A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

Hydrogeology of limited aquifer in a granitic terrain

 Detailed hydrogeological studies in a granitic micro-watershed have been carried out to determine the extent, behavior, and characteristics of the aquifer. The study includes analysis of lithologs, drill time log, pumping tests, and slug tests. Realistic field conditions have been taken into account for characterizing the aquifer system. Slug tests were carried out to estimate aquifer parameters at the wells which could not sustain pumping. Received: 20 November 1997 · Accepted: 23 February 1998     

Correlation between nitrate concentration in groundwater and parameters affecting aquifer intrinsic vulnerability

This paper is the result of a study which was carried out in order to verify if the traditional methods to evaluate the intrinsic vulnerability or vulnerability related parameters, are able to clarify the problem of nitrate pollution in groundwater. In particular, the aim was to evaluate limitations and problems connected to aquifer vulnerability methods applied to nitrate contamination prevision in groundwater. The investigation was carried out by comparing NO₃ ⁻ concentrations, measured in March and November 2004 in the shallow aquifer, and the vulnerability classes, obtained by using GOD and TOT methods. Moreover, it deals with a comparison between NO₃ ⁻ concentrations and single parameters (depth to water table, land use and nitrogen input). The study area is the plain sector of Piemonte (Northern Italy), where an unconfined aquifer nitrate contamination exists. In this area the anthropogenic presence is remarkable and the input of N-fertilizers and zootechnical effluents to the soil cause a growing amount of nitrates in groundwater. This approach, used in a large area (about 10,000 km²) and in several monitoring wells (about 500), allowed to compare the efficiency of different vulnerability methods and to verify the importance of every parameter on the nitrate concentrations in the aquifer. Furthermore it allowed to obtain interesting correlations in different hydrogeological situations. Correlations between depth to water table, land use and nitrogen input to the soil with nitrate concentrations in groundwater show unclear situations: in fact these comparisons describe the phenomenon trend and highlight the maximum nitrate concentrations for each circumstance but often show wide ranges of possible nitrate concentrations. The same situation could be observed by comparing vulnerability indexes and nitrate concentrations in groundwater. These results suggest that neither single parameters nor vulnerability methods (GOD and TOT) are able to describe individually the complex phenomena affecting nitrate concentrations in soil, subsoil and groundwater. In particular, the traditional methods for vulnerability analysis do not analyze physical processes in aquifers, such as denitrification and nitrate dilution. According to a recent study in the shallow unconfined aquifer of the Piemonte plain, dilution can be considered as the main cause for nitrate attenuation in groundwater.     

A natural-gradient field tracer test for evaluation of pollutant-transport parameters in a porous-medium aquifer

This paper describes a natural-gradient field tracer test to characterise solute-transport properties in a sand and gravel aquifer in the Hebei Province, northern China. Some laboratory-scale column tests on aquifer material and a local-scale field borehole-dilution test have been conducted previously, but the field test reported herein represents the only large-scale tracer test in the aquifer, which is the sole water supply to the city of Shi Jiazhuang and which is threatened by urban pollution. The aim of the study was to quantify the transport behaviour of nonreactive pollutants in this aquifer. Little quantitative data are available concerning its solute-transport properties; thus, the results of the tracer test are significant and critical for understanding pollutant transport and fate. The in-situ tracer test was carried out in the aquifer using a slug injection of the geochemically conservative, radioactive iodine tracer ¹³¹I. The longitudinal (α _L ) and transverse (α _T ) hydrodynamic dispersivities for solute transport in the field are 1.72 and 0.0013 m, respectively. The ratio of longitudinal dispersivity α _L and the flow length at the field scale is 1:10. The ratio between α _L and α _T from the in-situ test (~1,300:1) demonstrates a dominant longitudinal dispersion in this fluvial sand and gravel aquifer. The tracer test further indicates a relatively short transit time for the aquifer (linear velocities ~13 m/d) under natural-gradient conditions. Electronic Publication     

Assessment of aquifer vulnerability to contamination in Khanyounis Governorate, Gaza Strip—Palestine, using the DRASTIC model within GIS environment

Groundwater is a very important natural resource in Khanyounis Governorate (the study area) for water supply and development. Historically, the exploitation of aquifers in Khanyounis Governorate has been undertaken without proper concern for environmental impact. In view of the importance of quality groundwater, it might be expected that aquifer protection to prevent groundwater quality deterioration would have received due attention. In the long term, however, protection of groundwater resources is of direct practical importance because, once pollution of groundwater has been allowed to occur, the scale and persistence of such pollution makes restoration technically difficult and costly. In order to maintain basin aquifer as a source of water for the area, it is necessary to find out, whether certain locations in this groundwater basin are susceptible to receive and transmit contamination. This study aims to: (1) assess the vulnerability of the aquifer to contamination in Khanyounis governorate, (2) find out the groundwater vulnerable zones to contamination in the aquifer of the study area, and (3) provide a spatial analysis of the parameters and conditions under which groundwater may become contaminate. To achieve that, DRASTIC model within geographic information system (GIS) environment was applied. The model uses seven environmental parameters: depth of water table, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity to evaluate aquifer vulnerability. Based on this model and by using ArcGIS 9.3 software, an attempt was made to create vulnerability maps for the study area. According to the DRASTIC model index, the study has shown that in the western part of the study area the vulnerability to contamination ranges between high and very high due to the relatively shallow water table with moderate to high recharge potential, and permeable soils. To the east of the previous part and in the south-eastern part, vulnerability to contamination is moderate. In the central and the eastern part, vulnerability to contamination is low due to depth of water table. Vulnerability analysis of the DRASTIC Model indicates that the highest risk of contamination of groundwater in the study area originates from the soil media. The impact of vadose zone, depth to water level, and hydraulic conductivity imply moderate risks of contamination, while net recharge, aquifer media, and topography impose a low risk of aquifer contamination. The coefficient of variation indicates that a high contribution to the variation of vulnerability index is made by the topography. Moderate contribution is made by the depth to water level, and net recharge, while impact of vadose zone, hydraulic conductivity, soil media, and Aquifer media are the least variable parameters. The low variability of the parameters implies a smaller contribution to the variation of the vulnerability index across the study area. Moreover, the “effective” weights of the DRASTIC parameters obtained in this study exhibited some deviation from that of the “theoretical” weights. Soil media and the impact of vadose zone were the most effective parameters in the vulnerability assessment because their mean “effective” weights were higher than their respective “theoretical” weights. The depth of water table showed that both “effective” and “theoretical” weights were equal. The rest of the parameters exhibit lower “effective” weights compared with the “theoretical” weights. This explains the importance of soil media and vadose layers in the DRASTIC model. Therefore, it is important to get the accurate and detailed information of these two specific parameters. The GIS technique has provided an efficient environment for analysis and high capabilities of handling large spatial data. Considering these results, DRASTIC model highlights as a useful tool that can be used by national authorities and decision makers especially in the agricultural areas applying chemicals and pesticides which are most likely to contaminate groundwater resources.     

Hydrogeological and hydrochemical framework of regional aquifer system in Kali-Ganga sub-basin, India

 The central Ganga Basin is one of the major groundwater reservoirs in India. The Kali-Ganga sub-basin is a micro watershed of the central Ganga Basin, containing a number of productive aquifers. A detailed hydrogeological investigation was carried out, which reveals the occurrence of a single-tier aquifer system down to 163 m bgl (metres below ground level), but at places it is interleaved with clay layers; thus imparting it a two-to three-tier aquifer system. These aquifers are unconfined to confined in disposition. The transmissivity, storage coefficient and hydraulic conductivity are determined as 2178 m²/day, 1.12×10^–5 and 120 m/day, respectively. The groundwater of the basin is fresh, of an alkali-bicarbonate type and is suitable for irrigation and domestic use. However, in certain areas, extensive agricultural activities, and domestic and industrial effluents have caused some deterioration of groundwater quality. This study contains data of where the concentration of Fe, Pb, Cd, Cr and Ni are higher than the permissible limits, which may be hazardous to public health. Received: 2 March 2000 · Accepted: 3 July 2000     

Groundwater resource development in Jamui District,Bihar, India: an overview

Because agriculture is the main source of livelihood for the bulk of the population in Jamui District, the importance of developing irrigation facilities in any programme of economic regeneration can hardly be over emphasized. It is, therefore, imperative that groundwater development be considered as an important step to drought mitigation in the Jamui district. The present study was carried out in such a way that technical and economic viability of any groundwater development plan can be thoroughly scrutinized. In this paper the hydrogeological framework of the district was established based on aquifer disposition, orientation of potential fracture systems and their hydraulic characteristics. Considering the aquifer geometry and yield potential of different structures, a blueprint for a groundwater development plan was prepared. An economic analysis of the development plan also was attempted. The analysis yielded results that made it possible to evaluate parameters such as cost–benefit ratio, incremental benefits and internal rate of return used to assess the economic viability of the groundwater development plan. Electronic Publication     

Electrical imaging of the groundwater aquifer at Banting,Selangor, Malaysia

A geophysical study was carried out in the Banting area of Malaysia to delineate groundwater aquifer and marine clay layer of the alluvial Quaternary deposits of Beruas and Gula Formations. The Beruas Formation is formed by peat and clayey materials as well as silt and sands, whereas the Gula Formation consists of clay, silt, sand and gravels. Both Formations were deposited on top of the Carboniferous shale of the Kenny Hill Formation. A 2-D geoelectrical resistivity technique was used. Resistivity measurement was carried out using an ABEM SAS 4000 Terrameter. The 2-D resistivity data of subsurface material for each survey line was calculated through inverse modelling and then compared with borehole data. The resistivity images of all the subsurface material below the survey lines show similar pattern of continuous structure of layering or layers with some lenses with resistivity ranging from 0.1 to 50 Ωm. The upper layer shows resistivity values ranging from 0.1 to 10 Ωm, representing a clay horizon with a thickness up to 45 m. The second layer with depth varies from 45 to 70 m below surface and has resistivity values ranging from 10 to 30 Ωm. Borehole data indicate coarse sand with some gravels for this layer, which is also the groundwater aquifer in the study area. The lowermost layer at a depth of 70 m below ground level shows resistivity values ranging from 30–50 Ωm and can be correlated with metasedimentary rocks consisting of shale and metaquartzite.     

Variations in hydraulic conductivity with scale of measurement during aquifer tests in heterogeneous, porous carbonate rocks

 Previous studies have shown that hydraulic conductivity of an aquifer seems to increase as the portion of the aquifer tested increases. To date, such studies have all relied on different methods to determine hydraulic conductivity at each scale of interest, which raises the possibility that the observed increase in hydraulic conductivity is due to the measurement method, not to the scale. This study analyzes hydraulic conductivity with respect to scale during individual aquifer tests in porous, heterogeneous carbonate rocks in southeastern Wisconsin, USA. Results from this study indicate that hydraulic conductivity generally increases during an individual test as the volume of aquifer impacted increases, and the rate of this increase is the same as the rate of increase determined by using different measurement methods. Thus, scale dependence of hydraulic conductivity during single tests does not depend on the method of measurement. This conclusion is supported by 22 of 26 aquifer tests conducted in porous-flow-dominated carbonate units within the aquifer. Instead, scale dependency is probably caused by heterogeneities within the aquifer, a conclusion supported by digital simulation. All of the observed types of hydraulic-conductivity variations with scale during individual aquifer tests can be explained by a conceptual model of a simple heterogeneous aquifer composed of high-conductivity zones within a low-conductivity matrix. Received, January 1997 Revised, August 1997, November 1997 Accepted, November 1997     

Modified DRASTIC assessment for intrinsic vulnerability mapping of karst aquifers: a case study

Groundwater in karstic aquifers can be dangerously sensitive to contamination. In this paper, DRASTIC assessment was modified and applied, for the first time, to address the intrinsic vulnerability for karst aquifers. The theoretical weights of two of DRASTIC’s parameters (aquifer media and hydraulic conductivity) were modified through sensitivity analysis. Two tests of sensitivity analyses were carried out: the map removal and the single parameter sensitivity analyses. The modified assessment was applied for the karst aquifers underlying Ramallah District (Palestine) as a case study. The aquifer vulnerability map indicated that the case study area is under low, moderate and high vulnerability of groundwater to contamination. The vulnerability index can assist in the implementation of groundwater management strategies to prevent degradation of groundwater quality. The modified DRASTIC assessment has proven to be effective because it is relatively straightforward, use data that are commonly available or estimated and produces an end product that is easily interpreted.     

Hydrogeochemical stratification of the unconfined Samobor aquifer (Zagreb,Croatia)

In the western part of the city of Zagreb, Croatia, hydrogeochemical and isotopic investigations of the Samobor aquifer were carried out with the aim of determining the differences in hydrogeochemical characteristics at increasing aquifer depths. The aquifer comprises 40-m thick gravelly–sandy deposits, with lenses and interlayers of silt and clay. The analyses have proven that with increasing aquifer depth, there are decreases in groundwater temperature and the values of electrical conductivity and increases in the sodium, iron and manganese concentrations. The δ¹³C distribution shows an evident increase in biogenic carbon concentrations with increasing aquifer depth. The measured specific ¹⁴C activities showed that the deeper part of the aquifer is characterized by slow water exchange, while the shallower part is influenced by current recharge, although the pumping wells located on the well-field downstream penetrate the aquifer fully. A direct exchange of water from the Sava River and groundwater occurs in the near vicinity of the river. This exchange weakens further away, while the difference in hydrogeochemical characteristics between the Sava River water and groundwater increases.     

Modeling of lithology induced chemical anomalies in the aquifer systems of the Kazan Trona deposit area, Ankara, Turkey

The study was carried out in order to investigate existing hydrogeochemical relationships between groundwater environment and geological units in the Kazan trona deposit area, Ankara, Turkey. Evaluations indicate that concentrations of alkalinity, boron, chloride and sodium in the upgradient groundwater of the Eocene sedimentary units gradually increase toward downgradient by the interactions of saline minerals (searlesite, shortite, northupite and pyrite) present in the secondary structures (microfractures and irregular voids) at various levels. Inverse modeling calculations suggest that the range of dissolved mass amounts in millimoles per kilogram of water for searlesite, shortite and northupite minerals are 0.05–28.67, 2.62–24.39 and 0.01–24.19, respectively, in the aquifer between the upgradient and downgradient locations. The ranges of accompanying calcite and dolomite precipitations are 4.54–48.71 and 2.16–24.08 mmol per kg of water, respectively. Chemical composition of the groundwater in the overlying Neogene sedimentary unit includes also higher concentrations of the major ions as measured in groundwater of the underlying units. However the lack of saline mineral zones in the Neogene unit indicates that upward groundwater mixing takes place from the underlying aquifer as also suggested by the measured upward gradient. The mixing percentage of the underlying groundwater as determined from the nested wells ranges from 2.7 to 48.3%, from upgradient to downgradient, respectively. The unconfined alluvium aquifer overlying the Neogene unit includes relatively dilute groundwater except in two locations, where high-ion concentrations detected in groundwater of the underlying units are also high in these locations, suggesting upward groundwater mixing from the underlying aquifer due to upward gradient. However, groundwater input investigations from the alluvium aquifer to the nearby Ova stream indicate that the detected high concentrations in these locations are diluted or sorbed by the aquifer material toward downgradient (Ova Stream).     

Simulation of seawater intrusion into the Khan Yunis area of the Gaza Strip coastal aquifer

 The Gaza Strip coastal aquifer is under severe hydrological stress due to over-exploitation. Excessive pumping during the past decades in the Gaza region has caused a significant lowering of groundwater levels, altering in some regions the normal transport of salts into the sea and reversing the gradient of groundwater flow. The sharp increase in chloride concentrations in groundwater indicates intrusion of seawater and/or brines from the western part of the aquifer near the sea. Simulations of salt-water intrusion were carried out using a two-dimensional density-dependent flow and transport model SUTRA (Voss 1984). This model was applied to the Khan Yunis section of the Gaza Strip aquifer. Simulations were done under an assumption that pumping rates increase according to the rate of population growth, or about 3.8% a year. Model parameters were estimated using available field observations. Numerical simulations show that the rate of seawater intrusion during 1997–2006 is expected to be 20–45 m/yr. The results lead to a better understanding of aquifer salinization due to seawater intrusion and give some estimate of the rate of deterioration of groundwater. Received, September 1997 Revised, January 1998, July 1998 Accepted, August 1998     

Modelling the response of an alluvial aquifer to anthropogenic and recharge stresses in the United States Southern Great Plains

This paper uses Visual MODFLOW to simulate potential impacts of anthropogenic pumping and recharge variability on an alluvial aquifer in semi-arid northwestern Oklahoma. Groundwater withdrawal from the aquifer is projected to increase by more than 50% (relative to 1990) by the year 2050. In contrast, climate projections indicate declining regional precipitation over the next several decades, creating a potential problem of demand and supply. The following scenarios were simulated: (1) projected groundwater withdrawal, (2) a severe drought, (3) a prolonged wet period, and (4) a human adjustment scenario, which assumes future improvements in water conservation measures. Results indicate that the combined impacts of anthropogenic pumping and droughts would create drawdown of greater than 12 m in the aquifer. Spatially, however, areas of severe drawdown will be localized around large-capacity well clusters. The worst impacts of both pumping and droughts will be on stream–aquifer interaction. For example, the projected aquifer pumpage would lead to a total streamflow loss of 40%, creating losing stream system regionally. Similarly, a severe drought would lead to a total streamflow loss of >80%. A post-audit of the model was also carried out to evaluate model performance. By simulating various stress scenarios on the alluvial aquifer, this study provides important information for evaluating management options for alluvial aquifers.     

The hydrogeochemical characterization of Morsott-El Aouinet aquifer, Northeastern Algeria

A study of the hydrogeochemical processes in the Morsott-El Aouinet aquifer was carried out with the objective of identifying the geochemical processes and their relation with groundwater quality as well as to get an insight into the hydrochemical evaluation of groundwater. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation have been carried out using chemical and isotopic data to deduce a hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies and factors controlling groundwater quality. The ionic speciation and mineral dissolution/precipitation was calculated by WATEQF package software. The increase in salinity is related to the dissolution and/or precipitation processes during the water–rock interaction and to the cationic exchange reactions between groundwater and clay minerals. The isotopic analysis of some groundwater samples shows a similarity with the meteoric waters reflect their short residence time and a lowest evaporation phenomenon of infiltrated groundwater.     

基于遥感技术估算藏东南山区地下水径流模数方法

如何科学评估野外场地条件下的地下水径流模数对于满足工程水文地质需求具有重要应用价值.结合现场调查、遥感解译和气象水文观测等技术手段,通过建立线性回归模型,开展了帕隆藏布流域场地条件下的地下水径流模数估算研究.结果表明:研究区具有典型的季节性积雪融雪规律.冬季积雪在夏季大量融化产流,作为地下水的一个额外补给源.去除融雪产流对径流模数影响后,研究区岩浆岩裂隙型、变质岩裂隙型、碎屑岩裂隙型、碳酸盐岩-碎屑岩裂隙溶隙型含水介质地下水径流模数分别在1.081~2.792 L/s·km2、1.833~3.225 L/s·km2、1.128~2.889 L/s·km2、3.455~3.879 L/s·km2之间.估算结果显示本文所建立的地下水径流估算模型可作为藏东南地区及类似条件区域地下水径流模数估算新方法,为雅鲁藏布江下游梯级开发等大型基础工程提供重要的水文地质参数支撑.      

江夏法泗岩溶塌陷区冲孔桩施工引发岩溶塌陷的成因机理

依托武汉市岩溶地面塌陷区监测系统,开展江夏法泗冲孔桩施工过程裂隙岩溶含水层的水位、水压力和影响半径等关键参数的动态监测,研究施工过程岩溶含水层水压力的动态响应,探讨其诱发覆盖层突然塌陷的成因机理,结果表明:在第四系孔隙承压水含水层施工时,对该含水层的影响较大,但水位变幅相对较为平缓;在碳酸盐岩裂隙岩溶水含水层施工时,由于含水介质的不均一性,未揭穿岩溶通道时,对岩溶水的影响较小;当揭穿岩溶通道时,岩溶水水位可能产生突增,此时,诱发岩溶地面塌陷的风险加大。      

Hydrogeological characterization of a carbonate aquifer using geophysical and geochemical approach: case of the Krachoua Formation in Tataouine area,Southern Tunisia

An integrated hydrogeological investigation involving geological surface data, well data (lithostratigraphical and piezometric data) and the vertical electrical sounding (VES) method was carried out in Tataouine area, Southern Tunisia to characterize the hydrogeology and the geochemistry of the Krachoua Formation aquifer. The electrical data were used to differentiate lithostratigraphic units and characterize their hydrogeological potentialities. Major elements contents within groundwater samples were assessed and some plots and diagrams have been established in order to investigate the hydrochemical properties of this aquifer and the origin of its mineralization. The Krachoua aquifer exhibits a general drawdown of the piezometric level from 2004 to 2015 reflecting a dramatic decrease in groundwater resources due to increased groundwater abstraction during the last decades. Flow directions shows that the recharge of this aquifer considered as a free aquifer is directly ensured by rainfalls over the outcropping fractured limestones. The geometry of the Krachoua Formation aquifer is tectonically controlled and structured in horst and graben features that impacted greatly the hydrogeology and the hydrodynamics of the area. Subsequent thickness and facies variations within this aquifer influenced the reservoir quality and the groundwater flows. The increased values of salinity to the northwest of the study area seems to be mainly related to the dissolution of the Upper Liassic gypsum of Mestaoua Formation which outcrops widely and can be dissolute easily by meteoric water and contaminate the Krachoua aquifer. This fact is also supported by the sulfated and calci-magnesian chloride facies of this aquifer related to the dissolution of evaporitic rocks (gypsum, anhydrite, and halite). However low salinity values are recorded within the zone where these evaporitic rocks are relatively deep.     

Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh, India

Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater level, EC and pH were measured insitu. The major ion concentrations such as Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, and SO₄ ²⁻ were analyzed using ion chromatograph. CO₃ ⁻ and HCO₃ ⁻ concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ while that of anions is HCO₃ ⁻ > SO₄ ²⁻ > Cl⁻ > CO₃ ⁻. Ca–HCO₃, Na–Cl, Ca–Na–HCO₃ and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater. In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes, ion exchange and dissolution of minerals.