1996 COMPILATION OF ANALYTICAL DATA ON NINE GSJ GEOCHEMICAL REFERENCE SAMPLES, "SEDIMENTARY ROCK SERIES"

Analytical data compiled on nine Geological Survey of Japan (GSJ) reference samples, "Sedimentary rock series" received by February 1996 are reported. After excluding outliers and examining critically the analytical procedures employed, the data were evaluated statistically. Recommended or preferable values for fifteen major and sixty minor and trace elements are proposed.     

1988 COMPILATION OF ELEMENTAL CONCENTRATION DATA FOR USGS AGV-1, GSP-1 AND G-2

Concentration data on up to 90 individual constituents in USGS AGV-1, GSP-1, and G-2 have been collected from 1270 journal articles and technical reports. These data are summarized in consensus (mean) values with uncertainties expressed as +/- one standard deviation. Mean values are also calculated as a function of analytical procedure and all raw data are given in the tables. Recommended values are proposed based upon data criteria used by NIST (National Institute of Standards and Technology, formerly the National Bureau of Standards or NBS).     

1994 COMPILATION OF ANALYTICAL DATA FOR MINOR AND TRACE ELEMENTS IN SEVENTEEN GSJ GEOCHEMICAL REFERENCE SAMPLES, "IGNEOUS ROCK SERIES"

Analytical data for minor and trace elements published or communicated to us, on seventeen GSJ (Geological Survey of Japan) reference samples, "Igneous rock series" received up to April 1994 are compiled. The data were evaluated statistically in consideration of analytical methods. Based on the selected available data, 1994 recommended and proposed values for 65 minor and trace elements are presented.     

DATABASE ON INTERNET FOR GEOLOGICAL SURVEY OF JAPAN GEOCHEMICAL REFERENCE SAMPLES

A database on thirty-one Geological Survey of Japan (GSJ) geochemical reference samples has been set up on Internet which allows the retrieval of recommended or preferable values, compiled data, location, sample preparation and other relevant information. The URL location on WWW server is: http://www.aist.go.jp./RIODB/geostand/welcome.html     

ELEMENTAL CONCENTRATIONS IN NINE NEW JAPANESE ROCK REFERENCE SAMPLES

Twenty-eight major, minor and trace elements in nine new rock reference samples of Geological Survey of Japan (GSJ), JA-2, JA-3 JB-1a, JG-1a, JG-2, JG-3, JF-1, JF-2 and JP-1 have been determined using atomic absorption spectrometry, flame emission spectrometry and wet chemical techniques.     

GOLD IN TWENTY-SIX JAPANESE GEOCHEMICAL REFERENCE SAMPLES

Gold has been determined in 26 geochemical reference samples with graphite furnace AAS after digesting the samples with aqua regia and hydrofluoric acid and extracting gold by methyl isobutyl ketone (MIBK). This method yields clearly higher values than those by the partial attack using aqua regia digestion.     

DETERMINATION OF PHOSPHOROUS IN FIFTY-NINE GEOCHEMICAL REFERENCE SAMPLES BY EXTRACTIVE SPECTROPHOTOMETRY

A digestion procedure with sequential use of HF-HCl and HNO₃-HClO₄ involving yellow vanadium molybdophosphate complex and its extraction into isobutylmethylketone (IBMK) has been employed for estimation of phosphorus in 59 geochemical reference samples. The agreement between the results obtained from IBMK-extraction and the recommended values has been found to be better than those available from the usual procedures (i.e., estimation in the aqueous phase).     

中国大陆地区大地热流数据汇编

大地热流是地球内热在地表最为直接的显示,并能给出发生于地球内部深处各种作用过程间能量平衡的信息,因而日益引起地球科学界的广泛兴趣和普遍关注。我国大地热流研究始于60年代,易善锋(1966)曾报道过东北中生代盆地的三个热流数据。1979年,中国科学院地质研究所地热组正式公布了我国第一批大地热流数据25个。近十年来,不同单位和作者在华北、东北、攀西、西藏等地区又先后获得了一批热流数据。最近,本文第一作者受国际热流委员会的委托,负责将我国大陆地区热流数据进行汇总并作统计分析,以便纳入“世界热流数据汇编”。     

DETERMINATION OF TOTAL NITROGEN AND CARBON IN TWENTY-TWO SEDIMENTARY ROCK REFERENCE SAMPLES BY COMBUSTION ELEMENTAL ANALYZER

Total nitrogen and carbon have been determined in 22 sedimentary rock reference samples by combustion elemental analyzer. Satisfactory agreement is observed between the present study and the published values but much more data for nitrogen are required for better comparisons.     

DETERMINATION OF FLUORINE, CHLORINE, BROMINE AND IODINE IN SEVEN GEOCHEMICAL REFERENCE SAMPLES

The concentrations of fluorine, chlorine, bromine and iodine of seven geochemical reference samples have been determined. Analytical techniques were neutron activation analysis for chlorine, bromine and iodine and ion-selective potentiometry for fluorine. After irradiation of the samples, these halogens were separated from the matrix elements by pyrohydrolysis in presence of vanadium (V) oxide. This extraction allows to measure the four halogens in the same sample.     

化探数据处理的新技术

本文论述了一种新的空间点数据处理系统（ＮＡＳＳＤ）在化探数据处理扣的应用效果，以ＮＡＳＳＤ处理平均采样密度为每１５０００ｋｍ＾２一个，样品总数为５２９个泛滥平原沉积物数据，制作 的中国铜和银地球化学图，可以较清晰地指示出中国已知大型，超大型铜和银矿床的分布，以传统的数据处理方法无论是处理上述的极低密度采样数据处理还是每１ｋｍ＾２～５０ｋｍ＾２一个的区域水系沉积物测量数据，在制作（以相同含量间隔表示     

浙江左溪石英闪长岩成因的元素地球化学证据

左溪石英闪长岩赋存于浙江绍兴-江山断裂带中,其平均化学成分近似于出露在其北西侧的元古界双溪坞群;不同岩性的元素含量及比值具有线性演化关系,相似于不均一的二元混合物。对造岩元素及稀土元素含量的模拟计算表明:双溪坞群50%部分熔融的熔体相与残留相按不同混合比组成的混合相,相当于岩体中的不同岩性。因此,“部分熔融-不均一混合”的模型可以较好地解释岩体所具有的元素地球化学特征。     

ELEVEN GOLD GEOCHEMICAL REFERENCE SAMPLES (GAU 8–18)

Eleven gold geochemical reference samples, GAu 8–18, have been prepared by the Institute of Geophysical and Geochemical Exploration, People's Republic of China. The concentration range of gold in these samples is from 0.5 ng/g to 10 μg/g. Fifteen Chinese Institutes, experienced in gold analysis of geological samples, have participated in the certification procedure using seven reliable analytical methods.     

海上油气化探沉积物样品测试技术

介绍了国内海上油气化探沉积物样品中烃类指标的检测技术现状,涉及样品的采集、轻烃和重烃的检测技术以及现场分析测试技术.分析了目前所存在的主要问题,并探讨了今后海上油气化探沉积物样品中烃类指标检测技术的发展方向.     

地质标准物质的研制方法

地质标准物质作为地质材料成分分析的计量标准,在分析质量监控、方法评价等方面发挥着越来越重要的作用.研制与应用地质标准物质是推动地质分析技术与方法发展必不可少的重要工作.通过介绍地质标准物质的研制过程和技术方法,重点讨论了地质标准物质的样品加工制备、均匀性检验、稳定性检验及定值等方面的标准要求及技术方法.     

区域土壤环境地球化学研究——异常成因判别·环境质量·污染程度评价的思路与方法

从概念内涵和应用目标出发,认为土壤环境地球化学质量评价应该分为质量现状和污染程度两个方面.在此基础上探讨了区域地球化学资料在土壤环境现状质量评价、异常成因识别、污染元素累积速率和土壤污染程度评价研究的基本思路和方法.     

DETERMINATION OF MERCURY IN ONE HUNDRED AND EIGHTEEN GEOCHEMICAL REFERENCE SAMPLES BY COLD VAPOR ATOMIC ABSORPTION SPECTROMETRY

The mercury content of 118 geochemical reference samples have been determined by combustion followed by cold vapor atomic absorption spectrometry. The negative interference from volatile halogen and sulfur was eliminated by a packing of sodium carbonate in the combustion tube and addition of magnesium oxide to the samples. A comparison with published data show clearly the need for much more data on most reference samples.     

地球化学样品中钡的物相分析

为了更好地论证钡作为寻找石碌式铁矿的指示元素，需要研究其赋存状态。通过了解易溶状态，硫酸盐及硅酸盐状态的钡，可知岩石形成是属于正常沉积还是火山沉积，从而确定矿物或矿床的成因，说明矿与指示元素的关系，为解释化探异常提供一定的依据。     

ELEMENTAL CONCENTRATIONS IN TWENTY NIST STANDARDS OF GEOCHEMICAL INTEREST

Data are presented for twenty standard reference materials currently available from the USA's National Institute of Standards and Technology (NIST) that are of use in geochemical analyses. Some of these standards have not been previously presented in the geochemical literature and many elements'concentrations are reported here for the first time. Instrumental neutron activation analysis, X-ray fluorescence, colorimetry, and coulometry were employed to obtain results on ten major and thirty-eight trace element concentrations as well as H2O+ and H2O-. Error bars for the analyses as well as consensus values from the literature are presented and generally good agreement are obtained for the available values.