High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.     

Thermoremanence in red sandstone clasts and emplacement temperature of a quaternary pyroclastic deposit (Catalan Volcanic Zone,ne Spain)

Summary The application of the progressive thermal demagnetization procedure of volcanic rock debris has been frequently used to determine the emplacement temperatures of pyroclastic deposits and thus to characterize the nature of these volcanic deposits. This debris consists of a mixture of juvenile fragments derived from the explosive fragmentation of erupting magma and an assortment of lithic clasts derived mainly from the walls of a volcanic conduit, as well as from the ground. The temperature at which the clasts were deposited can be estimated by analyzing its remanent magnetization. To do this, oriented samples of clasts are subjected to progressive thermal demagnetization and the directions of the resulting remanent vectors provide the necessary information. Clasts of basalt, andesite, limestone, pumice and homebricks have previously been used to estimate the emplacement temperatures of pyroclastic deposits. According to our data, clasts of red sandstones also seem to be good carriers of thermoremanent magnetization. We have carried out a paleomagnetic study on a Quaternary, lithic-rich, massive, pyroclastic deposit from the Puig d'Adri volcano (Catalan Volcanic Zone), which contains a large number of red sandstone clasts. It is concluded that the studied deposit cannot be considered as a lahar or as a pyroclastic surge deposit, considering both the emplacement temperature and the morphological features.Presented at 3rd Biennial Meeting on New Trends in Geomagnetism, Smolenice Castle, West Slovakia, June 22–29, 1992     

Paleomagnetic determination of emplacement temperatures of pyroclastic deposits: an under-utilized tool

Paleomagnetic data from lithic clasts collected from Mt. St. Helens, USA, Volcán Láscar, Chile, Volcán de Colima, Mexico and Vesuvius, Italy have been used to determine the emplacement temperature of pyroclastic deposits at these localities and to highlight the usefulness of the paleomagnetic method for determining emplacement temperatures. At Mt. St. Helens, the temperature of the deposits (T _dep ) at three sites from the June 12, 1980 eruption was found to be ≥532°C, ≥509°C, and 510–570°C, respectively. One site emplaced on July 22, 1980 was emplaced at ≥577°C. These new paleomagnetic temperatures are in good agreement with previously published direct temperature measurements and paleomagnetic estimates. Lithic clasts from pyroclastic deposits from the 1993 eruption of Láscar were fully remagnetized above the respective Curie temperatures, which yielded a minimum T _dep of 397°C. Samples were also collected from deposits thought to be pyroclastics from the 1913, 2004 and 2005 eruptions of Colima. At Colima, the sampled clasts were emplaced cold. This is consistent with the sampled clasts being from lahar deposits, which are common in the area, and illustrates the usefulness of the paleomagnetic method for distinguishing different types of deposit. T _dep of the lower section of the lithic rich pyroclastic flow (LRPF) from the 472 A.D. deposits of Vesuvius was ~280–340°C. This is in agreement with other, recently published paleomagnetic measurements. In contrast, the upper section of the LRPF was emplaced at higher temperatures, with T _dep ~520°C. This temperature difference is inferred to be the result of different sources of lithic clasts between the upper and lower sections, with the upper section containing a greater proportion of vent-derived material that was initially hot. Our studies of four historical pyroclastic deposits demonstrates the usefulness of paleomagnetism for emplacement temperature estimation.     

An ignimbrite veneer deposit: The trail-marker of a pyroclastic flow

The term “ignimbrite veneer deposit” (IVD) is proposed for a new kind of pyroclastic deposit which is found associated with, and passes laterally into, Taupo ignimbrite of valley pond type in New Zealand. It forms a thin layer mantling the landscape over 15,000 km², and is regarded as the deposit from the trailing “tail” of a pyroclastic flow, where a relaxation of shear stress favoured the deposition of the basal part of the flow. The IVD differs little in grain-size from the associated ignimbrite, but it shows a crude internal stratification attributed to the deposition of a succession of layers, one after the passage of each pulse of the pyroclastic flow. It locally contains laterally-discontinuous lenses of coarse pumice (“lee-side lenses”) on the far-vent side of topographic obstacles. In nearvent exposures the Taupo IVD shows lensoid and cross-stratified bed-forms even where it stands on a planar surface, attributed to deposition from a flow travelling at an exceedingly high velocity.An IVD can be distinguished from a poorly sorted pyroclastic fall deposit because the beds in it show more rapid lateral variations in thickness, it may show a low-angle cross-stratification, and it contains carbonised wood from trees not in the position of growth; from the deposit of a wet base surge because it lacks vesicles and strong antidune-like structures and contains carbonised vegetation, and from a hot and dry pyroclastic surge deposit because it possesses a high content of pumice and “fines”.The significance of an IVD is that it records the passage of a pyroclastic flow, where the flow itself has moved farther on.     

Emplacement temperatures of pyroclastic and volcaniclastic deposits in kimberlite pipes in southern Africa

Palaeomagnetic techniques for estimating the emplacement temperatures of volcanic deposits have been applied to pyroclastic and volcaniclastic deposits in kimberlite pipes in southern Africa. Lithic clasts were sampled from a variety of lithofacies from three pipes for which the internal geology is well constrained (the Cretaceous A/K1 pipe, Orapa Mine, Botswana, and the Cambrian K1 and K2 pipes, Venetia Mine, South Africa). The sampled deposits included massive and layered vent-filling breccias with varying abundances of lithic inclusions, layered crater-filling pyroclastic deposits, talus breccias and volcaniclastic breccias. Basalt lithic clasts in the layered and massive vent-filling pyroclastic deposits in the A/K1 pipe at Orapa were emplaced at >570°C, in the pyroclastic crater-filling deposits at 200–440°C and in crater-filling talus breccias and volcaniclastic breccias at <180°C. The results from the K1 and K2 pipes at Venetia suggest emplacement temperatures for the vent-filling breccias of 260°C to >560°C, although the interpretation of these results is hampered by the presence of Mesozoic magnetic overprints. These temperatures are comparable to the estimated emplacement temperatures of other kimberlite deposits and fall within the proposed stability field for common interstitial matrix mineral assemblages within vent-filling volcaniclastic kimberlites. The temperatures are also comparable to those obtained for pyroclastic deposits in other, silicic, volcanic systems. Because the lithic content of the studied deposits is 10–30%, the initial bulk temperature of the pyroclastic mixture of cold lithic clasts and juvenile kimberlite magma could have been 300–400°C hotter than the palaeomagnetic estimates. Together with the discovery of welded and agglutinated juvenile pyroclasts in some pyroclastic kimberlites, the palaeomagnetic results indicate that there are examples of kimberlites where phreatomagmatism did not play a major role in the generation of the pyroclastic deposits. This study indicates that palaeomagnetic methods can successfully distinguish differences in the emplacement temperatures of different kimberlite facies.     

Palaeotemperature determinations for the 1.8-ka Taupo ignimbrite,New Zealand,and implications for the emplacement history of a high-velocity pyroclastic flow

Palaeomagnetic data from lithic clasts collected at 46 sites within layers 1 and 2 of the 1.8-ka Taupo ignimbrite, New Zealand, have been used to determine the palaeotemperatures and thermal structure of the deposit on its emplacement. Equilibrium temperatures from sites less than 30–40 km from vent are 150–300 °C, whereas at greater distances site equilibrium temperatures increase up to 400–500 °C. This variation is seen in both layer 1 and 2 deposits, with values for layer 1 being somewhat cooler, and with its increase in temperature occurring at a greater distance from vent. A temperature maximum at ~50 km from vent coincides with a zone of pink thermal-oxidation colouration of pumices previously inferred to reflect higher emplacement temperatures. Additional palaeomagnetic data collected by us and others from pumice clasts show comparable temperature variations, but these temperature estimates are shown here to be due to a chemical remanence and unreliable for accurate temperature estimates. Cooler temperatures in proximal parts of the ignimbrite are consistent with admixture of >20% cold lithic clasts at source and interaction with the pre-eruption Lake Taupo. The similar, but offset, increases in equilibrium temperatures for medial and distal layers 1 and 2 are consistent with both layers being deposited from the same flow. However, any proximal deposits left by the later, hotter material must have been subsequently eroded, or be so thin that our collection failed to sample them. Radial asymmetries in equilibrium temperatures as well as other physical parameters suggest that the deposit emplacement temperature is primarily determined at source, rather than by interaction with air during transport. These data support previous interpretations that a concentrated basal flow played a dominant role in emplacement and deposition of the Taupo ignimbrite.Editorial responsibility: T. Druitt     

Nature and origin of cone-forming volcanic breccias in the Te Herenga Formation, Ruapehu, New Zealand

 Volcanic breccias form large parts of composite volcanoes and are commonly viewed as containing pyroclastic fragments emplaced by pyroclastic processes or redistributed as laharic deposits. Field study of cone-forming breccias of the andesitic middle Pleistocene Te Herenga Formation on Ruapehu volcano, New Zealand, was complemented by paleomagnetic laboratory investigation permitting estimation of emplacement temperatures of constituent breccia clasts. The observations and data collected suggest that most breccias are autoclastic deposits. Five breccia types and subordinate, coherent lava-flow cores constitute nine, unconformity-bounded constructional units. Two types of breccia are gradational with lava-flow cores. Red breccias gradational with irregularly shaped lava-flow cores were emplaced at temperatures in excess of 580  °C and are interpreted as aa flow breccias. Clasts in gray breccia gradational with tabular lava-flow cores, and in some places forming down-slope-dipping avalanche bedding beneath flows, were emplaced at varying temperatures between 200 and 550  °C and are interpreted as forming part of block lava flows. Three textural types of breccia are found in less intimate association with lava-flow cores. Matrix-poor, well-sorted breccia can be traced upslope to lava-flow cores encased in autoclastic breccia. Unsorted boulder breccia comprises constructional units lacking significant exposed lava-flow cores. Clasts in both of these breccia types have paleomagnetic properties generally similar to those of the gray breccias gradational with lava-flow cores; they indicate reorientation after acquisition of some, or all, magnetization and ultimate emplacement over a range of temperatures between 100 and 550  °C. These breccias are interpreted as autoclastic breccias associated with block lava flows. Matrix-poor, well-sorted breccia formed by disintegration of lava flows on steep slopes and unsorted boulder breccia is interpreted to represent channel-floor and levee breccias for block lava flows that continued down slope. Less common, matrix-rich, stratified tuff breccias consisting of angular blocks, minor scoria, and a conspicuously well-sorted ash matrix were generally emplaced at ambient temperature, although some deposits contain clasts possibly emplaced at temperatures as high as 525  °C. These breccias are interpreted as debris-flow and sheetwash deposits with a dominant pyroclastic matrix and containing clasts likely of mixed autoclastic and pyroclastic origin. Pyroclastic deposits have limited preservation potential on the steep, proximal slopes of composite volcanoes. Likewise, these steep slopes are more likely sites of erosion and transport by channeled or unconfined runoff rather than depositional sites for reworked volcaniclastic debris. Autoclastic breccias need not be intimately associated with coherent lava flows in single outcrops, and fine matrix can be of autoclastic rather than pyroclastic origin. In these cases, and likely many other cases, the alternation of coherent lava flows and fragmental deposits defining composite volcanoes is better described as interlayered lava-flow cores and cogenetic autoclastic breccias, rather than as interlayered lava flows and pyroclastic beds. Reworked deposits are probably insignificant components of most proximal cone-forming sequences. Received: 1 October 1998 / Accepted: 28 December 1998     

Palaeomagnetic estimates of emplacement temperatures of pyroclastic deposits on Santorini,Greece

Thermal remanent magnetism provides a method of quantitatively determining the emplacement temperature of individual lithic clasts in a volcaniclastic rock. The technique is reviewed and applied to two types of Quaternary pyroclastic deposit on Santorini. Emplacement-temperature estimates for lithic clasts from two co-ignimbrite lithic breccias (Cape Riva and Middle Pumice eruptions) range from 250°C to 580°C, showing unambiguously that the breccias were emplaced hot. Good precision on temperature estimates (about ±20°C) were obtained from the Cape Riva breccias. Lithics in a Plinian airfall deposit from the Middle Pumice eruption give less precise results because the primary magnetisation has been partly overprinted by chemical (and/or viscous) remanence, and some clasts may have rotated during compaction of the deposit. Temperatures from proximal airfall are consistent with welding of the deposit within 1.5 km from vent. Temperature estimates for lithic clasts further from vent scatter, but a falloff of temperature away from vent can be recognised if an average emplacement temperature for the whole deposit is identified at each location. The study highlights some difficulties in interpreting quantitative temperature estimates for prehistoric pyroclastic deposits.     

The proximal facies of the Tosu pyroclastic-flow deposit erupted from Aso caldera,Japan

The Tosu pyroclastic flow deposit, a low-aspect-ratio ignimbrite (LARI), has widely distributed breccia facies around Aso caldera, Japan. The proximal facies, 9–34 km away from the source, consists of 3 different lithofacies, from bottom to top: a lithic-enriched and fines-depleted (FD) facies, a lithic-enriched (LI) facies with an ash matrix, and a fines- and pumice-enriched (NI) facies. Modes of emplacement of FD, LI, and NI are interpreted as ground layer, 2b-lithic-concentration zone, and normal ignimbrite, respectively. These stratigraphic components in the Tosu originated from the flow head (FD) and the flow body (LI and NI), and were generated by a single column collapse event. Remarkably thick FD and LI, in contrast to thin NI, suggest that due to high mobility most ash and punice fragments in the Tosu were carried and deposited as NI in the distal area. Heavier components were selectively deposited as FD and LI in the proximal area. The rate of falloff of lithic-clast size in the Tosu shows an inflection at 20 km from the source. In a survey of well-documented pyroclastic flows, the inflection distance of a LARI is generally greater than that of a high-aspect-ratio ignimbrite, so that the eruption of the former is probably more intense than the latter.     

The Holocene Pucón eruption of Volcán Villarrica, Chile: deposit architecture and eruption chronology

The Pucón eruption was the largest Holocene explosive outburst of Volcán Villarrica, Chile. It discharged >1.0 km³ of basaltic-andesite magma and >0.8 km³ of pre-existing rock, forming a thin scoria-fall deposit overlain by voluminous ignimbrite intercalated with pyroclastic surge beds. The deposits are up to 70 m thick and are preserved up to 21 km from the present-day summit, post-eruptive lahar deposits extending farther. Two ignimbrite units are distinguished: a lower one (P1) in which all accidental lithic clasts are of volcanic origin and an upper unit (P2) in which basement granitoids also occur, both as free clasts and as xenoliths in scoria. P2 accounts for ∼80% of the erupted products. Following the initial scoria fallout phase, P1 pyroclastic flows swept down the northern and western flanks of the volcano, magma fragmentation during this phase being confined to within the volcanic edifice. Following a pause of at least a couple of days sufficient for wood devolatilization, eruption recommenced, the fragmentation level dropped to within the granitoid basement, and the pyroclastic flows of P2 were erupted. The first P2 flow had a highly turbulent front, laid down ignimbrite with large-scale cross-stratification and regressive bedforms, and sheared the ground; flow then waned and became confined to the southeastern flank. Following emplacement of pyroclastic surge deposits all across the volcano, the eruption terminated with pyroclastic flows down the northern flank. Multiple lahars were generated prior to the onset of a new eruptive cycle. Charcoal samples yield a probable eruption age of 3,510 ± 60 ¹⁴C years BP.     

Interrelations among pyroclastic surge,pyroclastic flow,and lahars in Smith Creek valley during first minutes of 18 May 1980 eruption of Mount St. Helens,USA

A devastating pyroclastic surge and resultant lahars at Mount St. Helens on 18 May 1980 produced several catastrophic flowages into tributaries on the northeast volcano flank. The tributaries channeled the flows to Smith Creek valley, which lies within the area devastated by the surge but was unaffected by the great debris avalanche on the north flank. Stratigraphy shows that the pyroclastic surge preceded the lahars; there is no notable “wet” character to the surge deposits. Therefore the lahars must have originated as snowmelt, not as ejected water-saturated debris that segregated from the pyroclastic surge as has been inferred for other flanks of the volcano. In stratigraphic order the Smith Creek valley-floor materials comprise (1) a complex valley-bottom facies of the pyroclastic surge and a related pyroclastic flow, (2) an unusual hummocky diamict caused by complex mixing of lahars with the dry pyroclastic debris, and (3) deposits of secondary pyroclastic flows. These units are capped by silt containing accretionary lapilli, which began falling from a rapidly expanding mushroom-shaped cloud 20 minutes after the eruption's onset. The Smith Creek valley-bottom pyroclastic facies consists of (a) a weakly graded basal bed of fines-poor granular sand, the deposit of a low-concentration lithic pyroclastic surge, and (b) a bed of very poorly sorted pebble to cobble gravel inversely graded near its base, the deposit of a high-concentration lithic pyroclastic flow. The surge apparently segregated while crossing the steep headwater tributaries of Smith Creek; large fragments that settled from the turbulent surge formed a dense pyroclastic flow along the valley floor that lagged behind the front of the overland surge. The unusual hummocky diamict as thick as 15 m contains large lithic clasts supported by a tough, brown muddy sand matrix like that of lahar deposits upvalley. This unit contains irregular friable lenses and pods meters in diameter, blocks incorporated from the underlying dry and hot pyroclastic material that had been deposited only moments earlier. The hummocky unit is the deposit of a high-viscosity debris flow which formed when lahars mingled with the pyroclastic materials on Smith Creek valley floor. Overlying the debris flow are voluminous pyroclastic deposits of pebbly sand cut by fines-poor gas-escape pipes and containing charred wood. The deposits are thickest in topographic lows along margins of the hummocky diamict. Emplaced several minutes after the hot surge had passed, this is the deposit of numerous secondary pyroclastic flows derived from surge material deposited unstably on steep valley sides.     

Primary and redeposited facies from a large-magnitude, rhyolitic, phreatomagmatic eruption: Cana Creek Tuff, Late Carboniferous, Australia

The Cana Creek Tuff is one of four rhyolitic ignimbrite members of the Late Carboniferous Currabubula Formation, a volcanogenic conglomeratic braidplain sequence exposed along the western margin of the New England Orogen in northeastern New South Wales. The source is not exposed but was probably located tens of kilometres to the west of existing outcrops. The medial to distal parts of the tuff average about 70 m in thickness, are widespread (minimum present area 1400 km²), and comprise a primary pyroclastic facies (ignimbrite, ash-fall tuff) and a redeposited volcaniclastic facies (sandstone, conglomerate). Both facies are composed of differing proportions of crystal fragments (quartz, plagioclase, K-feldspar), pumiceous clasts (pumice, shards, fine ash), and accidental lithics. The eruption responsible for this unit was explosive and of large magnitude (dense rock equivalent volume about 100 km³). That it was also phreatomagmatic in character is proposed on the basis of: the intimate association of primary and redeposited facies; the presence of accretionary lapilli both in ignimbrite and in ash-fall tuff; the fine grain size of juvenile pyroclasts; the low grade of the ignimbrite; and the close similarity in facies, composition and magnitude to the deposits from the 20,000y. B.P. phreatomagmatic eruption at Taupo, New Zealand (the Wairakei and parts of the Hinuera Formations). The eruption began and ended from a vent with excess water available, possibly submersed in a caldera lake, and generated volcaniclastic sheet floods and debris flows. The emplacement of the primary pyroclastic facies is correlated with an intervening stage when the water:magma mass ratio was lower. The deposits from a large-magnitude, phreatomagmatic eruption are predicted to show systematic lateral variations in facies. Primary pyroclastic facies predominate near the source although the preserved stratigraphy is an incomplete record because of widespread contemporaneous erosion. Volcaniclastic facies, redeposited from proximal sites by floods, dominate at medial and distal locations. In areas hundreds of kilometres from the source, the eruption is registered by thin layers of fine-grained airfall ash.     

Paleomagnetic estimate of the emplacement temperature of the long-runout Nevado de Colima volcanic debris avalanche deposit, Mexico

Stoopes and Sheridan have mapped a volcanic debris avalanche of Nevado de Colima which has an exceptionally long runout (120 km) and low fall-height to length ratio (H/L = 0.04). We present paleomagnetic results from this volcanic debris avalanche deposit which provide evidence that this avalanche was emplaced at elevated temperatures. The majority of samples, collected from lithic clasts in the volcanic debris avalanche deposit, exhibit two-component remanent magnetizations with a low-temperature component (25–350°C) which is well grouped about the geomagnetic field direction at Colima and a high-temperature component (350–580°C) which is randomly oriented. Although the temperature of the deposit most likely varied with distance from the volcanic source and the thickness of the deposit, our results suggest an emplacement temperature of approximately 350°C at intermediate distances (18–26 km) from the source. In order for the rock clasts (20–40 cm diameter) to be heated to these temperatures, the avalanche was most likely the results of a magmatic, Bezymianny-type eruption. The mixing of hot, juvenile gases with the clasts provides an explanation for the high degree of fluidization of this material, as evidenced by the long runout of this avalanche deposit.     

Palaeotemperature estimation of the pyroclastic deposit covering the pre-Minoan palaeosol at Megalochori Quarry, Santorini (Greece): Evidence from magnetic measurements

Thermal remanent magnetization analyses were carried out on ceramic fragments and lithic clasts embedded in the first pumice fall deposits of the Minoan eruption. The aim of this study is to estimate the equilibrium temperature after deposition of these pyroclastic fall deposits and their thermal effect on the pre-Minoan surface. A total of 30 samples from 22 independent ceramic fragments and 20 samples from 14 lithic clasts have been studied. Samples were collected from the Megalochori Quarry, located at the southern part of Santorini island. Stepwise thermal demagnetization reveals that the ceramics were mostly re-heated at temperatures around 140–180°C; in few ceramics a higher temperature component is also present, probably related to the original heating or the use of the ceramics before the eruption. Thermal demagnetization of the lithic clasts shows similar results with slightly higher re-heating temperatures, around 180–240°C. The estimated temperatures represent the equilibrium temperatures obtained after the deposition of the pumice fall and show that the pyroclastic fall deposits at a distance of around 6 km from the eruption vent maintained a temperature high enough to re-heat the buried ceramics at temperatures around 140–180°C.     

Spatter-rich pyroclastic flow deposits on Santorini,Greece

Pyroclastic deposits exposed in the caldera walls of Santorini Volcano (Greece), contain several prominent horizons of coarse-grained andesitic spatter and cauliform volcanic bombs. These deposits can be traced around most of the caldera wall. They thicken in depressions and are intimately associated with ignimbrite and co-ignimbrite lithic lag breccias. They are interpreted as a proximal facies of pyroclastic flow deposits. Evidence for a flow origin includes the presence of a fine-grained pumiceous matrix, flow deformation of ductile spatter clasts, exceedingly coarse grain sizes several kilometres from any plausible vent, imbrication of flattened spatter clasts, intimate interbedding with normal pyroclastic flow deposits and the presence of inversely graded basal layers. The deposits contain hydrothermally altered, rounded lithic ejecta including gabbro nodules. The andesitic ejecta and the fine matrix are typically moderately to poorly vesicular indicating that magmatic gas had a subordinate role in the eruptive process. The andesitic clasts contain abundant angular lithic inclusions and some clasts are themselves formed of pre-existing agglutinate. We propose that these eruptions occurred when external water gained access to the vents, causing large-scale explosions which formed pyroclastic flows rich in coarse, semifluid but poorly vesicular ejecta. We postulate that large volumes of coarse pyroclastic ejecta and degassed lava accumulated in a deep crater prior to being disrupted by these large explosions to form pyroclastic flows.     

Columnar jointing in vapor-phase-altered,non-welded Cerro Galán Ignimbrite,Paycuqui, Argentina

Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10⁻³–8.5 × 10⁻²°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.     

The Albano maar lake (Colli Albani Volcano, Italy): recent volcanic activity and evidence of pre-Roman Age catastrophic lahar events

The evaluation of volcanic hazard in the Roman hinterland related to the quiescent Colli Albani Volcano has recently been the subject of renewed attention and several interpretations by many authors. However, very little was known of the recent history of the volcano, making such interpretations rather speculative. The most recent activity of Colli Albani Volcano originated from the Albano polygenetic maar lake, which erupted several phreatomagmatic units, the most recent of which, the Peperino Albano ignimbrite, has been dated at around 25 ka. An area of several square kilometers centered around Albano Lake is presently the site of shallow and frequent seismic activity and gaseous emission as well as hydrothermal activity and is therefore considered the most prone to geologic hazards. This paper presents new stratigraphic and geomorphologic data as well as age determinations that allow rejuvenation of the most recent activity of the Colli Albani Volcano, and particularly the Albano maar lake, to the Holocene. This study allows for the first time to identify a potential hazard related to the Albano maar lake withdrawal interpreted to be related to endogenous causes, namely CO₂ emission. The main results of the study are: (1) the Peperino Albano is not, as is generally believed, the last phreatomagmatic eruption from the Colli Albani Volcano; a previously unrecognized phreatomagmatic surge deposit has been identified overlying the paleosol at the top of the Peperino Albano and related lahar deposits; (2) two lahar deposits separated by paleosols top the stratigraphic succession and are dispersed only to the NW, corresponding to the lowest point of the maar rim, indicating that catastrophic hydrologic events occurred at the Albano Lake in recent times; rapid and substantial lake-level variations and lake withdrawal are reported by Roman historians and recorded by the stratigraphy of the Albano Lake lacustrine sediments; (3) microfracturing related to seismic energy release is linked to sudden variation of CO₂ flow and upwelling of hydrothermal fluids. These occurrences across the lake are the likely causes that triggered during Holocene several episodes of lake withdrawal, rising the water table and probably triggering convective rollover of the lake water.     

Emplacement temperatures of the November 22, 1994 nuée ardente deposits, Merapi Volcano, Java

A study of emplacement temperatures was carried out for the largest of the 22 November 1994 nuée ardente deposits at Merapi Volcano, based mainly on the response of plastic and woody materials subjected to the hot pyroclastic current and the deposits, and to some extent on eyewitness observations. The study emphasizes the Turgo–Kaliurang area in the distal part of the area affected by the nuée ardente, where nearly 100 casualties occurred. The term nuée ardente as used here includes channeled block-and-ash flows, and associated ash-clouds of surge and fallout origins. The emplacement temperature of the 8 m thick channeled block-and-ash deposit was relatively high, 550°C, based mainly on eyewitness reports of visual thermal radiance. Emplacement temperatures for ash-cloud deposits a few cm thick were deduced from polymer objects collected at Turgo and Kaliurang. Most polymers do not display a sharp melting range, but polyethylene terephthalate used in water bottles melts between 245 and 265°C, and parts of the bottles that had been deformed during fabrication molding turn a milky color at 200°C. The experimental evidence suggests that deposits in the Turgo area briefly achieved a maximum temperature near 300°C, whereas those near Kaliurang were <200°C. Maximum ash deposit temperatures occurred in fallout with a local source in the channeled block-and-ash flow of the Boyong river valley; the surge deposit was cooler (180°C) due to entrainment of cool air and soils, and tree singe-zone temperatures were around 100°C.     

Sedimentology of the Krakatau 1883 submarine pyroclastic deposits

The majority of tephra generated during the paroxysmal 1883 eruption of Krakatau volcano, Indonesia, was deposited in the sea within a 15-km radius of the caldera. Two syneruptive pyroclastic facies have been recovered in SCUBA cores which sampled the 1883 subaqueous pyroclastic deposit. The most commonly recovered facies is a massive textured, poorly sorted mixture of pumice and lithic lapilli-to-block-sized fragments set in a silty to sandy ash matrix. This facies is indistinguishable from the 1883 subaerial pyroclastic flow deposits preserved on the Krakatau islands on the basis of grain size and component abundances. A less common facies consists of well-sorted, planarlaminated to low-angle cross-bedded, vitric-enriched silty ash. Entrance of subaerial pyroclastic flows into the sea resulted in subaqueous deposition of the massive facies primarily by deceleration and sinking of highly concentrated, deflated components of pyroclastic flows as they traveled over water. The basal component of the deposit suggests no mixing with seawater as inferred from retention of the fine ash fraction, high temperature of emplacement, and lack of traction structures, and no significant hydraulic sorting of components. The laminated facies was most likely deposited from low-concentration pyroclastic density currents generated by shear along the boundary between the submarine pyroclastic flows and seawater. The Krakatau deposits are the first well-documented example of true submarine pyroclastic flow deposition from a modern eruption, and thus constitute an important analog for the interpretation of ancient sequences where subaqueous deposition has been inferred based on the facies characteristics of encapsulating sedimentary sequences.