Multiphase flow above explosion sites in debris-filled volcanic vents: Insights from analogue experiments

Discrete explosive bursts are known from many volcanic eruptions. In maar–diatreme eruptions, they have occurred in debris-filled volcanic vents when magma interacted with groundwater, implying that material mobilized by such explosions passed through the overlying and enclosing debris to reach the surface. Although other studies have addressed the form and characteristics of craters formed by discrete explosions in unconsolidated material, no details are available regarding the structure of the disturbed debris between the explosion site and the surface. Field studies of diatreme deposits reveal cross-cutting, steep-sided zones of non-bedded volcaniclastic material that have been inferred to result from sedimentation of material transported by “debris jets” driven by explosions. In order to determine the general processes and deposit geometry resulting from discrete, explosive injections of entrained particles through a particulate host, we ran a series of analogue experiments. Specific volumes of compressed (0.5–2.5 MPa) air were released in bursts that drove gas-particle dispersions through a granular host. The air expanded into and entrained coloured particles in a small crucible before moving upward into the host (white particles). Each burst drove into the host an expanding cavity containing air and coloured particles. Total duration of each run, recorded with high-speed video, was approximately 0.5–1 s. The coloured beads sedimented into the transient cavity. This same behaviour was observed even in runs where there was no breaching of the surface, and no coloured beads ejected. A steep-sided body of coloured beads was left that is similar to the cross-cutting pipes observed in deposits filling real volcanic vents, in which cavity collapse can result not only from gas escape through a granular host as in the experiments, but also through condensation of water vapour. A key conclusion from these experiments is that the geometry of cross-cutting volcaniclastic deposits in volcanic vents is not directly informative of the geometry of the “intrusions” that formed them. An additional conclusion is that complex structures can form quickly from discrete events.     

The loss of cadmium and zinc from sea water during accumulation experiments: its implication on toxicity threshold concentrations

The loss of cadmium and zinc from solutions contained in glass and polystyrene vessels has been determined at different metal concentrations (0.2–3 μg ml^?1). A substantial amount (37%) of cadmium was lost after 15 days, while 4% zinc was lost after 50 h. In view of this metal loss, it is stressed that interpretation of graphs, calculations and deductions cannot be made on the basis of spiking amounts alone. It is also suggested that in accumulation experiments use should be made of precontaminated apparatus and the fate of metals for each experiment must be monitored separately. These precautions were omitted in 62% of all papers dealing with metal pollution published by one serious biological journal in 1979. This greatly reduces the value of the reported results and conclusions. Similarly, many earlier papers and reviews reporting acute toxicity concentrations should be viewed with extreme caution.     

Color measurements of volcanic ash deposits from three different styles of summit activity at Sakurajima volcano,Japan: Conduit processes recorded in color of volcanic ash

We measured quantitatively colors of volcanic ash deposits erupted from three different styles of summit activity (Strombolian activity, Vulcanian explosions and continuous ash venting activity) at Sakurajima volcano from 1974 to 1985. Colors of Strombolian ash samples have larger yellow components of their visible spectra (b^? values) than those of explosion and continuous venting ash samples. Colors of explosion ash samples show larger variation in both red and yellow components of their visible spectra (a^? and b^? values, respectively), while colors of continuous venting ash samples are in the narrow ranges within colors of explosion ash samples. Colors of components with lower densities than 3.1 g/cm³ (groundmass and phenocrystic plagioclase) obtained by magnetic and heavy liquid separation methods are similar to the unseparated bulk ash samples. This result suggests that the color variations of ash deposits are mainly originated from the particles composed of groundmass. The particles can be classified into three different types of particles with different vesicularity and crystallinity (vesicular particle [VP], dense particle with vesicles [DPV] and dense particle without vesicles [DP]). Analytical results of component proportions, chemical compositions of groundmass glasses, ferrous iron contents and surface ferric materials show that (1) VP has larger yellow components of the visible spectrum (b^? values) and high ferrous iron content, and is less crystallized than the DP and DPV, (2) DP has larger red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves ferric materials on the surfaces produced by oxidation process, and (3) DPV has smaller red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves less ferric materials on the ash surfaces. Color differences of ash deposits from three different activity styles can be explained by the different mixing ratios of VP, DPV and DP. During the Strombolian activity, the VP is a main component in the ash, which is formed from relatively less degassed and crystallized magma. In the Vulcanian explosion and continuous ash venting activity, the proportions of DPV and DP in ash are larger than that in the Strombolian activity. The highly crystallized DP may correspond to a vent cap, and DPV to a magma below the cap. The color measurements of ash deposits provide information on the pre-eruptive processes at the shallower levels of a conduit.     

Sidewall erosion: Insights from in situ-produced 10Be concentrations measured on supraglacial clasts (Mont Blanc massif,France)

Sidewall erosion because of rockfalls is one of the most efficient erosional processes in the highest parts of mountain ranges; it is therefore important to quantify sidewall erosion to understand the long-term evolution of mountainous topography. In this study, we analyse how the ¹⁰Be concentration of supraglacial debris can be used to quantify sidewall erosion in a glaciated catchment. We first analyse, in a glaciated catchment, the cascade of processes that move a rock from a rockwall to a supraglacial location and propose a quantitative estimate of the number of rockfalls statistically mixed in a supraglacial sand sample. This model incorporates the size of the rockwall, a power law distribution of the size of the rockfalls and the mean glacial transport velocity. In the case of the Bossons glacier catchment (Mont Blanc massif), the ¹⁰Be concentrations obtained for supraglacial samples vary from 1.97 ± 0.24 to 23.82 ± 1.68 × 10⁴ atoms g⁻¹. Our analysis suggests that part of the ¹⁰Be concentration dispersion is related to an insufficient number of amalgamated rockfalls that does not erase the stochastic nature of the sidewall erosion. In the latter case, the concentration of several collected samples is averaged to increase the number of statistically amalgamated rockfalls. Variable and robust ¹⁰Be-derived rockwall retreat rates are obtained for three distinct rockfall zones in the Bossons catchment and are 0.19 ± 0.08 mm year⁻¹, 0.54 ± 0.1 mm year⁻¹ and 1.08 ± 0.17 mm year⁻¹. The mean ¹⁰Be retreat rate for the whole catchment (ca. 0.65 mm year⁻¹) is close to the present-day erosion rate derived from other methods. © 2019 John Wiley & Sons, Ltd.     

Evolution of crustal deformation in the northeast–central Japanese island arc: Insights from fault activity

We evaluated fault activity in northeast–central Japan based on fault orientation, regional stress field, and slip tendency analysis for active and non‐active faults (i.e. faults for which Quaternary activity has not been identified). Slip tendency is generally higher along active faults than non‐active faults, although a high slip tendency was observed along some non‐active faults, indicating their potential to become active. The potential for fault activity along non‐active faults can be modeled using the temporal evolution from non‐active to active during long‐term crustal deformation. The density of potentially active faults varies spatially across the study areas and reflects the temporal evolution of crustal deformation in northeast–central Japan.     

Measurement of persistent organic pollutants (POPs) in plastic resin pellets from remote islands: toward establishment of background concentrations for International Pellet Watch

Plastic resin pellets collected from remote islands in the Pacific, Atlantic, and Indian Oceans and the Caribbean Sea were analyzed for polychlorinated biphenyls (PCBs), dichloro-diphenyltrichloroethane and its degradation products (DDTs), and hexachlorocyclohexanes (HCHs). Concentrations of PCBs (sum of 13 congeners) in the pellets were 0.1-9.9 ng/g-pellet. These were 1-3 orders of magnitude smaller than those observed in pellets from industrialized coastal shores. Concentrations of DDTs in the pellets were 0.8-4.1 ng/g-pellet. HCH concentrations were 0.6-1.7 ng/g-pellet, except for 19.3 ng/g-pellet on St. Helena, where current use of lindane is likely influence. This study provides background levels of POPs (PCBs<10 ng/g-pellet, DDTs <4 ng/g-pellet, HCHs <2 ng/g-pellet) for International Pellet Watch. Sporadic large concentrations of POPs were found in some pellet samples from remote islands and should be considered in future assessments of pollutants on plastic debris.     

Chemical and isotopic variations in fumarolic discharge and thermal waters at Vulcano Island (Aeolian Islands, Italy) during 1996: evidence of resumed volcanic activity

Gas samples from some fumaroles at ‘La Fossa' crater and Baia di Levante on Vulcano Island and from a diffuse soil gas emission were analysed during 1995–1996, along with water samples from thermal wells in the area of Vulcano Porto. During 1996, we observed a significant increase both in the gas/steam ratio and in the CO₂ concentration, as well as strong variations in δ¹³C_CO2, δD_H2O and δ¹⁸O_H2O of fumarolic gases. These variations are probably related to an increased inflow of deep fluids of magmatic origin. The temperatures of fumaroles did not show remarkable variations except for fumarole F11. In this case, temperature increased by about 80°C from February to August 1996. During the same period, remarkable variations in temperature, phreatic level and chemical and isotopic composition of water were also recorded in one of the geothermal wells in the Vulcano Porto area (Camping Sicilia; T60°C). The observed variations in this well are probably related to a pressure build-up, occurring at least in the surficial part of the system, because of increased gas flux and/or decreased permeability of the fumarolic degassing system. Chemical and isotopic composition of the water showed that during this evolutionary phase, the content of fumarolic condensate in this well was about 80 to 90%. Based on the observation of physical and chemical variables of the Camping Sicilia fluids, during this phase of activity, it is concluded that this area is affected by a phreatic eruption hazard if a volcanic episode with high energy discharge in a limited time span occurs. It follows that this well may be considered as a preferential point for volcanic activity monitoring, both in the case of normal routine surveillance and in the case of inaccessibility to the crater area.     

PCBs in fish from the southern Baltic Sea: levels, bioaccumulation features, and temporal trends during the period from 1997 to 2006

Levels of seven marker polychlorinated biphenyls (PCBs) have been determined in five species of Baltic fish collected during 1997-2006. Downward time trends in the concentrations of heavier congeners of PCBs in different Baltic fish, with the exception of cod, have been observed between 1997 and 2001. In case of sprat and herring samples, the statistical significance of the time trends of the PCBs: 101, 118, 153, 138 and 180 concentrations has been proved. Species-specific bioaccumulation of PCBs has been indicated, and the lowest and highest levels of PCBs (expressed on the basis of lipid weight) have been observed in sprat and salmon samples, respectively. PCB profiles have been found to be similar in all the fish species tested. Sampling location has not been a crucial factor for the observed levels of various PCBs. In some fish species, PCB concentrations are negatively correlated with the fat content but have no relation with the fish length.     

Organochlorine pesticides in fish from the southern Baltic Sea: levels, bioaccumulation features and temporal trends during the 1995-2006 period

The levels of HCH isomers, HCB and summation DDTs were determined in five species of Baltic fish collected during 1995-2006. Some downward time trends of HCH isomer, pp'-DDE and pp'-DDD concentrations in Baltic fish were observed; in contrast, HCB and DDT concentrations did not exhibit any obvious trend. Concentrations of summation HCHs expressed on a lipid weight basis were very similar in all species studied. In contrast, concentrations of summation DDTs varied in tested species. The most abundant HCH isomer was beta-HCH and among DDT-related compounds, pp'-DDE prevailed. In our investigations the sampling sites were not a crucial factor for organochlorine pesticide concentrations and patterns observed in fish, but the occurrence of several inter-species differences in the bioaccumulation features of OC pesticides were observed. For cod there was a positive correlation between fish size (length) and summation DDT concentration. In herring, sprat and salmon samples, summation DDT concentrations were negatively correlated with fat content.     

Human activity during the late Pleistocene in the Lop Nur region,northwest China: Evidence from a buried stone artifact

The Lop Nur region, in the east part of Tarim Basin, was an important transportation junction between west and east, north and south Eurasia. However, previous studies on prehistoric human activity have concentrated mostly on the Bronze Age, whereas that during the Stone Age remains largely unresearched. Here, we present a new direct evidence of human activity in the late Pleistocene, recorded on a grinding stone buried in a lacustrine sediment section of the Lop Nur region. The grain size distribution of the sediment section indicates that the site was probably in the center of a lake with weak hydrodynamic environment. Therefore, the stone artifact can only be carried to here by people instead of river and it was never move as soon as left here. Results of radiocarbon dating, the evident stratigraphic relations between the stone artifact and the sedimentary formation, indicate that the human activity could extend to approximately 13 ka BP. Furthermore, the results of starch-grain and use-wear analyses suggest that ancient humans gathered seeds of Triticeae, roots, and tubers and used the grinding stone to simply process selected plant as plant foodstuffs during this period. It implies that the environmental conditions in the river delta of the Lop Nur were inhabitable during the late Pleistocene.     

Hg, Zn and Cu levels in the muscle and liver of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan: relationship between metal concentrations and body length

We analyzed Hg, Zn and Cu concentrations in the liver and muscle of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan. The Hg concentration in the muscle increased proportionally with body length in the tiger sharks, whereas that in the liver increased rapidly after maturity (defined by a length of over 2.7 m). Muscle Hg levels were higher than liver concentrations in immature sharks, with the inverse trend observed in mature sharks. Notably, the Zn and Cu concentrations in the liver tended to decrease with increasing body length. This rapid increase in hepatic Hg concentration concurrent with the onset of maturity in sharks may result from the continuous intake of Hg via food and the slower growth of mature sharks. The high concentrations of the essential metals Zn and Cu in immature sharks may be explained by the physiological demands related to rapid growth.