Results of monitoring of the changes in the hydrochemical structure of the central and Southern Caspian Sea over 1995–2005

The results of decennial monitoring of the Caspian Sea were summarized, which allowed revealing the “pumping” of nutrients from the euphotic layer to deepwater depressions of the Central and Southern Caspian Sea. In parallel, in the deepwater depressions, growth of hypoxia to values of 0.2–0.5 ml O₂/l proceeds. In 2006, hydrogen sulfide was registered in the near-bottom layer of the South Caspian Sea Basin. It is shown that the transformation of the hydrochemical structure was directed towards the conditions observed at the times of Bruevich (1933–1934), but no complete coincidence has yet been reached.     

Seasonal variations in temperature,salinity and density in the southern coastal waters of the Caspian Sea

Variability in water temperature, salinity and density was investigated based on field measurements near Anzali Port, in the Southern Caspian Sea in 2008. Seasonal changes of seawater properties were mainly observed through the upper 100 m layer, while below this layer seasonal variations of the parameters were minor. Vertical structure of the temperature in the southern coastal waters of the Caspian Sea is characterized by a significant seasonal thermocline between 20–50 m depths with vertical variation in temperature about 16°C in midsummer (August). Decrease of the thermocline occurs with the general cooling of the air and sea surface water, and deepening of the mixed layer during late of autumn and winter. Seasonal averages of the salinity were estimated in a range of 12.27–12.37 PSU. The structure of thermocline and pycnocline indicated agreement between changes of temperature and density of seawater. Seasonal pycnocline was observed in position of the thermocline layer.     

Evolution of the Northern Caspian Sea Region and the Volga delta in the late Pleistocene-Holocene

On the basis of geologic-geomorphologic studies, an alternative concept regarding the evolution of the Northern Caspian Sea Region and the adjacent areas in the boundary of the Pleistocene-Holocene is presented. A supposition is made about the existence of a large lagoon in the North Caspian Region that the Volga River emptied into forming a delta. Later, water from the lagoon flowed as a “stratum” stream into the Black Sea through the Manych Strait. A conclusion is reached that the Baer mounds were formed on the bottom of this stream.     

Macrophytobenthos of the Caspian Sea: Diversity,distribution, and productivity

In the Russian sector of the northern and middle Caspian Sea, 36 species of macroalgae have been identified. The green and red algae from the mesosaprobic group are dominant. An increase in the number of green algae species is revealed. The distribution of macroalgae is inhomogeneous. It is confined to the solid substrate and epiphyton. The biomass of seaweeds reaches 1.5 kg/m². Climate change has little influence on the appearance of new species in the northern Caspian Sea, but new invaders can appear in the Middle and Southern Caspian. The distribution of aquatic and coastal hygrophytic vegetation shows considerable spatial dynamics due to fluctuations in the level and salinity of the Caspian Sea. The biomass of aquatic vegetation varies in a wide range from 0.5 to 10.0 kg/m₂. Spatially detailed mathematical models adequately reflect the changes in key species of aquatic plants in space and time. It is shown that expansion of the zone of the seagrass Zostera noltii to shallow water areas is occurring at present, as well as shrinkage of the range of the dominant littoral aquatic plant Phragmites australis.     

Seismic expression and inferred depositional environments of Plio-Pleistocene sedimentary sequences in the southwestern Caspian Sea

Eight seismic profiles from the southwestern Caspian Sea were analyzed to establish the sedimentary environments and depositional history in the South Caspian Basin since Pliocene times. Based on reflection terminations, nine sequence boundaries (S1 to S9) were identified and traced across the study area. Consequently, nine depositional sequences (S1–S9) were defined on the basis of seismic facies analysis. The results suggest a transition from non-marine sedimentation in the Lower Pliocene to marine-dominated conditions in the Upper Pliocene (S1–S4). Marine conditions then continued to the present time; however, several sea-level changes led to the formation of sequences S5 to S9. Although no local sea-level curve is available due to a lack of well data, there is good agreement between the seismic stratigraphy of the study area and a published regional sea-level curve.     

On the nature of the Khvalynian transgression of the Caspian Sea

This paper presents a reconsideration of the hypothesis that the Khvalynian transgression of the Caspian Sea resulted from an abundant inflow of meltwaters from Siberian proglacial lakes through the Aral Sea and via the Uzboi channel and may be considered as a prototype of Noah’s Flood. A thorough analysis of the evidence suggested by the proponents of this hypothesis revealed a lack of factual substantiation; there are no facts indicating the existence of the Aral flow-through lake or of the Siberian proglacial water supply to the Caspian Sea. The spatial distribution of the mollusk fauna provides no support for the view that the Khvalynian transgression was essentially influenced by thawing of ice sheets on the Russian Plain. The Khvalynian transgression, though geologically short-term, could not be an analogue of Noah’s catastrophic flood. The sea level rose at a rate of a few centimeters per year for a few thousand years; this interval covered the lifetimes of many generations of the Caspian coast inhabitants. The Khvalynian water overflowing via the Manych Strait into the Pontian basin provided an even smaller influence. It resulted in flooding of the middle part of the Black Sea shelf, in a 30-m sea level rise, and in a water salinity increase by 5‰.     

Hydrocarbons in the Surface Layer of Bottom Sediments in the Northwestern Caspian Sea

The paper presents research results on the concentrations and compositions of aliphatic and polycyclic aromatic hydrocarbons in the surface layer of bottom sediments in the Northwestern Caspian Sea (2014) and compares them to data for sediments of the Middle and Southern Caspian (2012–2013). The seepage of hydrocarbons out of the sediment mass, resulting in abnormally high concentrations of aliphatic hydrocarbons per dry weight (up to 468 μg/g), as well as within the C_org composition (up to 35.2%), is considered the main source of hydrocarbons in sediments in the surveyed area of the Northern Caspian. This is also confirmed by the absence of any correlation between the hydrocarbon and C_org distributions, as well as by the transformed oil composition of high-molecular alkanes. The distribution of markers within polycyclic aromatic hydrocarbons points to a mixed genesis—petrogenic and pyrogenic—with prevalence of the latter. Unlike the shallow-water northern part of the Caspian Sea, the content and composition of hydrocarbons in deep-seated sediments are affected by facial conditions of sedimentation and by matter exchange at the water–bottom interface. Therefore, despite high C_org concentrations (up to 9.9%), sediments in deep-water depressions are characterized by a quite low concentration of aliphatic hydrocarbons (52 μg/g on average; 0.2% of C_org) with prevailing natural allochthonous alkanes.     

Characteristics of Underwater Irradiation in the Black Sea in Spring (1993 and 1995)

We present the data on the values of the coefficients of vertical attenuation and diffusive reflection of light in the Black Sea in spring 1993 and 1995, compute the depths of one-percent quantum irradiation and the parameter Μ specifying the fraction of attenuation of directed light as a result of scattering: Μ = σ/ɛ, and compare the characteristics of underwater irradiation in the sea in different seasons for 1989–1995. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 3, pp. 44–48, May–June, 2005.     

Tidal oscillations in the Caspian Sea

Long-term hourly data from 12 tide gauge stations were used to examine the character of tidal oscillations in the Caspian Sea. Diurnal and semidiurnal tidal peaks are well-defined in sea level spectra in the Middle and South Caspian basins. High-resolution spectral analysis revealed that the diurnal sea level oscillations in the Middle Caspian Basin have a gravitational origin, while those in the South Caspian Basin are mainly caused by radiational effects: the amplitude of diurnal radiational harmonic S₁ is much higher than those of gravitational harmonics О₁, P₁, and K₁. In the North Caspian Basin, there are no gravitational tides and only weak radiational tides are observed. A semidiurnal type of tide is predominant in the Middle and South Caspian basins. Harmonic analysis of the tides for individual annual series with subsequent vector averaging over the entire observational period was applied to estimate the mean amplitudes and phases of major tidal constituents. The amplitude of the M₂ harmonic reaches 5.4 cm in the South Caspian Basin (at Aladga). A maximum tidal range of 21 cm was found at the Aladga station in the southeastern part of the Caspian Sea, whereas the tidal range in the western part of the South Caspian Basin varies from 5 to 10 cm.     

Late glacial to Holocene climate and sedimentation history in the NW Black Sea

Gravity cores from the continental slope in the northwestern Black Sea were studied using high-resolution stable isotope, grain size and XRF-scanning data. The measurements provide a 30 000 years AMS ¹⁴C-dated record of variations in the hydrological regime of the Black Sea and give insight into changing paleoenvironments in the surrounding areas. Stable climatic conditions during the Last Glacial Maximum were followed by a series of meltwater pulses most likely originating from the Scandinavian ice sheet between 18 000 and 15 500 yr BP.¹ This meltwater input rose the level of the Caspian Sea to a point that Caspian water could spill into the Black Sea via the Manych-depression north of the Caucasian mountains. High-frequency oscillations in the XRF-data during this period suggest a probable link to the arctic climate regime. Later, during the Bølling/Allerød and the early Holocene, prevailing high temperatures led to authigenic calcite precipitation through increased phytoplankton activity, interrupted by the Younger Dryas and the “8200 yr BP cold event” with dominant clastic sedimentation.     

Dependence of the types of coasts and coastal eolian relief on the variations of the sea level using the example of the Caspian Sea

In this work, the history of the development of the Turali area (the Dagestan coast of the Caspian Sea) in the Late Holocene is under consideration. The analysis of the geological structure of the bay bar that separates the Bolshoy Turali lagoon from the sea, the granulometric analysis of the coastal deposits, and the data of geo-radar profiles make it possible to assert that the large eolian relief forms were formed during the New Caspian (Novokaspiyskoe) transgression of the Caspian Sea.     

Distribution of some rare and trace elements in modern bottom sediments of the Caspian Sea

The features of the distribution of some rare and trace elements in modern bottom sediments of the Caspian Sea have been studied from samples collected during cruises 35, 39, and 41 of the R/V Rift and the cruise of the R/V Nikifor Shurekov in 2013. It was established that bottom sediments in different areas of the Caspian Sea vary to some degree in the contents of Zr, Hf, Th, V, Cr, Co, Ni, Cu, Sr, and Ba in comparison to suspended matter discharged by the Volga River and rivers originating in the Caucasus. As follows from the results of a comparison of the geochemical features of modern bottom sediments of the Volga River delta and different sedimentary subsystems of the Caspian Sea with the chemical composition of Middle Archean granitoids and Paleozoic and Mesozoic–Cenozoic basalts, which are regarded as geochemical images of such provenance areas as the basement of East European Platform, Urals, and Caucasus, none of these regions is considered the dominant provenance area for all sedimentary subsystems of the Caspian Sea region. Here, the revealed similarity between modern bottom sediments of the northern, central and southern Caspian Sea regions, the Volga River delta, and Post-Archean average Australian shale (PAAS) in some parameters, including REE spectra, assumes that the Volga River discharge plays a dominant role in the formation of the geochemical image of Caspian Sea subsystems. The role of clastics, including the fine-grained fraction, which is supplied to the Caspian Sea from the Caucasus region and Elburz Mountains, is insignificant already in the coastal area, which is determined both by influence of the marginal filter (MF) and large-scale cholestatic current circulation.     

On the structural approach to studying the variability of the marine environment using data from color ocean scanners

The authors propose to treat the structure of the sea surface images from the ocean color scanners (OCS) as a complex integrated indication of the state of the marine environment. Supposedly, such an approach will make current the information on the water environment processes hidden in the spectral-radiance patterns of arbitrary shapes. They are typical of inland seas, straits, and other transition areas but attract no attention due to recognition difficulties. The authors give preliminary estimates of the repeatability of mesoscale structures found from data of the OCSs SeaWiFS and MODIS for the period of 1998–2007 in the oceanologically diverse Caspian Sea regions. The authors’ approach is shown to be useful for studying the long-term variability of marine aquatic areas from the satellite data archives.     

Structures of the northeasternmost South China Sea continental margin and ocean basin: geophysical constraints and tectonic implications

The northeastern part of the South China Sea is a special region in many aspects of its tectonics. Both recent drilling into the Mesozoic and new reflection seismic surveys in the area provide a huge amount of data, fostering new understanding of the continental margin basins and regional tectonic evolution. At least four half-grabens are developed within the Northern Depression of the Tainan Basin, and all are bounded on their southern edges by northwestward-dipping faults. One of the largest half-grabens is located immediately to the north of the Central Uplift and shows episodic uplift from the late Oligocene to late Miocene. Also during that period, the Central Uplift served in part as a material source to the Southern Depression of the Tainan Basin. The Southern Depression of the Tainan Basin is a trough structure with deep basement (up to 9 km below sealevel or 6 km beneath the sea bottom) and thick Cenozoic sedimentation (>6 km thick). Beneath the Southern Depression we identified a strong landward dipping reflector within the crustal layer that represents a significant crustal fault. This reflector coincides with a sharp boundary in crustal thicknesses and Moho depths. We show that the northeasternmost South China Sea basin, which may have undergone unique evolution since the late Mesozoic, is markedly different from the central South China Sea basin and the Huatung Basin, both geologically and geophysically. The Cenozoic evolution of the region was largely influenced by pre-existing weaknesses due to tectonic inheritance and transition. The South China Sea experienced multiple stages of Cenozoic extension.     

Caspian Sea Level Fluctuations in the Neopleistocene (Was There an Atelian Regression?)

The article deals with deposits exposed in sections along the rivers of the Caspian lowland and on the eastern slope of the Ergenei. The conclusion is made about the lagoonal origin of chocolate clays lying on high-capacity subaerial and alluvial–deltaic deposits. The impact of the Caspian Sea level rise on coastal processes is examined. Taking into account the regularities in the behavior of the coastal zone during sea level rise, subaerial deposits with such thickness in the outcrops could not have been preserved during the early Khvalynian transgression from –100 m. Another curve of Caspian Sea level fluctuations is proposed, where there is no deep Atelian regression between the Khazarian and Khvalynian transgressions. It is concluded that the Khazarian transgression was one of the largest in the history of the Caspian Sea. Its level was slightly less than that of the Khvalynian transgression. The rise of the level of the latter began not from –100 m, but from about 5–15 m; i.e., this transgression was in fact an oscillation of the Caspian Sea against its gradual regression after the Khazarian transgression. Sea level oscillations contributed to the formation of lagoonal-transgressive terraces, in which chocolate clays accumulated.

     

On the wind conditions of a shallow as a factor of the formation of satellite images of the Sea (Using the example of the South Caspian Sea)

Based on the scatterometer QuickScat wind data and the water-leaving radiances from the ocean color scanner SeaWiFS data for 2000–2004, we composed a pair of mean annual images of a testing site in the South Caspian Sea under conditions of west-bound and east-bound winds corresponding to the offset and onset state of the shallows in the east of the testing site. It was established that both the “offset” and “onset” radiances grow shorewards, but the former becomes about twice as large as the latter in the middle of the shallows with 10–15 m of water, while their difference tends to zero at the seaward and coastal boundaries of the shallow. These and other findings are hypothetically attributable to the inclination of the sea floor of the shallows, due to which the surfacing of bottom sediments resuspended by the drift current takes less time under the “offset” wind conditions than under the “onset” ones. The study’s results indicate that the effect of the bottom sediments resuspension upon the structure of the images of the marine shallows is universal in character and needs to be taken into account to improve the bio-optical algorithms for estimating the admixtures in the thickness of the shallows from the satellite data.     

Genealogical concordance,comparative species delimitation,and the specific status of the Caspian pipefish Syngnathus caspius (Teleostei: Syngnathidae)

To evaluate the specific validity of the Caspian pipefish Syngnathus caspius, we used a comparative molecular species delimitation method on a COI barcode library of Syngnathus, as well as principles of genealogical concordance. Comparative species delimitation allowed us to delineate putative species without a priori assignment of individuals to nominal species, while genealogical concordance extended our species delimitation results to multiple genes, multiple codistributed species, and comparisons with biogeographic evidence. All species delimitation analyses including two topology‐based, one network‐based, and one distance‐based analysis showed genetically isolated lineages of pipefish in the Black and Caspian Sea, corresponding to S. abaster and S. caspius, respectively. Mean evolutionary divergence between the two lineages (0.029) was within the range separating species of Syngnathus (0.024–0.217). The interclade/intraclade ratio of variation was comparable to the operational criterion of divergence between clades greater or equal to 10 × the level within clades to recognize separate species. Our argument on taxonomic validity of S. caspius is also supported by the principles of genealogical concordance as a conceptual basis for recognition of biological species. As a second objective, using a limited number of S. caspius specimens from two semi‐confined water bodies along the Caspian Sea south coastal zone (i.e., Anzali Wetland in the west and Gorgan Bay in the east), we searched for a possible matrilineal structure. The retrieved phylogeographic pattern was characterized by a shallow genealogy and lineage distributions varied, most probably caused by low to modest contemporary gene flow between populations of S. caspius across the southern Caspian Sea that are linked tightly through history.     

Composition of fragmental minerals of the surface layer of bottom sediments in the Caspian Sea

The mineral composition of heavy and light subfractions of the modern bottom sediments of the Caspian Sea is studied. The concentration of the minerals in the Caspian Sea made it possible to identify nine terrigeneous mineralogical provinces in its area. Based on the mineral composition of the heavy subfraction of the bottom sediments, the main sources of the fragmentary material supply are established. The distribution of the terrigeneous minerals over the bottom area in the modern bottom sediments of the Caspian Sea depends on the sources of the fragmentary material; the stability and flotation properties of minerals; the morphology of the bottom; and the hydrodynamic conditions.     

Annual and Seasonal Variations of the Sea Surface Heat Fluxes in the East Asian Marginal Seas

Based on the twice-daily marine atmospheric variables which were derived mostly from the weather maps for 18 years period from 1978 to 1995, the surface heat flux over the East Asian marginal seas was calculated at 0.5°×0.5° grid points twice a day. The annual mean distribution of the net heat flux shows that the maximum heat loss occurs in the central part of the Yellow Sea, along the Kuroshio axis and along the west coast of the northern Japanese islands. The area off Vladivostok turned out to be a heat-losing region, however, on the average, the amount of heat loss is minimum over the study area and the estuary of the Yangtze River also appears as a region of the minimum heat loss. The seasonal variations of heat flux show that the period of heat gain is longest in the Yellow Sea, and the maximum heat gain occurs in June. The maximum heat loss occurs in January over the study area, except the Yellow Sea where the heat loss is maximum in December. The annual mean value of the net heat flux in the East/Japan Sea is −108 W/m² which is about twice the value of Hirose et al. (1996) or about 30% higher than Kato and Asai (1983). For the Yellow Sea, it is about −89 W/m² and it becomes −75 W/m² in the East China Sea. This increase in values of the net heat flux comes mostly from the turbulent fluxes which are strongly dependent on the wind speed, which fluctuates largely during the winter season. This revised version was published online in August 2006 with corrections to the Cover Date.     

Stable Isotopic Composition of Particulate Organic Carbon in the Caspian Sea

The data on the isotopic composition of particulate organic carbon (δ¹³C_POC) in the Caspian Sea water in summer–autumn 2008, 2010, 2012, and 2013 are discussed in the paper. These data allowed as to reveal the predominant genesis of organic carbon in suspended particulate matter of the active seawater layer (from 0 to 40 m). The δ¹³C_POC =–27‰ (PDB) and δ¹³C_POC =–20.5‰ (PDB) values were taken as the reference data for terrigenous and planktonogenic organic matter, respectively. Seasonal (early summer, late summer, and autumn) variations in the composition of suspended particulate matter in the active sea layer were revealed. A shift of δ¹³C_POC towards greater values was seen in autumn (with a slight outburst in the development (bloom) of phytoplankton) in comparison with summer (with large accumulations and an extraordinary phytoplankton bloom confined to the thermocline area). The seasonal dynamics of autochthonous and allochthonous components in the suspended particulate matter of the Middle and Southern Caspian Sea was studied with the use of data on the concentration of particulate matter and chlorophyll a, the phytoplankton biomass and the POC content.