World's Largest In Situ Thermal Desorption Project: Challenges and Solutions

This paper presents the largest In Situ Thermal Desorption (ISTD) project completed to date. The redevelopment of a former aerospace manufacturing facility adjacent to a commercial airport was the main driver, requiring relatively rapid reduction of several chlorinated volatile organic compounds (CVOC) in a 3.2‐acre source zone. The source zone was divided into four quadrants with differing treatment depths, heated simultaneously using a total of 907 thermal conduction heater wells. Five different depths were selected across the area, according to the depth of contaminant impact. Prior to implementation, a risk and optimization study led to placement of a vertical sheet‐pile wall around the treatment zone to minimize groundwater flow, and a pilot test of a novel direct‐drive method for installation of the heater casings. Because of a shallow water table, a layer of clean fill was placed over the treatment zone, and partial dewatering was necessary prior to heating. A network of vertical multiphase extraction wells and horizontal vapor extraction wells was used to establish hydraulic and pneumatic control and to capture the contaminants. The site was split into four decision units, each with a rigorous soil sampling program which included collecting a total of 270 confirmatory soil samples from locations with the highest pretreatment CVOC concentrations requiring reduction to below 1 mg/kg for each contaminant. Temperature monitoring and mass removal trends were used to trigger the sampling events. Eventually, a small area near the center of the site required the installation of four additional heaters before the soil goals were reached after 238 days of heating. The total energy usage for heating and treating the source area was 23 million kWh—slightly lower than the estimated 26.5 million kWh. Actual energy losses and the energy removal associated with the extracted steam were lower than anticipated. An estimated 13,400 kg (29,800 lbs) of CVOC mass was removed, and all soil goals were met. This paper presents the challenges associated with a project of this scale and describes the solutions to successfully complete the ISTD remedy.     

Groundwater Storage Change in the Jinsha River Basin from GRACE,Hydrologic Models,and In Situ Data

Groundwater plays a major role in the hydrological processes driven by climate change and human activities, particularly in upper mountainous basins. The Jinsha River Basin (JRB) is the uppermost region of the Yangtze River and the largest hydropower production region in China. With the construction of artificial cascade reservoirs increasing in this region, the annual and seasonal flows are changing and affecting the water cycles. Here, we first infer the groundwater storage changes (GWSC), accounting for sediment transport in JRB, by combining the Gravity Recovery and Climate Experiment mission, hydrologic models and in situ data. The results indicate: (1) the average estimation of the GWSC trend, accounting for sediment transport in JRB, is 0.76 ± 0.10 cm/year during the period 2003 to 2015, and the contribution of sediment transport accounts for 15%; (2) precipitation (P), evapotranspiration (ET), soil moisture change, GWSC, and land water storage changes (LWSC) show clear seasonal cycles; the interannual trends of LWSC and GWSC increase, but P, runoff (R), surface water storage change and SMC decrease, and ET remains basically unchanged; (3) the main contributor to the increase in LWSC in JRB is GWSC, and the increased GWSC may be dominated by human activities, such as cascade damming and climate variations (such as snow and glacier melt due to increased temperatures). This study can provide valuable information regarding JRB in China for understanding GWSC patterns and exploring their implications for regional water management.     

In Situ Monitoring of Vapor Phase TCE Using a Chemiresistor Microchemical Sensor

A chemiresistor microchemical sensor has been developed to detect and monitor volatile organic compounds in unsaturated and saturated subsurface environments. A controlled study was conducted at the HAZMAT Spill Center at the Nevada Test Site, where the sensor was tested under a range of temperature, moisture, and trichloroethylene (TCE) concentrations. The sensor responded rapidly when exposed to TCE placed in sand, and it also responded to decreases in TCE vapor concentration when clean air was vented through the system. Variations in temperature and water vapor concentration impacted baseline chemiresistor signals, but at high TCE concentrations the sensor response was dominated by the TCE exposure. Test results showed that the detection limit of the chemiresistor to TCE vapor in the presence of fluctuating environmental variables (i.e., temperature and water vapor concentration) was on the order of 1000 parts per million by volume, which is about an order of magnitude higher than values obtained in controlled laboratory environments. Automated temperature control and preconcentration is recommended to improve the stability and sensitivity of the chemiresistor sensor.     

An In Situ Multilevel Sampler for Preventive Monitoring and Study of Hydrochemical Profiles in Aquifers

Abstract
A modular multilevel sampler was developed and utilized for sampling undisturbed ground water chemical profiles and gases in both the saturated and the unsaturated zone. Sampling at 3cm depth intervals is based on the dialysis-cell method and has no depth limitations. The sampler may be used for the development of early warning monitoring systems and research.     

A Low‐Cost,In Situ Resistivity and Temperature Monitoring System

We present a low‐cost, reliable method for long‐term in situ autonomous monitoring of subsurface resistivity and temperature in a shallow, moderately heterogeneous subsurface. Probes, to be left in situ, were constructed at relatively low cost with an electrode spacing of 5 cm. Once installed, these were wired to the CR‐1000 Campbell Scientific Inc. datalogger at the surface to electrically image infiltration fronts in the shallow subsurface. This system was constructed and installed in June 2005 to collect apparent resistivity and temperature data from 96 subsurface electrodes set to a pole‐pole resistivity array pattern and 14 thermistors at regular intervals of 30 cm through May of 2008. From these data, a temperature and resistivity relationship was determined within the vadose zone (to a depth of ~1 m) and within the saturated zone (at depths between 1 and 2 m). The high vertical resolution of the data with resistivity measurements on a scale of 5‐cm spacing coupled with surface precipitation measurements taken at 3‐min intervals for a period of roughly 3 years allowed unique observations of infiltration related to seasonal changes. Both the vertical resistivity instrument probes and the data logger system functioned well for the duration of the test period and demonstrated the capability of this low‐cost monitoring system.     

A Practical Approach to the Design, Operation, and Monitoring of In Situ Soil-Venting Systems

When operated properly, in situ soil venting or vapor extraction can be one of the most cost-effective remediation processes for soils contaminated with gasoline, solvents, or other relatively, volatile compounds. The components of soil-venting systems are typically off-the-shelf items, and the installation of wells and trenches can be done by reputable environmental firms. However, the design, operation, and monitoring of soil-venting systems are not trivial. In fact, choosing whether or not venting should be applied at a given site is a difficult decision in itself. If one decides to utilize venting, design criteria involving the number of wells, well spacing, well location, well construction, and vapor treatment systems must be addressed. A series of questions must be addressed to decide if venting is appropriate at a given site and to design cost-effective in situ soil-venting systems. This series of steps and questions forms a "decision tree" process. The development of this approach is an attempt to identify the limitations of in situ soil venting, and subjects or behavior that are currently difficult to quantify and for which future study is needed.     

A Practical Approach to the Design, Monitoring, and Optimization of In Situ MTBE Aerobic Biobarriers

A paradigm for the design, monitoring, and optimization of in situ methyl tert -butyl ether (MTBE) aerobic biobarriers is presented. In this technology, an oxygen-rich biologically reactive treatment zone (the "biobarrier") is established in situ and downgradient of the source of dissolved MTBE contamination in groundwater, typically gasoline-impacted soils resulting from leaks and spills at service station sites or other fuel storage and distribution facilities. The system is designed so that groundwater containing dissolved MTBE flows to, and through, the biobarrier treatment zone, ideally under natural gradient conditions so that no pumping is necessary. As the groundwater passes through the biobarrier, the MTBE is converted by microorganisms to innocuous by-products. The system also reduces concentrations of other aerobically degradable chemicals dissolved in the groundwater, such as benzene, toluene, xylenes, and tert -butyl alcohol. This design paradigm is based on experience gained while designing, monitoring, and optimizing pilot-scale and full-scale MTBE biobarrier systems. It is largely empirically based, although the design approach does rely on simple engineering calculations. The paradigm emphasizes gas injection–based oxygen delivery schemes, although many of the steps would be common to other methods of delivering oxygen to aquifers.     

利用InSAR技术研究2003年西藏班戈MS6.1地震发震构造

2003年7月7日发生在西藏与青海交界处的班戈M_S6.1地震, 由于缺乏余震分布等可靠资料, 其发震构造及其活动性质等问题一直认识不清。 几家机构利用远场波动资料给出的震源机制解差异很大。 本文利用ENVISAT卫星ASAR数据和D-InSAR技术, 计算获得了该地震LOS方向的同震形变场图像, 并以此为约束反演获得了该地震的断层几何参数和同震滑动分布。 结果表明, 班戈M_S6.1地震的发震构造为控制唐古拉山西边界的波涛湖—土门断裂, 其发震断层为走向161°的高角度右旋斜滑正断层, 破裂长度约10 km, 滑动量主要集中在3~7 km深度范围, 最大滑动量0.26 m, 矩震级M_W5.6。