闽江河口区沉积物中的抗生素分布特征及生态风险评价

采用固相萃取和液相色谱串联质谱(HPLC-MS/MS)分析方法对闽江河口区域沉积物中8类54种抗生素的含量以及分布特征进行分析探讨,并利用熵值法对抗生素的生态风险进行评价。结果表明,闽江河口区域24个站点共检出6类(大环内酯类、磺胺类、喹诺酮类、氯霉素类、硝基咪唑类和苯并咪唑类)19种抗生素,总量范围在4.16~64.74 ng/g,平均值为17.35 ng/g;其中大环内酯类、喹诺酮类和硝基咪唑类抗生素检出频率达到100%。抗生素总量的空间分布情况呈闽江河口上游>北港>南港>河口下游的趋势,人口密集区生活污水和医疗废水排放是上游和北港沉积物大环内脂类和喹诺酮类抗生素含量较高的主要原因,而海水养殖过程中的直接投放可能是河口下游硝基咪唑类抗生素的主要来源;生态风险评价结果显示,大部分抗生素的生态风险值RQ<1,然而替米考星和甲硝唑在研究区域的RQ>1,具有一定的潜在风险,可能会对该区域生态环境产生负面效应。     

福建漳江口红树林保护区浮游植物群落的季节变化研究

于2001年1月～2003年1月对福建省漳江口红树林区水体浮游植物群落的季节变化进行了研究。结果表明,漳江口红树林区浮游植物以硅藻门种类为主,优势种为长菱形藻(Nitzschia longissima)和菱形藻(Nitzschia sp.1)等,同时出现多种裸藻、绿藻和甲藻。本次调查共鉴定到浮游植物31属87种(包括变种),其中硅藻门23属75种(包括变种),蓝藻门3属3种,绿藻门1属4种,金藻门1属1种,甲藻门2属2种,裸藻门1属2种。浮游植物密度变化范围为2.78×104～1.14×106个/L,平均为3.51×105个/L,季节变化为双峰型。出现大量的底栖硅藻和淡水性藻类是该水域浮游植物的一个特点。浮游植物的组成和结构表明该水域水质较好。     

我国近岸海域富营养化评价新方法及应用

参考目前国际上被广泛应用的第2代富营养化评价方法体系,结合我国近岸海域生态环境特点和监测资料现状,建立了一种以压力-状态-响应模式为基本框架、以富营养化症状为主的第2代近岸海域富营养化评价体系。实际应用结果表明,应用本方法得出的长江口海域富营养化状况评价结论,与目前国外主流评价方法的评价结论一致,而且本方法具有评价指标代表性强、数据资料易得、评价标准有据、方法简便易行等优点。     

我国近岸海域富营养化评价新方法及应用

参考目前国际上被广泛应用的第2代富营养化评价方法体系,结合我国近岸海域生态环境特点和监测资料现状,建立了一种以压力-状态-响应模式为基本框架、以富营养化症状为主的第2代近岸海域富营养化评价体系。实际应用结果表明,应用本方法得出的长江口海域富营养化状况评价结论,与目前国外主流评价方法的评价结论一致,而且本方法具有评价指标代表性强、数据资料易得、评价标准有据、方法简便易行等优点。     

Silver in Tokyo Bay estuarine waters and Japanese rivers

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.     

Distributions of carbohydrates, including uronic acids, in estuarine waters of Galveston Bay

The concentrations of carbohydrates, including uronic acids, in dissolved (≤0.45μm) and colloidal (1 kDa—0.45 μm) phases were measured in estuarine waters of Galveston Bay, TX, in order to study their role in heavy metal detoxification. The concentrations of dissolved monosaccharides (MCHO) in Galveston Bay ranged from 13 to 62 μM-C, and those of dissolved polysaccharides (PCHO) ranged from 10 to 42 μM-C. On average, MCHO and PCHO contributed about 11% and 7% to dissolved organic carbon (DOC), respectively. The colloidal carbohydrates (CCHO) in Galveston Bay varied from 7 to 54 μM-C, and accounted for 9% to 24% of the colloidal organic carbon (COC), with an average value of 17%, suggesting that CCHO is abundant in the high molecular weight (HMW) fraction of DOC. The concentration of CCHO is generally significantly higher than that of PCHO. This result is attributed to entrainment of low molecular weight (LMW) carbohydrates into the retentate fraction during ultrafiltration. The concentration of total dissolved uronic acids (DUA) in the same samples varied from 1.0 to 8.3 μM-C, with an average value of 6.1 μM-C, while the colloidal uronic acids (CUA) ranged from 0.8 to 6.4 μM-C, with an average value of 4.8 μM-C. The concentrations of DUA are higher than the previously reported values in coastal waters. Furthermore, CUA represent a dominant component of DUA in Galveston Bay waters. More importantly, significant correlations of PCHO and DUA to dissolved Cu concentrations (≤0.45 μm) were found, suggesting that acid polysaccharides were produced in response to trace metal stressors.     

Numerical modelling of suspended sediment fluxes in estuarine waters

A two-dimensional finite difference numerical model, capable of predicting depth-averaged tidal flow fields in coastal and estuarine waters, has been extended to include tide-induced non-cohesive sediment transport processes. The partial differential equations governing the conservation of mass, momentum and suspended sediment in an incompressible turbulent flow are included in a depth-integrated form in the model. For the representation of the processes of erosion and deposition of sediment from the bed an empirically based source-sink term was refined, based on the results of three mobile bed flume studies. The model has been tested by simulating tidal flows and suspended sediment fluxes in two estuaries, with particular application to the Humber estuary in the U.K. The model was calibrated and found to produce an encouraging degree of agreement between the numerical predictions and corresponding field measurements for this estuary. Furthermore, the predicted gross deposition and erosion features of the estuary were found to be in close agreement with interpretations from Eulerian tidal residual predictions.     

In situ measurement of particle size in estuarine waters

A novel approach to particle sizing in estuarine waters using a submersible laser diffraction instrument is described. In situ measurements with this instrument are rapid and avoid both the physical disruption of fragile aggregates with pumping and the settlement of larger particles in isolated samples which interfere with currently available sizing techniques. Measurements of the size distributions of suspended particle populations in the Tamar Estuary using this apparatus are compared with measurements carried out on discrete samples obtained from the same depth by pumping. The results confirm the fragile nature of estuarine aggregates and the necessity for in situ measurements in studies of estuarine suspended particle dynamics and fluxes.     

Copper speciation in estuarine waters by forward and reverse titrations

The chemical speciation of copper in the estuarine waters of the Vigo Ria was determined by titrations with salicylaldoxime (reverse copper titrations) and with copper (forward titrations). The forward titrations quantified the concentrations of ligands present in excess whereas the reverse titrations demonstrated the presence of low concentrations of very strong binding ligands, approximately matching the copper concentration. The data obtained by the reverse titrations indicated that copper was about 10× stronger bound than data based on the usual forward titrations.The copper concentration in these ria waters was low at 5 nM with a minor mid-estuarine maximum of 8 nM. These copper levels are amongst the lowest reported for estuarine waters and therefore represent uncontaminated waters. The concentration of inorganic copper was very low across the ria at  10–100 fM, except at Bouzas harbour (salinity 35.5) where it was raised to  1 pM due to copper contamination, in waters affected by the port facilities, to total levels of 15 to 20 nM copper, exceeding the concentration of the very strong ligand detected by the reverse titrations.     

Prediction of riverine suspended sediment discharge using fuzzy logic algorithms, and some implications for estuarine settings

The ability of fuzzy logic algorithms to model relationships between stream flow and suspended sediment discharge was investigated using daily measurements of stream flow and suspended sediment discharge for the Escanaba River mouth station, situated on the shore of Lake Michigan and operated by the US Geological Survey. Three different configurations of inputs were applied, whereby the inputs were fuzzified into fuzzy subsets of variables by means of triangular membership functions. The relationships between inputs and suspended sediment discharge (output) were represented by a set of fuzzy rule expressed in IF–THEN format. The weighted average method served for defuzzification. The commonly used sediment rating curve was also applied to the data, and its performance compared with that of the three models by means of statistical analyses. For all three models, suspended sediment discharge predicted by the fuzzy logic algorithm was in satisfactory agreement with observations. Furthermore, the fuzzy logic algorithms performed better than the sediment rating curve, particularly at higher rates of suspended sediment discharge (in this study, more than 50  × 10⁶ g/day). Considered collectively, the use of fuzzy logic algorithms is suggested as a simple and effective approach for better prediction of suspended sediment discharge, also for estuaries.     

辽东湾近岸海域油污染生态风险评价研究

以2014–2015年海洋调查数据为基础,Arc GIS软件为平台,通过选取致灾因子危险性、承灾体脆弱性相关影响因子,基于灾害理论和层次分析法构建了辽东湾近岸海域油污染生态风险评价指标体系、评价模型及评价标准,将致灾因子危险性等级和承灾体脆弱性等级进行叠加,从而实现对研究海域油污染生态风险进行综合评价,并对该海域溢油风险可能导致的环境影响进行了系统分析、诊断和综合评价。结果表明:辽东湾近岸海域风险处于较高风险,应加强对环境敏感区域的保护,并完善环境监测体系。本文同时为重要湿地生态敏感区合理配置溢油应急资源和实施风险决策提供技术支撑,也为目前事故后的危机管理到预防性风险管理的转变提供理论依据。     

Seasonal variations of dissolved and particulate copper species in estuarine waters

This one-year survey conducted in the macrotidal estuary of Penzé (Brittany, Western part of the Channel, France) was aimed at examining the variations of the various dissolved and particulate copper species. Ten field stations along the whole freshwater–seawater mixing zone were sampled each month. Different biogeochemical parameters (SPM, chl-a, pH and DOC) were also measured. The levels in total dissolved and total particulate copper ranged from 1.8 to 9.5 nM and from 5 to 98 μg g⁻¹, respectively; such amounts are indicative of a pollution-free system. Extractable C₁₈ copper (non-polar hydrophobic organic copper species), in winter and spring, accounted for 30–40% of the total dissolved copper. In summer, this contribution rapidly rose to 60% in the salinity range 20–30; over the same period of time, total particulate copper decreased. The change in dissolved copper speciation and the lowering of particulate copper concentrations were attributed to the release of strong organic ligands by phytoplankton. Our field data evidenced a highly variable behaviour for the various copper species over the seasonal cycle, and then led us to identify the following mechanisms: (i) metal desorption from organic river-flown particles (winter and spring), (ii) metal desorption from resuspended sediment in the upstream section (summer), (iii) competition between particles, non-extractable C₁₈ organic ligands and phytoplankton-released extractable C₁₈ organic ligands to complex copper in the downstream section (summer), and (iv) removal of non-extractable C₁₈ organic copper by adsorption (autumn). Dissolved copper species fluxes were assessed: most of metal inputs to the estuary (60–74%) corresponded to non-extractable C₁₈ organic copper. Winter and spring metal output fluxes were mainly constituted of non-extractable C₁₈ organic complexes; on the other hand, extractable C₁₈ organic complexes were predominant in summer and autumn output fluxes.     

粤东汕头近岸海域灾害地质风险综合评价

基于粤东汕头近岸海域地质和地球物理资料,通过对物探数据进行解译,查明了该区域内主要有活动断层、埋藏古河道、浅层气、不规则浅埋基岩等灾害地质类型,并结合层次分析法和模糊数学法建立了以断层、埋藏古河道、浅层气、浅埋基岩为评价指标的风险评价体系,得出海域内的不同区块的风险性等级,共分低、较低、中、较高、高5个等级。研究区超过70%的区域灾害风险不高,高风险区分布在榕江外河口、海门湾南部,主要受埋藏古河道和断层影响。较高—高风险区工程地质条件较差,存在的不良地质条件可能会给海上工程建设带来风险,选址时应尽量避开此类区域。评价结果与已查明的灾害分布特点吻合,对以后海上工程项目施工有一定的参考价值。     

闽江口及附近海域渔业资源现存量评析

根据2006年夏季(8月)和冬季(1月)、2007年春季(4月)和秋季(10月)在闽江口及其附近海域利用底拖网作业的渔业资源调查资料,应用传统扫海面积法以及△-分布模型法分析了福建闽江口及其附近海域(25°42′-26°27′N,119°42′-120°15′E)的渔业资源现存量.研究结果表明,闽江口及其附近海域的鱼类、甲壳类的资源密度较高,而头足类资源密度较低.渔业资源密度秋季居首位,约为2569.11kg·km-2,夏季次之,约为1 120.23kg·km-2,而冬、春季资源密度较低,分别为867.16和553.60.29kg·km-2.年平均渔业资源现存量约为4599t,渔业潜在资源量达32451t.渔业资源分布与水温、水深关系较密切.该海域渔业资源已经明显衰退,急需加强渔业资源的管理和保护.     

Processes affecting the behavior of dissolved aluminum in estuarine waters

Although it is well-known that reactions occur within estuaries to alter the flux of dissolved aluminum from rivers into the oceans, the nature and relative importance of these reactions are not well defined. In this study we show that sediment-water interactions can have a significant influence on dissolved Al distributions in estuaries. Undisturbed sediments will act as a sink for dissolved Al because of diffusion across the sediment-water interface and reaction of Al within the sediment. Resuspension of sediments will cause a release of dissolved Al into relatively Si-depleted estuarine waters.Flocculation of colloidal material may cause a net consumption of dissolved Al in estuaries. Our results indicate, however, that this process may not, in many cases, be the primary cause for curvature in Al-Cl^? profiles. An alternative model, whereby Al is displaced from organic matter complexes and adsorption sites in the estuarine zone and reacts with Si and cations in solution, is consistent with the data presented in this study as well as many other studies. In this case, the extent of net Al removal in estuaries will be determined by both the amount and nature of the dissolved organic matter present.     

海岸河口泥沙数学模型研究进展

对海岸河口泥沙运动的基本方程、数值方法、边界条件、参数选取等进行了归纳总结和评述,以期对本学科的发展起到一定的引导和促进作用。     

239,240Pu in estuarine and shelf waters of the north-eastern United States

The distribution of ^239,240Pu between dissolved and particulate forms has been measured in four estuaries on the north-east coast of the United States (Connecticut River, Delaware Bay, Chesapeake Bay, and Mullica River). The data cover the whole salinity range from freshwater input to shelf waters at 35‰ and includes one profile from a nearly anoxic basin in the Chesapeake Bay.In the organic-rich Mullica River estuary, large-scale removal of riverine dissolved ^239,240Pu occurs at low salinities due to salt-induced coagulation, a mechanism analogous to that for iron and humic acids. Within the 0 to 25–30‰ zone in the other three estuaries, the activity of dissolved ^239,240Pu increases almost conservatively. The activities of particulate ^239,240Pu are highest in the more turbid waters of low salinity regime (0–15‰), but become increasingly insignificant with respect to dissolved ^239,240Pu as salinities increase. At higher salinities corresponding to shelf water, there is a sharp increase in dissolved ^239,240Pu activity. The dissolved ^239,240Pu activity within each estuary appears to be inversely related to the flushing time of water. For example, Chesapeake Bay has a 6–12 month flushing time and has much lower dissolved ^239,240Pu activities than does the Connecticut River Estuary which has a flushing time of a few days. This and other data from the shelf waters are interpreted as indicating that the sharp decrease in dissolved ^239,240Pu activities between shelf and estuarine waters is driven by removal within the estuaries themselves rather than on the shelf.Dissolved ^239,240Pu activities are lower in the nearly-anoxic bottom waters of Chesapeake Bay indicating enhanced removal by redox transformation of Pu [i.e., Pu(V) to Pu(IV)].     

Methodology of X-ray fluorescence analysis of suspended matter in estuarine waters

Twenty-seven samples of suspended sediments collected on Millipore filters from the St. Lawrence estuary were directly analysed for Si, Al, Ca, Mg, Na, K, Fe, Ti, Mn, Ni, Co, Cu, Cr and Zn by X-ray fluorescence using standards prepared from suspended matter collected by continuous flow centrifugation. Calibration curves prepared from the analysis of these standards could be directly used in calculating the weight percent of elements for the unknown samples, if the weight of the total suspended matter on the filters did not exceed 25 mg.     

基于浮标观测的长江口外海流特征分析

为了揭示长江口外海域海流的特征及其季节和垂向变化规律,于2006年8月1日-2007年7月31日在长江口外海域（平均水深约46.0m）利用大型浮标进行了1年的分层海流流速流向观测。结果表明：（1）该海域海流为顺时针方向的旋转流,在垂向上流向较一致,季节变化不显著。（2）长江口外海域水平流速总体较大,夏季表层最大流速为128.5cm/s,冬季最大表层流速为105.5cm/s;垂线平均流速相近（差异<8.0 cm/s）,夏季流速最大为47.0cm/s,冬季为40.8cm/s。小潮的平均流速为26.5cm/s,大潮平均流速为小潮的2倍。（3）剖面各层流速垂向差异明显,最大流速出现在表层（春季和冬季）或次表层（夏季和秋季）,最小流速均出现在底层;各层的最大平均流速为57.9cm/s,出现在夏季的18m层。（4）垂线平均余流为7.5~11.3 cm/s,春季最强冬季最弱;春季和冬季各层余流均为东向,夏季和秋季基本为东北向或北向。（5）观测海域海流受长江冲淡水、台湾暖流、季风、潮汐等动力作用的共同制约。     

海岸河口潮流数值模拟的研究与进展

对海岸河口地区潮流场的数值模拟方法进行了较为系统的归纳总结和评述,对潮流数值模拟的发展趋势进行了分析.