末次盛冰期以来C4草本虽然略有增加,但均以C3植物为主。同时,TOC和δ13Corg指标证明了B/A冰消期暖事件对盆地边缘区的湿地泥炭富集起到关键作用,而多指标揭示了近4 ka以来水域变浅并发展成为冲积环境的过程,也可能与石笋记录的夏季风减弱所带来的降水量减少有关。     

海峡沉积研究进展*

海峡是不同于三角洲、陆架的一类独特沉积环境,具有特殊的沉积作用组合。海峡的形态多样,长度为几千米至数百千米,深度为几十米至上千米; 海峡由狭窄区域向两端逐渐过渡为相对开阔海区,开阔海区大多深度相比海峡更深; 海峡的狭窄区域横截面积小、流体流速最大,通常以侵蚀地貌为特征; 流体流经狭窄区域后,由于海峡横截面积增加,导致流速向两端开阔海区域锐减,并表现为沉积地貌。浅水海峡通常以潮流为最主要的沉积作用,其他的沉积物搬运方式包括单向的海流和重力流; 深水海峡则以海流和重力流为主。海峡高能区沉积以砾石滞留和发育交错层理为特征,低能区表现为泥质沉积并发育流水砂纹; 在低海平面时期,暴露的浅水海峡以河流沉积作用为主; 海平面上升过程中,河流逐渐演化为三角洲/河口湾、海湾和贯通的海峡。     

重庆秀山小茶园锰矿南华系大塘坡组古环境*

认识渝湘黔地区南华系的沉积构造背景可以为该地区锰矿勘探提供新的依据,基于此,文中对重庆秀山小茶园锰矿ZK0606钻孔的南华系千子门组和大塘坡组开展了系统的沉积环境和地球化学分析。沉积相分析结果表明,该套地层共可划分出冰水浅海、局限边缘盆地和浅水陆棚3种沉积环境。地球化学分析结果表明,研究区大塘坡组稀土元素总量较高、富轻稀土元素、具Eu负异常,结合Al₂O₃/(Al₂O₃+Fe₂O₃)、Al/(Al+Fe+Mn)值等,推测其形成于被动大陆边缘背景。根据微量元素含量及其比值(U、V、Mo、V/Cr)等推测,大塘坡组一段沉积于缺氧—贫氧沉积环境,而大塘坡组二段逐渐过渡到氧化沉积环境;根据Al/Ca值、化学蚀变指数(CIA)等指标分析,该套地层自下而上化学风化强度逐渐增大、陆源碎屑供给增多,这可能与Sturtian冰期结束、气候变暖和海平面迅速升高有关。综合上述分析结果认为,重庆秀山小茶园锰矿主要产出于大塘坡组一段下部相对深水厌氧的局限边缘盆地环境中。     

华北盆地西部太原组遗迹化石组合对古水深变化的响应*

通过对豫西—晋中南地区上石炭统—下二叠统太原组碳酸盐岩中遗迹化石的组成、产状及分布特征的研究,结合部分生物潜穴中Sr含量、Sr/Ba值、1000×(Sr/Ca)值和δ¹³C值,得到不同地区太原组沉积期古水深的变化曲线,建立了3种不同水深的遗迹组合: (1)Nereites-Chondrites遗迹组合,产生于氧化还原界面附近水体相对较深的浅海下部环境;(2)Zoophycos-Teichichnus遗迹组合,形成于浪基面至氧化还原界面之间的浅海中部沉积环境;(3)Zoophycos-Thalassinoides遗迹组合,出现在平均海平面至浪基面之间的浅海上部或较为闭塞的海湾潟湖沉积环境。依据这3种遗迹组合在各剖面上的变化特征和古水深,认为在豫西—晋中南地区太原组沉积期发生过2次较大规模的海侵。这一成果为精细研究华北西部地区太原期沉积环境演变规律及对比地层提供了生物遗迹学方面的依据。     

珠江三角洲中部晚更新世以来的有孔虫记录与古环境演化*

珠江三角洲中部钻孔PRD20和PRD17晚第四纪以来的沉积记录较为完整,尤其是晚更新世海侵记录良好。以其为研究对象,对两孔的有孔虫微体动物群记录和沉积特征进行了分析和对比,并结合前人研究成果,重建珠江三角洲晚更新世以来的古环境演变,并着重分析了晚更新世海侵事件。约44500 cal a BP以前,研究区为河流环境,发育河道砂砾沉积。约44500—21300 cal a BP,发生晚更新世海侵,形成溺谷型河口湾,两孔沉积物中有孔虫的垂直分布记录了水体条件发生的多次变化,可辨识出2次海侵海退次级旋回;其中PRD20孔中有孔虫以滨岸广盐型占绝对优势,PRD17孔中以滨岸广盐型为主、海相—半咸水型有孔虫占有一定比例,表明研究区位于溺谷湾中径流与潮流共同作用的区域,且PRD20孔受径流影响更大。约21300 cal a BP后,受末次冰盛期海退影响,研究区暴露于地表遭受风化剥蚀,风化产物在PRD20孔表现为1层褐红色砂砾,在PRD17孔表现为1层花斑黏土。约8000 cal a BP,海平面回升导致河水滞留形成沼泽环境,PRD20孔发育1层泥炭层。约8000—5500 cal a BP,PRD20孔发育受径流影响较大的河口湾湾头沉积,仅在全新世海侵最盛时含有少量有孔虫记录。约5500 cal a BP后,研究区发育三角洲平原沉积。受构造抬升影响,PRD17孔地势较高,于约4700 cal a BP才开始重新接受沉积,零星出现潮水搬运而来的有孔虫。     

河北坝上丰宁黄土剖面记录的230 ka BP以来的环境演化*

河北坝上地区位于东亚季风气候边缘区,对气候变化响应敏感。丰宁黄土剖面为研究该区域长时间尺度的环境演化提供了理想材料。通过丰宁黄土剖面地球化学元素和磁化率分析,结合光释光测年结果,恢复了该地区230,ka BP以来的环境演化历史; 通过野外观察,识别出了S₁古土壤之下发育的风化淋滤黄土层,探讨了S₁古土壤发育时期的风化淋滤特征及其所揭示的气候变化问题。结果表明: (1)230,ka BP以来的磁化率记录可与深海氧同位素3—8阶段进行细节上的对比,表明丰宁黄土堆积区对全球气候变化有着积极的响应;(2)S₁古土壤发育时期,由于受到强降水的影响,土壤中元素受到强烈淋溶从而向下迁移到L₂黄土中,造成L₂上部地球化学记录与磁化率的差异;(3)从S₁古土壤顶部到钙结核层之间土壤属于酸性淋溶土,可能相当于现今中国北亚热带的黄棕壤,其剖面由土壤层、风化淋滤黄土层和CaCO₃淀积层构成;(4)S₁古土壤发育时期的温度和降水量与现今江苏泗洪和六合地区相当,表明当时研究区为亚热带气候。     

柴北缘西段侏罗系沉积特征*

柴达木盆地北缘中小盆地(包括苏干湖盆地)是中国西部潜在的油气资源战略接替区,前期工作揭示了在柴北缘西段发育具有一定生油潜力的中生界烃源岩。沉积特征和沉积环境分析对于研究烃源岩及储集层分布具有重要意义。但有关柴北缘西段沉积特征和沉积环境的认识相对较少,制约了油气勘探工作的进一步开展。通过野外露头观测、钻测井资料分析以及地球化学测试等技术手段,初步落实了柴北缘西段侏罗系的沉积体系和沉积环境,为今后的油气勘探提供了依据。研究表明,苏干湖盆地早中侏罗世发育扇三角洲—湖泊沉积,晚侏罗世发育辫状河,物源可能主要来自北部祁连山;赛什腾山南缘侏罗纪发育沼泽—三角洲—湖泊沉积体系,富含煤层,物源来自西北和东北;冷湖一带早侏罗世主要发育湖西山组深湖—半深湖沉积,物源可能来自西北部阿尔金山附近。泥岩样品沉积地化分析显示研究区整体为还原环境,不同采样点样品的稀土元素配分模式具有相似性。构造-沉积演化分析表明,早侏罗世柴达木盆地北缘西段初始断陷,湖盆沉积中心位于冷湖一带;中侏罗世中期(对应于大煤沟组四段)苏干湖盆地内部裂陷成盆,沉积中心向东转移,后期(对应于七段)湖泛形成大湖盆。侏罗系烃源岩主要发育于大煤沟组五段至七段湖平面上升时期。     

渤海湾盆地古近纪古地理特征与油气*

渤海湾盆地是一个典型的内陆裂谷盆地,内部发育6个坳陷、4个隆起、54个凹陷和44个凸起。沉积盆地的含油气性与其古地理分布有密切的关系。利用渤海湾盆地各坳陷大量的录井、岩心、古生物、测井、地震资料及前人的大量文献和数据,对渤海湾盆地各坳陷古近系孔店组、沙河街组沙四段、沙三段、沙二段、沙一段、东营组进行了全区对比和统层。在此基础上,对冀中坳陷、济阳坳陷、临清坳陷内东濮凹陷各组段的沉积相进行了分析,编制了这些区域的古地理图;充分利用前人文献和科研报告中所编制的辽河坳陷、黄骅坳陷、渤海海域古近系各组段的古地理图,编制了渤海湾盆地孔店组、沙河街组沙四段、沙三段、沙二段、沙一段、东营组的古地理图。渤海湾盆地发育数十个含油气凹陷,每个凹陷中心的深湖亚相泥岩构成烃源岩,而在凹陷的边缘发育近岸水下扇、扇三角洲、三角洲、滩坝等砂体,构成重要的储集层,在有利的成藏条件下,凹陷中央的烃源岩向周围与之互层的储集层供烃形成油藏,在凹陷中央的烃源岩中,还发育了页岩油、页岩气、致密油气等非常规油气。因此,每个凹陷就是油气生成、运聚的基本单元,是一个独立的油气运移—聚集系统。生油凹陷的分布及其古地理特征控制了油气在渤海湾盆地古近系中的平面分布。     

渤海湾盆地古近纪古地理特征与油气*

渤海湾盆地是一个典型的内陆裂谷盆地,内部发育6个坳陷、4个隆起、54个凹陷和44个凸起。沉积盆地的含油气性与其古地理分布有密切的关系。利用渤海湾盆地各坳陷大量的录井、岩心、古生物、测井、地震资料及前人的大量文献和数据,对渤海湾盆地各坳陷古近系孔店组、沙河街组沙四段、沙三段、沙二段、沙一段、东营组进行了全区对比和统层。在此基础上,对冀中坳陷、济阳坳陷、临清坳陷内东濮凹陷各组段的沉积相进行了分析,编制了这些区域的古地理图;充分利用前人文献和科研报告中所编制的辽河坳陷、黄骅坳陷、渤海海域古近系各组段的古地理图,编制了渤海湾盆地孔店组、沙河街组沙四段、沙三段、沙二段、沙一段、东营组的古地理图。渤海湾盆地发育数十个含油气凹陷,每个凹陷中心的深湖亚相泥岩构成烃源岩,而在凹陷的边缘发育近岸水下扇、扇三角洲、三角洲、滩坝等砂体,构成重要的储集层,在有利的成藏条件下,凹陷中央的烃源岩向周围与之互层的储集层供烃形成油藏,在凹陷中央的烃源岩中,还发育了页岩油、页岩气、致密油气等非常规油气。因此,每个凹陷就是油气生成、运聚的基本单元,是一个独立的油气运移—聚集系统。生油凹陷的分布及其古地理特征控制了油气在渤海湾盆地古近系中的平面分布。     

山东半岛全新世近岸泥质区沉积过程与沉积记录*

中国东部陆架边缘海发育多个全新世泥质区,是研究古海洋和古气候的理想区域。本研究从现代沉积过程和全新世沉积记录的视角,对山东半岛近岸泥质区的前人研究结果进行总结梳理,为后续相关研究提供参考。山东半岛近岸泥质区位于山东半岛沿岸,主要是来自黄河的沉积物在沿岸流、上升流、潮汐等相互作用下沉积而成,呈现独特的“Ω”形沉积模式。山东半岛近岸泥质区形成于全新世,物质来源主要是黄河,近岸侵蚀和当地小河流也贡献一定的物质来源。山东半岛近岸泥质区的形成和演化与古海洋条件、海平面升降、内陆古气候演变等多种因素有关,蕴藏着丰富的环境演化信息。山东半岛近岸泥质区沉积能够快速记录东亚季风的演变,其较高的沉积速率为研究黄河流域的古气候和古生态演化提供高分辨率的材料,可为预测未来全球变化背景下黄河流域的发展趋势提供参考。虽然前人对现代沉积过程进行了大量工作,但仍需加强现代观测和数值模拟等方面的工作,为更好地重建研究区的沉积动力过程提供数据和理论支撑。此外,该区在长时间尺度上的沉积物和有机质的沉积过程对古海洋和古气候的响应机制也亟待开展研究。     

Distribution of mercury species in water and sediments in Caohai Lake, Guizhou Province

Caohai Lake which is situated in Guizhou Province, has suffered drain project many times since 1958.The main mercury contamination includes industry waste water, litter and waste residue from refine zinc furnace and so on. The water and sediment samples which were collected from Caohai Lake in different seasons using metal clean protocols. Study sites were selected at the upper and down reaches and the tributaries of this lake, respectively. Total mercury （THg）, reactive mercury （RHg） and dissolved mercury （DHg） concentrations were measured by trap pre-concentration and CVAFS detection methods, and the concentrations of particulate mercury （PHg） are equal to difference of THg and DHg. Total methylmercury （MeH） and dissolved methylmercury （DMeHg） concentrations were measured by GC-CVAFS detection method. Mercury in sediment was measured by AAS method. The results in autumn were obtained as follows： the average concentrations of total mercury, reactive mercury,     

Research on the carbon isotopic composition of organic matter from Lake Chenghai and Caohai Lake sediments

The carbon isotopic composition of organic matter from lake sediments has been extensively used to infer variations in productivity. In this paper, based on the study of the contents and δ13C values of organic matter in different types of lakes, it has been found that δ13C values of organic matter have different responses to lake productivity in different lakes. As to the lakes dominated by aqutic macrophytes such as Lake Caohai, organic matter becomes enriched in 13C with increasing productivity. As to the lakes dominated by aquatic algae such as Lake Chenghai, δ13C values of organic matter decrease with increasing productivity, and the degradation of aquatic algae is the main factor leading to the decrease of δ13C values of organic matter with increasing productivity. Therefore, we should be cautious to use the carbon isotopic composition of organic matter to deduce lake productivity.     

岩溶地质碳汇的稳定性——以贵州草海地质碳汇为例

近几年来对岩溶碳汇的争论越来越多,其关键问题是岩溶作用产生的重碳酸根是否稳定.本文以贵州草海流域为研究区,基于前人研究基础,以碳同位素模型计算出岩溶作用产生的DIC((Dissolved Inorganic Carbon溶解无机碳)中58.8%为草海中为水生植物利用,草海地质碳汇量达588.67 tC/a.以此推算长江中下游湖泊沉水植物每年固碳量370602 tC/a,长江中下游湖泊中仅沉水植物稳定的地质风化CO2汇量约为75万吨.从而证明岩溶碳汇的相对稳定性和岩溶动力系统新理论的合理性.     

鄱阳湖沉积物近8ka来有机质碳同位素记录及其古气候变化特征

通过对鄱阳湖沉积物的高密度采样和有机质碳同位素分析,讨论了鄱阳湖近 8 ka来的古气候环境.鄱阳湖沉积物有机质δ 13C值为-22.42‰～-32.42‰,属 C3类植物来源.暖湿期δ 13C值相对偏负;冷(凉)干期δ 13C值相对偏正.这些记录表明,鄱阳湖近 8 ka来经历了 4次暖湿和 4次冷(凉)干的气候环境变化, 7 900～3 660 a B.P.、3 440～2 990 a B.P.、2 940～2 170 a B.P.、1 820～6 50 a B.P.属相对温暖湿润的气候环境;3 660～3 440 a B.P.、2 990～2 940 a B.P.、2 170～1 820 a B.P.、650～200 a B.P.为相对冷凉干旱的气候环境,自 200 a B.P.(1 750 A.D.)以来湖区气候开始转暖.暖湿期持续时间较长,冷(凉)干期持续时间较短,1 000 a B.C.左右为一次重要的气候变冷事件.我国全新世几个特征性气候在湖区均有不同的显示,并与孢粉、硅藻、历史记录所反映的古气候环境对应性较好,可以作为恢复古气候变化的灵敏指标.     

Reconstruction of millennial-scale variations in the East Asian summer monsoon over the past 300 ka based on the total carbon content of sediment from Lake Biwa,Japan

The total carbon content analysis for Takashima-oki core extracted from Lake Biwa with time resolutions of approximately 150 years was used to reconstruct millennial-scale climate change in the East Asian monsoon region over the past 300 ka. The total carbon content of the Takashima-oki core is an indirect proxy for the East Asian summer monsoon, because the total carbon content reflects primary productivity within the lake, which is controlled by precipitation in the catchment area. Using these data, we clarify temporal variations in the East Asian summer monsoon prior to MIS 5, which were previously unresolved. The observed variations show a ∼1,500-year cycle that is also recorded by paleoclimate indices in the North Atlantic region. We propose that the East Asian summer monsoon underwent abrupt millennium-scale changes during interglacial stages such as MIS 5 and 7.     

滇中星云湖地区200年来的环境演化

在对星云湖的近现代沉积物进行粒度、稳定同位素等测试分析的基础上,综合对比了多项环境指标,并从自然变化和人为影响2个方面揭示湖泊环境演化的动态过程和动力学机制以及各环境要素的内在联系.研究表明该地区近200 a来环境及生态演化具有以下区域性特点:19世纪初期气候较为温暖干旱,之后向温凉湿润转变,20世纪80年代开始,湖泊出现富营养化,1998年以来气温处于回升状态,现在正处于暖干气候阶段,人类活动正在日益深刻地影响着湖泊的环境演化.     

REE Geochemical Study of the Permian—Triassic Marine Sedimentary Environment in Guizhou Province

This paper deals with the REE geochemical characteristics of Permian-Triassic marine carbonate rocks in Guizhou Province.It is found that there are two broad categories of strati-graphic units in the region studied in accordance with their ΣREE contents and REE distribu-tion patterns: one is characterized by LREE enrichment and slight Ce depletion,with the REE distribution patterns similar to those of North American shales,and the other featrures relative HREE enrichment and relatively remarkable Ce depletion,with the REE distribution patterns close to those of pelagic sediments.In terms of their different ΣREE contents,five types of stratigraphic units can be distinguished.Incorporation of detrital minerals,REE complexing ca-pability,oxidation-reduction conditions of the media are the main factors affecting the REE com-position and REE distribution patterns of marine carbonate rocks in the region studied.In the light of REE geochemical characteristics of carbonate rocks,coupled with sedimentary facies analysis,this paper discusses the characteristics of the Permian-Triassic marine sedimentary environment in Guizhou Province and its evolutional rules.     

Environmental changes during the past 13500 cal. a BP deduced from lacustrine sediment records of Lake Qinghai,China

A 475-cm long sediment core (QH-2005) from Lake Qinghai was used to carry out multi-proxy analysis of δ18O and body length of ostracod valves and redness and grain size of sediments, in order to reconstruct environ-mental changes during the past 13500 cal. a BP. The age model was based on 6 14C dates for bulk orgnic carbon (BOC) and 2 14C dates for lignin. The lignin 14C dates are apparently younger than the corresponding layers’ BOC 14C dates, indicating that the reservoir age varied from 728 to 1222 a since the Late Glacial and from 2390 to 2490 a immediately before the pre-bomb era. Hence, the 14C age model for Core QH-2005 was corrected by the changing reservoir age. Ostracod δ18O values were primarily related to dilution and evaporative enrichment of the lake water. The reconstructed salinity based on ostracod body length coincides well with ostracod δ18O values. High redness and mean grain size (MZ) values indicate increased riverine supply to Lake Qinghai associated with increasing monsoon rainfall. Multi-proxy results show that climate during 13500-10900 cal. a BP was relatively cold and dry with fre-quent short-term fluctuations; a warm and wet climate began at about 10900 cal. a BP and culminated around 6500 cal. a BP as a result of monsoon strengthening; the climate became cold and dry afterwards and has remained rela-tively stable since 3400 cal. a BP. Our data also reveal short-term (millennial/centennial timescales) climatic fluctua-tions including: Younger Dryas events, ice-rafting events 8 and 1 (by ～11000 cal. a BP and ～1600 cal. a BP respec-tively), 8200 cal. a BP cold event, Little Ice Age and the Medieval Warm Period.     

Enzymatic and Microbial Degradation of Organic Matter in Lake Hongfeng, Guizhou Province, China

1IntroductionEnzymaticandmicrobialdegradationoforganicmatterhasabearingnotonlyonearlydiagene sis,butalsoonelementcyclingandmicrobedistributioninlakesediments.Somereportsshowedtheabundancevariationsoforganicmatterinsediments (BurdigeandGardner,1998;ArthurandDean ,1998;WanGuojiangetal.,2 0 0 0 ) .However,duetothecomplexchemicalcompositionoforganicmatter,mechanismsofenzymaticandmicrobialdegradationandvariationsofeachchemicalcomponentneedtobestudiedfurther.Underanoxiccondition ,SO2 -4 isanimpo…