Migration of Dust Particles and Delivery of Volatiles to the Terrestrial Planets

Results of computer simulations of the migration of small bodies and dust in the Solar System showed that a relative fraction of cometary and trans-Neptunian dust particles in the total balance of the dust encountering the terrestrial planets can be significant. The contribution of dust particles to the delivery of volatiles to the terrestrial planets is estimated to be 3–4 orders of magnitude less than that of small bodies. However, the dust particles could be most efficient in the delivery of organic or even biogenic matter to the Earth, because they experience substantially weaker heating when passing through the atmosphere.     

2002 Kuiper prize lecture: Dust Astronomy

Dust particles, like photons, carry information from remote sites in space and time. From knowledge of the dust particles' birthplace and their bulk properties, we can learn about the remote environment out of which the particles were formed. This approach is called “Dust Astronomy” which is carried out by means of a dust telescope on a Dust Observatory in space. Targets for a dust telescope are the local interstellar medium and nearby star forming regions, as well as comets and asteroids. Dust from interstellar and interplanetary sources is distinguished by accurately sensing their trajectories. Trajectory sensors may use the electric charge signals that are induced when charged grains fly through the detector. Modern in-situ dust impact detectors are capable of providing mass, speed, physical and chemical information of dust grains in space. A Dust Observatory mission is feasible with state-of-the-art technology. It will (1) provide the distinction between interstellar dust and interplanetary dust of cometary and asteroidal origin, (2) determine the elemental composition of impacting dust particles, and (3) monitor the fluxes of various dust components as a function of direction and particle masses.     

Protosolar nebula and composition of comets

Comets seem to be composed of matter, which is supposed to have the same molecular composition as protosolar nebula. Although there are no unbiased evidence that cometary nuclei retain the molecular composition inherited from the protosolar cloud, the observed properties of comets indicate that there is at least a resemblance between cometary composition and the material properties of dense interstellar clouds. Therefore the origin of comets could be searched in the cold stages of the protosolar nebula and molecular abundances of grain mantles in this nebula may be similar to those in the cometary dust. It is suggested that comets may contain pristine, virtually unaltered protosolar material and their study might be very relevant way to more information about processes in early stages of the solar nebula. Our knowledge about composition of the cometary nucleus is still relatively scarce, but we can partly deduce it from data obtained either by ground-based spectroscopy or by in situ mass spectrometry from space experiments. Most important were the discovery of fluffy CHON particles composed partly or even completely from compounds containing light elements. No consensus concerning the presence of interstellar pristine matter in comet has been reached from various approaches to determine the relationship between comets and interstellar grains. Most of these studies are based on infrared spectroscopy. Another method is the comparison on the chemical models of the protosolar nebula with the volatile compounds of the cometary nuclei. Both gas-phase and grain-surface chemistry are considered and initial gas-phase atomic abundances are assumed to be protosolar. The cometary matter is certainly not identical with the typical material of dense interstellar cool dense clouds, but it is closer to it than any other type of matter in solar system so far accessible to us. The data from comets combined with models of chemical evolution of matter in environment similar as prevailed the early stage of presolar nebula may at least impose constrains on the condition for comet formation. Here presented study is a preliminary contribution to such studies.     

On the formation of cometary nuclei in dense globules

Evolution of cometary orbits by planetary perturbations, weakly hyperbolic original orbits of comets calculated by Marsdenet al. (1978) are taken to indicate the interstellar origin of comets, and the possible formation of cometary nuclei in interstellar globules is discussed. The process is sedimentation of dust grains. It is shown that if a globule is at 40 K, its lifetime is sufficiently long to allow the sedimentation.     

Water and related chemistry in the solar system. A guaranteed time key programme for Herschel

“Water and related chemistry in the Solar System” is a Herschel Space Observatory Guaranteed-Time Key Programme. This project, approved by the European Space Agency, aims at determining the distribution, the evolution and the origin of water in Mars, the outer planets, Titan, Enceladus and the comets. It addresses the broad topic of water and its isotopologues in planetary and cometary atmospheres. The nature of cometary activity and the thermodynamics of cometary comae will be investigated by studying water excitation in a sample of comets. The D/H ratio, the key parameter for constraining the origin and evolution of Solar System species, will be measured for the first time in a Jupiter-family comet. A comparison with existing and new measurements of D/H in Oort-cloud comets will constrain the composition of pre-solar cometary grains and possibly the dynamics of the protosolar nebula. New measurements of D/H in giant planets, similarly constraining the composition of proto-planetary ices, will be obtained. The D/H and other isotopic ratios, diagnostic of Mars’ atmosphere evolution, will be accurately measured in H₂O and CO. The role of water vapor in Mars’ atmospheric chemistry will be studied by monitoring vertical profiles of H₂O and HDO and by searching for several other species (and CO and H₂O isotopes). A detailed study of the source of water in the upper atmosphere of the Giant Planets and Titan will be performed. By monitoring the water abundance, vertical profile, and input fluxes in the various objects, and when possible with the help of mapping observations, we will discriminate between the possible sources of water in the outer planets (interplanetary dust particles, cometary impacts, and local sources). In addition to these inter-connected objectives, serendipitous searches will enhance our knowledge of the composition of planetary and cometary atmospheres.     

The provenance and evolution of comets

The process of comet formation through the hierarchical aggregation of originally submicron-sized interstellar grains to form micron-sized particles and then larger bodies in the protoplanetary disc, culminating in the formation of planetesimals in the disc extending from Jupiter to beyond Neptune, is briefly reviewed. The ‘planetesimal’ theory for the origin of comets implies the existence of distinct cometary reservoirs, with implications for the immediate provenance of observed comets (both long-period and short-period) and their evolution as a result of planetary perturbations and physical decay, for example splitting and sublimation. The principal mode of cometary decay and collisional interaction with the terrestrial planets is through the formation and evolution of streams of cometary debris and hitherto undiscovered ‘families’ of cometary asteroids. Recent dynamical results, in particular the sungrazing and sun-colliding end-state for short-period comet and asteroid orbits, are briefly discussed.     

All comets are born equal: infrared emission by dust as a key to comet nucleus composition

The infrared emission of various comets can be matched within the framework that all comets are made of aggregated interstellar dust. This is demonstrated by comparing results on Halley (a periodic comet), Borrelly (a Jupiter family short period comet), Hale-Bopp (a long period comet), and extra-solar comets in the β Pictoris disk. Attempts have been made to generalize the chemical composition of comet nuclei based on the observation of cometary dust and volatiles and the interstellar dust model. Finally, we deduce some of the expected dust and surface properties of comet Wirtanen from the interstellar dust model as applied to other comets.     

Processing of cometary grains at the nucleus surface

Cometary material inevitably undergoes chemical changes before and on leaving the nucleus. In seeking to explain comets as the origin of many IDPs (interplanetary dust particles), an understanding of potential surface chemistry is vital. Grains are formed and transformed at the nucleus surface; much of the cometary volatiles may arise from the organic material. In cometary near-surface permafrost, one expects cryogenic chemistry with crystal growth and isotope. This could be the hydrous environment where IDPs form. Seasonal and geographic variations imply a range of environmental conditions and surface evolution. Interplanetary dust impacts and electrostatic forces also have roles in generating cometary dust. The absence of predicted cometary dust ‘envelopes’ is compatible with the wide range of particle structures and compositions. Study of IDPs would distinguish between this model and alternatives that see comets as aggregates of core-mantle grains built in interstellar clouds.     

Assessment of the interstellar processes leading to deuterium enrichment in meteoritic organics

Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.     

Cosmic Ray-Induced Polycondensate Hydrocarbons in Giant Molecular Clouds

Astrophysical and cosmochemical data show that many kinds of hydrocarbons are widespread in space, including giant molecular clouds, diffuse interstellar medium, comets, interplanetary dust particles, and carbonaceous meteorites. Here an effort is made to show the close relation between high-molecular weight hydrocarbons observed in space and existing on Earth. Results of astrochemical modelling of dust grains in dense collapsing cores of giant molecular clouds are also presented. They show that about 10% of the total abundance of dust grains may be the result of aliphatic hydrocarbons. This dust serves as initial material for comets, formed in protosolar nebula. The problem of survival of cometary organics during impact onto the Earth is discussed, and it is shown that the so-called soft-landing comet hypothesis may explain the accumulation of complex hydrocarbons on the Earth's surface. We conclude that a significant fraction of terrestrial prebiotic petroleum was delivered by extraterrestrial matter.     

What can we expect from the in situ chemical investigation of a cometary nucleus by gas chromatography: First results from laboratory studies

Comets are probably the most primitive bodies of the solar system, and they participated in the early bombardment of the primitive planets. Consequently, the knowledge of their composition can play a key role in our understanding of the solar system formation, the origin of the planetary volatile constituents, and the origin of the organics implied in terrestrial prebiotic chemistry. However, we still do not have any direct information about the molecular composition of the cometary nucleus. This is why the COmetary SAmpling and Composition experiment (COSAC), onboard the surface landing probe of the Rosetta cometary mission, is specifically devoted to the molecular and enantiomeric analysis of a cometary nucleus. This experiment includes a gas chromatograph instrument dedicated to the specific identification and quantification of the general molecular species present in samples collected at the nucleus surface. In order to evaluate the performances of the integrated chromatographic system which was selected for the flight model instrument, experiments were carried out with a laboratory set up that reproduced the flight configuration and mimicked the in situ operating conditions. The obtained results demonstrate the ability for the gas chromatograph to identify a wide range of organic and inorganic volatile compounds, even those present at trace level, within the constrained space operating conditions. The aim of this paper is to present, for the first time, the performances of this system and to discuss the potential role of in situ gas chromatographic measurements in the future cometary, planetological and prebiotic chemistry studies.     

Processing of cometary grains at the nucleus surface

Cometary material inevitably undergoes chemical changes before and on leaving the nucleus. In seeking to explain comets as the origin of many IDPs (interplanetary dust particles), an understanding of potential surface chemistry is vital. Grains are formed and transformed at the nucleus surface; much of the cometary volatiles may arise from the organic material. In cometary near-surface permafrost, one expects cryogenic chemistry with crystal growth and isotope. This could be the hydrous environment where IDPs form. Seasonal and geographic variations imply a range of environmental conditions and surface evolution. Interplanetary dust impacts and electrostatic forces also have roles in generating cometary dust. The absence of predicted cometary dust envelopes is compatible with the wide range of particle structures and compositions. Study of IDPs would distinguish between this model and alternatives that see comets as aggregates of core-mantle grains built in interstellar clouds.     

Non‐silica aerogels as hypervelocity particle capture materials

Abstract– The Stardust sample return mission to the comet Wild 2 used silica aerogel as the principal cometary and interstellar particle capture and return medium. However, since both cometary dust and interstellar grains are composed largely of silica, using a silica collector complicates the science that can be accomplished with these particles. The use of non‐silica aerogel in future extra‐terrestrial particle capture and return missions would expand the scientific value of these missions. Alumina, titania, germania, zirconia, tin oxide, and resorcinol/formaldehyde aerogels were produced and impact tested with 20, 50, and 100 μm glass microspheres to determine the suitability of different non‐silica aerogels as hypervelocity particle capture mediums. It was found that non‐silica aerogels do perform as efficient hypervelocity capture mediums, with alumina, zirconia, and resorcinol/formaldehyde aerogels proving to be the best of the materials tested.     

Relationship of comets and planets

We analyze our earlier data on the numerical integration of the equations of motion for 274 short-period comets (with the period P<200 yr) on a time interval of 6000 yr. As many as 54 comets had no close approaches to planets, 13 comets passed through the Saturnian sphere of action, and one comet passed through the Uranian sphere of action. The orbital elements of these 68 comets changed by no more than ±3 percent in a space of 6000 yr. As many as 206 comets passed close to Jupiter. We confirm Everhart’s conclusion that Jupiter can capture long-period comets with q = 4–6 AU and i < 9° into short-period orbits. We show that nearly parabolic comets cross the solar system mainly in the zone of terrestrial planets. No relationship of nearly parabolic comets and terrestrial planets was found for the epoch of the latest apparition of comets. Guliev’s conjecture about two trans-Plutonian planets is based on the illusory excess of cometary nodes at large heliocentric distances. The existence of cometary nodes at the solar system periphery turns out to be a solely geometrical effect.     

A Jupiter fragmented comet: Cause of the K/T boundary record

The extended period of mass extinctions around the K/T boundary correlating with extraterrestrial amino acids in the sediment record constitutes strong evidence of a cometary cause. The input of extraterrestrial matter over 10⁵ yr supports the hypothesis of a giant comet, fragmented into subcomets on close encounter with Jupiter, and subsequently perturbed into Earth-crossing orbits. Copious amounts of dust were emitted via this and possibly successive fragmenting encounters, and via normal cometary evaporation. The dynamics of dust from the disintegrating comet fragments favours retention in Earth-crossing orbits of the sub-micron fraction of organic composition. The shroud of dust accreted in the Earth's upper atmosphere varied with time and imposed climatic stresses that caused species extinctions over 10⁵ yr. While the iridium peak in the sediments coincides with the Chicxulub crater impactor, other iridium detail suggests that some of the impactor material was reinjected into space and in part re-accreted by Earth from the interplanetary orbits.School of Mathematics, University of Wales College of Cardiff.     

Possible consequences of absence of “jupiters” in planetary systems

The formation of the gas giant planets Jupiter and Saturn probably required the growth of massive 15 Earth-mass cores on a time scale shorter than the 10⁷ time scale for removal of nebular gas. Relatively minor variations in nebular parameters could preclude the growth of full-size gas giants even in systems in which the terrestrial planet region is similar to our own. Systems containing failed Jupiters, resembling Uranus and Neptune in their failure to capture much nebular gas, would be expected to contain more densely populated cometary source regions. They will also eject a smaller number of comets into interstellar space. If systems of this kind were the norm, observation of hyperbolic comets would be unexpected. Monte Carlo calculations of the orbital evolution of region of such systems (the Kuiper belt) indicate that throughout Earth history the cometary impact flux in their terrestrial planet regions would be 1000 times greater than in our Solar System. It may be speculated that this could frustrate the evolution of organisms that observe and seek to understand their planetary system. For this reason our observation of these planets in our Solar System may tell us nothing about the probability of similar gas giants occurring in other planetary systems. This situation can be corrected by observation of an unbiased sample of planetary systems.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Searches for transplutonian planets using long-period comets

We discuss the dynamical connection of long-period and nearly parabolic comets with hypothetical transplutonian planets. The statistics includes 792 comets with periods P > 200 years. The orbital plane of the parent planet can be determined from the observed distribution of the perihelia and poles of cometary orbits. The radius of a planetary orbit can be calculated using the Radzievsky-Tisseran criterion. We calculated the minimum distance of each of the 792 orbits to 11 hypothetical planetary orbits. Testing for the kinematic connection of comets with transplutonian planets yielded a negative result. The presence of the nodes of cometary orbits in the transplutonian region is shown to be the result of a geometric effect. We found a high concentration of the nodes and perihelia of cometary orbits in the zone of the terrestrial planets.     

Ice clathrate as a possible source of the atmospheres of the terrestrial planets

The presence and compositions of atmospheres on the terrestrial planets do not follow directly from condensation models which would have Earth accreting near 500°K. No single mechanism yet proposed adequately accounts for the abundances of noble gases and carbon and nitrogen in the atmospheres. We show that the composition of clathrates forming at low temperatures in cold regions of the nebula can be predicted. Addition of about 1 ppm clathrate material to the Earth can explain observed abundances of Ar, Kr, and Xe. Condensation and adsorption processes occuring at 400–500°K are necessary to explain the observed abundances of Ne, H₂O, C, and N. Possible sources of clathrates could be cometary bodies formed in the outer solar system.     

Traces of cometary material in the area of the Tunguska impact (1908)

A short overview of the studies of the authors and their colleagues performed over many years, which resulted in the discovery of traces of cometary matter in the peat at the epicenter of the Tunguska catastrophe in 1908, is given here. In the epicenter of the Tunguska cosmic body (TCB) explosion, the shifts in the isotopic composition of hydrogen and carbon relative to their values for the upper and lower layers of the same column were found in the catastrophic layers of peat grown up in 1908. These shifts cannot be attributed to any known terrestrial processes: the conservation of mineral and organic dust in peat, peat humification, the emission of hydrocarbon gases from the Earth, climate changes, and other physical and chemical processes. In the catastrophic layers of the control peat columns, the isotopic shifts are absent. The isotopic data agree well with the increased concentration of iridium and other platinum-group elements in the same peat layers, which is a reliable indicator of the presence of cosmic material in terrestrial objects. The cosmogenic character of the isotopic effects is confirmed by the presence of “dead” carbon (not containing radioactive ¹⁴C) in the catastrophic layers. To provide the shifts observed in the isotopic composition of carbon, cosmic carbon preserved in peat should be isotopically superheavy—from +50‰ to +60‰ according to calculations. Such isotopically heavy carbon is absent both on the Earth and in ordinary meteorites. It occurs only in individual mineral phases of CI carbonaceous chondrites, close to cometary dust in chemical composition, ratios of the content of iridium and other platinoids and rear-earth elements also points to the cometary nature of the TCB. In the near-catastrophic peat layers, the anomalous increase of the concentration of many volatiles was detected, which also suggests that the TCB was a cometary core. The studies of the content and the isotopic composition of nitrogen in the peat revealed traces of heavy acid rains induced by the flyby and explosion of the TCB.     

Origin of water in the inner Solar System: A kinetic Monte Carlo study of water adsorption on forsterite

The origin of water in the inner Solar System is not well understood. It is believed that temperatures were too high in the accretion disk in the region of the terrestrial planets for hydrous phases to be thermodynamically stable. Suggested sources of water include direct adsorption of hydrogen from the nebula into magma oceans after the terrestrial planets formed, and delivery of asteroidal or cometary material from beyond the zone of the terrestrial planets. We explore a new idea, direct adsorption of water onto grains prior to planetary accretion. This hypothesis is motivated by the observation that the accretion disk from which our planetary system formed was composed of solid grains bathed in a gas dominated by hydrogen, helium, and oxygen. Some of that hydrogen and oxygen combined to make water vapor. We examine quantitatively adsorption of water onto grains in the inner Solar System accretion disk by exploring the adsorption dynamics of water molecules onto forsterite surfaces via kinetic Monte Carlo simulations. We conclude that many Earth oceans of water could be adsorbed.