Tube fossils from gossanites of the Urals VHMS deposits,Russia: Authigenic mineral assemblages and trace element distributions

The occurrence, types, morphology, and mineralogical characteristics of tube microfossils were studied in gossanites from twelve VHMS deposits of the Urals. Several types of tube microfossils were recognized, including siboglinids, polychaetes and calcerous serpulids, replaced by a variety of minerals (e.g. hematite–quartz, hematite–chlorite, carbonate–hematite) depending on the nature of the substrate prior to the formation of the gossanites. Colonial hematite tube microfossils (~ 150 μm across,1–2 mm long) are composed of hematitic outer and inner walls, and may exhibit a cellular structure within their cavities. Spherical forms are saturated with Fe-oxidizing bacteria inside the tubes – probably analogues of trophosomes. Colloform stromatolitic outer wall surfaces are characterized by the presence of numerous interlaced filaments of hematite (2–3 μm diameter, up to 1–2 mm long). Between tube microfossils, the hematitized cement contains bundles of hematitized filaments with structures similar to the hyphae of fungi. Hematite–chlorite tube microfossils are scattered in gossanites, mostly as biological debris. They are typically 30 to 300 μm in diameter and 1 to 5 mm long. The layered structure of their tube walls is characterized by hematite–quartz and chlorite layers. Abundant filamentous bacteria coated by glycocalix and chlorite stromatolite are associated with hematite–chlorite tubes. The carbonate–hematite tube microfossils (up to 300 μm across, 2–3 mm long) occur in carbonate-rich gossanites. The tubes are characterized by fine (~ 10 μm thick) walls of hematite and cavities dominated by relatively dark carbonate or hematite. Carbonates may be present both in walls and cavities. Stromatolite-like leucoxene or hematite–carbonate aggregates were also found in association with tubes. Randomly oriented filaments are composed of ankerite. Single filaments are composed of individual cells, typically smaller than 100 nm across, similar to that of magnetotactic bacteria.Three dimensional tomographic images of all types of tube microfossils demonstrate a clear wavy microlayering from outer and inner walls, which may reflect segmentation of the tube worms. The traces of burrowing or fragments of glycocalix with relict spheres are typical of tube microfossils from gossanites.The carbon isotopic composition of carbonates associated with tube microfossils from hematite–quartz, hematite–carbonate, and hematite–chlorite gossanites average − 7.2, − 6.8, –22.8‰, PDB, respectively. These values are indicative of a biogenic origin for the carbonates. The oxygen isotopic composition of these carbonates is similar in all three gossanite types averaging + 13.5, + 14.2, + 13.0‰ (relative to SMOW), and indicative of active sulfate reduction during the diagenetic (and anadiagenetic) stages of the sediments evolution. The trace element characteristics of hematite from tube microfossils are characterized by high contents of following trace elements (average, ppm): Mn (1529), As (714), V (540), W (537), Mo (35), and U (5). Such high contents are most likely the result of metal and metalloid sorption by fine particles of precursor iron hydroxides during the oxidation of sulfides and decomposition of hyaloclasts via microbially-mediated reactions.     

Significance of slope sediments layering on physical characteristics and interflow within the Critical Zone – Examples from the Colorado Front Range,USA

The subalpine to montane zones within the Critical Zone (CZ) of the Colorado Front Range, USA outside Pleistocene glaciation limits are characterized by the abundance of stratified and multilayered slope deposits exhibiting depths >1 m. Initial luminescence dating for the upper sediment layers in different profiles give last glacial ages ranging between 40 and 12 ka. A periglacial origin by solifluction is hypothesized for these slope deposits, which is corroborated by geomorphic and sedimentologic parameters. The stratified slope sediments have a strong influence on the physical and chemical properties as well as on soil forming processes in the CZ. Examples are provided for the sediment derived contribution of some elements and common clay minerals together and the great importance of slope sediments as barriers and pathways for the interflow that runs in sediment layers are shown.     

Particle shape effect on thermal conductivity and shear wave velocity in sands

This study presents the correlations between quantified shape parameters and geotechnical properties for nine sand specimens. Four shape parameters, sphericity, convexity, elongation and slenderness, were quantified with two-dimensional microscopic images with the aid of image processing techniques. An instrumented oedometer cell is used to measure compressibility, thermal conductivity and shear wave velocity during loading, unloading and reloading stages. As the particle shape inherently determines the initial loose packing condition, initial void ratio and shape parameters are well correlated with compressibility. The applied stress in soils increases the interparticle contact area and contact quality; round particles tend to achieve higher thermal conductivity and shear wave velocity during stress-induced volume change. Multiple linear regression is implemented to capture the relative contributions of involved variables, revealing that the thermal evolution is governed by the initial packing density and particle shape. The experimental observations underscore the predominant effect that particle shape has on the geomechanical and physical properties upon stress-induced soil behavior.     

Polycyclic aromatic hydrocarbon fingerprints in the Pichavaram mangrove–estuarine sediments,southeastern India

The sources and historical deposition of 16 polycyclic aromatic hydrocarbons (PAHs) were investigated in dated sediment cores from the Pichavaram mangrove–estuarine complex. The ΣPAH flux in mangrove and estuarine sediments was 0.064 ± 0.031 μg/cm²/yr and 0.043 ± 0.020 μg/cm²/yr, respectively. The PAH flux in sediments increased up-core, coinciding with rapid urbanization since the 1970s. The flux showed a decrease in recent years (since 1990), coinciding with less riverine discharge, and perhaps more effective implementation of environmental regulations. The sediments were dominated by low molecular weight PAHs, suggesting anthropogenic input. Ratios of specific PAH isomer pairs suggested a greater input of petrogenic vs. pyrogenic derived PAHs. Notably, the deposition of high molecular weight PAHs increase in mangrove surface sediments was due to lignite and firewood combustion. Because of their overall low concentration in sediments it is unlikely these PAHs pose an immediate ecological hazard.     

Frictional properties of megathrust fault gouges at low sliding velocities: New data on effects of normal stress and temperature

Friction data used in modelling studies of subduction zone seismogenesis are often poorly representative of in situ conditions. We investigated the influence of in situ effective stresses and temperatures on the frictional properties of (simulated) fault gouges, prepared either from Nankai ODP material or illite shale, at sliding velocities approaching those relevant for earthquake nucleation and SSEs. Biaxial (double direct shear) experiments were performed at room temperature, normal stresses of 5–30 MPa, and sliding velocities of 0.16–18 μm/s. All materials exhibited velocity strengthening under these conditions, along with an increase in the friction coefficient and slip hardening rate with increasing normal stress. Illite gouge showed increased velocity strengthening towards higher normal stresses. The effect of temperature was investigated by means of ring shear experiments on illite gouge at 200–300 °C, an effective normal stress of 170 MPa, a pore-fluid pressure of 100 MPa and sliding velocities of 1–100 μm/s. These experiments showed a transition from velocity strengthening to velocity weakening at ∼250 °C. Our results provide a possible explanation for the updip seismogenic limit within subduction zone megathrusts and imply an enhanced tendency for earthquake nucleation and SSEs at low effective normal stresses.     

Influence of humic acid on the sorption of pentachlorophenol by aged sediment amended with rice-straw biochar

Black carbon (BC), especially biochar, is a potential material for the remediation of hydrophobic organic compounds (HOCs) pollution in soils and sediments. Recent studies have reported that the adsorption capability of BC in sediment was reduced as time increased. It was hypothesised that this behaviour was caused by the presence of natural organic matter (NOM), but few systematic studies have examined the influence of NOM on the sorption ability of BC in sediment (S). The results of this study revealed that a humic acid (HA) coating changed the surface properties, blocked the micropores, and decreased the sorption capacity of rice-straw biochar (RBC) towards pentachlorophenol. With increasing aging time, the reductions in the sorption capacity of the S + RBC and S + HA + RBC systems occurred more rapidly than in the S + HA/RBC (HA-coated RBC) system, and the sorption curves became closer to that of the S + HA/RBC system, indicating that HA may play a primary role in reducing the sorption capacity of RBC in the sediment. With higher HA contents, the sorption capacity of the complex sediments was lower and decreased more rapidly.     

Holocene variability of the Southern Hemisphere westerlies in Argentinean Patagonia (52°S)

High-resolution analyses of allochthonous pollen input into crater lake sediments of Laguna Potrok Aike in the semi-arid Patagonian steppe reflect the variability of zonal wind intensities during the Holocene at 52° southern latitude. These indicators for Southern Hemisphere westerlies (SHW) strength vary on centennial timescales in concert with carbon/nitrogen (C/N) ratios and titanium (Ti) contents, interpreted as differential organic matter sources and minerogenic input to the sediment, respectively. The correlations underline a linkage between hydrological variability and west wind variability in Extra-Andean Patagonia. A shift to generally more intense SHW suggests intensification towards modern wind conditions at that latitude since 9.2 ka cal BP.     

Advection and diffusion determine vertical distribution of microbial communities in intertidal sediments as revealed by combined biogeochemical and molecular biological analysis

Porewater advection stimulates nutrient exchange and microbial activity in shallow marine sediments, whereas element cycling in deeper diffusion-dominated sediments is comparatively slow due to limited nutrient supply. We studied the vertical distribution of microbial communities and organic matter (OM) cycling in these contrasting porewater regimes down to 5 m depth at an intertidal flat of the southern North Sea. Archaea, Bacteria and Eukarya were targeted, combining intact polar lipid (IPL) analysis with qualitative and quantitative molecular biological techniques. The largely sandy section 1 of the core (<75 cm) is characterized by rapid burial of fresh marine OM and intense porewater advection. This supply fuels heterotrophic microbes, as evident from the ¹³C isotopic composition of total organic carbon and IPL derivatives. Major sources of OM are algae and cyanobacteria, as suggested by the elevated amount of eukaryotic 18S rRNA gene copies and phosphate-free IPLs. The relative abundance of most phospholipids remained largely constant over the entire core, except for diphosphatidylglycerol, which represented about half of total IPL abundance in the lower part of section 1 (>50 cm) and the diffusion-dominated section 2 (75–490 cm). This suggests bacteria adapting their membranes in response to increasing physicochemical stress and starvation in the nutrient limited, fine grained sediments of section 2 with less bioavailable, predominantly terrestrial, OM. Relative amounts of bacterial acyl ether and diether phospholipids increased in this lower section and were assigned to sulfate reducers and yet uncultured myxobacteria. Archaea were an order of magnitude less abundant than Bacteria, and were affiliated mainly with Methanosarcinales and Methanomicrobiales. Accordingly, the archaeal IPL composition was typical for a methanogenic community. IPLs not exclusively derived from in situ microbial production emphasize that these biomarkers have to be interpreted with caution in sediments with complex hydrogeology. Our results demonstrate that contrasting subsurface flow regimes significantly impact on the vertical zonation of biogeochemical properties and microorganisms in marine sediments.     

Mapping the sub-trappean Mesozoic sediments in the western part of Narmada–Tapti region of Deccan Volcanic Province,India

Deccan Traps spread over large parts of south, west and central India, possibly hiding underneath sediments with hydrocarbon potential. Here, we present the results of seismic refraction and wide-angle reflection experiments along three profiles, and analyze them together the results from all other refraction profiles executed earlier in the western part of Narmada–Tapti region of the Deccan Volcanic Province (DVP). We employ travel time modelling to derive the granitic basement configuration, including the overlying Trap and sub-trappean sediment thickness, if any. Travel time skips and amplitude decay in the first arrival refraction data are indicative of the presence of low velocity sediments (Mesozoic), which are the low velocity zones (LVZ) underneath the Traps. Reflection data from the top of LVZ and basement along with the basement refraction data have been used to derive the Mesozoic sediment thickness.In the middle and eastern parts of the study region between Narmada and Tapti, the Mesozoic sediment thickness varies between 0.5 and 2.0 km and reaches more than 2.5 km south of Sendhwa between Narmada and Tapti Rivers. Thick Mesozoic sediments in the eastern parts are also accompanied by thick Traps. The Mesozoic sediments along the present three profiles may not be much prospective in terms of its thickness, except inside the Cambay basin, where the subtrappean sediment thickness is about 1000–1500 m. In the eastern part of the study area, the deepest section (>4 km) has thick (∼2 km) Mesozoic sediments, but with almost equally thick Deccan Trap cover. Results of the present study provide important inputs for future planning for hydrocarbon exploration in this region.     

Mercury in sediments from gold and copper exploitation areas in the Camaquã River Basin,Southern Brazil

Mercury concentrations were determined in stream sediments from the Camaquã River Basin, located in the shield region of the state of Rio Grande do Sul, southern Brazil. The resulting geochemical data show that overbank floodplain deposits exhibit higher concentrations than sediments collected from the active channel bed. In addition, higher Hg concentrations were measured in the fine(<63 μm) sediment fraction of the samples. Total Hg concentrations in the fine fraction of active stream sediments from Lavras do Sul County, which have been influenced by past gold mining activities, have decreased during the last five years to values ≤142 ng g⁻¹. However, in a settling pond containing abandoned mine wastes, the Hg concentration of a bulk sample remained exceptionally high (5220 ng g⁻¹). Preliminary speciation results show that Hg⁰ is the predominant species in most of the samples. This was the form of Hg released by the gold amalgamation activities in the area, and appears to be relatively stable under the existing E_h and pH conditions.     

Radon emanation of heterogeneous basin deposits in Kathmandu Valley,Nepal

Effective radium-226 concentration (EC_Ra) has been measured in soil samples from seven horizontal and vertical profiles of terrace scarps in the northern part of Kathmandu Valley, Nepal. The samples belong to the Thimi, Gokarna, and Tokha Formations, dated from 50 to 14 ky BP, and represent a diverse fluvio-deltaic sedimentary facies mainly consisting of gravelly to coarse sands, black, orange and brown clays. EC_Ra was measured in the laboratory by radon-222 emanation. The samples (n = 177) are placed in air-tight glass containers, from which, after an accumulation time varying from 3 to 18 days, the concentration of radon-222, radioactive decay product of radium-226 and radioactive gas with a half-life of 3.8 days, is measured using scintillation flasks. The EC_Ra values from the seven different profiles of the terrace deposits vary from 0.4 to 43 Bq kg^?1, with profile averages ranging from 12 ± 1 to 27 ± 2 Bq kg^?1. The values have a remarkable consistency along a particular horizon of sediment layers, clearly demonstrating that these values can be used for long distance correlations of the sediment horizons. Widely separated sediment profiles, representing similar stratigraphic positions, exhibit consistent EC_Ra values in corresponding stratigraphic sediment layers. EC_Ra measurements therefore appear particularly useful for lithologic and stratigraphic discriminations. For comparison, EC_Ra values of soils from different localities having various sources of origin were also obtained: 9.2 ± 0.4 Bq kg^?1 in soils of Syabru–Bensi (Central Nepal), 23 ± 1 Bq kg^?1 in red residual soils of the Bhattar-Trisuli Bazar terrace (North of Kathmandu), 17.1 ± 0.3 Bq kg^?1 in red residual soils of terrace of Kalikasthan (North of Trisuli Bazar) and 10 ± 1 Bq kg^?1 in red residual soils of a site near Nagarkot (East of Kathmandu). The knowledge of EC_Ra values for these various soils is important for modelling radon exhalation at the ground surface, in particular in the vicinity of active faults. Importantly, the study also reveals that, above numerous sediments of Kathmandu Valley, radon concentration in dwellings can potentially exceed the level of 300 Bq m^?3 for residential areas; a fact that should be seriously taken into account by the governmental and non-governmental agencies as well as building authorities.     

Comparison of the structural,spectroscopic and phenanthrene binding characteristics of humic acids from soils and lake sediments

The structural, spectroscopic and phenanthrene binding characteristics were compared for humic acids (HA) extracted from two different sources: eight soils and six lake sediments. The elemental analysis revealed that HA from sediments had higher H/C, N/C, and (N + O)/C ratios compared to HA from soils, reflecting a lower degree of humification and more autochthonous organic input upon the formation of the HA for lake sediments versus soil environments. HA from soils exhibited a higher content of aromatic carbon structures than the sediment HA based on ¹³C NMR results. The source of HA was easily distinguished by comparing the synchronous fluorescence spectra of each HA group. The presence of a protein like fluorescence was prominent for the HA from sediment while it was minor for the HA from soil. Irrespective of the HA source, however, humification index (HIX) exhibited a common positive correlation with the aromatic content, and a negative correlation with O-alkyl carbon structures of the HA. The correlations were consistent with the general structural trends of humification processes, suggesting that HIX may serve as a source independent predictor to describe the structural information and humification degree of terrigenous HA. Aromatic carbon structures did contribute to enhancing the phenanthrene binding for both sources of HA. However, the primary structures associated with non-ideal phenanthrene binding (i.e., non-linear sorption isotherm) appear to differ by the HA source because the opposed correlations were obtained between aromaticity and the isotherm linearity for the two HA groups. Our results suggest that the HA structural function associated with specific non-linear sorption for hydrophobic organic contaminants (HOCs) may be more strongly governed by the HA source than by the apparent physico-chemical properties.     

Exploring former subglacial Hodgson Lake,Antarctica. Paper II: palaeolimnology

Direct exploration of subglacial lakes buried deep under the Antarctic Ice Sheet has yet to be achieved. However, at retreating margins of the ice sheet, there are a number of locations where former subglacial lakes are emerging from under the ice but remain perennially ice covered. One of these lakes, Hodgson Lake (72°00.549′S, 068°27.708′W) has emerged from under more than 297–465 m of glacial ice during the last few thousand years. This paper presents data from a multidisciplinary investigation of the palaeolimnology of this lake through a study of a 3.8 m sediment core extracted at a depth of 93.4 m below the ice surface. The core was dated using a combination of radiocarbon, optically stimulated luminescence, and relative palaeomagnetic intensity dating incorporated into a chronological model. Stratigraphic analyses included magnetic susceptibility, clast provenance, organic content, carbonate composition, siliceous microfossils, isotope and biogeochemical markers. Based on the chronological model we provisionally assign a well-defined magnetic polarity reversal event at ca 165 cm in the lake sediments to the Mono Lake excursion (ca 30–34 ka), whilst OSL measurements suggest that material incorporated into the basal sediments might date to 93 ± 9 ka. Four stratigraphic zones (A–D) were identified in the sedimentological data. The chronological model suggests that zones A–C were deposited between Marine Isotope Stages 5–2 and zone A during Stage 1, the Holocene. The palaeolimnological record tracks changes in the subglacial depositional environment linked principally to changing glacier dynamics and mass transport and indirectly to climate change. The sediment composition in zones A–C consists of fine-grained sediments together with sands, gravels and small clasts. There is no evidence of overriding glaciers being in contact with the bed reworking the stratigraphy or removing this sediment. This suggests that the lake existed in a subglacial cavity beneath overriding LGM ice. In zone D there is a transition to finer grained sediments characteristic of lower energy delivery coupled with a minor increase in the organic content attributed either to increases in allochthonous organic material being delivered from the deglaciating catchment, a minor increase in within-lake production or to an analytical artefact associated with an increase in the clay fraction. Evidence of biological activity is sparse. Total organic carbon varies from 0.2 to 0.6%, and cannot be unequivocally linked to in situ biological activity as comparisons of δ¹³C and C/N values with local reference data suggest that much of it is derived from the incorporation of carbon in catchment soils and gravels and possibly old CO₂ in meteoric ice. We use the data from this study to provide guidelines for the study of deep continental subglacial lakes including establishing sediment geochronologies, determining the extent to which subglacial sediments might provide a record of glaciological and environmental change and a brief review of methods to use in the search for life.     

Electrokinetic iron pan generation in unconsolidated sediments: implications for contaminated land remediation and soil engineering

Electrokinetic remediation is an emerging technology that has generated considerable interest as a technique for the in situ remediation of clay-rich soils and sediments. Despite promising experimental results, however, at present there is no standardised universal electrokinetic soil/sediment remediation approach. Many of the current technologies are technically complex and energy intensive, and geared towards the removal of 90% or more of specific contaminants, under very specific field or laboratory-based conditions. However, in the real environment a low-tech, low-energy contaminant reduction/containment technique may be more appropriate and realistic. Such a technique, FIRS (Ferric Iron Remediation and Stabilisation), is discussed here. The FIRS technique involves the application of a low magnitude (typically less than 0.2 V/cm) direct electric potential between two or more sacrificial, Fe-rich, electrodes emplaced in, or either side of, a contaminated soil or sediment. The electric potential is used to generate a strong pH (and E_h) gradient within the soil column (pH 2–13), and force the precipitation of an Fe-rich barrier or “pan” in the soil between the electrodes. Geochemical and geotechnical data for FIRS-treated sediments from the Ravenglass estuary, Cumbria, UK indicate that the technique can significantly reduce contaminant concentration in treated soil, by remobilisation of contaminants and concentration on, or around, the Fe-rich barrier. Arsenic, in particular, seems highly amenable to the FIRS treatment, due to its solubility under the high pH conditions generated near to the cathode, and its marked geochemical affinity with the freshly precipitated Fe oxides and oxyhydroxides in the Fe barrier. Geotechnical tests indicate that the Fe barrier produced by the technique is practically impervious (permeability = 10⁻⁹ m/s or less), and has moderate mechanical strength (UCS ∼11 N/mm²). Notably, a large increase in shear strength in the treated soil near to the anode electrode (due to Fe cementation and/or dewatering) is also observed, without significant loss of porosity. The data indicate that the FIRS technique shows considerable promise as an in situ method for contaminated land remediation and soil water containment, and for improving the mechanical properties of soils (contaminated or otherwise) for civil engineering purposes.     

Effect of suspended sediment concentration on local scour around cylinder for clay–sand mixed sediment beds

Suspended sediments present in the flow are known to affect the flow resistance, velocity distribution and turbulent characteristics. Experiments were conducted in the laboratory flume to see the effect of suspended sediment concentration (SSC) on local scour around a cylindrical pier for a wide range of clay–sand mixed sediment beds for SSC up to 2700 mg/L. It has been observed that the effect of SSC on equilibrium scour hole parameters such as maximum equilibrium scour depth, and longitudinal and transverse extent of scour hole can be significant. Present data showed that the presence of SSC in the range 993–1332 mg/L can increase maximum equilibrium scour depth as much as 1.54 times compared to the clear water case. However, tests made for SSC in the range 2456–2700 mg/L showed that the maximum equilibrium scour depth reduced compared to that for SSC in the range 993–1332 mg/L, but these maximum equilibrium scour depths were still larger than that obtained for clear water. The effect of SSC on time variation of scour and equilibrium scour hole geometry was further investigated.     

Sedimentological characteristics of small rivers with loessic headwaters in the Chaco,South America

Some sedimentological characteristics of fluvial environments located in the northeastern region of the Chaco–Pampa plain were analysed in order to determine the possible influence of the loessic headwaters of local basins. Concentrations of suspended sediments, as well as grain size of the river beds, were compared. Unexpectedly, it was found that the suspended load has an inverse relationship with the hydrometric levels, with the exception of highly saline streams (conductivity values between 4300 and 11,000 μS cm⁻¹). The mean concentration of suspended sediments was 63.1 and 206.3 mg l⁻¹ in flood and low water periods, respectively. The grain size of bed sediments was relatively homogeneous along the whole hydrological cycle. Sandy–silty bottoms predominate in channels, followed by silty–sandy and clayey–silty bottom types. Sediment transport mainly occurs in accelerating flow suspension, overcoming the critical erosion velocity. During flood periods, some parameters exceeded by 70% the values recorded during the low water phase.     

Sorption and precipitation of Co(II) in Hanford sediments and alkaline aluminate solutions

Sorption and precipitation of Co(II) in simplified model systems related to the Hanford site high-level nuclear waste tank leakage were investigated through solution studies, geochemical modeling, and X-ray absorption fine structure (XAFS) spectroscopy. Studies of Co(II) sorption to pristine Hanford sediments (ERDF and Sub), which consist predominantly of quartz, plagioclase, and alkali feldspar, show an adsorption edge centered at pH ≈ 8.0 for both sediments studied, with sorption >99% above pH ≈ 9.0. Aqueous SiO₂ resulting from dissolution of the sediments increased in concentration with increasing pH, though the systems remained undersaturated with respect to quartz. XAFS studies of Co(II) sorption to both sediment samples reveal the oxidation of Co(II) to Co(III), likely by dissolved O₂, although this oxidation was incomplete in the Sub sediment samples. The authors propose that Fe(II) species, either in aqueous solution or at mineral surfaces, partially inhibited Co(II) oxidation in the Sub sediment samples, as these sediments contain significantly higher quantities of Fe(II)-bearing minerals which likely partially dissolved under the high-pH solution conditions. In alkaline solutions, Al precipitated as bayerite, gibbsite, or a mixture of the two at pH > 7; an amorphous gel formed at pH values less than 7. Aqueous Co concentrations were well below the solubility of known Co-bearing phases at low pH, suggesting that Co was removed from solution through an adsorption mechanism. At higher pH values, Co concentrations closely matched the solubility of a Co-bearing hydrotalcite-like solid. XAFS spectra of Co(II) sorbed to Al-hydroxide precipitates are similar to previously reported spectra for such hydrotalcite-like phases. The precipitation processes observed in this study can significantly reduce the environmental hazard posed by ⁶⁰Co in the environment.     

The morphodynamics and internal structure of intertidal fine-gravel dunes: Hills Flats,Severn Estuary,UK

In the macrotidal Severn estuary, UK, the dynamics of intertidal fine-gravel dunes were investigated. These dunes are migrating across a bedrock platform. Systematic observations were made of hydraulic climate, geometry, migration rates and internal sedimentary structures of the dunes. During spring tides, the ebb flow is dominant, dunes grow in height and have ebb orientated geometry with bedrock floors in the troughs. During neap tides, a weak flood flow may dominate. Dunes then are flood orientated or symmetrical. Neap dune heights decrease and the eroded sediment is stored in the dune troughs where the bedrock becomes blanketed by muddy gravel. During spring tides, instantaneous bed shear stresses reach 8 N m^− 2, sufficient to disrupt a 9 mm-gravel armour layer. However, a sustained bed shear stress of 4 N m^− 2 is required to initiate dune migration at which time the critical depth-mean velocity is 1 m s^− 1. Ebb and flood inequalities in the bed shear stress explain the changes in dune asymmetry and internal structures. During flood tides, the crests of the dunes reverse such that very mobile sedimentary ‘caps’ overlie a more stable dune ‘core’. Because ebb tides dominate, internal structures of the caps often are characterised by ebb orientated steep open-work foresets developed by strong tidal currents and some lower angle crossbeds deposited as weaker currents degrade foresets. The foresets forming the caps may be grouped into cosets (tidal bundles) and are separated from mud-infused cores of crossbeds that lie below, by reactivation and erosion surfaces blanketed by discontinuous mud drapes. The cores often exhibit distinctive muddy toe sets that define the spacing of tidal cosets.     

Autocompaction of shallow silty salt marsh clay

Empirically derived algorithms are suggested by means of which it is possible to evaluate relations between physical properties in silty salt marsh clay. A relation between loss on ignition, sand content and bulk dry density in the topmost 5 cm was found to explain 84% of the variation of the latter. The bulk dry density in the topmost ≈ 0.5 m was found to vary as a logarithmic function of depth below the surface controlled by two constants directly dependent on the bulk dry density in the topmost 5 cm. Integration of this function illustrates that mass depth (MSD_z) down core can be directly related to the bulk dry density of the surface layer. For sediments with a surface bulk dry density between 400 kg m^? 3 and 800 kg m^? 3 the porosity was found to vary (+/?10%) with MSD_z as another logarithmic function. The results allow for an evaluation of the use of marker horizons in the topmost layers. Right after such a layer has been spread on the surface, sedimentation measured in length per time (accretion), will be significantly larger than for subsequent periods. Using marker horizons, it is therefore not trivial to know the level of the marker, as deeper located markers will indicate successively smaller accretion rates with the same sediment input.     

Late and Middle Pleistocene deposits at Somersham,Cambridgeshire, U.K.: a model for reconstructing fluvial/estuarine depositional environments

Gravel quarries at Somersham, Cambridgeshire, have yielded evidence for a Pleistocene channel of the R. Great Ouse, containing temperate stage sediments between cold stage sediments. In the earlier cold stage, fluviatile gravels and floodplain loessic sediment accumulated. In the later cold stage a further series of gravel units and floodplain sediments were deposited, together with lake sediments. The lake sediments are associated with Lake Sparks, dammed by Late Devensian ice in the Wash at ca. 18.5 ka BP. The lake sediments overlie gravels with a radiocarbon date from an organic horizon indicating a Middle Devensian age. Clast lithological analyses from the earlier and later gravels suggest that reworking of gravels has occurred within a relatively stable catchment. The petrography of the earlier cold stage loessic sediment and temperate stage fine sediment indicates an Anglian affinity, which conflicts with the biostratigraphic interpretation. Pollen and macroscopic plant remains from sediments of both cold stages and from the temperate stage indicate, respectively, assemblages with a typical full-glacial aspect with a rich flora of shrubs and open ground herbs(including an assemblage at ca. 18 ka), and temperate freshwater and marine-influenced organic sediments. On the basis of pollen analysis these are ascribed to substages Ip II and III of the Ipswichian Stage(O.I.S. 5e), with a Pinus-Quercus-Corylus biozone in the former and a biozone with Carpinus in the latter. Marine-influenced sediments, at −3.7 to −0.3 m OD, indicate transgression in Ip II and regression in Ip III.Molluscan assemblages from the temperate stage and the later cold stage are described; two are from the Late Devensian, at a time near the maximum extension of ice into the Wash. Foraminifer and ostracod faunas are described from post-Ipswichian sediments and may be reworked. Radiocarbon dates confirm the age of the later gravel suite as Devensian and a calibration of the measurements is given. Amino acid ratios from Corbicula fluminalis valves from temperate stage sediments are reported, with measurements from different parts of the valve; the results tend to support an Ipswichian age. TL measurements of the earlier cold stage loessic sediment and associated sand indicate a pre-Ipswichian age for the sediments. The earlier cold stage is correlated with the pre-Ipswichian cold stage, the Wolstonian of Mitchell et al.(1973); problems with this correlation are discussed.Various periglacial phenomena, including thermal contraction networks and cracks, diapirs, involutions and coversand are associated with the Devensian sequence. The complex environmental history, based on stratigraphy and palaeontology, is described, and related to other nearby sites in southern Fenland.