利用海表盐度等遥感观测产品重构三维盐度场的性能评估

Several remotely sensed sea surface salinity(SSS) retrievals with various resolutions from the soil moisture and ocean salinity(SMOS) and Aquarius/SAC-D missions are applied as inputs for retrieving salinity profiles(S) using multilinear regressions. The performance is evaluated using a total root mean square(RMS) error, different error sources, and the feature resolutions of the retrieved S fields. In the mixed layer of the salinity, the SSS-S regression coefficients are uniformly large. The SSS inputs yield smaller RMS errors in the retrieved S with respect to Argo profiles as their spatial or temporal resolution decreases. The projected SSS errors are dominant, and the retrieved S values are more accurate than those of climatology in the tropics except for the tropical Atlantic, where the regression errors are abnormally large. Below that level, because of the influence of a sea level anomaly, the areas of high-accuracy S values shift to higher latitudes except in the high-latitude southern oceans, where the projected SSS errors are abnormally large. A spectral analysis suggests that the CATDS-0.25° results are much noisier and that the BEC-L4-0.25° results are much smoother than those of the other retrievals. Aquarius-CAP-1° generates the smallest RMS errors, and Aquarius-V2-1° performs well in depicting large-scale phenomena. BEC-L3-0.25°,which has small RMS errors and remarkable mesoscale energy, is the best fit for portraying mesoscale features in the SSS and retrieved S fields. The current priority for retrieving S is to improve the reliability of satellite SSS especially at middle and high latitudes, by developing advanced algorithms, combining both sensors, or weighing between accuracy and resolutions.     

Underwater measurements of carbon dioxide evolution in marine plant communities: A new method

We developed a new methodology to determine CO₂ fluxes in intertidal and shallow subtidal plant communities, namely seagrasses, both when the plants are submerged and when they are air-exposed. The apparatus comprises closed incubation chambers and a gas exchange column, designed to remove carbon dioxide from the water. Different types of incubation chambers were designed and built to adapt the system to distinct environments and incubation requirements. The methodology was tested under a comprehensive range of situations and its advantages and limitations are discussed. Overall, the method provides precise measurements of community carbon dioxide fluxes, through a fast and non-intrusive process, allowing repeatable in situ measurements of carbon uptake both in submerged and air-exposed conditions. As the experimental apparatus is identical, directly comparable measurements of air-exposed and submerged community production may be obtained, allowing sound estimates of daily carbon budgets of intertidal and shallow subtidal communities.     

一种计算有限水深波能功率的新方法

海洋波浪能平均功率的准确计算是波浪能开发和利用的基础。实践中,波浪能转换装置一般安装在有限水深区域。对于随机波,只有当详尽的波浪谱已知的时候,有限水深区的波能功率才能被准确计算出来。由于种种原因,实践中波浪的实测数据大多以散点图或有义波高和统计波周期的形式给出,而波浪谱信息有时则很难获得。基于这种情况,传统上人们利用无限水深条件下的相关公式来估算有限水深区域的波能功率,但这种做法会造成较大的误差。本研究显示,对于50 m水深的理论波谱JONSWAP谱来说该误差高达14.6%。为了提高波能功率计算的准确性,本文提出了一种基于能量频率的一阶和二阶近似算法,可以在未知波浪谱的情况下较为准确地计算不同水深时的波能功率。针对两种理论波浪谱的计算结果表明,本方法在计算有限带宽内的波能功率时计算误差低于2.8%。     

A two-channel method for retrieval of the Black Sea surface temperature from Landsat-8 measurements

Izvestiya, Atmospheric and Oceanic Physics - The present work is devoted to the development of a retrieval algorithm for the sea surface temperature from the two-channel measurements of the...     

A new fluorometric method of analysis of selenium in sea water

A new method of determination of selenium and separation of Se(IV) and Se(VI) in sea water is described. The selenium is determined by fluorometric method using Se-DAN complex in cyclohexane media. Prior to the fluorometric determination, Se(IV) is separated from sea water by means of Se(IV)-DDTC complex which is adsorbed on the macroreticular resin. As to the separation of the total selenium from sea water sample, the reduction and coprecipitation method is used. Se(VI) is determined with the same method as used for the total selenium after the separation of Se(IV). The average recoveries are 92.5±1.3% for Se(IV) and 97.4±0.9% for Se. The standard deviation of analytical results is below 10%.     

Net biological oxygen production in the ocean—II: Remote in situ measurements of O2 and N2 in subarctic pacific surface waters

Net community biological production in the euphotic zone of the ocean fuels organic matter and oxygen export from the upper ocean, which has a large influence on the atmospheric pressure of carbon dioxide and is the driving force for metabolite distributions in the sea. We determine the net annual biological oxygen production in the mixed layer of the northeast subarctic Pacific Ocean from in situ O₂ and N₂ measurements. Temperature, salinity, total gas pressure and O₂ were measured every 3 h for 9 months in 2007 at about 3 m depth on a surface mooring at Station P (50°N, 145°W). The concentration of nitrogen gas, N₂, determined from separate total gas pressure and pO₂ measurements, was used as an inert tracer of the physical processes that induce gas departure from thermodynamic equilibrium with the atmosphere. We use a simple model of the ocean’s mixed layer along with the nitrogen concentration to constrain the importance of bubbles, gas exchange and horizontal advection, which are then used in the oxygen mass balance to derive net biological oxygen production. The mixed-layer oxygen mass balance is dominated by exchange with the atmosphere, and we determine a mean summertime oxygen production of 24 mmol O₂ m^?2 d^?1. The annual pattern in the difference between the supersaturation of oxygen and nitrogen in the surface waters reveals very little net oxygen production during the winter at this location. The calculated annual net community production (NCP) of carbon from this new method, 2.5 mol m^?2 yr^?1, agrees to within its error of about×40% with previous determinations at this location from oxygen mass balance, NO₃^? draw down and ²³⁴Th measurements. This value is either indistinguishable from or lower than annual NCP measurements in the subtropical North Pacific, indicating that there is no experimental evidence for differences in annual NCP between the subarctic and subtropical North Pacific Ocean.     

多波束水体数据对台西南盆地天然气水合物的揭示

在台西南盆地陆坡上进行了多波束测量,获取了海底地形数据和水体数据。对多波束数据进行处理,展示了多波束水体数据形成的声学水柱影像。研究表明：在台西南盆地天然气水合物富集区,多波束水柱影像异常,呈现羽状流特点,揭示了台西南盆地的天然气资源,多波束声呐系统为探测海底天然气水合物提供了精确高效的方法。     

A new method of combination of electroosmosis,vacuum and surcharge preloading for soft ground improvement

As a rapid and effective ground improvement method is urgently required for the booming land reclamation in China＇s coastal area, this study proposes a new combined method of electroosmosis, vacuum preloading and surcharge preloading. A new type of electrical prefabricated vertical drain （ePVD） and a new electroosmotic drainage system are suggested to allow the application of the new method. This combined method is then field-tested and compared with the conventional vacuum combined with surcharge preloading method. The monitoring and foundation test results show that the new method induces a settlement 20% larger than that of the conventional vacuum combined with surcharge preloading method in the same treatment period, and saves approximately half of the treatment time compared with the vacuum combined with surcharge preloading method according to the finite element prediction of the settlement. The proposed method also increases the vane shear strength of the soil significantly. The bearing capacity of the ground improved by use of the new proposed method raises 118%. In comparison, there is only a 75% rise when using the vacuum combined with surcharge preloading method during the same reinforcement period. All results indicate that the proposed combined method is effective and suitable for reinforcing the soft clay ground. Besides, the voltage applied between the anode and cathode increases exponentially versus treatment time when the output current of power supplies is kept constant. Most of the voltage potential in electroosmosis is lost at electrodes, leaving smaller than 50% of the voltage to be effectively transmitted into the soil.     

A new expression for the production rate of sea water droplets on the sea surface

A new set of empirical formulas for the production rate and the number concentration of sea-water droplets on the sea surface are proposed, synthesizing past observation data of sea-salt particles in the sea and water droplets in wind-wave tanks. A new levelz _c is introduced as the effective wind-sea surface where seawater droplets are produced. The new formulas are expressed in linear functions in logarithmic scales ofu*²/v _p , a parameter to describe overall conditions of airsea boundary processes, whereu _* is the friction velocity of air,v the kinematic viscosity of air and _p the peak angular frequency of wind-wave part of wave spectra. A model of coexistence of spray droplets and suspended particles near the sea surface is proposed. As for the independent parameter, a comparison between the uses ofu*²/v _p and ofu _* ³ which was the traditional way of parameterization excluding wave measure, shows that the advantage of usingu*²/v _p is statistically significant with a confidence limit 89% in F-test.     

On observing underwater objects through a wavy water surface: A new algorithm for image correction and laboratory experiment

The possibility of correcting refraction distortions in images of the sea bottom or an underwater object observed through a wavy water surface is studied. A fast-operating algorithm of recovering the “regular” image by its random realization and spatial distribution of surface slopes at the instant of observation has been proposed and approbated. A technique of determining surface slopes by the surface image with the following correction of the underwater object image based on the data about the surface slopes has been developed under conditions of a laboratory experiment.     

Determination of copper complexation with natural organic ligands in seawater by equilibration with MnO2 II. Experimental procedures and application to surface seawater

The MnO₂ adsorption method combined with voltammetry is proposed for the direct determination of metal complexation in seawater of various salinities as a more satisfactory alternative to direct voltammetric measurements and bioassay methods. A small quantity of MnO₂ is equilibrated with copper ions in filtered seawater. Natural organic ligands in the seawater compete for copper with the MnO₂. Total dissolved copper is measured by differential pulse anodic stripping voltammetry after filtration and acidification of the sample. Preconcentration of natural water samples is unnecessary and measurement is performed at the natural equilibrium pH of the aerated sample. The analytical limit of detection of the method depends on contamination from the filtration step, and for copper complexation a ligand concentration of 5 × 10^?8 M was obtained. The sensitivity can be increased by use of radioisotopes as tracers. The method is very versatile in that complexation of various metals may be determined by any analytical method that measures total dissolved metal concentrations. Neither organic ligands nor their complexes with copper adsorb on the MnO₂ at pH8, but at pH 1.8 MnO₂ is an efficient scavenger for electroactive organic material.Samples of surface water from the Irish Sea and the Atlantic Ocean were found to contain ligand concentrations of 1.7 × 10^?7 and 1.1 × 10^?7 M, with conditional stability constants (log values) of 9.84 ± 0.13 and 9.86 ± 0.23, respectively, at pH 8.0.     

Impact of high water pressure on oil generation and maturation in Kimmeridge Clay and Monterey source rocks: Implications for petroleum retention and gas generation in shale gas systems

This study presents results for pyrolysis experiments conducted on immature Type II and IIs source rocks (Kimmeridge Clay, Dorset UK, and Monterey shale, California, USA respectively) to investigate the impact of high water pressure on source rock maturation and petroleum (oil and gas) generation. Using a 25 ml Hastalloy vessel, the source rocks were pyrolysed at low (180 and 245 bar) and high (500, 700 and 900 bar) water pressure hydrous conditions at 350 °C and 380 °C for between 6 and 24 h. For the Kimmeridge Clay (KCF) at 350 °C, Rock Eval HI of the pyrolysed rock residues were 30–44 mg/g higher between 6 h and 12 h at 900 bar than at 180 bar. Also at 350 °C for 24 h the gas, expelled oil, and vitrinite reflectance (VR) were all reduced by 46%, 61%, and 0.25% Ro respectively at 900 bar compared with 180 bar. At 380 °C the retardation effect of pressure on the KCF was less significant for gas generation. However, oil yield and VR were reduced by 47% and 0.3% Ro respectively, and Rock Eval HI was also higher by 28 mg/g at 900 bar compared with 245 bar at 12 h. The huge decrease in gas and oil yields and the VR observed with an increase in water pressure at 350 °C for 24 h and 380 °C for 12 h (maximum oil generation) were also observed for all other times and temperatures investigated for the KCF and the Monterey shale. This shows that high water pressure significantly retards petroleum generation and source rock maturation. The retardation of oil generation and expulsion resulted in significant amounts of bitumen and oil being retained in the rocks pyrolysed at high pressures, suggesting that pressure is a possible mechanism for retaining petroleum (bitumen and oil) in source rocks. This retention of petroleum within the rock provides a mechanism for oil-prone source rocks to become potential shale gas reservoirs. The implications from this study are that in geological basins, pressure, temperature and time will all exert significant control on the extent of petroleum generation and source rock maturation for Type II source rocks, and that the petroleum retained in the rocks at high pressures may explain in part why oil-prone source rocks contain the most prolific shale gas resources.     

A method for detecting the breaking of wind-generated waves in deep water

The breaking of wind-generated waves is an important phenomenon in the ocean, having close relation to many aspects of the ocean, such as air-sea interaction, ocean wave dynamics, oceanic remote sensing and ocean engineering. The first problem encountered in both its theoretical study and practical measurement is how to detect the breaking of waves.     

A new method to estimate phase speed and vertical velocity of internal solitary waves in the South China Sea

A new method of estimating the phase speed and vertical velocity of internal solitary waves (ISW) based on dynamic governing equations using Acoustic Doppler Current Profiler (ADCP) data was developed. This method was applied to a representative ISW case, which was captured in the South China Sea in the 2007 summer experiment. The result shows that this ISW had a phase speed of approximately 2.6?m?s^?1. This method provides an excellent alternative in estimating the phase speed of ISWs, especially useful in the absence of vertical stratification needed in solving the Korteweg–de Vries (KdV)-type equation, e.g., long-term mooring observation. Analyses show that the new method is fairly self-consistent, and it can be applied when only a part of the ISW observations is available. The computed vertical velocity of the ISW using the new method has a good agreement with the ADCP observations both in magnitude and pattern.     

Distribution of gamma-ray radionuclides in surface sediments of the KongsQorden,Arctic: Implications for sediment provenance

The Kongsfjorden is highly sensitive region to climate variability,however,the study of gamma-ray radionuclides in related areas is relatively scarce.In this study,the grain size,total organic carbon(TOC),13 Corg isotopes,and specific activities of seven gamma nuclides were analysed in surface sediments of the Kongsfjorden in the Arctic during the summer of 2017.The specific activities of 210 Pb_ex,137 Cs,238 U,226 Ra,228 Ra,228 Th,and 40 K were 12–256 Bq/kg,0–3.8 Bq/kg,25–42 Bq/kg,24–38 Bq/kg,22–40 Bq/kg,22–40 Bq/kg,and 354–738 Bq/kg,respectively,with average values of(121±94)Bq/kg,(2.0±1.2)Bq/kg,(34±6)Bq/kg,(32±4)Bq/kg,(32±6)Bq/kg,(33±6)Bq/kg,and(611±119)Bq/kg.This study observed a significant positive correlation(r=0.845,p<0.05)between TOC and 210 Pb_ex,highlighting the strong influence of organic matter on the distribution of 210 Pb_ex.The boundary scavenging of210 Pb from the open sea contributed 27.5%–46.2%to the total 210 Pb_ex in the sediments of the outer Kongsfjorden.The grain size was an important factor affecting the activity distribution of several radionuclides(238 U,228 Ra,228 Th,226 Ra,and 40 K).The specific activity of 137 Cs indicated the transport of terrestrial materials from the exposed area of the Kongsfjorden.The sediments in the Kongsfjorden were derived from various material contributions of glacial meltwater debris,glacial rivers,bare soil,atmospheric deposition,and marine sources.This study explains the source of the Kongsfjorden sediment and the distribution characteristics of radionuclides,and illustrateas the main factors affecting the distribution of radionuclides,which provides a reference for the behavior of polar radionuclides in future research.     

Distribution of gamma-ray radionuclides in surface sediments of the Kongsfjorden,Arctic: Implications for sediment provenance

The Kongsfjorden is highly sensitive region to climate variability, however, the study of gamma-ray radionuclides in related areas is relatively scarce. In this study, the grain size, total organic carbon(TOC), 13 Corg isotopes, and specific activities of seven gamma nuclides were analysed in surface sediments of the Kongsfjorden in the Arctic during the summer of 2017. The specific activities of 210 Pbex, 137 Cs, 238 U, 226 Ra, 228 Ra, 228 Th, and 40 K were 12–256 Bq/kg, 0–3.8 Bq/kg, 25–42 Bq/k...     

Time-series of surface water CO2 and oxygen measurements on a platform in the central Arkona Sea (Baltic Sea): Seasonality of uptake and release

High resolution measurements of carbon dioxide and oxygen were made in surface waters of the central Arkona Sea (Baltic Sea) from May 2003 to September 2004. Sensors for CO₂ partial pressure (pCO₂^w) and oxygen (O₂) concentration were mounted in 7 m depth on a moored platform which is used for hydrographic and meteorological monitoring. The pCO₂^w data were obtained in half hour intervals and O₂ was measured each hour as an average of a 10 min measurement. To check the performance of the sensors, pCO₂^w and O₂ were determined by shipboard measurements on a research vessel which visited the site in 1–2 month intervals. In addition, pCO₂^w was measured on a “volunteer observing ship” (VOS) passing the platform each second day at a distance of about 25 km. Minima of 220 to 250 μatm of pCO₂^w were observed at the time of the spring bloom and a cyanobacteria bloom in mid-summer. During winter the pCO₂^w was mostly close to equilibrium with the atmosphere but maxima of 430 to 530 μatm were also observed. The seasonality of oxygen and pCO₂^w showed an opposing pattern. From a multiple regression analysis, we concluded that two processes primarily controlled pCO₂^w during our study: biological turnover and mixing. A parameterization, based on apparent oxygen utilisation (AOU) and salinity (S) only (pCO₂^w = 1.23 AOU + 43 S), reproduced the seasonality of pCO₂^w in surface water reasonably well. Based on our pCO₂, salinity, and temperature data set, we attempted to separate processes changing total inorganic carbon concentrations (C_T) by using an alkalinity–salinity relation for the area. The contribution of CO₂ gas exchange and mixing were calculated and from this the biological turnover was deduced to reveal the calculated C_T changes.The net annual uptake of CO₂ in the central Arkona Sea was estimated to be about 1.5 Tg (1.5·10¹² g) which was approximately balanced by a net oxygen release considering the uncertainties of the flux calculations. Near-coast CO₂ emission due to episodic upwelling partly compensated the uptake of the central part of the Arkona Sea reducing the overall magnitude of the CO₂ uptake.     

A new method for separation of 2D incident and reflected waves by the Morlet wavelet transform

A new method based on the Morlet wavelet transform for separating a 2D wave field into incident and reflected waves is proposed in this paper. The principle of this method, first, is derived for constant depths. Then, using the linear shoaling theory, the method is extended to an arbitrary sloping bathymetry. Owing to the time-frequency characteristic of wavelet transform, the present method can separate waves in the real time domain and is not confined by the stationary assumption of waves. The efficiency and accuracy of this method are demonstrated using numerical simulated data.     

A method for the continuous determination of the partial pressure of carbon dioxide in the upper ocean

An experimental method for the continuous determination of the partial pressure of carbon dioxide was attempted during a cruise in the Mediterranean Sea. The method, which uses infrared analysis of air continuously equilibrated with pumped seawater, is described. Calculations to obtain pCO₂ in seawater from measured pCO₂ are given with an example of the results.     

地下卤水中镭的富集与测定方法研究

以自配人工卤水,采用硫酸钡（镭）共沉淀法富集其中的镭,同时用γ谱仪同步测量^226Ra和^228Ra的含量。不同pH和共沉淀剂作用下的化学及放化回收率计算表明,该方法操作简单,回收率高,适用于地下卤水及其它水体较高含量^226Ra、^228Ra的同步测定。用该方法测定的莱州湾地下卤水^226Ra和^228Ra含量分别为0．341Bq／L和1．615Bq／L,远高于海水中镭的含量。