Timing and preservation mechanism of deglacial pteropod spike from the Andaman Sea,northeastern Indian Ocean

The aragonite compensation depth (ACD) fluctuated considerably during the last glacial until the Holocene with a dominant pteropod preservation spike during the deglacial period, which is prominently seen in three well‐dated cores covering the Andaman Sea, northeastern Indian Ocean. The precise time period of the preservation spike of pteropods is not known but this knowledge is crucial for stratigraphical correlation and also for understanding the driving mechanism. Isotopic and foraminiferal proxies were used to decipher the possible mechanism for pteropods preservation in the Andaman Sea. The poor preservation/absence of pteropods during the Holocene in the Andaman Sea may have implications for ocean acidification, driven by enhanced atmospheric CO₂ concentration. Strengthening of the summer monsoon and the resultant high biological productivity may also have played a role in the poor preservation of pteropods. The deglacial pteropod spike is characterized by high abundance/preservation of the pteropods between ～19 and 15 cal. ka BP, associated with very low atmospheric CO₂ concentration. Isotope data suggest the prevalence of a glacial environment with reduced sea surface temperature, upwelling and enhanced salinity during the pteropod preservation spike. Total planktic foraminifera and Globigerina bulloides abundances are low during this period, implying a weakened summer monsoon and reduced foraminiferal productivity. Based on the preservation record of pteropods, it is inferred that the ACD was probably deepest (>2900 m) at 16.5 cal. ka BP. The synchronous regional occurrence of the pteropod preservation spike in the Andaman Sea and in the northwestern Indian Ocean could potentially be employed as a stratigraphic marker.     

Aragonite preservation in late Quaternary sediment cores on the Brazilian Continental Slope: implications for intermediate water circulation

We present late Quaternary records of aragonite preservation determined for sediment cores recovered on the Brazilian Continental Slope (1790–2585 m water depth) where North Atlantic Deep Water (NADW) dominates at present. We have used various indirect dissolution proxies (carbonate content, aragonite/calcite contents, and sand percentages) as well as gastropodal abundances and fragmentation of Limacina inflata to determine the state of aragonite preservation. In addition, microscopic investigations of the dissolution susceptibility of three Limacina species yielded the Limacina Dissolution Index which correlates well with most of the other proxies. Excellent preservation of aragonite was found in the Holocene section, whereas aragonite dissolution gradually increases downcore. This general pattern is attributed to an overall increase in aragonite corrosiveness of pore waters. Overprinted on this early diagenetic trend are high-frequency fluctuations of aragonite preservation, which may be related to climatically induced variations of intermediate water masses. Received: 9 November 1998 / Accepted: 25 August 1999     

Constraints on paleowater dissolved loads and on catchment weathering over the past 16 ka from Sr/Sr ratios and Ca/Mg/Sr chemistry of freshwater ostracode tests in sediments of Lake Constance, Central Europe

Sr isotope and Ca/Mg/Sr chemical compositions of freshwater ostracode tests separated from a sediment core represent the last 16 ka of sedimentation in Lake Constance, Central Europe. The chemical evolution of the paleowater's dissolved load of Lake Constance was estimated by correcting the ostracode data for Ca/Mg/Sr fractionation due to biogenic calcification. Since the Late Pleistocene deglaciation, the Ca/Sr molar ratios of paleowaters increased systematically from about 100 (a near marine signature) to about 200. Ca/Mg molar ratios varied in the range of 1–25. The ⁸⁷Sr/⁸⁶Sr ratios indicate Late Pleistocene paleowater compositions of 0.7086–0.7091, significantly more radiogenic than present day waters (0.7085). Sr isotopes and Ca/Mg/Sr chemical data together show that weathering of Mesozoic evaporites consistently dominated the dissolved Sr load (80–90%). Carbonate and silicate weathering were less important (1–10%). Trends of Sr dissolved loads were therefore not related to Mg which was mainly mobilized by carbonate weathering. Biotite weathering was an important source of radiogenic Sr in the paleowaters. The short-term release (duration about 600–800 years) of radiogenic Sr during glacier retreat started 15.2 ka ago and was due to enhanced biotite weathering at the glacier base. Long-term release of radiogenic Sr was due to biotite weathering in glacial soils and silicate rocks, and has gradually declined since the Late Pleistocene/Holocene transition.     

多元地球化学指标指示的32～9 ka B.P.罗布泊地区环境及其对全球变化的响应

对位于新疆罗布泊地区罗北洼地的CK-2钻孔柱样,自距顶0.94 m到10.35 m部分,以5 cm间距采样,6个样的质谱,铀系法年龄为32～9 ka B.P.,用仪器-化学分析法得到了样品中Na、K、Ca、Mg、Fe、cu、Hg、Zn、Mn、Sr、As、Pb、P、Cl和TOC共15种元素的含量.通过对元素含量变化和主成分序列分析,探讨了罗布泊地区在32～9 ka B.P.期间,经历的从末次盛冰期(阶段Ⅰ)、暖干期(阶段Ⅱ)、末次冰期晚期(阶段Ⅲ),到全新世早期(阶段Ⅳ)的不同程度冷湿与暖干的变化阶段.与格陵兰冰芯(GISP2)和深海沉积物氧同位素序列对比结果表明,罗布泊地区经历了MIS3晚期、MIS2和早M1S1早期.在罗布泊环境演化序列中也出现了发生在北大西洋冰漂碎屑的Heinrich事件(H3、H2和H1)和新仙女木(YD)事件,以及快速回暖的D/O事件(IS4、IS3、IS2和IS1).这表明高纬度的大气环流影响到中纬度西风带的强度、相位和位移,制约了我国西北干旱化地区气候环境变化的格局.为此,罗布泊地区的湖相沉积环境不仅记录了受到西风带、青藏高原隆升以及远离东亚和南亚季风影响所具有区域性的冷湿与暖干的水热配置特点,并且还具有全球变化的印迹.     

The impact of solution chemistry on Mytilus edulis calcite and aragonite

Magnesium/calcium, Sr/Ca, and Na/Ca atom ratios were determined in the calcite and aragonite regions of Mytilus edulis shells which were grown in semi-artificial ‘seawater’ solutions having varying Mg/Ca, Sr/Ca, and Na/Ca ratios. These ratios were measured by instrumental neutron activation, atomic absorption, and electron microprobe analytical techniques. Strontium/calcium ratios in both calcite and aragonite were linearly proportional to solution Sr/Ca ratios. Magnesium/calcium ratios in calcite increased exponentially when solution Mg/Ca ratios were raised above the normal seawater ratio; whereas in aragonite, Mg/Ca ratios increased linearly with increases in solution Mg/Ca ratios. Sodium/calcium and sulfur/calcium ratios in calcite covaried with Mg/Ga solution ratios. Conversely, in aragonite, Na/Ca ratios varied linearly with solution Na/Ca ratios.Magnesium is known to inhibit calcite precipitation at its normal seawater concentration. We infer from the results of the work reported here that Mytilus edulis controls the Mg activity of the outer extrapallial fluid, thus facilitating the precipitation of calcitic shell. Increases in sulfur content suggest that changes in shell organic matrix content occur as a result of environmental stress. Certain increases in Mg content may also be correlated to stress. Sodium/calcium variations, and their absolute amounts in calcite and aragonite, are best explained by assuming that a substantial amount of Na is adsorbed on the calcium carbonate crystal surface. Strontium/calcium ratios show more promise than either Mg/Ca or Na/Ca ratios as seawater paleochemistry indicators, because the Sr/Ca distribution coefficients for both aragonite and calcite are independent of seawater Ca and Sr concentrations.     

Diagenesis and its impact on Sr/Ca ratio in Holocene Acropora corals

The effect of early diagenesis on Sr/Ca ratios encapsulated in coral skeletons was evaluated by comparing mineralogical, structural and geochemical characteristics of modern and Holocene, branching Acropora colonies. The modern specimens (Acropora danai, Acropora formosa) come from Réunion island (Western Indian Ocean) and the Great Barrier Reef of Australia respectively. The Sr/Ca ratios of modern specimens range from 9.08 to 9.37 mmol/mol. The fossil acroporids (Acropora group danai-robusta) were collected from a 50-m core drilled through a barrier reef in Tahiti island; their C-14 ages range from 3,200 to 10,200 calendar years B.P. Fossil skeletons are 100% aragonite. Earlier diagenesis has occurred in the marine environment; it is expressed by growth of secondary inorganic aragonite over primary skeletal aragonite needles, development of syntaxial aragonite cements within intraskeletal cavities and decrease in size of original 1-1,050-µm-wide pores (residual porosity ranges from 25 to 28%), which results in a volume reduction by 34 to 49%. Cementation increases with increasing age of the corals. Later diagenesis has occurred in a mixed marine-freshwater environment. It includes partial dissolution of skeletal and growth of cement aragonite fibres in the form of spherolites, irregular meshes of large squarely terminated laths; this results in an increase in porosity from 30 to 59%. By reference to modern well-preserved acroporids, this diagenetic alteration has led to an increase of Sr/Ca values (from 9.08-9.37 to 8.89-10.55 mmol/mol). This variation in Sr/Ca ratio can be linked to the increase in the amount of Sr-enriched cements relative to the volume of the skeletal aragonite and to a more homogeneous distribution of these cements throughout the skeleton. The uncritical use of Sr/Ca ratios as paleothermometers from diagenetically altered skeletons may cause serious misinterpretations. Accordingly, estimate of the degree of diagenetic alteration in skeletons is a prerequisite to any paleoclimatic reconstruction based on coral records.     

洞穴次生碳酸盐沉积的Mg/Ca与Sr/Ca比值研究进展——兼论洞穴次生沉积物Mg/Ca与Sr/Ca的影响机制

微量元素是岩溶洞穴沉积中非常重要的一类古气候环境替代指标,为近20年来国内外的一个研究热点。总结前人的研究,主要取得了以下一些重要认识:（1）洞穴上覆土壤 和围岩是洞穴次生碳酸盐沉积Mg、Sr的主要来源;（2）Mg/Ca与Sr/Ca能够指示气候环境变化,但需结合其它指标综合考虑。（3）洞穴次生碳酸盐沉积Mg/Ca与Sr/Ca受多种气候环境因素（包括土壤和围岩的组成和性质、水-岩相互作用、先期碳酸盐沉积、分配系数等）影响,其古气候环境指示意义具有多解性;（4）矿物结晶作用对Mg/Ca与Sr/Ca有一定的影响,特别是文石在向方解石转变的过程中容易丢失Mg、Sr,此外,杂质的混入也将抑制Mg、Sr进入方解石,从而引起洞穴次生碳酸盐沉积Mg/Ca与Sr/Ca比值的变化。今后应进一步加强对石笋中这些微量元素的影响机制研究,尤其是对一些影响因素与微量元素含量变化之间的定量关系进行探讨。      

黄土高原南部全新世黄土-古土壤 序列若干元素分布特征及意义*

选择黄土高原南部的XJN,XMC和JYC全新世剖面为研究对象。通过对地层中Ca,Ba,Rb和Sr元素分布的研究,发现Ba/Sr和Rb/Sr比值在不同地层中含量差异十分明显,并与成土作用强度显著正相关,可作为良好的气候替代指标;表生环境中Rb和Ba较稳定,Sr和Ca元素十分活跃,易于迁移,其中Ca的迁移能力高于Sr元素;从XJN→XMC→JYC剖面,Rb和Ba元素含量增加,而Sr和Ca元素含量降低,这与区域环境差异有关;全新世中期暖湿的亚热带气候主要出现关中盆地地区,六盘山以西则是暖温带气候。     

Strontium heterogeneity and speciation in coral aragonite: implications for the strontium paleothermometer

Sea surface temperatures (SSTs) have been inferred previously from the Sr/Ca ratios of coral aragonite. However, microanalytical studies have indicated that Sr in some coral skeletons is more heterogeneously distributed than expected from SST data. Strontium may exist in two skeletal phases, as Sr substituted for Ca in aragonite and as separate SrCO₃ (strontianite) domains. Variations in the size, quantity, or both of these domains may account for small-scale Sr heterogeneity. Here, we use synchrotron X-ray fluorescence to map Sr/Ca variations in a Porites lobata skeleton at a 5 μm scale. Variations are large and unrelated to changes in local seawater temperature or composition. Selected area extended X-ray absorption fine structure (EXAFS) spectroscopy of low- and high-Sr areas indicates that Sr is present as a substitute ion in aragonite i.e., domains of Sr carbonate (strontianite) are absent or in minor abundance. Variations in strontianite abundance are not responsible for the Sr/Ca fluctuations observed in this sample. The Sr microdistribution is systematic and appears to correlate with the crystalline fabric of the coral skeleton, suggesting Sr heterogeneity may reflect nonequilibrium calcification processes. Nonequilibrium incorporation of Sr complicates the interpretation of Sr/Ca ratios in terms of SST, particularly in attempts to extend the temporal resolution of the technique. The micro-EXAFS technique may prove to be valuable, allowing the selection of coral microvolumes for Sr/Ca measurement where strontium is incorporated in a known structural environment.     

Climatic change recorded by stable isotopes and trace elements in a British Holocene tufa

Combined stable isotope (δ¹⁸O and δ¹³C) and trace element (Mg, Sr) geochemistry from bulk tufa calcite and ostracod shell calcite from an early Holocene British tufa reveal clear records of Holocene palaeoclimatic change. Variation in δ¹⁸O is caused principally by change in the isotopic composition of Holocene rainfall (recharge), itself caused mainly by change in air temperature. The δ¹³C variability through much of the deposit reflects increasing influence of soil‐zone CO₂, owing to progressive woodland soil development. Bulk tufa Mg/Ca and Sr/Ca are controlled by their concentrations in the spring water. Importantly, Mg/Ca ratios are not related to δ¹⁸O values and thus show no temperature dependence. First‐order sympathetic relationships between δ¹³C values and Mg/Ca and Sr/Ca are controlled by aquifer processes (residence times, CO₂ degassing and calcite dissolution/reprecipitation) and probably record intensity of palaeorainfall (recharge) effects. Stable isotope records from ostracod shells show evidence of vital effects relative to bulk tufa data. The ostracod isotopic records are markedly ‘spiky’ because the ostracods record ‘snapshots’ of relatively short duration (years), whereas the bulk tufa samples record averages of longer time periods, probably decades. The δ¹⁸O record appears to show early Holocene warming, a thermal maximum at ca. 8900 cal. yr BP and the global 8200 yr BP cold event. Combined δ¹³C, Mg/Ca and Sr/Ca data suggest that early Holocene warming was accompanied by decreasing rainfall intensity. The Mg/Ca data suggest that the 8200 yr BP cold event was also dry. Warmer and wetter conditions were re‐established after the 8200 yr BP cold event until the top of the preserved tufa sequence at ca. 7100 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

鲕粒原生矿物识别及对海水化学成分变化的指示意义

鲕粒是碳酸盐沉积过程中一类非常特殊的颗粒类型, 为研究当时的沉积背景、水动力条件、气候环境, 甚至储层特征提供了重要线索。然而, 鲕粒的矿物组成及控制因素问题, 长期受到忽视。组成鲕粒的原生矿物类型在地质历史时期呈周期性变化, 在显生宙表现为三个以文石和高镁方解石占主导的时期以及两个以低镁方解石占主导的时期, 这也被称作“文石海”和“方解石海”时期。原生矿物的组成, 制约着鲕粒的纹层结构、保存程度以及成岩特征, 还蕴含着海水化学成分变化的线索。鲕粒原生矿物识别主要依据:①原生纹层结构;②保存程度;③微量元素浓度, 尤其是Sr-Mg的浓度。文石质鲕粒受文石不稳定性的影响, 原生结构保存程度较差;一般保存有典型的文石残余纹层结构(例如砖砌结构、溶解变形结构以及偏心结构等);在封闭成岩环境下原生矿物为文石质的鲕粒Sr浓度往往大于2 000 ppm;纹层结构主要为切线状(占主导)和放射状。方解石质鲕粒包括低镁方解石和高镁方解石两种类型:低镁方解石为稳定矿物, 原生结构一般保存良好。尽管高镁方解石也为亚稳定矿物, 但成岩转换后的保存程度好于文石。两者Sr含量一般均低于1 000 ppm, Mg含量一般在0~20 mol % MgCO₃(两者以4 mol % MgCO₃为界)。高镁方解石受成岩作用影响, 在纹层中往往保留有微粒白云石包裹体;海相地层中保存的方解石质鲕粒为放射状或同心-放射状结构。另外还存在一类由两种矿物共同构成的双矿物鲕粒, 可以通过分析两类纹层在结构和保存特征上的差异进行区分。鲕粒原生矿物成分随时间的波动变化受到海水化学条件, 尤其是Mg/Ca比值, 大气二氧化碳分压以及碳酸盐饱和度的控制。Mg/Ca比值的波动决定着鲕粒原生矿物类型的长期变化规律。一些突发性事件可能会扰动(区域)短时间尺度下鲕粒原生矿物的组成, 造成鲕粒原生矿物的转换。通过研究碳酸盐鲕粒原生矿物特征以及控制因素进而了解海水的化学特征, 是独立于古生物学和地球化学分析之外的一种较为可靠的沉积学方法。     

Major-ion chemistry, ��13C and 87Sr/86Sr as indicators of hydrochemical evolution and sources of salinity in groundwater in the Yuncheng Basin, China

Processes controlling hydrogeochemistry in the Yuncheng Basin, China, were characterised using major-ion chemistry, ⁸⁷Sr/⁸⁶Sr ratios and ??¹³C values. Evapotranspiration during recharge increased solute concentrations by factors of ??5?C50 in deep palaeowaters, while higher degrees of evapotranspiration have occurred in shallow, modern groundwater. Aquifer sediments (loess) contain approximately 15 weight% calcite; trends in groundwater HCO₃ concentrations and ??¹³C values (ranging from ?16.4 to ?8.2??) indicate that carbonate weathering is a significant source of DIC. Groundwater ⁸⁷Sr/⁸⁶Sr ratios (0.7110?C0.7162, median of 0.7116) are similar to those in both loess carbonate (0.7109?C0.7116) and local rainfall (0.7112), and are significantly lower than Sr in aquifer silicates (0.7184?C0.7251). Despite evidence for substantial carbonate dissolution, groundwater is generally Ca-poor (<?10% of total cations) and Na-rich, due to cation exchange. Saturation with respect to carbonate minerals occurs during or soon after recharge (all calcite and dolomite saturation indices are positive). Subsequent carbonate dissolution in the deep aquifer must occur as a second-stage process, in response to Ca loss (by ion exchange) and/or via incongruent dissolution of dolomite and impure calcite. The latter is consistent with positive correlations between ??¹³C values and Mg/Ca and Sr/Ca ratios (r ²?=?0.32 and 0.34).     

Variations in chemical element compositions in different types of Holocene calcareous root tubes in the Tengger Desert,NW China,and their palaeoenvironmental significance

Calcareous root tubes (CRTs) contain abundant information about palaeoenvironmental conditions and have been used for palaeoenvironmental studies in the desert hinterlands of arid regions. However, as subclasses of CRTs, calcareous sheaths and rhizocretions are formed by different processes, and it remains unclear whether these differences produce variations in the chemical element composition. Furthermore, it remains uncertain whether variations in chemical element concentrations amongst different subclasses of the CRTs can affect palaeoenvironmental reconstructions. In this study, we collected 54 CRT samples from the Tengger Desert of northwestern China. All samples were dated by accelerator mass spectrometry (AMS) ¹⁴C dating, and the chemical element composition and concentration differences of the two CRT subclasses were determined using X‐ray fluorescence spectrometry. The CRT samples were dated to the Holocene. The calcareous sheath and rhizocretion samples contained varying concentrations of the same chemical elements. The rhizocretions had high concentrations of mobile elements (Ca, Mg and Sr) and P, whereas the calcareous sheaths had high concentrations of stable elements, including Al, Si, Ti, Zr, Rb and Ba. These differences were due to the different formation processes of the two subclasses of CRTs. Moreover, the Sr/Ca and Mg/Ca ratios in the calcareous sheaths were higher than those in the rhizocretions from the same period, but these ratio differences had little effect on palaeo‐effective moisture reconstructions at the millennial scale during the Holocene. The reconstructions were not influenced by the various CRT subclasses. The Holocene millennial‐scale moisture changes in the Tengger Desert revealed by the Sr/Ca and Mg/Ca ratios showed that there was an arid period during the Early Holocene, a humid period during the Middle Holocene and a humid to arid period during the Late Holocene.     

Laser ablation ICP-MS screening of corals for diagenetically affected areas applied to Tahiti corals from the last deglaciation

Fossil corals are unique archives of past seasonal climate variability, providing vital information about seasonal climate phenomena such as ENSO and monsoons. However, submarine diagenetic processes can potentially obscure the original climate signals and lead to false interpretations. Here we demonstrate the potential of laser ablation ICP-MS to rapidly detect secondary aragonite precipitates in fossil Porites colonies recovered by Integrated Ocean Drilling Program (IODP) Expedition 310 from submerged deglacial reefs off Tahiti. High resolution (100 μm) measurements of coralline B/Ca, Mg/Ca, S/Ca, and U/Ca ratios are used to distinguish areas of pristine skeleton from those afflicted with secondary aragonite. Measurements of coralline Sr/Ca, U/Ca and oxygen isotope ratios, from areas identified as pristine, reveal that the seasonal range of sea surface temperature in the tropical south Pacific during the last deglaciation (14.7 and 11 ka) was similar to that of today.     

Palaeohydrological significance of late Quaternary strontium isotope ratios in a tropical lake

Ostracods preserved in late Quaternary sediments of Wallywash Great Pond, a fresh coastal lake in SW Jamaica, record temporal variations in the strontium-isotope composition of lake water. Oxygen-isotope and Sr/Ca ratios in ostracods reveal temporal variations in the lake's hydrology, related to effective precipitation, and in its salinity related to varying marine-saline groundwater input from changes in relative sea level. Evaluation of isotopic and trace-element data indicates that the stratigraphic variations in ⁸⁷Sr/⁸⁶Sr ratios during the late Quaternary are best explained by climatically-controlled hydrological changes. During wetter periods, the lake's Sr budget was dominated by springwater input with relatively low ⁸⁷Sr/⁸⁶Sr ratio, whereas during drier times reduced springflow, possibly coupled with input of more-radiogenic Sr from other sources, such as sea-spray aerosols and perhaps Saharan dust, led to an increase in the Sr-isotope ratio of the lake water. Despite proximity of the lake to the sea and evidence for slight intrusion of marine saline groundwater in the past, however, the extent of marine input appears to have had limited influence on the lake's Sr-isotope ratios. Whereas the ⁸⁷Sr/⁸⁶Sr ratios cannot be used as a palaeosalinity proxy in this particular lake, they do provide valuable information about the mechanisms underlying hydrological change.     

Effect of orthophosphate on the dissolution kinetics of biogenic magnesian calcites

The dissolution behavior of two biogenic Mg-calcites, the echinoid, Tripneustes (12 mol% MgCO₃), and the red alga, Neogoniolithon (18 mol% MgCO₃ plus brucite), was studied using free-drift methods in distilled water and phosphate-spiked solutions at 25°C and P_CO2 = 1 atm. Small concentrations of phosphate strongly inhibit dissolution rates. Inhibition increases with increased phosphate levels and with approach toward saturation. Near saturation, dissolution rates are reduced by 10³ by the presence of 0.6 μmol adsorbed-P/m². The magnitude of phosphate inhibition is similar to that observed for low-Mg calcite, and like calcite, the mechanism of inhibition is probably by adsorption of P at surface kink sites. Phosphate appears to inhibit removal of Mg and Ca equally during Mg-calcite dissolution. Rates of brucite dissolution are unaffected by phosphate.Mg-calcites containing >8.5 mol% MgCO₃ should be thermodynamically unstable relative to aragonite in most natural waters. Recent work, however, shows that in contrast to its effect on the behavior of Mg-calcites. phosphate does not inhibit aragonite dissolution. The presence of phosphate might thus reverse the relative stability of these two minerals during diagenesis of shallow marine carbonate sediments.     

Ca/Sr and Sr isotope systematics of a Himalayan glacial chronosequence: carbonate versus silicate weathering rates as a function of landscape surface age

We explored changes in the relative importance of carbonate vs. silicate weathering as a function of landscape surface age by examining the Ca/Sr and Sr isotope systematics of a glacial soil chronosequence located in the Raikhot watershed within the Himalaya of northern Pakistan. Bedrock in the Raikhot watershed primarily consists of silicate rock (Ca/Sr ≈ 0.20 μmol/nmol, ⁸⁷Sr/⁸⁶Sr ≈ 0.77 to 1.2) with minor amounts of disseminated calcite (Ca/Sr ≈ 0.98 to 5.3 μmol/nmol, ⁸⁷Sr/⁸⁶Sr ≈ 0.79 to 0.93) and metasedimentary carbonate (Ca/Sr ≈ 1.0 to 2.8 μmol/nmol, ⁸⁷Sr/⁸⁶Sr ≈ 0.72 to 0.82). Analysis of the exchangeable, carbonate, and silicate fractions of seven soil profiles ranging in age from ∼0.5 to ∼55 kyr revealed that carbonate dissolution provides more than ∼90% of the weathering-derived Ca and Sr for at least 55 kyr after the exposure of rock surfaces, even though carbonate represents only ∼1.0 wt% of fresh glacial till. The accumulation of carbonate-bearing dust deposited on the surfaces of older landforms partly sustains the longevity of the carbonate weathering flux. As the average landscape surface age in the Raikhot watershed increases, the Ca/Sr and ⁸⁷Sr/⁸⁶Sr ratios released by carbonate weathering decrease from ∼3.6 to ∼0.20 μmol/nmol and ∼0.84 to ∼0.72, respectively. The transition from high to low Ca/Sr ratios during weathering appears to reflect the greater solubility of high Ca/Sr ratio carbonate relative to low Ca/Sr ratio carbonate. These findings suggest that carbonate weathering controls the dissolved flux of Sr emanating from stable Himalayan landforms comprising mixed silicate and carbonate rock for tens of thousands of years after the mechanical exposure of rock surfaces to the weathering environment.     

Late Quaternary changes in surface productivity and oxygen minimum zone (OMZ) in the northwestern Arabian Sea: Micropaleontologic and sedimentary record at ODP site 728A

Changes in the abundance of selected planktic foraminiferal species and some sedimentological parameters at ODP site 728A were examined to understand the fluctuations in the surface productivity and deep sea oxygenation in the NW Arabian Sea during last ∼540 kyr. The increased relative abundances of high fertility taxa, i.e., Globigerinita glutinata and Globigerina bulloides mainly during interglacial intervals indicate intense upwelling. Strong SW summer monsoon probably increased the upwelling in the western Arabian Sea during interglacial intervals and caused high surface productivities due to the lateral transport of eutrophic waters. Most of the glacial periods (i.e., MIS 2, 4, 6, 8 and 12) are characterized by higher relative abundances of Neogloboquadrina pachyderma and Neogloboquadrina dutertrei associated with Globigerinoides ruber. The more stratified condition and deep mixed layer due to increased NE winter monsoon are mainly responsible for the higher relative abundances of N. pachyderma during glacial periods. Some of the glacial intervals (i.e., MIS 6 and 8) are also characterized by pteropod spikes reflecting deepening of aragonite compensation depth (ACD) and relatively less intense oxygen minimum zone (OMZ) in this region due to deep sea mixing and thermocline ventilation, and relatively less intense surface productivity during winter monsoon. The interglacial periods are largely devoid of pteropod shells indicating more aragonite dissolution due to increased intensity of OMZ in the northwestern Arabian Sea.     

Marine glacial and interglacial stratigraphy in Vendsyssel, northern Denmark: foraminifera and stable isotopes

The marine Quaternary of Vendsyssel has been studied in a series of new boreholes in the area, and the climatic development is discussed on the basis of foraminiferal assemblages and stable isotopes. The foraminiferal zones are correlated with previously published records from northern Denmark, and the spatial local and regional distribution is discussed in details based on the new evidence. The new data show that the marine sedimentation in Vendsyssel was not continuous from the Late Saalian to the Middle Weichselian, as previously thought. For example, there is indication of a hiatus at our key site, Åsted Vest in the central part of Vendsyssel, at the transition between regional foraminiferal zones N4 and N3, i.e. at the Late Saalian (MIS 6) – Eemian (MIS 5e) transition. The hitherto most complete Early Weichselian succession (zone N2) in Vendsyssel is presented from Åsted Vest. Deposits from the Early Weichselian sea‐level lowstands (MIS 5d and 5b) may, however, be missing in parts of the area. Two major breaks in the marine deposition during the Middle Weichselian represent glacial advances into northern Denmark. The first event occurred just after deposition of the regional foraminiferal zone N2 (late MIS 4), and the second event in the middle part of zone N1 (early MIS 3). Zone N1 is succeeded by a series of non‐marine units deposited during the sea‐level lowstand of the Weichselian maximum glaciation (late MIS 3 and MIS 2), including deeply incised tunnel valleys, which have been refilled with non‐marine sediments during the Late Weichselian. Vendsyssel was inundated by the sea again during the Late Weichselian, at c. 18 kyr BP. Subsequently, the marine conditions were gradually changed by forced regression caused by local isostatic uplift, and around the Weichselian–Holocene transition most of Vendsyssel was above sea level. A continuous deposition across the Late Weichselian–Holocene boundary only occurred at relatively deep sites such as Skagen. The environmental and climatic indications for Vendsyssel are in accordance with the global sea‐level curve, and the Quaternary record is correlated with the oxygen isotope record from the NorthGRIP ice core, as well as the marine isotope stages.     

白令海北部陆坡100ka来的古海洋学记录及海冰的扩张历史

白令海北部陆坡B2-9柱状样中生源组分的研究显示, 自MIS5.3期以来表层生产力指标的粗组分和蛋白石含量呈阶梯状增加, 反映表层生产力阶段式的增长.全新世表层生产力达到最高, 并且MIS3.2~2期高, 比MIS5.3~3.3期最低.高有机碳含量对应于高C/N比值, 显示有机碳混合来源, 不能作为表层生产力的指标.MIS5.1, 3.3~3.2期和全新世高的有机碳含量和C/N比值反映间冰期陆源有机物质输入量的增加.MIS5.3期至中全新世, 不断增加的陆源砂级和粉砂级颗粒组分说明随着气候的逐渐变冷, 陆架海冰在不断扩张.伐冰碎屑和碳屑颗粒冰期、间冰段和末次冰消期升高, 而间冰期降低, 反映冰期白令海陆架海冰扩张和间冰期海冰消融的过程.冰期海冰扩张与北美大陆气候的相互关联, 揭示了晚第四纪冰期旋回中白令海海冰扩张及其对全球气候变化的响应.