Influence of oxidability of carboniferous coals from the Dobrudja foredeep on vitrinite reflectance

Importance of the study of the influence of coal oxidability on vitrinite reflectance (VR) as a criterion of the quality of coals and indicator of paleogeothermal regime is shown. Overview of relevant concepts demonstrates that this issue remains debatable. Carboniferous coals of the Dobrudja foredeep, which belong to the class of helitolites in terms of their microcomponent composition, were studied. They were subjected to oxidation during storage outdoors. Consequently, the VR value of high volatile bituminous (long-flame and gas ranks, according to the Russian classification) coals decreased, but this parameter remained virtually unaltered for medium volatile bituminous (fat) coals. Bulgarian researchers obtained similar results for Carboniferous coals of the Dobrudja basin represented by helitolites and mixtohumolites. In our opinion, the VR decrease in the course of coal oxidation is caused by decrease in the condensation and density of aromatic structures and increase in the share of nonaromatic carbon atoms.     

Cosmic microspheres in the Carboniferous deposits of the Usolka section (Urals foredeep)

Magnetite microspheres from the Carboniferous deposits of the Usolka reference section were studied by probe microanalysis, with comparison of the distributions of chemical elements and microspheres. The presence of microspheres in sedimentary strata is considered to be an additional factor for stratigraphic correlation between sedimentary sections. The microspheres are shown to be of cosmic nature. The Late Paleozoic paleoclimatic changes (extreme cooling) and biotic crises were caused by the periodical Solar System motion in the Galaxy, cosmic-dust fallout, and meteorite bombardments of the Earth.     

Magmatic-dominated fluid evolution in the Jurassic Nambija gold skarn deposits (southeastern Ecuador)

The Jurassic (approximately 145 Ma) Nambija oxidized gold skarns are hosted by the Triassic volcanosedimentary Piuntza unit in the sub-Andean zone of southeastern Ecuador. The skarns consist dominantly of granditic garnet (Ad_20–98) with subordinate pyroxene (Di_46–92Hd_17–42Jo_0–19) and epidote and are spatially associated with porphyritic quartz-diorite to granodiorite intrusions. Endoskarn is developed at the intrusion margins and grades inwards into a potassic alteration zone. Exoskarn has an outer K- and Na-enriched zone in the volcanosedimentary unit. Gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn and occurs mainly in sulfide-poor vugs and milky quartz veins and veinlets in association with hematite. Fluid inclusion data for the main part of the prograde stage indicate the coexistence of high-temperature (500°C to >600°C), high-salinity (up to 65 wt.% eq. NaCl), and moderate- to low-salinity aqueous-carbonic fluids interpreted to have been trapped at pressures around 100–120 MPa, corresponding to about 4-km depth. Lower-temperature (510–300°C) and moderate- to low-salinity (23–2 wt.% eq. NaCl) aqueous fluids are recorded in garnet and epidote of the end of the prograde stage. The microthermometric data (Th from 513°C to 318°C and salinity from 1.0 to 23 wt.% eq. NaCl) and δ¹⁸O values between 6.2‰ and 11.5‰ for gold-bearing milky quartz from the retrograde stage suggest that the ore-forming fluid was dominantly magmatic. Pressures during the early retrograde stage were in the range of 50–100 MPa, in line with the evidence for CO₂ effervescence and probable local boiling. The dominance of magmatic low-saline to moderately saline oxidizing fluids during the retrograde stage is consistent with the depth of the skarn system, which could have delayed the ingression of external fluids until relatively low temperatures were reached. The resulting low water-to-rock ratios explain the weak retrograde alteration and the compositional variability of chlorite, essentially controlled by host rock compositions. Gold was precipitated at this stage as a result of cooling and pH increase related to CO₂ effervescence, which both result in destabilization of gold-bearing chloride complexes. Significant ingression of external fluids took place after gold deposition only, as recorded by δ¹⁸O values of 0.4‰ to 6.2‰ for fluids depositing quartz (below 350°C) in sulfide-rich barren veins. Low-temperature (<300°C) meteoric fluids (δ¹⁸O_water between −10.0‰ and −2.0‰) are responsible for the precipitation of late comb quartz and calcite in cavities and veins and indicate mixing with cooler fluids of higher salinities (about 100°C and 25 wt.% eq. NaCl). The latter are similar to low-temperature fluids (202–74.5°C) with δ¹⁸O values of −0.5‰ to 3.1‰ and salinities in the range of 21.1 to 17.3 wt.% eq. CaCl₂, trapped in calcite of late veins and interpreted as basinal brines. Nambija represents a deep equivalent of the oxidized gold skarn class, the presence of CO₂ in the fluids being partly a consequence of the relatively deep setting at about 4-km depth. As in other Au-bearing skarn deposits, not only the prograde stage but also the gold-precipitating retrograde stage is dominated by fluids of magmatic origin.     

Evidence for Jurassic subduction from the Northern Calcareous Alps (Berchtesgaden; Austroalpine,Germany)

The closure of the western part of the Neotethys Ocean started in late Early Jurassic. The Middle to early Late Jurassic contraction is documented in the Berchtesgaden Alps by the migration of trench-like basins formed in front of a propagating thrust belt. Due to ophiolite obduction these basins propagated from the outer shelf area (=Hallstatt realm) to the interior continent (=Hauptdolomit/Dachstein platform realm). The basins were separated by nappe fronts forming structural highs. This scenario mirrors syn-orogenic erosion and deposition in an evolving thrust belt. Active basin formation and nappe thrusting ended around the Oxfordian/Kimmeridgian boundary, followed by the onset of carbonate platforms on structural highs. Starved basins remained between the platforms. Rapid deepening around the Early/Late Tithonian boundary was induced by extension due to mountain uplift and resulted in the reconfiguration of the platforms and basins. Erosion of the uplifted nappe stack including obducted ophiolites resulted in increased sediment supply into the basins and final drowning and demise of the platforms in the Berriasian. The remaining Early Cretaceous foreland basins were filled up by sediments including siliciclastics. The described Jurassic to Early Cretaceous history of the Northern Calcareous Alps accords with the history of the Western Carpathians, the Dinarides, and the Albanides, where (1) age dating of the metamorphic soles prove late Early to Middle Jurassic inneroceanic thrusting followed by late Middle to early Late Jurassic ophiolite obduction, (2) Kimmeridgian to Tithonian shallow-water platforms formed on top of the obducted ophiolites, and (3) latest Jurassic to Early Cretaceous sediments show postorogenic character.     

Origin of calcium-chloride brines in Middle Jurassic volcanic deposits (Western Caucasus)

An analysis of the calcium chloride brines and the composition of the host rocks occurring in the Bajocian volcanic formation indicate that these formations represent the parent rocks in which the calcium chloride brines were generated. The original brines were of the sodium chloride type and were altered to calcium chloride as the result of ion exchange between the brine and minerals of the rocks and the process of zeolitization, resulting in concentrated calcium chloride brines. — E.A. Alexandrov.     

A characterization and the formation conditions of the Callovian-Upper Jurassic deposits in the Akhtsu zone (Krasnodar Krai)

Deposits in the Akhtsu zone have been characterized, with the Mzymta River valley as an example. A lithological-paleontological and geochemical characterization of Callovian-Tithonian deposits has been given. A paleogeographic model has been proposed for the Akhtsu reef, and a chronostratigraphic profile has been established for the Callovian-Albian sedimentary basin in the Easter Black Sea region.     

Radiolarians from Upper Jurassic (Middle Oxfordian and Upper Kimmeridgian) deposits of Yaroslavl oblast

The middle Oxfordian and late Kimmeridgian radiolarian assemblages from Upper Jurassic deposits of Yaroslavl oblast are studied for the first time. The middle Oxfordian assemblage is dominated by stauraxonic morphotypes of genera Paronaella and Pseudocrucella occurring in association with discoid forms. Nassellarian radiolarians are very rare in this assemblage of extremely low taxonomic diversity, which is lacking spheroidal morphotypes. The late Kimmeridgian assemblage is more diverse in morphological and taxonomic aspects. It includes spheroidal forms, those of the family Pantanelliidae Pessagno inclusive, and more frequent nassellarian species, but stauraxonic radiolarians are less abundant in its composition. This assemblage is comparable to a considerable extent with the Kimmeridgian radiolarians from Moscow oblast, being of the South Boreal type according to its composition.     

Rare earth, major and trace elements in Jurassic manganese shales of the Northern Calcareous Alps: hydrothermal versus hydrogenous origin of stratiform manganese deposits

Summary ?The rare earth, major and trace element geochemistry of Jurassic deep marine manganese shales allow insight into their environment of deposition. We present data of 24 samples from the Northern Calcareous Alps (Eastern Alps), collected from Late Jurassic strata of the Tennengebirge and from Early Jurassic strata of the Karwendel Mts. Whereas major and trace element geochemistry is controlled by the detrital input, rare earth element data and the relationship between total organic carbon and (pyritic) sulfur can be used to constrain the origin of the manganese accumulation. The data of this study are compatible with a hydrogenous precipitation of manganese by strongly varying redox-conditions at the sediment–water interface of a slope basin. Received December 21, 2001; revised version accepted February 18, 2002     

Calcareous nannoplankton, planktonic foraminiferal, and carbonate carbon isotope stratigraphy of the Cenomanian–Turonian boundary section in the Ultrahelvetic Zone (Eastern Alps, Upper Austria)

Ultrahelvetic units of the Eastern Alps were deposited on the distal European continental margin of the (Alpine) Tethys. The Rehkogelgraben section (“Buntmergelserie”, Ultrahelvetic unit, Upper Austria) comprises a 5 m thick succession of upper Cenomanian marl-limestone cycles overlain by a black shale interval composed of three black shale layers and carbonate-free claystones, followed by lower Turonian white to light grey marly limestones with thin marl layers. The main biostratigraphic events in the section are the last occurrence of Rotalipora and the first occurrences of Helvetoglobotruncana helvetica and Quadrum gartneri. The thickest black shale horizon has a TOC content of about 5%, with predominantly marine organic matter of kerogen type II. Vitrinite reflectance and Rock-Eval parameter T_max (<424 °C) indicate low maturity. HI values range from 261 to 362 mg HC/g TOC. δ¹³C values of bulk rock carbonates display the well documented positive shift around the black shale interval, allowing correlation of the Rehkogelgraben section with other sections such as the Global Boundary Stratotype Section and Point (GSSP) succession at Pueblo, USA, and reference sections at Eastbourne, UK, and Gubbio, Italy. Sediment accumulation rates at Rehkogelgraben (average 2.5 mm/ka) are significantly lower than those at Pueblo and Eastbourne.     

Characterization and correlation of Upper Jurassic (Oxfordian) bentonite deposits in the Paris Basin and the Subalpine Basin, France

Abstract Explosive volcanic activity is recorded in the Upper Jurassic of the Paris Basin and the Subalpine Basin of France by the identification of five bentonite horizons. These layers occur in Lower Oxfordian (cordatum ammonite zone) to Middle Oxfordian (plicatilis zone) clays and silty clays deposited in outer platform environments. In the Paris Basin, a thick bentonite (10–15 cm), identified in boreholes and in outcrop, is dominated by dioctahedral smectite (95%) with trace amounts of kaolinite, illite and chlorite. In contrast, five bentonites identified in the Subalpine Basin, where burial diagenesis and fluid circulation were more important, are composed of a mixture of kaolinite and regular or random illite/smectite mixed-layer clays in variable proportions, indicating a K-bentonite. In the Subalpine Basin, a 2–15 cm thick bentonite underlain by a layer affected by sulphate–carbonate mineralization can be correlated over 2000 km². Euhedral zircon, apatite and biotite crystals have been identified in all the bentonites. The geochemical composition of the bentonites in both basins is characterized by high concentrations of Hf, Nb, Pb, Ta, Th, Ti, U, Y, Zr and low concentrations of Cr, Cs and Rb. Biostratigraphical and geochemical data suggest that the thick bentonite in the Paris Basin correlates with the thickest bentonite in the Subalpine Basin, located 400 km to the south. These horizons indicate that significant explosive volcanic events occurred during the Middle Oxfordian and provide potential long-distance isochronous marker beds. Immobile element discrimination diagrams and rare-earth element characteristics indicate that the original ash compositions of the thickest bentonites correspond to a trachyandesitic source from a within-plate alkaline series that was probably related to North Atlantic rifting.     

Palynostratigraphy of the Lower-Middle Jurassic deposits,borehole section Vostok 4 (Southeast of West Siberia)

This work presents the results of palynological investigation of the Vostok 4 borehole section situated in the Azharma region of the Ob-Irtysh facies area, where drilling has penetrated through the Urmanskaya, Ilansk, Peshkovskaya, and Tyumen formations. Six palynoassemblages are distinguished in the section based on the analyzed distribution of spores, pollen of terrestrial plants, and microphytoplankton. According to their succession, the section is subdivided into biostratigraphic units ranked as beds with palynomorphs. Comparative analysis and correlation with the Siberian palynostratigraphic standard scale of the Lower-Middle Jurassic, where succession of palynoassemblages is coordinated with ammonite zones, substantiate the Pliensbachian-Bajocian age of the deposits studied. Diverse microphytoplankton (dinoflagellate cysts, acritarchs, prasinophytes, zignematacean and colonial algae) occurs throughout the section. The facies environment of sedimentation is reconstructed based on quantitative proportions of microphytoplankton taxa.     

某水库库区侏罗系钙质砾岩对水库渗漏的影响

某拟建水库地层中存在溶孔和溶洞等溶蚀现象,可构成潜在渗漏通道。在对水库库区地质、水文地质条件调查、分析基础上,重点研究了库区钙质砾岩溶蚀的发育机理、特点和空间发育规律。由此,初步认为：库区钙质砾岩条带溶蚀不甚发育,不存在贯通性的渗漏通道,不会引起水库严重渗漏。     

Main phytostratigraphic boundaries in the Jurassic deposits of Western Siberia

The study of the large collections of plant remains gained from cores of numerous boreholes drilled in Western Siberia made it possible to determine the taxonomic composition of the Jurassic flora of this region, the stages of its evolution, and the sequence of floral assemblages, which characterize the regional stratigraphic horizons indirectly correlated via series of parallel faunal, microfaunal, spore and pollen zonal scales with a general stratigraphic scale. The compositions of floral assemblages was established in the Hettangian-lower part of the upper Pliensbachian, upper part of the upper Pliensbachian, lower Toarcian, upper Toarcian, Aalenian, Bajocian, Bathonian, and Callovian-Oxfordian sediments. Criteria were elaborated to substantiate the Triassic-Jurassic and Lower-Middle Jurassic boundaries. Lithologically and biostrati-graphically, the Middle-Upper Jurassic boundary is poorly expressed.     

Calcareous nannofossils from late Jurassic sediments of the Volga Basin (Russian Platform): evidence for productivity-controlled black shale deposition

The Jurassic/Cretaceous boundary interval in the northern hemisphere is characterized by the widespread occurrence of black shales. About 60% of all petroleum source rocks comprise sediments of late Jurassic and early Cretaceous age with the origin of such black shales still under discussion. In order to better understand the factors that controlled black shale sedimentation, 78 samples were analyzed for calcareous nannofossils from two sections (Gorodische, Kashpir) of the Volga Basin (NE Russia). Calcareous nannofossils are ideal proxies for deciphering nutrient, temperature and salinity fluctuations. Additionally 58 samples from both sections were also analyzed for clay mineralogy, ¹³C_org , TOC and CaCO₃ composition. Both sections contain calcareous claystones and intercalated organic rich shales overlain by phosphorite beds. The presence of the calcareous nannofossil species Stephanolithion atmetros throughout both successions allows a biostratigraphic assignment to the S. atmetros Nannofossil Biozone (NJ 17), which corresponds to the Dorsoplanites panderi Ammonite Biozone of the Middle Volgian. The marlstones of the Kashpir section yield a well-preserved rich and diverse nannoflora, whereas all black shale beds are essentially barren of calcareous nannofossils. Only the uppermost black shale layers yield an impoverished assemblage of low diversity and abundance. Geochemical data suggest an early diagenetic nannofossil dissolution in the black shales of the Kashpir section. This is supported by the occurrence of coccoliths in black shale horizons of the Gorodische section. The assemblages in both sections are dominated by coccoliths of the Watznaueriaceae group (Watznaueria barnesae, Watznaueria fossacincta, Watznaueria britannica, Watznaueria communis), Biscutum constans and Zeugrhabdotus erectus. In Kashpir rare specimens of Crucibiscutum salebrosum occur in the higher part of the section. These taxa indicate boreal affinities. B. constans and Z. erectus are considered to be taxa indicative of a higher productive environment, while C. salebrosum is a cool-water species. From base to top of the Kashpir section, consecutive mass occurrences of different taxa/groups were observed: W. barnesae–W. fossacincta acme, W. britannica–W. communis acme, Z. erectus acme, B. constans acme (including sparse occurrences of C. salebrosum).The observed distribution patterns have been interpreted as characterizing a transition from a low productive, oligotrophic setting with high abundances of K-selected cosmopolitan species (Watznaueriaceae) and predominating marlstone sedimentation to a higher productive, mesotrophic setting. Cooler water temperatures marked by r-selection and acmes of opportunistic species (Z. erectus, B. constans) are coincident with the deposition of black shales and phosphorites in the higher part of the section. Interpretation of clay mineral distribution indicates that black shale deposition occurred under semi-arid hinterland climatic conditions concomitant with a sea level rise. This induced dysoxic conditions in the deeper parts of the Volga Basin, favoring the preservation of organic matter. The cause of the nutrient enrichment in the surface water is still unclear, but possible river water input from the continents does not seem to have been the controlling factor under a semi-arid climate. The occurrence of phosphorites in the upper part of both sections presumably indicates that enhanced productivity may be better explained by the upwelling of nutrient-rich bottom water and thereby causing the recycling of nutrients from oxidized phytoplankton back into the photic zone. This recycling effect finally may have led to an intensified phytoplankton growth which seemed to be a sufficient source for the enrichment of organic matter. This is well correlated with the increase in black shale horizons in the upper part of the Kashpir section.     

Organic matter from the Callovian (Middle Jurassic) deposits of Lithuania: Compositions,sources and depositional environments

This study presents the first organic geochemical and petrographical investigation of the Callovian deposits of the eastern part of the Central European Basin. It is shown that in both the terrigenous Papil? Formation (Lower Callovian) and shallow- to deeper-marine facies of the Papartin? and Skinija formations (Middle and Upper Callovian, respectively), terrestrial organic matter predominates. This is reflected by the carbon preference index values higher than 1.2 for all samples and in some cases higher than 2, as well as the occurrence of characteristic higher plant biomarkers like cadalene, dehydroabietane, simonellite and retene. Moreover, in the case of the Papil? Formation, sugiol – a natural product terpenoid produced by distinct conifer families, has been detected in clay sediments. The occurrence of such a biomolecule in the Middle Jurassic clays is reported for the first time. Its occurrence is probably connected with the presence of small wood debris in the clay sediments. In samples of the Papil? Formation, charcoal fragments co-occurring with unsubstituted polycyclic aromatic hydrocarbons were detected, indicating that wildfires took place during the Early Callovian of Lithuania and/or neighbouring areas. In the Middle and Upper marine Callovian sediments of Lithuania there is no evidence of anoxic conditions occurring in the water column. However, periodic anoxic or strongly dysoxic episodes may have occurred, most probably below the photic zone, during the deepest phase of the Late Callovian transgression, as is evidenced from pyrite framboid diameter distribution and general impoverishment of benthic fauna. Huminite reflectance (R_r) values for the investigated area are in the range of 0.21–0.31%, suggesting the occurrence of immature organic matter. Such values indicate that these investigated deposits were close to the surface during their whole diagenetic history, and the thickness of younger cover did not exceed ca. 500 m. This is also supported by a biomarker analysis in which less thermally stable ββ-hopanes and hopenes significantly dominated.     

Stratigraphy of Middle-Upper Jurassic deposits in the East Russian plate

The work is aimed at litho-, bio- and magnetostratigraphic subdivision of the Middle-Upper Jurassic sedimentary succession in the northeast of the Ul’yanovsk-Saratov depression (the East Russian plate). Problems of regional and interregional correlation of distinguished subdivisions are considered. As is shown, the ammonite biostratigraphy is most effective method for solving problems of chronostratigraphy.     

Late Jurassic tectonics and sedimentation: breccias in the Unken syncline,central Northern Calcareous Alps

This study analyses and discusses well preserved examples of Late Jurassic structures in the Northern Calcareous Alps, located at the Loferer Alm, about 35 km southwest of Salzburg. A detailed sedimentary and structural study of the area was carried out for a better understanding of the local Late Jurassic evolution. The Grubhörndl and Schwarzenbergklamm breccias are chaotic, coarse-grained and locally sourced breccias with mountain-sized and hotel-sized clasts, respectively. Both breccias belong to one single body of breccias, the Grubhörndl breccia representing its more proximal and the Schwarzenbergklamm breccia its more distal part, respectively. Breccia deposition occurred during the time of deposition of the Ruhpolding Radiolarite since the Schwarzenbergklamm breccia is underlain and overlain by these radiolarites. Formation of the breccias was related to a major, presumably north-south trending normal fault scarp. It was accompanied and post-dated by west-directed gravitational sliding of the Upper Triassic limestone (“Oberrhätkalk”), which was extended by about 6% on top of a glide plane in underlying marls. The breccia and slide-related structures are sealed and blanketed by Upper Jurassic and Lower Cretaceous sediments. The normal fault scarp, along which the breccia formed, was probably part of a pull-apart basin associated with strike slip movements. On a regional scale, however, we consider this Late Jurassic strike-slip activity in the western part of the Northern Calcareous Alps to be synchronous with gravitational emplacement of “exotic” slides and breccias (Hallstatt mélange), triggered by Late Jurassic shortening in the eastern part of the Northern Calcareous Alps. Hence, two competing processes affected one and the same continental margin.     

Jurassic microbial communities in hydrothermal manganese crust of the Rifian Calcareous Chain,Northern Morocco

The stratigraphic record of the Middle and Upper Jurassic in the Western Tethys is characterized by successive eustatic and tectonic events recorded as stratigraphic unconformities, which are revealed by hardgrounds, palaeokarsts, palaeosoils, and by the deposition of Fe–Mn crusts. The study of a Mn crust from the Middle-Upper Jurassic discontinuity in the Jbel Moussa Group (Rifian Cordillera), from stratigraphic, geomicrobiologic, mineralogical, and geochemical standpoints allows us to establish its hydrothermal origin. The manganese crust is composed by Ca-birnessite, cryptomelane and coronadite. Major- and trace-elements analyses of the whole crust show high contents in MnO (> 70 wt.%), a negative Ce anomaly and a positive Eu anomaly. Analysis of the microstructures under scanning electron microscopy reveals crystalline and microbial laminations, probably owing to fungal mycelium. Mineralogical and geochemical composition, together with microbial structures, suggest that this Mn crust formed as a result of venting hydrothermal fluids through synsedimentary faults. Chemosynthetic microbes were probably involved in the precipitation of Mn.     

Mesozoic (Late Jurassic) palynomorphs and charcoal from a sandstone pebble from Quaternary glacial deposits of the North Sea

The palynological contents as well as macroscopic charcoal fragments from a calcareous sandstone pebble from Quaternary glacial deposits of the North Sea (80 km SW of the Dogger Bank) are described. The taxonomic composition of the palynoflora points to a Late Jurassic (or Late Jurassic/Early Cretaceous) age of the sandstone. The charcoal is interpreted as direct evidence of palaeo‐wildfire occurring during this period in the source area of the sediments of this particular sandstone. This finding, together with already published data on Mesozoic deposits, allows to conclude that wildfires were obviously widespread during this period in the area of the modern day North Sea and adjacent areas. Copyright © 2012 John Wiley & Sons, Ltd.