Gently sloping shear zones in the Belomorian Mobile Belt: Geology,structure, and <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> parameters

The Belomorian Mobile Belt (BMB) in northern Karelia mostly consists of gently sloping shear zones, whose gneisses and migmatized amphibolites and blastomylonites are typically thinly banded, with their banding consistently dipping north- and northeastward. These gently sloping shear zones were not affected by folding after they were produced and are not cut by Paleoproterozoic metabasite dikes. Intrusive metabasites in the gently sloping shear zones make up relatively small (usually <5 m) equant or elongate bodies and occur as fragments of larger bodies. These fragments are often concentrated in stripes. Metabasites in the gently sloping shear zone are sometimes also found as lenses and tabular bodies of relatively small thickness, which are conformable with the foliation of the host rocks. The gently sloping shear zones cut across older domains of more complicated structure, which suggests that these zones are gently sloping ductile shear zones. Along these zones, the nappes were thrust south- and southwestward, and this process was the last in the origin of major structural features of BMB when the Paleoproterozoic Lapland–Kola orogen was formed. Practically identical age values were obtained for the gently sloping shear zone in the two widely separated Engonozero and Chupa segments of BMB: 1879 ± 21 Ma (⁴⁰Ar/³⁹Ar amphibole age of amphibolite whose protolith was mafic rock) and 1857 ± 13 Ma (Sm–Nd mineral isochron age of garnet amphibolites after gabbronorite). The P–T metamorphic parameters in these gently sloping shear zones are remarkably different from the metamorphic parameters outside these zones: the pressure is 3–4 kbar lower and the temperature is 60–100°C lower. Thrusting-related decompression triggered the transition from the older high-pressure episode of Paleoproterozoic metamorphism to a younger syn-thrusting higher temperature metamorphic episode. The peak metamorphic parameters corresponding to the boundary between the amphibolite and granulite facies were reached only in the central portions of the shear zones: T= 680–760°C, P = 8.0–11.9 kbar. In areas of the most intense migmatization, temperature estimates in the central portions of the shear are as high as 810–830°C. The marginal portions of the shear zones were formed at lower temperatures of 610–630°C. The temperature heterogeneous and rock heating in the gently sloping shear zones may have resulted from flows of high-temperature metamorphic fluid that were focused to the central portions of the zones.     

Experimental study of eclogitization and melting of basic rocks at <Emphasis Type="Italic">Р</Emphasis> = 4 GPa and <Emphasis Type="Italic">Т</Emphasis> = 1200–1400°С

Experimental study of gabbro–norite eclogitization and melting at P = 4 GPa has made it possible to reveal the effective influence of fluid and temperature on the phase relationships. The melt composition varies from andesite–dacite in “dry conditions” to phonolite and carbonate in the presence of a fluid. The Grt-containing melting curve is replaced by the Cpx-containing liquidus as the temperature changes or a fluid is added. Hence, the possible presence of “garnetitite” and “clinopyroxenite” in the upper mantle was proved experimentally. The ultimate pressure of the spinel facies at the depth of the eclogite upper mantle is controlled by the stability of Cht ≤ 4 GPa. The revealed similarity of the spectra of REE-adakite, tonalite–trondhjemite–granodiorite (TTG), and melts formed under the partial melting of eclogitized gabbro–norite does not contradict the existing ideas of the eclogite source of the TTG rocks. Wide variations in the interphase microelement distribution factors D (Grt, Cpx)/L are indicative of effective fractionation of the microelements in the course of eclogite melting and differentiation.     

Analysis of MOST light curves of the active stars <Emphasis Type="Italic">ɛ</Emphasis> Eri AND <Emphasis Type="Italic">κ</Emphasis> Cet

We have analyzed light curves from the MOST satellite for the two active dwarfs ? Eri and κ Cet. Our maps of the stellar surface-temperature inhomogeneities were obtained with no a priori assumptions about the shape, configuration, and number of spots. We find variations of the surface-temperature inhomogeneities with time, also on time scales about equal to their rotation periods. We consider a model of a spotted star with two types of surface inhomogeneities—spots and related plage fields—and demonstrate that the best agreement between the theoretical and observed light curves is achieved for small ratios of the plage-field area to the area of cool spots. This conclusion indicates that long-term brightness variations of stars younger than the Sun are mainly due to variable spots on their surfaces, while the contribution from plage fields becomes more significant for older stars.     

Homogenization of carbonate-bearing microinclusions in diamond at <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> parameters of the upper mantle

The staged high-pressure annealing of natural cubic diamonds with numerous melt microinclusions from the Internatsional’naya kimberlite pipe was studied experimentally. The results mainly show that the carbonate phases, the daughter phases in partially crystallized microinclusions in diamonds, may undergo phase transformations under the mantle P–T conditions. Most likely, partial melting and further dissolution of dolomite in the carbonate–silicate melt (homogenization of inclusions) occur in inclusions. The experimental data on the staged high-pressure annealing of diamonds with melt microinclusions allow us to estimate the temperature of their homogenization as 1400–1500°C. Thus, cubic diamonds from the Internatsional’naya pipe could have been formed under quite high temperatures corresponding to the lithosphere/asthenosphere boundary. However, it should be noted that the effect of selective capture of inclusions with partial loss of volatiles in relation to the composition of the crystallization medium is not excluded during the growth. This may increase the temperature of their homogenization significantly between 1400 and 1500°C.     

Metamorphic <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> paths of the Zanhuang amphibolites and metapelites: constraints on the tectonic evolution of the Paleoproterozoic Trans-North China Orogen

Garnet-bearing metapelites and amphibolites are exposed in the south and middle parts of the Zanhuang complex, which is located in the central segment of the nearly NS-striking Trans-North China Orogen. These rocks preserve three metamorphic mineral assemblages forming at the prograde, peak and post-peak decompression stages. The prograde metamorphic stage (M₁) is represented by mineral inclusions within garnet porphyroblasts, the peak metamorphic stage (M₂) is represented by garnet rims and matrix minerals, whereas the retrograde stage (M₃) is represented by amphibole + plagioclase symplectite rimming garnet porphyroblasts in the amphibolites and biotite + plagioclase symplectite rimming garnet porphyroblasts in the metapelites. All garnet porphyroblasts in the metapelites preserve prograde chemical zoning except for the ubiquitous, quite narrow zones from the underwent post-peak decompression. It has been determined through thermobarometric computation that the metamorphic conditions are 650–710°C at 8.2−9.2 kbar for the M₁ (inclusion) assemblages, >810°C at >12.5 kbar for the metamorphic peak M₂ (matrix) assemblages, and 660–680°C at 4.4–4.5 kbar for the retrograde M₃ (symplectite) assemblages. These rocks are thus determined to have undergone metamorphism with clockwise P–T paths involving nearly isothermal decompression (ITD) segments, which is inferred to be related to the amalgamation of the Eastern and Western Blocks to form the coherent basement of the North China Craton along the Trans-North China Orogen in the late Paleoproterozoic (1.88–1.85 Ga).     

<Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">V</Emphasis>–<Emphasis Type="Italic">T</Emphasis> equation of state of CaAl<Subscript>4</Subscript>Si<Subscript>2</Subscript>O<Subscript>11</Subscript> CAS phase

The thermoelastic parameters of the CAS phase (CaAl₄Si₂O₁₁) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V _0,300 = 324.2 ± 0.2 Å³ and K _0,300 = 164 ± 6 GPa for K′ _0,300 = 6.2 ± 0.8. With K′ _0,300 fixed to 4.0, we obtained: V _0,300 = 324.0 ± 0.1 Å³ and K _0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V _0,300 = 324.2 ± 0.1 Å³, K _0,300 = 171 ± 5 GPa, K′ _0,300 = 5.1 ± 0.6 (?K _0,T /?T) _P  = ?0.023 ± 0.006 GPa K^?1, and α_0,T  = 3.09 ± 0.25 × 10^?5 K^?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl₄Si₂O₁₁. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone.     

Immobilized <Emphasis Type="Italic">β</Emphasis>-lactamase on Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> magnetic nanoparticles for degradation of <Emphasis Type="Italic">β</Emphasis>-lactam antibiotics in wastewater

The emergence of antibiotics residues in pharmaceutical industrial wastewater has been a significant environment problem. However, current methods of treating antibiotic-polluted wastewater are inefficient, of high cost and time-consuming. In this study, highly effective enzymatic Fe₃O₄ magnetic nanoparticles were developed, which is extremely simple and can degrade antibiotics in a fast manner at a low cost. β-Lactamase, a representative enzyme for β-lactam antibiotic degradation, was covalently immobilized on the surface of magnetic nanoparticles modified with amino groups by a simple cross-linking process. The immobilized β-lactamase displayed a wider pH and temperature range for penicillin G degradation than the free enzyme. Meanwhile, the thermostability and storage stability of the immobilized β-lactamase were improved. Fifty milligrams magnetic nanoparticles immobilized with β-lactamase can thoroughly degrade 100 mL penicillin G (5–50 mg L^?1) within 5 min. Even if the β-lactamase immobilized on the nanoparticles was reused 35 times in the 5 mg L^?1 penicillin G solution, it still kept more than 95% degradation efficiency. These suggest that magnetic nanoparticles immobilized with β-lactamase have a sufficient capacity for degrading antibiotics in wastewater and will serve as a practical and economical solution to antibiotic pollution in pharmaceutical industrial wastewater treatment.     

Photoluminescence spectra of S<Subscript>2</Subscript><Superscript><Emphasis Type="Bold">−</Emphasis></Superscript> center in natural and heat-treated scapolites

The emission and excitation spectra of yellow luminescence due to S₂ ⁻ in scapolites (#1 from Canada and #2 from an unknown locality) were observed at 300, 80 and 10 K. Emission and excitation bands at 10 K showed vibronic structures with a series of maxima spaced 15–30 and 5–9 nm, respectively. The relative efficiency of yellow luminescence from scapolite #2 was increased up to 117 times by heat treatment at 1,000°C for 2 h in air. The enhancement of yellow luminescence by heat treatment was ascribed to the alteration of SO₃ ²⁻ and SO₄ ²⁻ to S₂ ⁻ in scapolite.     

Bearing capacity factor, <Emphasis Type="Italic">N</Emphasis><Subscript><Emphasis Type="Italic">γ</Emphasis></Subscript>, for unsaturated soils by ZEL method

Bearing capacity of foundations is often determined for saturated state of the soil, regarding its simple and conservative results. This assumption, however, results in very uneconomic and overconservative design for a wide range of climates in the world. In this paper, plasticity equations were employed and extended for unsaturated soils to establish a theoretical approach to investigate the bearing capacity of unsaturated soils. It is achieved by combining the concept of effective stress and plasticity equations in terms of effective stress in unsaturated soils. The advantage of Bishop’s (4) effective stress concept was employed to simplify the equations. The equations were then transformed onto the zero extension lines directions to generalize this method for both associative and non-associative problems by which both stress and velocity field can be determined for unsaturated soils. A computer code was also developed to solve the relatively complex plasticity equations for a wide range of soil friction angles and matric suctions to compute the corresponding bearing capacity factor, N _γ , for strip foundations with smooth and rough base. This factor seems to be one of the major contributors in the bearing capacity of shallow foundations. The results have been presented in design charts and theoretical equations.     

Absorption in the H(93–95)<Emphasis Type="Italic">α</Emphasis> and H(78–79)<Emphasis Type="Italic">α</Emphasis> recombination lines in the HII region of the quasar 3C 345

Absorption of the synchrotron emission of the quasar 3C 345 in the continuum and H(93–95)α and H(78–79)α radio recombination lines is studied. The upper limit for absorption in the H(93–95)α lines is T_al/T_ac < 0.7%; absorption in the H(78–79)α lines with antenna temperature T_al = 25 mK, linewidth Δf = 5.3 ± 0.08 MHz, and T_al/T_ac ≥ 0.3% has been detected. A correction to the redshift Δz = 0.00135 ± 0.00008 (z = 0.59365) has been determined.     

Analytical approximation for the Fe <Emphasis Type="Italic">K</Emphasis><Subscript>α</Subscript> emission line in quasar spectra

The spectra of many Seyfert galaxies display broad Fe K _α emission. The line profile has two maxima, suggesting that the line emerges in the innermost regions of an accretion disk around a black hole, making it necessary to take into account general relativistic (GR) effects. Identifying GR processes occuring in active galactic nuclei (AGN) requires reconstructing the parameters of the accreting system from the line profile using some reasonably quick algorithm. We present here a numerical approximation for the Fe K _α emission line using analytical functions. The approximation encompasses a range of the disk radial coordinate r and the angle θ between the line of sight and the disk normal, and makes it possible to decrease the computing time by six orders of magnitude in certain astrophysical problems, while taking into account all GR effects. Results of the approximation are available at http://www.iki.rssi.ru/people/repin/approx.     

Hydrodynamical modeling of mass transfer in the close binary system <Emphasis Type="Italic">β</Emphasis> Lyr

We present results of two-dimensional hydrodynamical simulations of mass transfer in the close binary system β Lyr for various radii of the accreting star and coefficients describing the interaction of the gaseous flow and the main component (primary). We take the stellar wind of the donor star into account and consider various assumptions about the radiative cooling of the gaseous flow. Our calculations show that the initial radius of the flow corresponding to our adopted mass-transfer rate through the inner Lagrange point (L₁) of (1–4) × 10^?5M_⊙/yr is large: 0.22–0.29 (in units of the orbital separation). In all the models, the secondary loses mass through both the inner and outer (L₁ and L₂) Lagrange points, which makes the mass transfer in the system nonconservative. Calculations for various values of the primary radius show a strong dependence on the coefficient fv that models the flow-primary interaction. When the radius of the primary is 0.5, there is a strong interaction between the gas flow from L1 and the flow reflected from the primary surface. For other values of the primary radius (0.1 and 0.2), the flow does not interact directly with the primary. The flow passes close to the primary and forms an accretion disk whose size is comparable to that of the Roche lobe and a dense circum-binary envelope surrounding both the disk and the binary components. The density in the disk varies from 10¹² to 10¹⁴ cm^?3, and is 10¹⁰–10¹² cm^?3 in the circum-binary envelope. The temperature in the accretion disk ranges from 30000 to 120000 K, while that in the circum-binary envelope is 4000–18000 K. When radiative cooling is taken into account explicitly, the calculations reveal the presence of a spiral shock in the accretion disk. The stellar wind blowing from the secondary strongly interacts with the accretion disk, circum-binary envelope, and flow from L₂. When radiative cooling is taken into account explicitly, this wind disrupts the accretion disk.     

Bearing capacity of strip footings on <Emphasis Type="Italic">c</Emphasis>–<Emphasis Type="Italic">φ</Emphasis> soils with square voids

The presence of underground voids has an adverse influence on the performance of shallow foundations. In this study, the bearing capacity and failure mechanism of footings placed on cohesive-frictional soils with voids are evaluated using discontinuity layout optimization. By introducing a reduction coefficient, a set of design charts that can be directly applied to the classical bearing capacity formulation is presented. The results indicate that the undrained bearing capacity with voids is sensitive to soil weight and cohesion, as both the bearing capacity and stability issues exist in the problem. The failure mechanism is directly related to a variety of soil properties, the locations of single voids, and the horizontal distance between two voids. The presence of voids has a more dominant effect on c–φ soils compared to that on undrained soil. An interpretation of the critical and adverse locations for single-void and dual-void cases with various soil strengths is presented.     

The evolving narrative of the Darfur conflict as represented in <Emphasis Type="Italic">The New York Times</Emphasis> and <Emphasis Type="Italic">The Washington Post</Emphasis>, 2003–2009

News media influence local to global interactions between people, societies, and governments by producing place images. Representations of Africa in Western news media are heavily imbued with colonialist notions of cultural geography. In particular, Western news media have represented conflicts in Africa as ‘tribal’, a trope that erases geographic and historical context, and discourages actions that could prevent or reduce violent conflict. To determine if ‘tribalism’ remains important in coverage of African conflict, we use framing analysis to evaluate news on Sudan’s Darfur region in The New York Times and The Washington Post during 2003–2009. We find that these newspapers predictably relied on stereotypes related to tribalism to simplify Darfur’s geography and make the conflict meaningful to intended readers. Tribal portrayal of African war is inherently political, and, problematically, neither newspaper recognized that their use of the tribal narrative was parallel to the views of both the Sudanese government and external observers that challenged the actions of the Sudanese government. However, we also found that stereotypical representations became less prominent over time, apparently because reporters found that the initial, simplistic framing of the conflict did not match their encounters with geographic reality. We emphasize the decline in stereotypical tropes, because this suggests behind-the-scenes negotiation about representations in these news organizations. Recognizing voices that challenge stereotypical portrayals is necessary to developing place images that are geographically more accurate.     

Strong magnetic linear dichroism in Fe <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript> and O <Emphasis Type="Italic">K</Emphasis> electron energy-loss near-edge spectra of antiferromagnetic hematite α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>

We report strong magnetic linear dichroism (MLD) at the Fe L₂₃ and O K edges of the antiferromagnetic compound hematite -Fe₂ O₃ in high-resolution orientation- and temperature-dependent electron energy-loss spectroscopy (EELS). Large intensity differences of corresponding spectral features are observed when the Fe L₂₃ and O K edges are measured with momentum transfer either parallel or perpendicular to the magnetization. The resultant difference spectra for the Fe L₂₃ edges is consistent with the MLD observed in X-ray absorption spectroscopy. For the first time we have observed MLD at the O K edge, where the magnetic origin of this dichroism is demonstrated by temperature-dependent investigations across the Morin transition temperature T_M= 263 K, at which the Fe electron spins, i.e. the magnetic moments, rotate by 90°. The O K edge MLD is interpreted in terms of superexchange between the spins of the Fe 3d and O 2p electrons through overlapping Fe 3d and O 2p orbitals. The experiments were performed in a transmission electron microscope (TEM), yielding information about the anisotropic electronic structure at nanoscale spatial resolution when operated with a focused electron probe. The effects of MLD at the Fe L₂₃ edges on the determination of Fe³⁺/Fe in hematite at submicrometre scale using different independent quantification methods are discussed.