Distribution and pollution assessment of heavy metals in surface sediments in the Yellow Sea

Heavy metal concentrations in surface sediments at 56 stations during two cruises in the Yellow Sea in summer and winter, 2011 were analyzed by inductively coupled plasma-mass spectrometry. The pollution status was assessed via the Geoaccumulation index and Hankanson potential ecological risk index. Higher concentrations of heavy metals (except for Mn) were found in the central Southern Yellow Sea and the western Northern Yellow Sea. The higher contents of Mn were much closer to Shandong Peninsula. Correlation analyses indicated that Pb, Cu, Fe, Ni, Zn and Co probably had the same origin and were controlled by grain size and total organic carbon. Pollution assessment showed that most areas of the Yellow Sea were not or lowly contaminated with the exception of the northwest and south parts of the Southern Yellow Sea showing Cd-contamination. The pollution status of the Yellow Sea in summer was worse than that in winter.     

Sediment dispersal and deposition due to sand mining in the coastal waters of Korea

Understanding the impact of marine sand mining operations in a complex coastal environment requires a combined observational and modeling approach. Here, we use field measurements collected during mining operations in Kyunggi Bay, Korea to develop sediment parameters and source conditions for a three-dimensional (3D) sediment transport model built on the Regional Ocean Modeling System (ROMS). The model is run with realistic forcing obtained from a 9 km meteorological model, tides, and river discharges. The resulting vertical and horizontal distributions of sediment show encouraging agreement with the field data, demonstrating markedly different dispersal patterns due largely to the differential settling of the various sand classes. The resulting depositional patterns suggest that only the coarser size classes (500 and 250 μm) particles remain close to the mined site, while finer size classes are widely dispersed. These results suggest that this new methodology of multi-size class, 3D sediment transport modeling is quite promising, and further work is ongoing to include more realistic representation of sediment resuspension processes.     

Community composition, distribution, and contribution of microbenthos in offshore sediments from the Yellow Sea

We investigated the spatial distribution and composition of microbenthos in the seafloor sediments from 48 stations in the Yellow Sea using epifluorescence microscopy and quantitative protargol staining techniques. The bacterial abundance ranged from 2.4×10⁸ to 1.9×10⁹ cells cm⁻³ in the wet sediment, about three orders of magnitude higher than that of phototrophic (PNFs, from 6.4×10⁵ to 8.8×10⁶ cells cm⁻³) and heterotrophic nanoflagellates (HNFs, from 5.8×10⁴ to 5.9×10⁶ cells cm⁻³) and four orders of magnitude higher than that of cyanobacteria (from 2.3×10⁴ to 2.3×10⁶ cells cm⁻³) in the upper 5 cm of sediments. The abundance of diatoms varied greatly, from 3-1.1×10⁵ cells cm⁻³ in the upper 8 cm of sediments, whereas those of heterotrophic microflagellates (HMFs, 1-182 cells cm⁻³) and ciliates (1-221 cells cm⁻³) were less varied and lower. The biomass partitioning indicates the primary importance of benthic bacteria (50.3 μg C cm⁻³ on average), followed by PNFs (40.7 μg C cm⁻³), HNFs (19.3 μg C cm⁻³), and finally by cyanobacteria (8.8 μg C cm⁻³). Benthic diatoms (0.8 μg C cm⁻³), ciliates (0.15 μg C cm⁻³), and HMFs (0.03 μg C cm⁻³) contribute relatively small fractions to the total biomass of the microbenthos. About 95% of diatoms, 77% of ciliates, and 56% of HMFs were distributed in the upper 2 cm of sediments, whereas no distinct vertical distributions were observed for bacteria, cyanobacteria, PNFs, and HNFs. The microbenthos are quantitatively important in the shallow seafloor, wherein their main components have an average abundance three orders of magnitude higher than the corresponding planktonic organisms in the same sea area. Our estimates indicate that pico-sized phytobenthos might contribute a large proportion to the primary production. Benthic ciliates and heterotrophic flagellates contribute about 90% to the estimated combined metabolic rate of micro- and meiobenthic consumers in the whole sea area, with nanoheterotrophs accounting for the majority. The data suggest the potential for the rapid primary and secondary production of microbenthos and detrital utilization in the shallow seafloor sediments of the Yellow Sea.     

Metal (Al, Fe, Mn and Cu) distributions and origins of polycyclic aromatic hydrocarbons (PAHs) in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, total metal (Al, Fe, Mn and Cu) and PAHs analyses have been done in the surface sediments. Sediment samples have been collected from seven parts of the Marmara Sea and the coast of Istanbul during 2009. Total Al, Fe, Mn and Cu contents vary between 1.8% and 5.4%; 1.1% and 2.8%; 122 and 259 μg g⁻¹; 27 and 416 μg g⁻¹, respectively. EF and CF values of Fe and Mn are lower than 1.5 and 1, respectively, in all the stations. Total PAH contents range between 135 and 6009 ng g⁻¹ in the surface sediments. The origin of PAHs has been found pyrolitic according to the Phe/Ant ratio in the all stations. Contrastingly, at K0, MKC and MY1 Stations, PAH origins have been observed petrogenic according to the Flu/Pyr ratio.     

Modelling of hydrodynamics and cohesive sediment transport in Tanshui River estuarine system,Taiwan

A laterally averaged two-dimensional numerical model is used to simulate hydrodynamics and cohesive sediment transport in the Tanshui River estuarine system. The model handles tributaries as well as the main stem of the estuarine system. Observed time series of salinity data and tidally averaged salinity distributions have been compared with model results to calibrate the turbulent diffusion coefficients. The overall model verification is achieved with comparisons of residual currents and salinity distribution. The model reproduces the prototype water surface elevation, currents and salinity distributions. Comparisons of the suspended cohesive sediment concentrations calculated by the numerical model and the field data at various stations show good agreement. The validated model is applied to investigate the tidally averaged salinity distributions, residual circulation and suspended sediment concentration under low flow conditions in the Tanshui River estuarine system. The model results show that the limit of salt intrusion in the mainstem estuary is located at Hsin-Hai bridge in Tahan Stream, 26 km from the River mouth under Q75 flow. The null point is located at the head of salt intrusion, using 1 ppt isohaline as an indicator. The tidally averaged sediment concentration distribution exhibits a local maximum around the null point.     

Heavy metals in surface sediments from nine estuaries along the coast of Bohai Bay,Northern China

Concentrations of heavy metals in river water and sediment were investigated in nine estuaries along the coast of Bohai Bay, Northern China. Multivariate statistical techniques such as principal component analysis and cluster analysis, in combination with metal concentration analysis and correlation analysis, were used to identify the possible sources of the metals and the pollution pattern in nine estuaries along the coast of Bohai Bay. The environmental risks of metals, evaluated by sediment quality guidelines and background values, revealed Hg contamination in the estuaries. However, levels of Cd in estuarine sediments were low, and they were less than those levels in river sediments, partly due to the high mobility and dilution of river or seawater. Cd did not contribute to sediment deposits in estuaries. High organic matter from effluents from large municipal sewage treatment plants was predominantly responsible for restricting Hg mobility from the river to Bohai Bay.     

Multi-residues of organic pollutants in surface sediments from littoral areas of the Yellow Sea, China

Concentrations of all studied organic pollutants, except for DDTs, were greatest at sites in Dalian Bay, where surface sediment concentrations of PHCs, PAHs, PCBs and DDTs exceeded the corresponding ERL values. The sum concentration of DDTs was greatest in Haizhou Bay exceeding the related ERM value. In terms of compositions of PAHs and PAEs, the predominant components were the MMW and HMW compounds, DBP and DEHP, respectively. The main degradation product of p,p'-DDT was p,p'-DDD at most sampling sites. The principal sources of PAHs and DDTs involved various pyrolytic processes (i.e., combustion of biomass and vehicle exhaust), and application of technical DDT (in the form of impurity or raw material), and a mixture of technical DDT and technical dicofol. Moreover, the coastal site with greatest potential ecological risk from total PAHs was located in Dalian Bay, while the littoral areas of Dalian Bay, two harbor cities (Yantai-Weihai), Jiaozhou Bay, and Haizhou Bay, had relatively high potential risk from DDTs, especially in Haizhou Bay.     

Lateral dynamics and associated transport of sediment in the upper reaches of a partially mixed estuary,Chesapeake Bay,USA

Data from time series of transects made over a tidal period across a section of the upper Chesapeake Bay, USA, reveal the influence of lateral dynamics on sediment transport in an area with a deep channel and broad extents of shallower flanks. Contributions to lateral momentum by rotation (Coriolis plus channel curvature), cross channel density gradients and cross channel surface slope were estimated, and the friction and acceleration terms needed to complete the balance were compared to patterns of observed lateral circulation. During ebb, net rotation effects were larger because of river velocity and reinforcement of Coriolis by curvature. During flood, stratification was greater because of landward advection of strong vertical density gradients. Together, the ebb intensified lateral circulation and flood intensified stratification focused sediment and sediment transport along the left side of the estuary (looking seaward). The tendency for greater stratification on flood and net sediment flux toward the left-hand shoal are contrary to more common models which, in the northern hemisphere, predict greater resuspension on flood and move sediment toward the right-hand shoal. These tidal asymmetries interact with the lateral circulation to focus net sediment flux on the left side of the estuary, and to produce net ebb directed sediment transport at the surface of the same order of magnitude as net flood directed sediment transport at the bottom.     

Assessment of metal contamination in surface sediments from Zhelin Bay,the South China Sea

Metals and biogenic elements were analyzed from surface sediments collected from Zhelin Bay in the South China Sea in December 2008. The high concentrations of TOC, TN and BSi indicate the high nutrient level and diatom productivity in Zhelin Bay. The concentrations of metals were generally far lower than the effects-range-low (ERL) values that define pollutant levels. Enrichment factors (EF) and geoaccumulation indices (I_geo) suggest there are pollution levels of Cd, Cu and Zn at some stations. As, Cu, and Pb are potentially biotoxic in some stations. Correlation and principal component analyses indicate that most of the metals primarily originate from natural sources, and from maricultural activities as well. Mariculture contributes considerable Cd and Cu contamination. As and Pb comes primarily from combustion of gasoline and diesel fuel by ships.     

Regularity of sediment transport and sedimentation during floods in the lower Yellow River,China

The flood season is the main period of flow,sediment transport,and sedimentation in the lower Yellow River(LYR).Within the flood season,most of the flow,sediment transport,and sedimentation occurs during flood events.Because of the importance of floods in forming riverbeds in the LYR,the regularity of sediment transport and sedimentation during floods in the LYR was studied.Measured daily discharge and sediment transport rate data for the LYR from 1960 to 2006 were used.A total of 299 floods wer...     

Properties of suspended sediment in the estuarine turbidity maximum of the highly turbid Humber Estuary system, UK

Measurements are presented of the properties of suspended particulate matter (SPM) in the estuarine turbidity maximum (ETM) of the upper Humber and Ouse estuaries during transient, relatively low freshwater inflow conditions of September 1995. Very high concentrations of near-bed SPM (more than 100 g l⁻¹) were observed in the low-salinity (less than 1), upper reaches. SPM within the ETM consisted largely of fine sediment (silt and clay) that existed as microfloc and macrofloc aggregates and individual particles. Primary sediment particles were very fine grained, and typically, about 20–30% was clay-sized at high water. The clay mineralogy was dominated by chlorite and illite. There was a pronounced increase in particle size in the tidal river, up-estuary of the ETM. The mean specific surface area (SSA) of near-bed SPM within the ETM was 22 m² g⁻¹ on a spring tide and 24 m² g⁻¹ on a neap tide. A tidal cycle of measurements within a near-bed, high concentration SPM layer during a very small neap tide gave a mean SSA of 26 m² g⁻¹. The percentage of silt and clay in surficial bed sediments along the main channel of the estuary varied strongly. The relatively low silt and clay percentage of surficial bed sediments (about 10–35%) within the ETM’s region of highest near-bed SPM concentrations and their low SSA values were in marked contrast to the overlying SPM. The loss on ignition (LOI) of near-bed SPM in the turbid reaches of the estuary was about 10%, compared with about 12% for surface SPM and more than 40% in the very low turbidity waters up-estuary of the ETM. Settling velocities of Humber–Ouse SPM, sampled in situ and measured using a settling column, maximized at 1.5 mm s⁻¹ and exhibited hindered settling at higher SPM concentrations.     

Changes in sediment transport in the Kuye River in the Loess Plateau in China

In this paper, the changes in sediment transport over 51 years from 1955 to 2006 in the Kuye River in the Loess Plateau in China are assessed. Key factors affecting sediment yield and sediment transport, such as precipitation depth, discharge, and human activities are studied. To investigate the changes in sediment yield in this watershed, a trend analysis on sediment concentration, precipitation depth, and discharge is conducted. Precipitation depths at 2 Climate Stations （CSs）, as well as discharge and sediment transport at 3 Gauging Stations （GSs） are used to assess the features of sediment transport in the Kuye River. The rtmoff modulus （defined as the annual average discharge per unit area, L/（s·km^2）） and the sediment transport modulus （defined as the annual suspended sediment transport per unit area, t/（yr km^2）） are introduced in this study to assess the changes in runoff and sediment yield for this watershed. The results show that the highest average monthly discharge during the study period in the Kuye River is 66.23 m^3/s in August with an average monthly sediment concentration of 88.9 kg/m^3. However, the highest average monthly sediment concentration during the study period in the Kuye River is 125.34 kg/m^3 and occurs in July, which has an average discharge of 42.6 m^3/s that is much less than the average monthly discharge in August. It is found that both the runoff modulus and sediment transport modulus at Wenjiachuan GS on the Kuye River has a clear downward trend. During the summer season from July to August, the sediment transport modulus at Wenjiachuan GS is much higher than those at Toudaoguai and Longmen GSs on the Yellow River. The easily erodible loess in the Kuye River watershed and the sparse vegetation are responsible for the extremely high sediment yield from the Kuye River watershed. The analyses of the grain size distribution of suspended load in the Kuye River are presented. The average monthly median grain size of suspended load in the Kuye River is largest in February and then decreases until June. In July, the average monthly median grain size of suspended load approaches another peak and decreases until September. Then, the median grain size of suspended load starts to increase until February of the following year. However, the average monthly median grain size of suspended load in the Yellow River at Toudaoguai and Longmen GSs is the smallest between early summer and late fall The median grain size in the Yellow River starts to increase in November and approaches the largest size in January.     

Occurrence and distribution of microplastics in marine sediments along the Belgian coast

Plastic debris is known to undergo fragmentation at sea, which leads to the formation of microscopic particles of plastic; the so called ‘microplastics’. Due to their buoyant and persistent properties, these microplastics have the potential to become widely dispersed in the marine environment through hydrodynamic processes and ocean currents. In this study, the occurrence and distribution of microplastics was investigated in Belgian marine sediments from different locations (coastal harbours, beaches and sublittoral areas).Particles were found in large numbers in all samples, showing the wide distribution of microplastics in Belgian coastal waters. The highest concentrations were found in the harbours where total microplastic concentrations of up to 390 particles kg⁻¹ dry sediment were observed, which is 15-50 times higher than reported maximum concentrations of other, similar study areas.The depth profile of sediment cores suggested that microplastic concentrations on the beaches reflect the global plastic production increase.     

Assessment of reservoir sedimentation effect on coastal erosion in the case of Nestos River,Greece

Coastal erosion that is generated by the reduction of the annual sediment yield at river outlets, due to the construction of reservoirs, constitutes one of the main environmental problems in many parts of the world. Nestos is one of the most important boundary rivers, flowing through Bulgaria and Greece, characterized by its great biodiversity. In the Greek part of the river, two reservoirs, the Thisavros Reservoir and the Platanovrysi Reservoir, have already been constructed and started operating in 1997 and 1999, respectively. The present paper constitutes the first attempt where the assessment of reservoir sedimentation effect on the coastal erosion for the case of the Nestos River delta and the adjacent shorelines is addressed in detail, through mathematical modeling, modem remote sensing techniques and field surveying. It is found that the construction and operation of the considered reservoirs have caused a dramatic decrease （about 83%） in the sediments supplied directly to the basin outlet and indirectly to the neighbouring coast and that this fact has almost inversed the erosion/accretion balance in the deltaic as well as the adjacent shorelines. Before the construction of the reservoirs, accretion predominated erosion by 25.36%, while just within five years after the construction of the reservoirs, erosion predominates accretion by 21.26%.     

Sponges and sediments as monitoring tools of metal contamination in the eastern coast of the Red Sea, Saudi Arabia

Sediments and sponges were collected from various locations along the eastern coast of the Red Sea, the Kingdom of Saudi Arabia. Total concentrations of Cd, Zn, Ag, Cu, Pb, As and Hg in the sediments were measured. Metal contamination was not significant in most of the studied sites and only one site was moderately polluted by Zn, Cu, and Pb. Sponges accumulated specific metals readily even though the metal exposure was low in the ambient environment. Contrasting interspecies differences in metal accumulation patterns were observed among the nine collected species of sponges. Significant positive correlations were found between the metal concentrations in the two species of sponges collected from the same sites. The strong ability to accumulate specific metals and the diversity of sponges that live in the Red Sea coastal areas make them a promising biomonitor of metal contamination in the areas.     

The influence of tides, wind and waves on the net sand transport in the North Sea

Large-scale redistribution of sand by hydrodynamical processes in shelf seas is important for basin and coastal evolution on time scales of a thousand to tens of thousands of years. The influence of tides on the large-scale net sand-transport patterns in the North Sea has received much attention, but the influence of wind-driven flow and wind waves has hardly been investigated. Here, to establish the present-day situation and to develop a method that can also be used for palaeo-situations and forecasts for different sea levels, this influence is assessed for the present southern North Sea using a numerical flow model, a parametric wave model and a wave-averaged sand-transport formulation. Various forcing combinations are used to identify the dominant transport mechanisms: tides only, tides and wind, tides and waves, and combined tides, wind and waves. Wind forcing is applied in two ways to find an efficient, but still representative, method of incorporating this stochastic process: a statistical wind climatology and an observed time series. The results show that (i) the wind climatology yields a good approximation of the sand transport computed using the time series; (ii) wind-driven flow and waves only contribute significantly to the net sand transport by tides when acting together where tidal currents are small; and (iii) various combinations of forcings dominate the net sand transport in different regions of the southern North Sea: (a) tides dominate in the southern, middle and northwestern parts of the Southern Bight and in the region of The Wash; (b) tides, wind-driven flow and waves all are important in the northeastern part of the Southern Bight; and (c) wind-driven flow and waves dominate north of the Friesian Islands, in the German Bight and on the Dogger Bank. Qualitative comparison with observations shows good agreement.     

Physiological disturbance of the Manila clam,Ruditapes philippinarum,by altered environmental conditions in a tidal flat on the west coast of Korea

To examine the influence of habitat alteration by tideflat reclamation on the physiological ecology of Ruditapes philippinarum, seasonal variations in its condition, gross biochemical composition, and reproductive cycle were compared for a yearly cycle between a reclaimed flat (Gomsohang, GS) and a natural flat (Hajun, HJ) in Gomso Bay, Korea. Concentrations of chlorophyll a and seston (as well as its energy value as food available to the clam) were consistently higher at HJ than at GS. Condition, dry tissue weight, and energy reserves (proteins and carbohydrates) of the clams were much higher at HJ than at GS during spring–summer, when fast growth and gametogenic development occur. Furthermore, their spring gametogenic development and spawning were advanced at HJ compared with GS. Our results suggest that the Manila clam encounters nutritionally stressful environmental conditions in altered habitats after tideflat reclamation that lead to lowered nutrient accumulation and a changing reproductive cycle.     

Latitudinal distribution of iodine in sediments in the Chukchi Sea and the Bering Sea

Iodine is a trace element playing an important role in vital activities of organisms. It is im-portant for human bodys thyroid gland. Deficient or excessive iodine will not only influence hu-man health but also cause feeblemindedness, so great attention h…     

Suspended sediment transport in the Gulf of Lions (NW Mediterranean): Impact of extreme storms and floods

In situ observations were combined with 3D modeling to gain understanding of and to quantify the suspended sediment transport in the Gulf of Lions (NW Mediterranean Sea). The outputs of a hydrodynamic–sediment transport coupled model were compared to near-bottom current and suspended sediment concentration measurements collected at the head of seven submarine canyons and at a shallow shelf site, over a 6-month period (November 2003–May 2004). The comparisons provide a reasonable validation of the model that reproduces the observed spatial and time variations. The study period was marked by an unusual occurrence of marine storms and high river inputs. The major water and sediment discharges were supplied by the Rhone, the largest Mediterranean river, during an exceptional flood accompanying a severe marine storm in early December 2003. A second major storm, with moderate flooding, occurred in February 2004. The estimate of river input during the studied period was 5.9 Mt. Our study reveals (i) that most of the particulate matter delivered by the Rhone was entrapped on the prodelta, and (ii) that marine storms played a crucial role on the sediment dispersal on the shelf and the off-shelf export. The marine storms occurring in early December 2003 and late February 2004 resuspended a very large amount of shelf sediment (>8 Mt). Erosion was controlled by waves on the inner shelf and by energetic currents on the outer shelf. Sediment deposition took place in the middle part of the shelf, between 50 and 100 m depth. Resuspended sediments and river-borne particles were transported to the southwestern end of the shelf by a cyclonic circulation induced by these onshore winds and exported towards the Catalan shelf and into the Cap de Creus Canyon which incises the slope close to the shore. Export taking place mostly during marine storms was estimated to reach 9.1 Mt during the study period.     

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of the Hormuz strait,Persian Gulf

The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the sediment from the Hormuz strait, Persian Gulf. The sum of 16 PAHs (ΣPAH) concentrations varied from 72.17 to 277.77 ng g⁻¹ dry weight, with an average value of 131.20 ± 59.29 ng g⁻¹ dry weight. An ecological risk assessment of PAHs, indicated that adverse biological effects caused by acenaphthene and acenaphthylene occasionally may take place in the sediment of Hormuz strait. PAH source identification showed that the PAHs in the sediments come from pyrogenic and mixed origin. Based on classification of pollution levels, sediments from Hormuz strait could be considered as low to moderately polluted with PAHs.