The geostatistics of the metal concentrations in sediments from the eastern Brazilian continental shelf in areas of gas and oil production

Geostatistical techniques were used to evaluate the differences in the geochemistry of metals in the marine sediments along the Eastern Brazilian continental margin along the states of Ceará and Rio Grande do Norte (Northeastern sector) and Espírito Santo (Southeastern sector). The concentrations of Al, Fe, Mn, Ba, Cd, Cu, Cr, Ni, Pb, V, Hg, and Zn were obtained from acid digestion and quantified using flame atomic absorption spectrometry (AAS), inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES). The metals showed a similar order of concentration: Al > Fe > Ba > Mn > V > Ni > Pb > Cr > Zn > Cu, in both the Ceará; and Rio Grande do Norte shelf regions but different in the Espírito Santo shelf (Fe > Al > Mn > Ba > Zn > V > Cr > Ni > Pb > Cu. The concentrations of Hg and Cd were below the detection limit in all areas. A multivariate analysis revealed that the metals of siliciclastic origin on the continental shelf of Ceará are carried by Al. In addition, a large portion of metal deposits is connected to the iron and manganese oxides on the continental margin of Rio Grande do Norte. The metals from the continental supply on the coast of Espírito Santo (Cu, Ni, Ba, and Mn) are associated with Al; whereas Cr, Pb, V, and Zn are associated with iron in this southern area. Geochemical evaluations are needed to distinguish the origin and mineralogical differences of marine sediments within the regions. Scanning electron microscopy/energy dispersive spectrometry (SEM/EDS) applied to the sediments from the coast of Ceará showed the morphological diversity of sediment grains: biological fragments, multifaceted particles, aggregates, and crystals occurred in the three regions analyzed. Among these grains, calcite, Mg-calcite, and aragonite were predominant in the northeastern sector, whereas silicates and other minerals were predominant the southeastern sector. Mg, K, Ti, and Zr as well as the lanthanides La and Ce were identified using SEM/EDS and added to the geochemical analysis of the data.     

Mapping of quick clay formations using geotechnical and geophysical methods

Quick clay has been involved in most serious, large clay slides in Sweden, Norway, and Canada. This paper describes geotechnical and geophysical methods that can be used to locate and map the extent of quick clay formations. Surface resistivity measurements and four different sounding methods have been tested. The results have been compared with sensitivities determined using fall-cone tests. The investigation shows that there is a correlation between sensitivity and electrical resistivity, which can be used to discriminate between marine clays that have been leached sufficiently to possibly form quick clay and those for which the salt content remains sufficiently high to prevent this. Although the most reliable evaluation of the variation in sensitivity was obtained by the CPT with additional measurement of total penetration force, this investigation suggests that any sounding method that uses a constant rate of advance into the ground and in which the penetration force applied on the top of the rods is measured may be used for quick clay mapping.     

Detection of seepage paths in earth dams using self-potential and electrical resistivity methods

Earth and rockfill dams are designed to operate under steady state seepage. Anomalous seepage may be a threat to the integrity of the structure. In spite of advances made in the fields of geotechnical engineering, it is not possible to have 100% leak-proof structure. Any excessive and unplanned seepage may lead to the failure of the dam, especially in unconsolidated or fractured terrains. Geophysical methods play an important role in mapping seepage paths and monitoring the changes of the seepage with time, enabling to plan technically and economically worthwhile remedial measures. In the present paper, utilisation of electrical methods for delineation of seepage zones at two of the four Saddle dams of the Som-Kamla-Amba project, Rajasthan State, India; which is founded on heterogeneous rock mass, is discussed. Electrical resistivity method was used to delineate zones favourable for seepage, whereas, self-potential (SP) method was used to delineate the seepage paths. SP measurements have shown negative anomaly of the order of 10–20 mV in amplitude, indicating low seepage, coinciding with the seepage measurements made by the project authorities.     

柴达木盆地西部地区古—始新世残-坡积物的判别及意义

柴达木盆地新生代沉积特征复杂、相变快、岩性类型多样.本文从柴达木盆地昆北断阶带地质背景、岩心特征、岩石学特征等方面,系统地分析了昆北断阶带基岩上覆地层的岩性组合特征,确定其为残-坡积物.残-坡积物的新认识增加了柴达木盆地油气勘探的岩性油气藏新类型,为柴达木盆地基岩上覆地层的油气勘探提出了新的勘探方向.     

东海泥质区表层沉积物中多环芳烃的分布特征及物源

以 GC/MSD内标法定量测定了东海近岸和远岸泥质沉积区 18个表层沉积物中多环芳烃 (PAHs)的含量,探讨了多环芳烃在这些泥质区的分布特征、影响因素及来源.结果显示 ,近岸泥质区多环芳烃含量普遍较高,介于 180.3～ 424.8 ng/g(干重 )之间;冲绳海槽次之,含量为 211.7 ng/g ;济州岛西南泥质区最低,含量介于 117.1～ 211.7 ng/g之间.东海泥质区多环芳烃的分布主要受控于离物源的远近、沉积物粒度、有机碳含量以及东海环流体系.东海泥质区的多环芳烃主要来源于热成因,大气干湿沉降和河流输入是其进入泥质区的主要途径.东海泥质区多环芳烃的污染程度中等.     

Jurassic sediments in the Irkut basin and southwestern Transbaikalia: correlations based on paleobotanical and geochronological data

The Jurassic growth of mountain ranges along the southern edge of the Siberian platform occurred in an active tectonic setting related to the closure of the Mongol-Okhotsk Ocean. The oceanic subduction and subsequent continent collision events induced compressive deformations at the platform boundary. Understanding the paleogeography related to the Mesozoic closure of the Mongol-Okhotsk Ocean requires dating and correlation of the Jurassic Prisayan Formation in the Irkut basin and Tugnuyskaya Formation in southwestern Transbaikalia. This work presents structural and paleobotanic results within both formations. ⁴⁰Ar/³⁹Ar dating of underlying volcanics from the upper member of the Ichetuyskaya Formation is used to refine the age of the sediment series and provide probable correlation. The results show that the Tugnuyskaya Formation initiated at the end of the Middle Jurassic-beginning of the Late Jurassic and was not coeval with the Prisayan Formation, whose upper fine-grained members were deposited in the early Middle Jurassic. ⁴⁰Ar/³⁹Ar dating of volcanics from the upper member of the Ichetuyskaya Formation yielded a Middle Jurassic age of 167.7 ± 1.2 Ma (Bajocian to Bathonian). The paleogeographic data analysis based on facies and mineralogical composition of sediments and on a study of source areas from Sm-Nd data and the U-Pb ages of detrital zircons from the deposits in the southern Irkut basin indicates that the deposition of the Prisayan Formation was followed by the intensification of relief building along the southern edge of the Siberian Platform. Our geochronological data show that active tectonic deformations in southwestern Transbaikalia evidenced in the volcanoclastic Ichetuyskaya Formation in the Tugnuy basin also occurred during the Middle Jurassic. The uppermost sediments of the Tugnuy basin were deposited at the end of the Middle Jurassic-Late Jurassic in a quiet tectonic setting with low relief and lacustrine-boggy depositional environments.     

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.     

The identification of organic input sources of sediments from the santa catalina basin using factor analysis

Individual neutral lipids, including hydrocarbons, ketones, alcohols, sterols, keto-ols and diols have been analysed from eight horizons in a sediment core taken from the Santa Catalina Basin, Calif. Variations in the concentration of individual lipid components between sites are studied using factor analysis to determine their inputs. Several sources of organic material are postulated from the composition of hypothetical factors, including methanogenic bacteria, higher plants and algae including coccolithophores, dinoflagellates and diatoms. Sources for long chain keto-ols and diols and a C₃₅ bicyclic alkene are suggested as methanogenic bacteria and algae respectively.     

深海沉积物中的稀土矿产资源研究进展

近年发现,太平洋和印度洋的深海盆地中存在大量富含稀土的深海沉积物。主要类型为多金属软泥、沸石黏土和远洋黏土,其中的全稀土含量(∑REY,∑REE+Y)为400×10-6~2000×10-6,最高可达6600×10-6,重稀土含量(HREE)已达到或超过中国南方离子吸附型矿床的重稀土品位两倍以上,是潜在的新型稀土资源,具有重要的经济价值。目前不少学者对富稀土的深海沉积物进行了大量地球化学及部分矿物学的工作,认为多金属软泥中的稀土元素多赋存于与海底热液作用有关的铁锰氧化物和氢氧化物中,而沸石黏土和远洋黏土中稀土元素的富集则与磷酸盐的混入密切相关,其稀土元素主要存在于与磷灰石成分相当的生物鱼骨屑中。深海黏土的北美页岩标准化稀土配分模式与海水相似,表明其中的稀土元素主要来自于海水,REY富集成矿可能主要受控于磷灰石早期成岩阶段,期间稀土元素未发生分异。尽管近些年对深海沉积物中的稀土元素研究取得了不少成果,但是,对于沉积物中的稀土富集机制及影响因素等问题仍然需要更加深入的研究。作为稀土资源大国,为了争取我国在国际海底稀土资源竞争中的话语权,维护中国的稀土利益,中国应加紧开展相关的稀土资源勘查和潜力评价。     

The ambient environment of the Gangetic sediments of chalcolithic period

There is considerable controversy regarding the mode of deposition of the OCP culture-associated sediments in the Gangetic valley and their ecological implications. SEM and sedimentologic studies show a fluvial mode of deposition of sediments originally derived from a glacial environment.     

Palaeomagnetic correlation and dating of Plio/Pleistocene sediments at the southern margins of the North Sea Basin

A series of discontinuous sediment sequences, of Plio/Pleistocene age, occur onshore around the southern North Sea margins, notably in the East Anglian region of Britain. Intensive lithological and palaeontological analyses of these sediments have shown that they record both major and minor oscillations in climate, sea level and environmental conditions. However, significant uncertainties exist regarding the absolute and relative chronostratigraphies of many of these sequences, hindering understanding of the relative impacts of climatic, eustatic and tectonic changes on the palaeogeographic development of the southern North Sea basin. Here, a number of key East Anglian Plio/Pleistocene sites are subjected to robust palaeomagnetic and mineralogical examination, in order to determine those sediments which display reliable, syn‐depositional magnetic polarities, which are thus of use in ascribing a palaeomagnetically determined age from comparison with the Geomagnetic Polarity Timescale (GPTS). Based on a range of palaeomagnetic and complementary mineralogical methods, reliable palaeomagnetic directions were obtained from eight sites, with reversed polarities displayed by sediments from three sites. These polarity determinations can be used to infer absolute ages and test published, between‐site correlations. Copyright © 2005 John Wiley & Sons, Ltd.     

Joint analysis of SAR interferometry and electrical resistivity tomography surveys for investigating ground deformation: the case-study of Satriano di Lucania (Potenza, Italy)

We have jointly applied microwave remote sensing imaging and ground-based geophysical methodologies for investigating ground deformation. In particular, the Differential Interferometric Synthetic Aperture Radar (DInSAR) technique referred to as Small BAseline Subset (SBAS) algorithm and the Electrical Resistivity Tomography (ERT) method have been applied. The former is a tool for investigating large areas, allowing us to detect deformation phenomena and to analyse their spatial patterns and temporal evolution; the latter permits us to reconstruct, with high spatial resolution, the geometry of near-surface geological structures and to estimate the electrical resistivity of outcropping terrains. The starting point of our analysis has been a DInSAR survey carried out on an area of about 400 km² centred around the town of Potenza (Basilicata region, Italy), for which SAR data acquired by the ERS-1/2 sensors in the time interval 1992–2000 were available. The DInSAR analysis allowed us to detect an unknown ground deformation effect which involves the urban area of Satriano di Lucania, located close to Potenza. An on-site ERT survey was then carried out in order to characterize in detail the physical properties of the terrains involved in the main deformation pattern detected via the DInSAR processing. The integration of the DInSAR and ERT measurements permitted us to investigate areas where the deformation have space-variant characteristics and allowed us to formulate a hypothesis on the origin of the detected displacement processes that, although not fully conclusive, is consistent with the overall DInSAR and ERT analysis.     

Insights into Wasatch fault vertical slip rates using the age of sediments in Timpanogos Cave, Utah

Timpanogos Cave, located near the Wasatch fault, is about 357 m above the American Fork River. Fluvial cave sediments and an interbedded carbonate flowstone yield a paleomagnetic and U–Th depositional age of 350 to 780 ka. Fault vertical slip rates, inferred from calculated river downcutting rates, range between 1.02 and 0.46 mm yr^− 1. These slip rates are in the range of the 0–12 Ma Wasatch Range exhumation rate ( 0.5–0.7 mm yr^− 1), suggesting that the long-term vertical slip rate remained stable through mid-Pleistocene time. However, the late Pleistocene (0–250 ka) decelerated slip rate ( 0.2–0.3 mm yr^− 1) and the accelerated Holocene slip rate ( 1.2 mm yr^− 1) are consistent with episodic fault activity. Assuming that the late Pleistocene vertical slip rate represents an episodic slowing of fault movement and the long-term (0–12 Ma) average vertical slip rate, including the late Pleistocene and Holocene, should be  0.6 mm yr^− 1, there is a net late Pleistocene vertical slip deficit of  50–75 m. The Holocene and late Pleistocene slip rates may be typical for episodes of accelerated and slowed fault movement, respectively. The calculated late Pleistocene slip deficit may mean that the current accelerated Wasatch fault slip rate will extend well into the future.     

Assessment of organic pollutants in the offshore sediments of Dubai, United Arab Emirates

Fifteen stations (st) were selected along Dubai coastal region to delineate the distribution and the source of total petroleum hydrocarbon (TPH), total organic carbon (TOC), total Kjeldhal nitrogen (TKN), polycyclic aromatic hydrocarbon (PAHs) and polychlorinated biphenyls. The concentrations of TPH fluctuated between 2 μg g ⁻¹ and 48018 μg g ⁻¹ and the values of TOC were in the range of 0.16–5.9 wt%, while TPAHs ranged from 0.09 μg g ⁻¹ to 161.72 μg g ⁻¹. On the other hand, TPCBs showed values between 0.8 μg kg⁻¹ and 93.3 μg kg⁻¹ and TKN values varied from 218 μg g⁻¹ to 2457 μg g ⁻¹. Distribution of oil and organic compounds in Dubai sediments are safe compared with previous studies except for limited areas at the northeastern offshore. These readings are probably due to: (1) presence of commercial or industrial ports, dry docks and fishing harbours and (2) population centers mainly concentrated at the northern part of the study area. Results indicate that TOC can be used as indicator of oil pollution only in heavily oiled sediments. The highest values of TOC, TPH, TPAHs and TPCBs corresponded to the stations covered with fine sand, due to adsorption properties and larger surface area. The evaporation of low boiling point compounds from surface layers led to enrichment of sediments with the thick residual. Al-Hamriya St 3 exhibited the highest values of TPH, TOC, TPAHs and TPCBs and the second highest value of TKN.     

Modeling of seismic hazard for Turkey using the recent neotectonic data

Recent developments in the neotectonic framework of Turkey introduced new tectonic elements necessitating the reconstruction of Turkey's seismic hazard map. In this regard, 14 seismic source zones were delineated. Maximum earthquake magnitudes for each seismic zones were determined using the fault rupture length approximation. Regression coefficients of the earthquake magnitude–frequency relationships for the seismic zones were compiled mostly from earlier works. Along with these data, a strong ground motion attenuation relationship developed by Joyner and Boore [Joyner, W.B., Boore, D.M., 1988. Measurement, characterization, and prediction of strong ground motion. Earthquake Engineering and Soil Dynamics, 2. Recent Advances Ground Motion Evaluation, pp. 43–102.] was utilized to model the seismic hazard for Turkey using the probabilistic approach. For the modeling, the “earthquake location uncertainty” concept was employed. A grid of 5106 points with 0.2° intervals was constituted for the area encompassed by the 25–46°E longitudes and 35–43°N latitudes. For the return periods of 100 and 475 years, the peak horizontal ground acceleration (pga) in bedrock was computed for each grid point. Isoacceleration maps for the return periods of 100 and 475 years were constructed by contouring the pga values at each node.     

Evaluation of trace-metal enrichments from the 26 December 2004 tsunami sediments along the Southeast coast of India

The tsunami sediments deposited after the December 2004 tsunami were sampled immediately in the coastal environment of Tamil Nadu State on the southeast coast of India. Fifty-four sediment samples were collected and 14 representative samples were selected to identify the level of metal contamination in tsunami sediments. The results indicate that the sediments are mainly of fine to medium-grained sand and contain significantly high contents of dissolved salts in sediments (Na⁺, K⁺, Ca⁺², Mg⁺², Cl⁻) in water-soluble fraction due to seawater deposition and evaporation. Correlation of acid leachable trace metals (Cr, Cu, Ni, Co, Pb, Zn) indicate that Fe-Mn oxyhydroxides might play an important role in controlling their association between them. Enrichment of trace metals is observed in all the locations with reference to the background samples. High values of trace metals in the southern part of the study area are due to the large-scale industries along the coast, and they are probably anthropogenic in nature and of marine origin, which could cause serious environmental problems.     

Effects of galvanic distortions on magnetotelluric data: Interpretation and its correction using deep electrical data

The non-inductive galvanic disturbances due to surficial bodies, lying smaller than high frequency skin depth, cause serious interpretational errors in magnetotelluric data. These frequency independent distortions result in a quasi-static shift between the apparent resistivity curves known as static shift. Two-dimensional modelling studies, for the effects of surficial bodies on magnetotelluric interpretation, show that the transverse electric (TE) mode apparent resistivity curves are hardly affected compared to the transverse magnetic (TM) mode curves, facilitating the correction by using a curve shifting method to match low frequency asymptotes. But in the case of field data the problem is rather complicated because of the random distribution of geometry and conductivity of near surface inhomogeneities. Here we present the use of deep resistivity sounding (DRS) data to constrain MT static shift. Direct current sensitivity studies show that the behaviour of MT static shift can be estimated using DC resistivity measurements close to the MT sounding station to appreciable depths. The distorted data set is corrected using the MT response for DRS model and further subject to joint inversion with DRS data. Joint inversion leads to better estimation of MT parameters compared to the separate inversion of data sets.     

Astronomical time-scale for physical property records from Quaternary sediments of the northern North Atlantic

Deep sea sediment cores taken between 50° and 75°N in the North Atlantic, in water depths varying between 1340 and 3850 m, were examined to provide an astronomically calibrated late Quaternary time-scale based on physical property records. Magnetic susceptibility and gamma ray attenuation porosity evaluator (GRAPE) density changes of these cores revealed significant responses to orbital forcing in the eccentricity (100 kyr), obliquity (41 kyr) and precessional (23, 19 kyr) bands. At 75°N (Greenland Sea), a response to obliquity forcing was weak despite the fact that it should become more pronounced in sediments at high latitudes. Application of bandpass filtering at the obliquity period (41 kyr), however, showed that variance at this period did exist in the magnetic susceptibility record, but at a very low power. At 50°N stacked curves of magnetic susceptibility correlated strongly with the SPECMAP curve for the past 500 ka. Since about 65 ka, dropstone layers are recorded in both magnetic susceptibility and GRAPE data of Rockall Plateau sediments. Although Rockall Plateau sediments show peaks in physical properties that correlate with Heinrich events (H₁, H₂, H₄, H₅, H₆), such a relationship was not readily observed in Norwegian-Greenland Sea records. Heinrich events at Rockall Plateau sites indicate a northward flow of icebergs in the eastern North Atlantic. This flow pattern and the presence of Heinrich events during the past 65 ka raise the questions of whether similar events occurred before this time period, and to what kind of ice sheet dynamics and climatic-oceanographic conditions favoured major iceberg surges from the Laurentide ice sheet to the North Atlantic at 50°N.     

A morphological, sedimentological and geophysical investigation of the Woore Moraine, Shropshire, England

The Bar Hill-Whitchurch-Wrexham Morainic Complex is a large-scale glacial landform thought to represent either the maximum extent or the re-advance of the British-Irish Ice Sheet during the Late Devensian. The origin of the moraine remains uncertain as its key characteristics have not been studied in detail due to a lack of exposures from which its large-scale structure can be determined. The development of new technologies has enabled detailed examination of the topography and internal structure of such large-scale landforms. This paper describes a multi-disciplinary approach involving digital geomorphological mapping using enhanced resolution NextMAP™ digital surface models, geophysical imaging (electrical resistivity tomography) and conventional sedimentological analyses. This combination of techniques is useful for elucidating the origin of a large glacial landform in a region of poor exposure. Digital elevation models such as NextMAP™ offer an efficient and accurate method for landform-mapping, whilst electrical resistivity tomography was able to map the major constituent sediments of the moraine, which had in turn been identified in the single exposure available. Additional geophysical techniques should however be applied to provide further structural data and thereby enable a more detailed interpretation of the moraine's internal structure. Preliminary findings indicate that the moraine is a glaciotectonic landform composed of diamicton and glaciofluvial sediments, an origin consistent with recent suggestions that the Cheshire Plain contained an active ice lobe during the last glacial maximum.     

Bauxite formation on Tertiary sediments in the coastal plain of Suriname

Lateritic bauxites in the coastal lowlands of Suriname form part of a belt along the northern margin of the Guiana Shield that has long been one of the world's major bauxite producing regions. The Surinamese deposits, many of which with an extensive mining history, originated on Tertiary siliciclastic sediments and were mostly buried under a layer of young sediments. The bauxite-bearing sequences are generally topped with an iron-rich layer largely made up of hematite and goethite. It covers a gibbsite-rich bauxite horizon that passes downward into a kaolinitic bottom section containing anatase and zircon as main accessory minerals. Weathering profiles across formerly mined deposits were analyzed for geochemical and mineralogical properties aimed at exploring compositional diversity, underlying controls of bauxite-formation and the nature of precursor sediments.Studied profiles in different parts of the coastal plain reveal overall similarities between individual deposits in showing significant depletion of Si, K, Na, Mg and Ca and strong, primarily residual, relative enrichment of Al, Ti, Zr, Nb, Hf, Ta and Th. In detail, however, there are distinct differences in major and trace-element signatures, accessory mineral assemblages, facies distribution and provenance of the terrigenous precursor sediments. Enrichments in high field-strength elements and heavy rare earth elements are largely attributable to accumulation of heavy minerals like zircon in the precursor. Petrological and trace-element evidence does not support a direct genetic relationship between bauxite and the underlying saprolitic clays. The complex petrologic characteristics and compositional heterogeneity of the coastal-plain deposits can essentially be explained by element fractionation, primarily through selective leaching, in combination with relative and absolute enrichment processes, erosion and reworking during two-stage, polycyclic bauxitization of a heterogeneous precursor.