Paleogeography of the Laptev Sea eastern shelf in the first half of Holocene based on faunal and palynological evidence

The Holocene paleogeography of the Laptev Sea eastern shelf is reconstructed based on mollusks, foraminifers, ostracodes, spores and pollen found for the first time. Environmental changes in the course of the postglacial (Holocene) transgression are detectable from quantitative analysis of three ostracod assemblages. Three phases of the transgression are established based on ostracode assemblages from the AMS ¹⁴C-dated core from the ancient valley of Yana River, central part of the Laptev Sea eastern shelf. After the first phase of coastal brackish-water environment (11.3–11.1 ka), shallow-water marine taxa appeared in the transitional phase (11.1–10.3 ka), and the third phase of modern sea conditions commenced 10.3 ka ago. Spore and pollen assemblages from the core indicate that the early Holocene land vegetation was dominated by tundra plant communities adapted to climatic conditions not warmer than at present. In the interval of 9.3–8.0 ka, climate was increasingly humid and warm, and forest-tundra vegetation occupied more favorable zones of the region.     

Sources of organic carbon in the Portuguese continental shelf sediments during the Holocene period

Organic C (OC) and total N (TN) concentrations, and stable isotope ratios (δ¹³C) in muddy deposit sediments of the Northern and Southern Portuguese continental shelf were used to identify sources of fine-sized organic matter (<63 μm) during the Holocene period. Sedimentary columns off the Guadiana (core CRIDA 05), Tagus (core MD 992332) and Douro (core KSGX 57) estuaries are characterised by elemental and isotopic values that reflect distinct sources of organic matter (OC/TN and δ¹³C ranging, respectively, from 8.5 to 21 and from −22.4‰ to −27‰). Intense supplies to the Guadiana continental shelf of fine terrigenous particles during the Younger-Dryas Event are closely linked with higher OC/TN values and lower δ¹³C ratios. During the postglacial transgression phase, an increasing contribution of marine supplies (up to 80%) occurred. Higher δ¹³C (up to −22.4‰) values and low OC/TN ratios (down to 8.5) are found as the sea level approaches the current one. The Upper Holocene records emphasize the return to enhanced terrestrial supplies except for the Little Climatic Optimum between the 11th and 15th centuries AD. This climatic event is especially obvious in the three cores as a return to marine production and a decrease in terrestrial sediment supply to the continental shelf. The return to a cooling event, the Little Ice Age, between the 15th and 19th centuries AD, is mirrored by decreased terrigenous supplies in core KSGX 57. Gradually increasing sedimentation in estuaries, as well as formation of coastal dune fields, have been hypothesized on the basis of increasing δ¹³C and decreasing OC, TN and OC/TN values.     

Seasonal and interannual variability of Siberian river discharge in the Laptev Sea inferred from stable isotopes in modern bivalves

Stable oxygen and carbon isotope profiles from modern bivalve shells were investigated in order to reconstruct short-term hydrographical changes in the river-shelf system of the Laptev Sea. Oxygen isotopic profiles obtained from the aragonitic species Astarte borealis exhibit amplitude cycles interpreted as annual hydrographical cycles. These records reflect the strong contrast between summer and winter bottom water conditions in the Laptev Sea. The seasonal variations in δ¹⁸O are mainly controlled by the riverine freshwater discharge during summer with 0.5‰ per salinity unit. Corrected for a defined species-dependent fractionation offset of -0.37‰, time-dependent salinity records were reconstructed from these δ¹⁸O profiles. They indicate a good correspondence to seasonal hydrographic changes and synoptical data. Persistent trends with shell growth towards more negative δ¹³C values are observed in all specimens and appear to be related to metabolic changes of the bivalves during ontogeny. In contrast, short-term fluctuations are likely linked to seasonal variabilities of the river water outflow patterns and enhanced phytoplankton productivity during summer. This is corroborated by a clear watermass-related distinction of the various δ¹³C records made on the basis of water depth and distance from the riverine source.     

Depositional environment of the Laptev Sea (Arctic Siberia) during the Holocene

The Holocene depositional setting of the Laptev Sea was studied using three marine sediment cores from water depths between 77 and 46 m. Based on sedimentary parameters (TOC content, δ¹³C_org, sedimentation rates) controlled by radiocarbon age models the palaeoenvironment of a strongly coupled river-shelf system was reconstructed since ˜11 ka BP. Caused by a transgressing sea after the last glaciation, all cores reveal progressive decreases in sedimentation rates. Using the sedimentary records of a core from the Khatanga-Anabar river channel in the western Laptev Sea, several phases of change are recognized: (1) an early period lasted until ˜10 ka BP characterized by an increased deposition of plant debris due to shelf erosion and fluvial runoff; (2) a transitional phase with consistently increasing marine conditions until 6 ka BP, which was marked at its beginning near 10 ka BP by the first occurrence of marine bivalves, high TOC content and an increase in δ¹³C_org; (3) a time of extremely slow deposition of sediments, commencing at ˜6 ka BP and interpreted as Holocene sea-level highstand, which caused a southward retreat of the depositional centres within the now submerged river channels on the shelf; (4) a final phase with the establishment of modern conditions after ˜2 ka BP.     

The Variation of Soil Organic Matter in a Forest-Cultivation Sequence Traced by Stable Carbon Isotopes

On the basis of different photosynthetic pathways.there is an obvious difference in δ^13C values between C3 and C4 plants,In terms of this characteristic,we analyzed the organic carbon content (forestlands:1.81%-16.00%;farmland:0.45%-2.22%) and δ^13C values(forestlands:-23.86‰--27.12‰;farmland:-19.66‰--23.26‰)of three profile-soil samples either in farmland or in forestland near the Maolan Karst virgin forest,where there were developed plant C3 plants previously and now are C4 plants.Results showed that the deforestation has accelerated the decomposition rate of soil organic matter and reduced the proportion of active components in soil organic matter and thus soil fertility.     

Stable carbon and oxygen isotopes distribution in carbonates from the Central Barents Sea shelf sediments

Carbonate macrofaunal remains and diagenetic tubes collected from a number of structures in the Central Barents Sea area during the 18th TTR (Training Through Research) cruise were subdivided into three groups according to the results of stable carbon and oxygen isotopes analysis. The first group includes carbonates that were formed from bicarbonate only from surrounding sea waters. The carbonates of the second group were formed during diagenesis with use of mixed sources of bicarbonate. The fourth group includes methane-derived carbonates that were formed as a result of anaerobic oxidation of methane (AOM).     

The dynamics of organic matter in soil size and density fractions traced by stable carbon isotopes

1IntroductionSoilorganicmatter (SOM)isakeysourceofnutrientsforplantgrowth ,itisessentialforthemaintenanceofsoilstructureanditcontributestotheabilityofsoiltoretainnutrientsandwater.AnimprovedunderstandingofSOMdynamicsiscentraltothedevelopmentofmoreenvironmentallysoundandsustainablepracticesofagriculturalmanagement (Collinsetal.,2 0 0 0 ) .Avarietyofcon ceptualmethodshavebeenusedtodescribetheprocessesofSOMaccumulationandturnover (Jen kinsonandRayner,1 977;Duxburyetal.1 989;Partonetal.,1 99…     

Anthropogenic CO2 in Southern Ocean surface waters: evidence from stable organic carbon isotopes

We present an approach for tracing the fate of anthropogenic CO₂, compiling a large data set of stable organic carbon isotope ratios from surface sediments, plankton, and sinking matter in the Atlantic Ocean. The δ¹³C values of sinking matter are generally lower by 0.5–4.6‰ compared to the surface sediments. This difference increases with increasing latitude, which is explained by a stronger modern increase in surface water [CO₂ (aq)] in the Southern Ocean relative to the Tropical/Subtropical Ocean. Preindustrial dissolved CO₂ concentrations in Atlantic surface waters, estimated from the δ¹³C_org of surface sediments, are compared to recently measured surface water [CO₂ (aq)] values taken from literature. We obtain only a slight increase in [CO₂ (aq)] at lower latitudes but a significant change of about 7 ± 2 μ m in high latitudinal surface waters which we attribute to anthropogenic perturbation. Our results suggest that CO₂ released by human activities has been stored in Southern Ocean surface waters.     

Paleoenvironmental changes in the northern shelf of the Sea of Okhotsk during the Holocene

The combined micropaleontological (spores and pollen, diatoms, benthic foraminifers), lithologic, and isotopic-geochemical analysis of sediments from the northern shelf of the Sea of Okhotsk recovered by hydrostatic corer from the depth of 140 mbsl elucidated environmental changes in this part of the basin and adjacent land areas during the last 12.7 thousands cal. years. Geochronological scale of the core is established using the acceleration mass-spectrometry method for radiocarbon dating of benthic Foraminifera tests. The first insignificant warming in the northern part of the sea after glaciation occurred in the mid-Boreal time (9.6 ka ago) but not at the onset of the Holocene. The strongest warming in the region took place in the mid-Atlantic epoch to reach climatic optimum in the second half of the Subboreal (6 to 2.5 ka ago). A cooling in the northern shelf and adjacent land areas is established at the beginning of the Subatlantic (2.5 ka). A comparison of results obtained for Core 89211 with dated hydrological and climatic changes in central and southern parts of the Sea of Okhotsk (Gorbarenko et al., 2003, 2004) is used for a high-resolution analysis of climatic fluctuations in the study region and other areas of the basin during deglaciation and the Holocene.     

Sediment transport to the Laptev Sea (Siberian Arctic) during the Holocene — evidence from the heavy mineral composition of fluvial and marine sediments

Heavy mineral studies of East Siberian river sediments, Laptev Sea surface sediments, and a sediment core of the western Laptev Sea were carried out in order to reconstruct the pathways of modern and ancient sediment transport from the Siberian hinterland to the Laptev Sea. The modern heavy mineral distribution of Laptev Sea surface sediments reflects mainly the riverine input. While the eastern and central part of the Laptev Sea is dominated by amphibole, which is supplied by the Lena River, the western part is dominated by pyroxene imported from the Siberian Trap basalts by the Khatanga River. The distribution of garnet and opaque minerals is additionally influenced by hydrodynamic processes. As a consequence of their high density, these minerals are predominantly deposited close to the river mouths. Heavy mineral and sedimentological studies of a sediment core of the western Laptev Sea were applied to reconstruct the postglacial history of the shelf area during the last 11 ka. In the lowermost interval of the core (> c. 10 ka), high accumulation rates and a heavy mineral composition similar to that of the modern Khatanga river indicate fluvial conditions. Additionally, the high mica content in this interval may indicate meltwater inflow from the Byrranga mountains. Strong variations in accumulation rates, grain-size distribution, and heavy mineral composition are observed in the time interval between c. 10 and 6 ka, which represents the main transgression of the Laptev Sea shelf. During the uppermost interval (<6 ka), rather stable conditions similar to the modem situation prevailed.     

Modern and Holocene hydrographic characteristics of the shallow Kara Sea shelf (Siberia) as reflected by stable isotopes of bivalves and benthic foraminifera

River discharge of Ob and Yenisei to the Kara Sea is highly variable on seasonal and interannual time scales. River water dominates the shallow bottom water near the river mouths, making it warmer and less saline but seasonally and interannually more changeable than bottom water on the deeper shelf. This hydrographic pattern shows up in measurements and modelling, and in stable isotope records (δ¹⁸O, δ¹³C) along the growth axis of bivalve shells and in multiple analyses of single benthic foraminiferal shells. Average isotope ratios increase, but sample-internal variability decreases with water depth and distance from river mouths. However, isotope records of bivalves and foraminifera of a sediment core from a former submarine channel of Yenisei River reveal a different pattern. The retreat of the river mouth from this site due to early Holocene sea level rise led to increasing average isotope values up core, but not to the expected decrease of the in-sample isotope variability. Southward advection of cold saline water along the palaeo-river channel probably obscured the hydrographic variability during the early Holocene. Later, when sediment filled the channel, the hydrographic variability at the core location remained low, because the shallowing proceeded synchronously with the retreat of the river mouth.     

Environmental changes in the eastern shelf of the Laptev Sea in the late-glacial time

Data on the interaction of the land-sea system have been obtained based on complex palynological analysis (pollen and spores of terrestrial plants and cysts of dinoflagellates and green algae) and the SEM analysis of sediments from boreholes drilled on the Laptev Sea’s eastern shelf and dated by the radiocarbon method. The spore and pollen ensemble revealed for the first time in late-glacial sediments of the boreholes indicates that warming which started within the time interval 15.6–10.7 ka ago was accompanied by short-term cooling events. Sedge and herb phytocoenosis predominated in the vegetation cover of East Arctic Siberia during the cooling. The climate warming favored the distribution of shrub birch tundra. The results of the analysis of organic-walled phytoplankton and the low value of the AH criterion indicate cold-water conditions with a longstanding ice sheet at sea. After the interval that ended 10.7 ka ago, thermophilic species of dinocysts appeared on the outer shelf, and the AH-criterion value increased, which suggests an active inflow of relatively warm North-Atlantic water to the shelf. Based on the comparison of the obtained results, an inference has been made about frequent changes of the climate in the region and the environment in the eastern part of the Laptev Sea during the deglaciation epoch.     

Ionic composition of pore water in shallow shelf deposits of the Laptev Sea

The cationic and anionic compositions of pore water in shallow deposits of Buor-Khaya Bay is studied. Significant concentration heterogeneity of the vertical ionic profile in the studied drill columns is shown. It is established that the vertical ionic profile of shelf deposits of the Laptev Sea is basically formed under the influence of thawing of underwater permafrost, hydrodynamic conditions, the water mass, and heat flows and depends on the lithological and granulometric types of the deposits. The highest concentrations of ions are registered in plant detritus represented by ground grass vegetation. A relationship between the ionic composition of pore water and cryogenic state of the sequence and its variability is demonstrated using the method of major components.     

东海陆架泥质区沉积有机质的物源分析

色谱和色谱／质谱分析表明，济州鸟西南泥质区正构烷烃、姥鲛烷、植烷、藿烷和甾烷等生物标志物的特征与现代长江口、老黄河口和新黄河口的河流沉积物均区别很大，该泥质区的沉积有机质主要来源于海洋低等生物（如细菌和藻类等）以及陆源高等植物的输入，表现为不同来源和成熟度的生物标志物的混合，同时该泥质区沉积有机质与矿物碎屑沉积物来源不尽相同。长江口泥质区正构烷烃高相对分子质量部分与长江口沉积物相似，正构烷烃和藿烷所反映的有机质成熟度高于现代长江和老黄河口沉积物，甾烷的成熟度与长江相仿而明显高于老黄河口沉积物。长江口泥质区的沉积有机质主要来源于长江输入的陆源高等植物碎片和海洋源的低等生物。东海陆架近岸与远端泥质区沉积有机质的物源很不相同。     

Burial of organic carbon and carbonate on inner shelf of the northern South China Sea during the postglacial period

Two vibrocores from the inner shelf off Hong Kong are investigated to compare the contents of organic and inorganic carbon in postglacial sediments. The compositions of organic elements and carbonate are highly variable in the core sediments, but overall drop within the compositional ranges of modern seabed sediments in the Zhujiang estuarine and its shelf area. The Holocene sediments in the inner shelf have never been subject to subaerial exposure and the organic matter and carbonate can be preserved well. The burial of carbon in river-dominated shelf environments is highly dependent on the river flux with time. Nevertheless, it is difficult to establish a simple relationship between carbon burial in sediments in relation to climatic changes of basin-wide scale due to complex controls of production, transport and deposition of organic matter and carbonate. Our study suggests that the organic carbon to nitrogen ratio can not reliably identify the sources of depositional organic matters because of selective decomposition of organic matter components during humification and sedimentation. Caution is therefore needed in using organic elemental compositions as indicators of organic matter sources and paleoenvironmental changes in the East Asian continental shelves where intense river-sea interaction and variable carbon flux in geologic record occur.     

The role of hydrology in annual organic carbon loads and terrestrial organic matter export from a midwestern agricultural watershed

Defining the control that hydrology exerts on organic carbon (OC) export at the watershed scale is important for understanding how the source and quantity of OC in streams and rivers is influenced by climate change or by landscape drainage. To this end, molecular (lignin phenol), stable carbon isotope, and dissolved organic carbon (DOC) data were collected over a range of flow conditions to examine the influence of hydrology on annual OC export from an 850 km² Midwestern United States agricultural watershed located in west central Indiana. In years 2002 and 2003, modeled annual DOC loads were 19.5 and 14.1 kg ha⁻¹yr⁻¹, while 71% and 85%, respectively, of the total annual OC was exported in flow events occurring during less than 20% of that time. These results highlight the importance of short-duration, high-discharge events (common in smaller watersheds) in controlling annual OC export. Based on reported increases in annual stream discharge coupled with current estimates of DOC export, annual DOC loads in this watershed may have increased by up to 40% over the past 50 years. Molecular (lignin phenol) characterization of quantity and relative degradation state of terrestrial OC shows as much temporal variability of lignin parameters (in high molecular weight dissolved organic carbon) in this one watershed as that demonstrated in previously published studies of dissolved organic matter in the Mississippi and Amazon Rivers. These results suggest that hydrologic variability is at least as important in determining the nature and extent of OC export as geographic variability. Moreover, molecular and bulk stable carbon isotope data from high molecular weight dissolved organic carbon and colloidal organic carbon showed that increased stream flow from the study watershed was responsible for increased export of agriculturally derived OC. When considered in the context of results from other studies that show the importance of flood events and in-stream processing of terrestrial organic carbon, our results show how hydrologic variability in smaller watersheds can reflect landscape-scale carbon dynamics in ways that cannot necessarily be measured at the outlets of large rivers due to multiple source signals and attenuated hydrology.     

全新世渭河流域植被演替对陆地生态系统碳储量的影响

陆地生态系统古碳储量演化历史既是理解过去区域碳循环过程的基础, 也是预测未来陆地碳库变化趋势的重要参照。以往由于实测记录的缺乏和现代碳循环模型应用的局限, 难于实现过去陆地碳库的准确重建。本研究通过地质时期86个点位的孢粉记录与古碳循环模型模拟的结合, 在定量化重建全新世渭河流域古气候参数空间格局的基础上, 模拟了自然植被时空演化过程及其陆地生态系统碳储量变化。结果表明, 全新世早期到中期, 流域森林面积覆盖度由34%增至63%, 导致陆地生态系统碳储量从2.48PgC增至3.40PgC; 全新世中期到晚期, 流域森林面积覆盖度降至20%, 陆地生态系统碳库储量随之减少了1.03PgC。空间上, 流域碳密度变化主要受控于植被类型的分布, 后者又与地貌条件密切相关。全新世中期全球增温情形下渭河流域森林植被大面积扩张和碳储量显著增加的结果, 预示着未来全球变暖背景下该流域陆地生态系统具有较强的碳汇潜力。

     

Composition and Flux of Holocene Sediments on the Eastern Laptev Sea Shelf, Arctic Siberia

A 467-cm-long core from the inner shelf of the eastern Laptev Sea provides a depositional history since 9400 cal yr. B.P. The history involves temporal changes in the fluvial runoff as well as postglacial sea-level rise and southward retreat of the coastline. Although the core contains marine fossils back to 8900 cal yr B.P., abundant plant debris in a sandy facies low in the core shows that a river influenced the study site until 8100 cal yr B.P. As sea level rose and the distance to the coast increased, this riverine influence diminished gradually and the sediment type changed, by 7400 cal yr B.P., from sandy silt to clayey silt. Although total sediment input decreased in a step-like fashion from 7600 to 4000 cal yr B.P., this interval had the highest average sedimentation rates and the greatest fluxes in most sedimentary components. While this maximum probably resulted from middle Holocene climate warming, the low input of sand to the site after 7400 cal yr B.P. probably resulted from further southward retreat of the coastline and river mouth. Since about 4000 cal yr B.P., total sediment flux has remained rather constant in this part of the Laptev Sea shelf due to a gradual stabilization of the depositional regime after completion of the Holocene sea-level rise.