藏北羌塘中部戈木日榴辉岩的岩石学、矿物学及变质作用pTt轨迹

羌塘中部榴辉岩位于龙木错－双湖缝合带中段,改则县古姆乡片石山地区。榴辉岩的主要矿物成分为石榴子石、绿辉石、多硅白云母、金红石、角闪石等,围岩为石榴白云母片岩和蓝片岩,石榴白云母片岩主要由石榴子石、多硅白云母和石英构成,蓝片岩由石榴子石、角闪石（含蓝闪石）、多硅白云母等构成。岩石学和矿物学研究显示,榴辉岩主要经历了3期变质作用：①峰期榴辉岩相变质作用阶段,以石榴子石、绿辉石和多硅白云母为特征,变质温度和压力分别为500℃和2.3GPa;②绿帘角闪岩相变质作用阶段,以后期形成的冻蓝闪石、镁红闪石、绿帘石、钠长石等交代早期矿物为特征;③绿片岩相变质作用阶段,以毛发状阳起石等为特征。榴辉岩的变质演化过程代表了青藏高原北部古特提斯洋俯冲消减和冈瓦纳与劳亚大陆碰撞造山的过程。     

西藏羌塘中部榴辉岩岩石学、年代学及其构造演化过程

羌塘中部榴辉岩是2004年报道的青藏高原内部首例榴辉岩.榴辉岩出露于龙木错-双湖缝合带的中部,岩体呈透镜状、块状产在石榴白云母片岩和蓝片岩的高压变质带中,直接围岩为石榴白云母片岩.榴辉岩块体大小不一,大者可达数百米,小者仅几个厘米.主要矿物成分为:石榴子石、绿辉石、多硅白云母、角闪石、金红石、榍石、绿帘石、磷灰石、斜长石和石英等.     

新疆西南天山哈布腾苏河高压-超高压变质带中榴辉岩和蓝片岩的岩石学及变质演化

对西南天山哈布腾苏河一带出露的典型榴辉岩和蓝片岩进行了详细的岩相学、矿物化学和温压条件综合研究。榴辉岩可分为蓝闪石榴辉岩、钠云母榴辉岩、绿帘石榴辉岩和蓝闪石榴角闪岩(退变榴辉岩)4类,蓝片岩可分为含蓝闪石石榴白云母钠长片岩、石榴白云母蓝闪片岩和石榴白云母蓝闪石英片岩3类。新鲜榴辉岩主要矿物组合为石榴石+绿辉石+钠云母+绿帘石,退变榴辉岩则为石榴石+蓝闪石+角闪石;蓝片岩主要矿物组合为石榴石+蓝闪石+多硅白云母+钠云母+钠长石+石英。榴辉岩和蓝片岩中石榴石变斑晶均保存进变质生长环带,从核部到边部XMn和XFe降低,XMg和XCa升高,指示了升温进变质的演化过程。根据榴辉岩矿物共生组合、石榴石内部包体组合分布特征及传统地质温压计估算结果,确定榴辉岩经历了4阶段的变质演化:早期硬柱石蓝片岩相进变质阶段、峰期榴辉岩相变质阶段(t=543～579℃,p=1.5～1.6 GPa)、峰后绿帘蓝片岩相退变质阶段(t=～450℃,p1.0GPa)和晚期蓝闪绿片岩相退变质阶段(t400℃,p0.5 GPa)。利用p-T视剖面图计算的榴辉岩、蓝片岩峰期变质温压条件与传统地质温压计估算结果十分相近,其中榴辉岩的峰期变质条件t=520～550℃,p=1.7～1.9 GPa;蓝片岩峰期变质条件t=520～620℃,p=1.7～2.3 GPa。本文估算的榴辉岩峰期变质压力条件与前人根据柯石英的发现而认为研究区部分榴辉岩及其围岩曾经历超高压变质作用的认识明显相悖,原因可能如下:①后期退变质作用引起研究区榴辉岩全岩成分、矿物化学成分的调整,在采用Grt-Cpx-Phe温压计和以全岩成分为基础的相平衡模拟方法估算峰期温压条件时受到影响,从而使估算峰期压力条件普遍偏低;②西南天山的榴辉岩可能并非全都经历了超高压变质作用,高压、超高压榴辉岩可能分别代表了不同变基性岩块在不同俯冲深度变质的产物。     

青藏高原拉萨地块松多榴辉岩的岩相学特征和变质演化过程

松多榴辉岩出露于拉萨地块的石英片岩中,主要由较为基性的金红石榴辉岩和较为酸性的石英榴辉岩组成。榴辉岩相矿物组合为石榴子石 绿辉石 绿帘石±多硅白云母±石英±金红石。岩石发生了较强烈的退变质作用,退变质矿物有角闪石、绿帘石、石英、钠长石及绿泥石。石榴子石变斑晶具有生长环带结构,变斑晶和基质石榴子石主要落入C类榴辉岩区,少数石榴子石变斑晶边部和基质石榴子石落入B类榴辉岩区;单斜辉石主要为绿辉石,少数Ⅰ世代和Ⅲ世代为普通辉石;角闪石均为钙质角闪石。根据石榴子石-绿辉石-多硅白云母矿物温压计计算,获得的温压范围为630～777℃和2.58～2.70GPa,峰期变质条件接近于石英-柯石英转变线。榴辉岩的原岩经历了从高绿片岩相、角闪岩相、榴辉岩相、角闪岩相到高绿片岩相的变质过程,这反映了与古特提斯洋闭合有关的俯冲进变质作用和随后的折返退变质作用。     

滇西澜沧谦迈地区榴辉岩岩石学、矿物学特征及变质演化p-T轨迹

澜沧谦迈地区位于西南三江昌宁-孟连结合带中段。新近在该地区发现榴辉岩,与双江县勐库地区退变榴辉岩一样,谦迈地区榴辉岩也产于湾河蛇绿混杂岩带内,岩石新鲜,后期退变质作用改造弱,岩石学信息保留完整。主要矿物成分为石榴子石、绿辉石、多硅白云母、金红石、角闪石、绿帘石、石英等,直接围岩为白云(钠长)片岩和斜长角闪岩,白云(钠长)片岩主要由多硅白云母、石英和长石构成。根据岩石学和矿物学特征将谦迈地区榴辉岩划分为4个变质阶段,其中峰期矿物组合为石榴子石+绿辉石+多硅白云母+硬柱石+蓝闪石+金红石+石英。初步研究表明,峰期榴辉岩相变质温度和压力分别为600℃和2.5GPa。新发现的榴辉岩为研究三江地区特提斯构造演化提供了关键性资料,该榴辉岩变质演化p-T轨迹的研究对探讨古特提斯洋的俯冲-造山过程具有重要意义。     

昌宁-孟连杂岩带澜沧岩群的岩石学、地球化学和变质演化及其对古特提斯构造演化的启示

云南三江地区昌宁-孟连杂岩带中的澜沧岩群内出露多种类型变沉积岩,主要包括含十字蓝晶石榴云母片岩、石榴云母片岩、硬绿泥石白云母片岩和绿泥蓝闪钠长片岩等。系统的岩相学观察、矿物化学和相平衡模拟研究结果表明,不同类型的变沉积岩保存了不同的变质演化历史。含十字蓝晶石榴云母片岩记录了自中温榴辉岩相降温降压至角闪岩相的退变质过程,峰期矿物组合为石榴子石+蓝晶石+多硅白云母+硬玉,变质温压条件为600～750℃和19～30kbar。通过石榴子石的X_(Prp)和X_(Grs),和多硅白云母的Si值限定石榴云母片岩的峰期矿物组合包括石榴子石+多硅白云母+绿辉石+硬柱石+钠云母,峰期温压条件为430～475℃和17～19.5kbar。硬绿泥石白云母片岩矿物组成包括硬绿泥石+多硅白云母+钠云母,然而峰期矿物组合则以多硅白云母+钠云母+纤柱石为特征,通过多硅白云母的Si值限定峰期温压条件约为300～330℃和17～19kbar。石榴云母片岩和硬绿泥石白云母片岩较为一致地记录了从峰期硬柱石蓝片岩相升温降压至绿帘石蓝片岩相的退变质过程。绿泥蓝闪钠长片岩主要通过变质反应和成因矿物学特征大致估算其温压条件约为430～520℃和9～11kbar。岩石地球化学性质研究结果表明,这些变沉积岩的平均化学成分与大陆岛弧、活动大陆边缘和上地壳沉积物成分较为接近,其原岩主要为一套成熟度较差的泥砂质岩类和少量的中基性火山岩。该泥砂质原岩的沉积物源以中酸性岩浆岩为主,存在不同程度古老沉积物的加入。构造判别图解表明,研究区样品主要形成于大陆岛弧或活动大陆边缘的构造背景。变质作用特征和原岩地球化学属性综合分析表明,昌宁-孟连杂岩带内大面积分布的澜沧岩群均发生不同程度的俯冲-消减过程,表现出多样的变质演化P-T轨迹的特征,表明澜沧岩群经历了多期/多阶段复杂的构造演化历史。     

新疆西天山高压变质带的变质矿物与变质作用演化

新疆西天山高压变质带主要由石榴石，角闪石，绿辉石，多硅白云母，钠云母，绿帘石，绿泥石，钠长石，石英，榍石和金红石等组成，石榴石主要含铁铝榴石组份，角闪石有蓝闪石，亚铁蓝闪石，青铝闪石，冻蓝闪石等类型，变质矿物组合显示高压变质带经历了由硬柱石蓝片岩相，榴辉岩相，绿帘蓝片岩相至绿片岩相的变质作用演化进程。     

西大别造山带红安高压榴辉岩的变质相平衡研究

西大别造山带红安高压榴辉岩含有大量角闪石,被称为角闪石榴辉岩.其主要矿物组成为石榴子石、绿辉石、冻蓝闪石、石英和绿帘石,有时可见蓝闪石、多硅白云母和钠云母.该区高压榴辉岩引起很多学者的关注,但在峰期变质条件和矿物共生组合方面尚有争论.     

藏北羌塘中部高压变质带中石榴子石白云母片岩的岩石学和变质特征

羌塘中部的高压变质带位于龙木错-双湖-澜沧江板块缝合带之上,由榴辉岩、蓝片岩和石榴子石白云母片岩组成,其形成过程对探讨板块缝合带的构造演化具有重要意义。以其中的石榴子石白云母片岩为研究对象,通过岩相学研究并结合电子探针成分分析,认为石榴子石白云母片岩中的石榴子石具有多期次变质结晶的特征,保留了岩石多期次变质的信息。结合岩石组构特征,最终确定石榴子石白云母片岩至少经历了3期次的变质作用。第一、二期均为绿片岩相,当时岩石不具定向构造且未达到高压;第三期为低温高压蓝片岩相变质作用,与区域上蓝片岩的形成及榴辉岩的蓝片岩相退变质作用大体同时,该期变质变形作用形成了岩石的片理,最终成为石榴子石白云母片岩,变质作用时代为218Ma左右。     

藏北羌塘中部高压变质带中石榴子石白云母片岩的岩石学和变质特征

羌塘中部的高压变质带位于龙木错-双湖-澜沧江板块缝合带之上,由榴辉岩、蓝片岩和石榴子石白云母片岩组成,其形成过程对探讨板块缝合带的构造演化具有重要意义。以其中的石榴子石白云母片岩为研究对象,通过岩相学研究并结合电子探针成分分析,认为石榴子石白云母片岩中的石榴子石具有多期次变质结晶的特征,保留了岩石多期次变质的信息。结合岩石组构特征,最终确定石榴子石白云母片岩至少经历了3期次的变质作用。第一、二期均为绿片岩相,当时岩石不具定向构造且未达到高压;第三期为低温高压蓝片岩相变质作用,与区域上蓝片岩的形成及榴辉岩的蓝片岩相退变质作用大体同时,该期变质变形作用形成了岩石的片理,最终成为石榴子石白云母片岩,变质作用时代为218Ma左右。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案（1999/30/EC）,对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.