山西某芒硝矿床中硼磷镁石的研究

硼磷镁石 (Lueneburgite,)系一种稀少的含水含磷硼酸盐矿物。该矿物1870年发现于德国汉诺威的吕内堡。现已知国外产地有:美国新墨西哥二叠纪含盐盆地,苏联里海的卡拉—博加兹—戈尔海湾及喀尔巴阡的斯捷布尼克等地区。此     

Alteration of a pelagic chalk below a paleokarst surface,Oxford, South Island,New Zealand

A small isolated outlier of Lower Oligocene chalk, which grades upwards into what was originally a sandy marl, has been truncated by a paleokarst surface, which is overlain by cross-bedded, well-sorted glauconitic sands. A sandy clay horizon (probably originally tuffaceous) and a basaltic lava flow of probable Miocene age cap the local sequence. Below the paleokarst surface and roughly parallel to it, the original sediment has been intensely altered to an average depth of 1.5 m. The alteration front is sharply defined, even where it extends along the walls of glauconitic sand-filled fissures in the chalk.In the alteration zone, the chalk has been entirely replaced by silica (opal-CT, largely in the form of lepispheres). The calcareous fraction of the marl has been replaced by montmorillonite and clinoptilolite. Rounded gravel clasts (largely basaltic) in the base of the overlying glauconitic sands also have been replaced (by montmorillonite), which suggests that all alteration followed deposition of the sands. However, neither the glauconite nor any other mineral in the sands appears highly altered. Similarly, the quartz grains show no evidence of dissolution or silica precipitation. Preservation of most silica sponge spicules, the only siliceous microfossils in the chalk, indicates that the source of the silica was extraneous to the carbonate sediments.Migrating interstitial liquid, largely confined to the sands between the impervious cap of sandy clay plus basalt and the porous but less permeable chalk, is inferred to have been the causal agent for the replacement. Silica, and any other components necessary for the formation of opal-CT, montmorillonite and clinoptilolite, were probably derived by chemical alteration of the capping volcanics in a groundwater regimen. Replacement reactions in the chalk and marl presumably were dependent on the original presence of calcium carbonate, and apart from montmorillonitization of volcanic material, occurred only where this compound was present.     

The environmental influence of a volcanic plume,a new technique of study,Mount Etna,sicily

Detailed study of the chemistry of volcanic plumes has previously been hindered by the difficulties of sampling, particularly if data on trace elements are required. In an attempt to overcome this problem, and to learn more about the regional effects of the plume of Mt. Etna, it was decided to investigate whether lichens, which are used as indicators of aerial pollution, would be suitable for this type of study. Samples collected from the slopes of Etna were assayed, mainly for heavy metals. The results show that this technique has great potential, that lichens can be used to determine semiquantitatively the minor and trace element composition of the plume, and can detect the influence of the plume on the chemistry of local rainfall.     

Brussels, a truncated metropolis

This paper describes and analyses the geographical development and the governmental, budget and administrative structure of Brussels. It defines the place Brussels occupies among the cities of Europe and assesses the value of its Regional Development Plan. Brussels appears to be highly successful in international inter-city competition, but it also appears to be unable to develop a strategy for dealing with the problems of the divided city it has become in the late-20th century. Key factors in explaining this paradox are a discrepancy between the political delimitation of the Brussels Capital Region (a member state of the federal state of Belgium) and the geographical urban region, and the administrative fragmentation of the Brussels Capital Region. These factors are strongly related to the reform of the Belgian state and the forces behind this reform. In the absence of a strategy based on solidarity within the metropolitan community, one has to fear for the development towards a repressive city. This revised version was published online in August 2006 with corrections to the Cover Date.     

Petrology of a mantle-derived rhyolite, Hokkaido, Japan

The Miocene Kitami rhyolite, consisting of orthopyroxene and plagioclase-phyric lavas and dikes, occurs on the back-arc side of the Kuril arc with coeval basalts and Fe-rich andesites. Temperatures estimated from orthopyroxene–ilmenite pairs exceed 900°C. Although the whole rock compositions of the Kitami rhyolite correspond to S-type granites (i.e., high K, Al, large ion lithophile elements, and low Ca and Sr), Sr–Nd isotope compositions are remarkably primitive, and similar to those of the coeval basalts and andesites. They are distinct from those of lower crustal metamorphic rocks exposed in the area. Comparison of chondrite-normalized rare earth element (REE) patterns between the rhyolite and the basalts and andesites show that the rhyolite is more light REE enriched, but has similar heavy REE contents than the basalts. All rhyolites show negative Eu anomalies. The geochemical data suggest that did not formed by simple dehydration melting of basaltic rocks or fractional crystallization of basaltic magmas. The features of slab-derived fluids expected from recent high pressure experimental studies indicates that mantle wedge is partly metasomatized with “rhyolitic” materials from subducted slabs; it is more likely that very low degree partial melting of the metasomatized mantle wedge formed the rhyolite magma.     

Evidence for a shock-metamorphic breccia within a buried impact crater,Lake Raeside,Yilgarn Craton,Western Australia

Mineral exploration drilling 60 km west of Leonora in 2008 intersected >95 m of poorly consolidated granitoid-dominated breccia at the base of a Cenozoic paleochannel beneath Lake Raeside. The breccia, initially interpreted as a kimberlite, is composed of poorly consolidated fragments of granitic gneiss, felsite and metamorphosed mafic rock within a matrix of fine to medium-grained breccia. Microscopic examination revealed quartz grains displaying well-developed planar deformation features (PDFs) dominated by the ω? {1013} planar set, diaplectic silica glass and diaplectic plagioclase glass. These features constitute the diagnostic hallmarks of shock metamorphism owing to high-velocity impact of a large meteorite or asteroid. The PDFs in quartz grains of the breccia are distinctly different from metamorphic deformation lamellae produced tectonically or in diatremes. Airborne total magnetic intensity data suggest an outline of an 11 km-diameter crater, consistent with the significant thickness of the shock-metamorphosed breccia at >95 m, suggestive of the existence of a large impact structure.     

Althausite,a new mineral from Modum,Norway

Althausite occurs as cleavable masses in serpentine-magnesite deposits at Modum, Norway. The proposed formula in Mg₂PO₄ (OH_0.37F_0.25O_0.10)_0.81 with partly vacant halide sites. It is orthorhombic, space group Pna2₁, $\text{a}\text{= 8.258,}\text{b}\text{= 14.383,}\text{c}\text{= 6.054}\text{A}\text{?}\text{, Z}\text{= 8.}\text{D(meas)}\text{=2.97, ?(}\text{calc}\text{) = 2.91}\text{g/cm}{}^3\text{(}\text{X-ray}\text{), ?(}\text{calc}\text{) = 3.06}\text{g/cm}{}^3\text{(}\text{Gladstone-Dale}\text{),}\text{H}\text{= 3}\text{1}\text{2}\text{?4.}$ The strongest X-ray powder lines (41 given, FeKα radiation) with intensities and indices are 3.593 (100)(040), 3.316 (90)(211), 3.024 (80)(002), 2.786 (60)(112), 2641 (60)(122).The mineral is light grey with vitreous lustre, running brown on alteration to apatite. Non-fluorescent. Perfect cleavage {001}, distinct cleavage {101}. It is biaxial positive, α=1.588, β=1.592, γ=1.598, 2V_γ(calc)=78.5°, negative elongation, X=b, Y=c, Z=a. IR, DTA and TGA data are given.     

Coral-stromatolite reef framework, Upper Miocene, Almería, Spain

Stromatolitic crusts on stick-like and platy Porites corals forming Messinian reefs in Almería played an important role in supporting and binding the brittle corals. The crusts were previously regarded as probable marine cements. However, their clotted, peloidal, and micritic fabrics are directly comparable with those of stromatolites. They accreted allochthonous grains even on vertical faces, and include bushy fabrics closely comparable with those produced by cyanobacterial calcification. They contain numerous fenestrae, exhibit rapid fabric variation, and locally form micro-columns and laminated domes. Their similarities to peloid micrite crusts in Recent reefs suggest that at least some of these Recent crusts are microbial in origin, even though they have widely been interpreted as marine cements. The sedimentary effects of crust development substantially affected both the morphology and relief of the reefs and the generation of reefal clasts. Binding of the reef-frame in the Pinnacle and Thicket zones in the lower and middle parts of the reef created a rigid margin which shed large (commonly up to 5 m) cuboidal blocks of coral-stromatolite frame. The blocks broke along planes of weakness provided by the vertical Porites sticks and were deposited on the Fore-Reef Slope. In the uppermost parts of the reefs crusts dominate the structure, constituting 80% or more of the rock. Veneers up to 15 cm thick encrust thin irregular Porites plates to create a solid Reef Crest Zone which has not been recognized before. The coral-stromatolite framework is associated with echinoids, crustose corallines and halimedacean algae which, together with the scleractinians, indicate normal marine salinity throughout reef growth.     

Three-dimensional temperature field simulation of a cooling of a magma chamber,La Primavera caldera,Jalisco, Mexico

The La Primavera caldera lies close to the triple junction of the Tepic-Zacoalco, Colima, and Chapala rifts in the western part of the Mexican Volcanic Belt. It is a promising geothermal field with 13 deep wells already drilled. We calculated solute geothermometric temperatures (Na–K, Na–Li, and SiO₂) from the chemistry of geothermal water samples; determined values are generally between 99°C and 202°C for springs and between 131°C and 298°C for wells. Thermal modelling is an important geophysical tool as documented in the study of this and other Mexican geothermal areas. Using the computer program TCHEMSYS, we report new simulation results of three-dimensional (3-D) thermal modelling of the magma chamber underlying this caldera through its entire eruptive history. Equations (quadratic fit) describing the simulated temperatures as a function of the age, volume and depth of the magma chamber are first presented; these indicate that both the depth and the age of the magma chamber are more important parameters than its volume. A comparison of 3-D modelling of the La Primavera and Los Humeros calderas also shows that the depth of the magma chamber is more important than its volume. The best model for the La Primavera caldera has 0.15 million years as the emplacement age of the magma chamber, its top at a depth of 4 km, and its volume as 600 km³. Fresh magma recharge events within the middle part of the magma chamber were also considered at 0.095, 0.075, and 0.040 Ma. The simulation results were evaluated in the light of actually measured and solute geothermometric temperatures in five geothermal wells. Future work should involve a smaller mesh size of 0.050 or 0.10 km on each side (instead of 0.25 km currently used) and take into account the topography of the area and all petrogenetic processes of fractional crystallization, assimilation, and magma mixing as well as heat generation from natural radioactive elements.     

翼龙重建：方法论的一个研究例子

Reconstructions of fossil animals are widespread and often very high profile, yet many of these reconstructions exhibit low standards of scientific accuracy.     

Salinization properties of a shallow groundwater in a coastal reclaimed area,Yeonggwang, Korea

The need for more agricultural or residential land has encouraged reclamation at the coastal areas of Korea since 1200 ad (approximately). The groundwaters of these reclaimed areas could be expected to reveal hydrogeochemical properties different from those of areas directly affected by seawater intrusion. The purpose of this study, therefore, was to examine the salinization of shallow groundwater in a coastal reclaimed area and to identify the effect of land reclamation on groundwater quality. Major cations and anions, iodide, total organic carbon, δD, δ ¹⁸O and δ ¹³C were measured to assist the hydrogeochemical analysis. Chloride, δD and δ ¹⁸O data clearly show that the Na–Cl type water results from mixing of groundwater with seawater. In particular, the δD and δ ¹⁸O of Ca+Mg–Cl+NO₃ type groundwaters are close to the meteoric water line, but Na–Cl type waters enriched in chloride are ¹⁸O-enriched with respect to the meteoric water line. Meanwhile, carbon isotopic data and I/Cl ratios strongly suggest that there are various sources of salinity. The δ ¹³C values of Na–Cl type groundwaters are generally similar to those of Ca+Mg–Cl+NO₃ type waters, which are depleted in ¹³C with respect to seawater. I/Cl ratios of Na–Cl type groundwater are 10–100 times higher than that of seawater. Because the reclamation has incorporated a large amount of organic matter, it provides optimum conditions for the occurrence of redox processes in the groundwater system. Therefore, the salinization of groundwater in the study area seems to be controlled not only by saltwater intrusion but also by other effects, such as those caused by residual salts and organic matter in the reclaimed sediments.     

Multicomponent diffusion of a suite of tracers (HTO, Cl, Br, I, Na, Sr, Cs) in a single sample of Opalinus Clay

Diffusion experiments with HTO, ³⁶Cl⁻, Br⁻, I⁻, ²²Na⁺, ⁸⁵Sr²⁺ and ¹³⁴Cs⁺ at trace concentrations in a single sample of Opalinus Clay are modeled with PHREEQC’s multicomponent diffusion module. The model is used first in a classical approach to derive accessible porosities, geometrical factors (the ratio of pore tortuosity and constrictivity) and sorption behavior of the individual tracers assuming that the clay is homogeneous. The accessible porosity for neutral species and cations is obtained from HTO, the anion exclusion volume from ³⁶Cl⁻ and Br⁻, and the cation exchange capacity from ²²Na⁺. The homogeneous model works well for tritium, the anions and ²²Na⁺. However, the ⁸⁵Sr²⁺ and ¹³⁴Cs⁺ experiments show an early arrival of the tracer and a front-form that suggest a dual porosity structure. A model with 10% dead-end pores, containing 19% of the total exchange capacity, can satisfactorily calculate all the experimental data. The Cs⁺ diffusion model builds on a 3-site exchange model, constructed from batch sorption data. The excellent agreement of modeled and measured data contradicts earlier reports that the exchange capacity for Cs⁺ would be smaller in diffusion than in batch experiments.The geometrical factors for the anions are 1.5 times larger than for HTO, and for the cations 2-4 times smaller than for HTO. The different behavior is explained by a tripartite division of the porespace in free porewater, diffuse double layer (DDL) water, and interlayer water in montmorillonite. Differences between estimated and observed geometrical factors for cations are attributed to increased ion-pairing of the divalent cations in DDL water as a result of the low relative dielectric permittivity. Interlayer and/or surface diffusion contributes significantly to the diffusive flux of Cs⁺ but is negligible for the other solutes. The geometrical factors for anions are higher than estimated, because pore constrictions with overlapping double layers force the anions to take longer routes than HTO and the cations. Small differences among the anions can also be attributed to different ion-pairing in DDL water.     

The motion of a globular cluster inside a rotating,layered, inhomogeneous elliptical galaxy

We consider the spatial motion of a globular cluster with a constant or variable mass inside a rotating, layered, inhomogenous elliptical galaxy with a constant or variable mass. An analog to the Jacobi integral is found, regions of possiblemotion are determined, and zero-velocity surfaces constructed. Stationary solutions (libration points) are determined, together with their stability according to the Lyapunov criterion. In the case of variable mass, the autonomization method is used to solve the equations of motion, and the autonomization criteria used to establish an analog of the Eddington-Jeans law for the variation of the density of the galaxy.     

Precipitation of iron,manganese, zinc,and copper on clean,ceramic surfaces in a stream draining a polymetallic sulfide deposit

Acid-cleaned ceramic plates placed upstream and downstream from a Cu-Zn-Pb sulfide deposit (Magruder mine) developed a precipitate of Fe-Mn oxides in a 36-day period. Copper and Zn concentrations on the coated surface, normalized to surface area and ratios with Fe and/or Mn, are distinctly anomalous for a distance of 2 km downstream from the mine.The major source of metals in the coatings is interpreted to be groundwater percolating into the stream bed. Anomalous concentrations of Cu and Zn in groundwater from the Magruder mine area, due to oxidation of sulfide minerals, probably accounts for the anomaly identified on the ceramic plates.     

Trapped liquid from a nepheline syenite: a re-evaluation of Na-, Zr-, F-rich interstitial glass in a xenolith from Tenerife, Canary Islands

Interstitial glass and pyroxene in a nepheline syenite described by Wolff (1987) have been more precisely and accurately re-analysed using a cryogenic microprobe technique. The glass compositions, with Na₂O = 13.4−17.0 wt.% and (Na+K)/Al = 1.81−2.26 at SiO₂ = 53−56.5 wt.% (on a 100% normalised basis) are more extreme than any known erupted magma. ZrO₂ contents of the glasses are 1.4%–1.8% by weight, while F ranges between 1% and 1.4%. The high Zr content is due to the failure of a Zr-silicate phase to precipitate, despite predicted zircon saturation of the liquids above their probable quench temperatures. Partitioning of Zr between pyroxene and liquid is highly variable and apparently controlled by sector zoning; Zr is preferentially incorporated into aegirine {001} growth sectors. The glasses demonstrate the extent to which peralkaline phonolitic liquids can be fractionated in closed magma systems.     

Characterisation of a Natural Quartz Crystal as a Reference Material for Microanalytical Determination of Ti,Al, Li,Fe, Mn,Ga and Ge

A natural smoky quartz crystal from Shandong province, China, was characterised by laser ablation ICP‐MS, electron probe microanalysis (EPMA) and solution ICP‐MS to determine the concentration of twenty‐four trace and ultra trace elements. Our main focus was on Ti quantification because of the increased use of this element for titanium‐in‐quartz (TitaniQ) thermobarometry. Pieces of a uniform growth zone of 9 mm thickness within the quartz crystal were analysed in four different LA‐ICP‐MS laboratories, three EPMA laboratories and one solution‐ICP‐MS laboratory. The results reveal reproducible concentrations of Ti (57 ± 4 μg g^?1), Al (154 ± 15 μg g^?1), Li (30 ± 2 μg g^?1), Fe (2.2 ± 0.3 μg g^?1), Mn (0.34 ± 0.04 μg g^?1), Ge (1.7 ± 0.2 μg g^?1) and Ga (0.020 ± 0.002 μg g^?1) and detectable, but less reproducible, concentrations of Be, B, Na, Cu, Zr, Sn and Pb. Concentrations of K, Ca, Sr, Mo, Ag, Sb, Ba and Au were below the limits of detection of all three techniques. The uncertainties on the average concentration determinations by multiple techniques and laboratories for Ti, Al, Li, Fe, Mn, Ga and Ge are low; hence, this quartz can serve as a reference material or a secondary reference material for microanalytical applications involving the quantification of trace elements in quartz.     

Naquite,FeSi, a New Mineral Species from Luobusha,Tibet, Western China

A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral is cubic, space group P213. The irregular crystals range from 15 to 50 μm in diameter and form an intergrowth with luobusaite. Naquite is steel grey in color, opaque, with a metallic lustre and gives a grayish-black streak. The mineral is brittle, has a conchoidal fracture and no apparent cleavage. The estimated Mohs hardness is 6.5, and the calculated density is 6.128 g/cm3. Unit-cell parameters are a 4.486 (4) ?, V 90.28 (6) ?3, Z=4. The five strongest powder diffraction lines [d in ? (hkl) (I/I0)] are: 3.1742 (110) (40), 2.5917(111) (43), 2.0076 (210) (100), 1.8307 (211) (65), and 1.1990 (321) (36). Originally called ‘fersilicite’, the species and new name have now been approved by the CNMNC (IMA 2010–010).