Identification and significance of a late Pleistocene tephra in Canterbury district,South Island,New Zealand

A rhyolitic ash 4 to 8 cm thick is well preserved within a thick loess unit in a coastal section 2 km long near Teviotdale, Canterbury district, South Island, New Zealand. The ash (informally named Tiromoana ash) contains fresh glass shards which give a fission-track age of 20,300 ± 7100 yr B.P. The only possible source for such a tephra with this age range is from Taupo Volcanic Zone (TVZ), North Island, some 550 km north of Teviotdale. Within the time span ca. 15,000 to 42,000 yr B.P. five widespread and voluminous rhyolitic tephras (viz. Rerewhakaaitu Ash, Rotoehu Ash, Kawakawa Tephra, Omataroa Tephra, and Mangaone Tephra) were erupted from TVZ. On the basis of the fission-track age, ferromagnesian mineralogy, and electron-microprobe analyses of glass shards and titanomagnetites from Tiromoana ash and the five possible correlatives listed above, Tiromoana ash is correlated with Kawakawa Tephra (dated by ¹⁴C at ca. 20,000 yr B.P.). This is the only known occurrence to date of Kawakawa Tephra in the South Island. Its preservation is attributed to special site conditions (low precipitation and minimal sheet erosion) leeward of a prominent terrace. The identification of the ash at Teviotdale as Kawakawa Tephra supports recently revised age assignments for the upper loess sheet in Canterbury. Moreover, it implies that loess enclosing Kawakawa Tephra in nonglaciated districts of southern North Island and Taupo Volcanic Zone is a correlative.     

Late Quaternary vegetation, fire and climate history reconstructed from two cores at Cerro Toledo, Podocarpus National Park, southeastern Ecuadorian Andes

The last ca. 20,000 yr of palaeoenvironmental conditions in Podocarpus National Park in the southeastern Ecuadorian Andes have been reconstructed from two pollen records from Cerro Toledo (04°22'28.6"S, 79°06'41.5"W) at 3150 m and 3110 m elevation. Páramo vegetation with high proportions of Plantago rigida characterised the last glacial maximum (LGM), reflecting cold and wet conditions. The upper forest line was at markedly lower elevations than present. After ca. 16,200 cal yr BP, páramo vegetation decreased slightly while mountain rainforest developed, suggesting rising temperatures. The trend of increasing temperatures and mountain rainforest expansion continued until ca. 8500 cal yr BP, while highest temperatures probably occurred from 9300 to 8500 cal yr BP. From ca. 8500 cal yr BP, páramo vegetation re-expanded with dominance of Poaceae, suggesting a change to cooler conditions. During the late Holocene after ca. 1800 cal yr BP, a decrease in páramo indicates a change to warmer conditions. Anthropogenic impact near the study site is indicated for times after 2300 cal yr BP. The regional environmental history indicates that through time the eastern Andean Cordillera in South Ecuador was influenced by eastern Amazonian climates rather than western Pacific climates.     

Chemical and petrographical characterization of feed coal, fly ash and bottom ash from the Figueira Power Plant, Paraná, Brazil

The aim of the present study is the petrographic and chemical characterization of the coal at the Figueira Power Plant, Paraná, Brazil, prior and after the beneficiation process and the chemical characterization of fly and bottom ashes generated in the combustion process.Petrographic characterization was carried out through maceral analysis and vitrinite reflectance measurements. Chemical characterization included proximate analysis, determination of calorific value and sulphur content, ultimate analysis, X-ray diffraction, X-ray fluorescence, Inductively Coupled Plasma — Mass Spectrometry (ICP-MS) and Inductively Coupled Plasma — Atomic Emission Spectrometry (ICP-AES) analysis, and determination of Total Organic Carbon (TOC) content.Vitrinite reflectance analyses indicate a high volatile B/C bituminous coal (0.61 to 0.73% Rrandom). Maceral analyses show predominance of the vitrinite maceral group (51.6 to 70.9 vol.%, m.m.f). Except of the Run of mine (ROM) coal sample, the average calorific value of the coals is 5205 kcal/kg and ash yields range from 21.4 to 38.1 wt.%. The mineralogical composition (X-ray diffraction) of coals includes kaolinite, quartz, plagioclase and pyrite, whereas fly and bottom ashes are composed by mullite, ettringite, quartz, magnetite, and hematite. Analyses of major elements from coal, fly and bottom ashes indicate a high SiO₂, Al₂O₃, and Fe₂O₃ content. Trace elements analysis of in-situ and ROM coals by ICP-MS and ICP-AES show highest concentration in Zn and As. Most of the toxic elements such as As, Cd, Cr, Mo, Ni, Pb, and Zn are significantly reduced by coal beneficiation. Considering the spatial distribution of trace elements in the beneficiated coal samples, which were collected over a period of three months, there appears to be little variation in Cd and Zn concentrations, whereas trace elements such as As, Mo, and Pb show a larger variation.In the fly and bottom ashes, the highest concentrations of trace elements were determined for Zn and As. When compared with trace element concentrations in the feed coal, fly ashes show a significant enrichment in most trace elements (As, B, Be, Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, Pb, Sb, Tl, and Zn), suggesting a predominantly volatile nature for these elements. In contrast, Sn is distributed evenly within the different ash types, whereas U shows depleted concentration in both bottom and fly ash samples.According to the International Classification of in-seam coals the Cambuí coals are of para/ortho bituminous rank of low grade (except for the ROM sample), and are characterized by the predominance of vitrinite macerals.     

Late Quaternary distal tephra-fall deposits in lacustrine sediments, Kenai Peninsula, Alaska

Tephra-fall deposits from Cook Inlet volcanoes were detected in sediment cores from Tustumena and Paradox Lakes, Kenai Peninsula, Alaska, using magnetic susceptibility and petrography. The ages of tephra layers were estimated using 21 ¹⁴C ages on macrofossils. Tephras layers are typically fine, gray ash, 1-5 mm thick, and composed of varying proportions of glass shards, pumice, and glass-coated phenocrysts. Of the two lakes, Paradox Lake contained a higher frequency of tephra (0.8 tephra/100 yr; 109 over the 13,200-yr record). The unusually large number of tephra in this lake relative to others previously studied in the area is attributed to the lake's physiography, sedimentology, and limnology. The frequency of ash fall was not constant through the Holocene. In Paradox Lake, tephra layers are absent between ca. 800-2200, 3800-4800, and 9000-10,300 cal yr BP, despite continuously layered lacustrine sediment. In contrast, between 5000 and 9000 cal yr BP, an average of 1.7 tephra layers are present per 100 yr. The peak period of tephra fall (7000-9000 cal yr BP; 2.6 tephra/100 yr) in Paradox Lake is consistent with the increase in volcanism between 7000 and 9000 yr ago recorded in the Greenland ice cores.     

Expansion of Magellanic Moorland during the late Pleistocene: Palynological evidence from northern Isla de Chiloé, Chile

The late Quaternary vegetation of northern Isla de Chiloé is inferred from palynological analysis of a section in the Río Negro drainage (42°03′S, 73°50′W). At ca. 30,500 yr B.P., maxima of Astelia and Donatia occurred, suggesting wetland development. From that time until ca. 27,000 yr B.P., steppe indicators such as Compositae/Gramineae dominated, suggesting drier conditions. After 27,000 yr B.P., the moorland shrub Dacrydium gradually increased, reaching a maximum by 18,000 yr B.P. At this time Astelia increased again, suggesting development of cushion bog during cold and wet conditions. The glacial-postglacial transition is characterized by a marked change from peaty sediments to clays, a decrease in the cushion bog flora, and the prevalence of Gramineae/ Compositae and swamp taxa. This vegetation prevailed until ca.7000 yr B.P. when forest taxa became dominant. The floristic pattern inferred from the pollen spectra of the Rio Negro section suggests that the late Pleistocene vegetation of Chiloé resembled modern Magellanic Moorland vegetation (52°–56°lat S). Based on climatic conditions presently associated with Magellanic Moorland, its occurrence in Chiloé at low elevations during the late Pleistocene implies a decrease in average temperature of at least 4°C and an increase in annual precipitation of at least 1500 mm.     

Warming at 18,000 yr B.P. in the Tropical Andes

Palynological, paleopedological, and glacial geomorphological evidence from the area of the high plain of Bogotá in the Colombian Eastern Cordillera indicates a significant climatic warming around 18,000¹⁴C yr B.P. Comparison of dated vegetation changes, pedogenic episodes, and glacier fluctuations provides the basis for defining the so-called “La Laguna Interstadial” that lasted from 19,500 to 17,000 yr B.P. During this interstadial period, mean annual temperatures in the tropical Andes were up to 4°C higher than during the preceding and following stadial periods, when full-glacial conditions prevailed and temperatures were up to 8°C colder than at present.     

Quaternary volcanic ash zones on the Iceland Plateau,southern Norwegian Sea

Four Quaternary volcanic ash zones in the southern Norwegian Sea have been investigated in core P57-7 from the Iceland Plateau. Both the geochemical composition and morphological variation of each ash layer have been studied. The four volcanic ash zones appear in the light oxygen isotope stages 1, 5, 7 and 11. The ash zones are composed of transparent platy grains, light brown transparent grains, brown blocky and black blocky grains and white/transparent pumice, and each zone shows a distinct stratigraphic evolution. The geochemical results show a mixture of basaltic and silicic grains in each ash zone, and that each zone contains grains from more than one eruption. The geochemical investigations strongly suggest that all the ashes are derived from Iceland. The youngest ash zone includes two layers, which based on their geochemical composition and stratigraphic position are correlated with the ¹⁴C-dated Vedde Ash (10 600 yr BP) and Saksunarvatn Ash (9 100 yr BP). Possible sources on Iceland for these layers are discussed.     

Provenance of the Lower Paleozoic Balcarce Formation (Tandilia System, Buenos Aires Province, Argentina): Implications for paleogeographic reconstructions of SW Gondwana

Lower Paleozoic moderately sorted quartz–arenites from the Balcarce Formation deposited in eastern Argentina (Tandilia System) comprise mainly detrital material derived from old upper crustal material. The sources were magmatic, sedimentary, and subordinated felsic metamorphic terranes. High concentrations of tourmaline and Ti-rich heavy minerals, including zircon and nearly euhedral chromite, are common. Trace element concentrations (Nb, Cr) on rutile indicate pelitic and metabasaltic sources, respectively. Major element analyses on chromites indicate a basic volcanic protolith of mid-oceanic ridge origin, which was exposed close to the depositional basin. The delivery of chromite may be associated with convergent tectonics causing the consumption and obduction of oceanic crust during pre-Upper Ordovician times. The oblique/orthogonal collision of the Precordillera Terrane with the western border of the Rio de la Plata Craton, west of the Balcarce Basin or source further to the east from a Lower Palaeozoic extensional basin are possibilities.Geochemical and petrographic data exclude the underlying Precambrian and Cambrian sedimentary rocks as dominant sources, and favour the basement of the Río de La Plata Craton, including Cambrian rift-related granites of South Africa and the Sierras Australes (eastern Argentina), as main suppliers of detritus. Trace element geochemistry of recycled pyroclastic material, associated with the quartz–arenites, also suggests volcanic arc sources. The provenance of the pyroclastic material may either be the Puna–Famatina arc, located in north and central Argentina, or a hypothetical active margin further to the south. These ash layers are equivalent in age to volcanic zircons found in the Devonian Bokkeveld Group in western South Africa.The deposition of a glacial diamictite of Hirnantian age (Sierra del Volcán Diamictite) is interpreted as a member of the Balcarce Formation. Based on the stratigraphic re-location of the glacial diamictite and trace fossils, the Balcarce Formation is considered here to be Ordovician to Silurian in age. The Balcarce Formation can be correlated with similar rocks in South Africa, the Peninsula Formation, and the upper Table Mountain Group (Windhoek and Nardouw subgroups), including the Hirnantian glacial deposit of the Pakhuis Formation.     

Pleistocene glaciation in the southern Lake District of Chile

Relative-age criteria permit deposits of successive Andean glacier advances in the southern Lake District of Chile to be divided into four mappable drift sheets, the oldest two of which overlie Tertiary bedrock along the eastern flank of the Cordillera de la Costa. Only the youngest drift (Llanquihue) is datable by radiocarbon. During the most extensive ice advance of the last glaciation the Lago Llanquihue glacier was about 95 km long and reached an estimated maximum thickness of between 1000 and 1300 m. Glacier equilibrium lines at that time lay about 1000 m below their present level and rose eastward with a gradient of about 5 m/km. Successive ice advances in the Lago Llanquihue basin, which resulted in construction of end moraines and associated outwash plains beyond the lake margin, culminated sometime before about 20,000 yr ago and between 20,000 and 19,000 yr ago. A later readvance, inferred from the sedimentary record of lake-level fluctuations in the basin, had begun by about 15,000 yr ago and culminated shortly after 13,000 yr ago. A comparable, but less-closely dated, record of ice advances is found northwest of Seno Reloncaví and on Isla Chiloé. Deglaciation following the latest advance is likely to have been rapid, for the major glacier lobes fronted on deep water bodies that would have promoted extensive calving.     

Cretaceous stratigraphy and palaeoenvironments of the Southern Petén Basin, Guatemala

The Cretaceous deposits of the Southern Petén Basin, an oil-producing province, are located to the south of the Yucatan Platform and to the east of the Chiapas Carbonate Platform of Mexico. The succession in the southern part of this basin has been studied both in wells and at outcrop by microfacies analysis. It is composed of 5000 m of shallow marine carbonates and evaporites with a few thin layers of pelagic limestones rich in organic carbon and planktic foraminifera deposited during peak transgressions or maximum flooding. The sedimentation of this thick succession was not continuous, and the section is punctuated by subaerial erosional bounding surfaces and a single hardground which marks the final drowning of the carbonate platform during the late Maastrichtian. New age determinations have been obtained on the basis of planktic and benthic foraminifera from the Aptian to Santonian Cobán Formation, D, C, B and A Members. Cobán C (Albian) and B (Cenomanian) Members are the present oil reservoirs. The rudist and alveolinid limestones of late Campanian and Maastrichtian age referred to the Campur Formation in the Southern Petén Basin are here reassigned to the Angostura Formation, as recognized in the Chiapas area. The Actela Formation is defined here to encompass the limestone breccia deposits that occur at the Cretaceous–Tertiary boundary and extend into the Parvularugoglobigerina eugubina Zone of early Danian age. The D, C, B and A Members of the Cobán Formation and the Angostura Formation represent second order transgressive and regressive trends in a passive margin area where the deposits indicate a succession of various environments, including fluviatile, salinas, shallow marine carbonate platform, outer shelf and intrashelf basin. High subsidence rates, sea-level changes and tectonic uplift controlled the sedimentation.

Abstract

Les formations crétacées du sud-est du Bassin du Petén, région pétrolière du nord du Guatemala, sont situées au Sud du Yucatan et à l'Est du Chiapas au Mexique. Ces sédiments ont été étudiés à la fois dans deux puits et à l'affleurement par l'analyse des microfaciès. Cet ensemble sédimentaire est composé de 5000 m de carbonates de plate-forme de faible profondeur et d'évaporites, dans lesquels s'intercalent de minces couches de calcaires pélagiques riches en matière organique et en foraminifères planctoniques. Ces calcaires pélagiques se sont déposés lors des maximums de transgressions. La sédimentation de cette épaisse série n'est pas continue et est ponctuée par quelques surfaces d'érosion sub-aérienne et une surface durcie qui souligne l'ennoyage définitif de la plate-forme carbonatée au Maastrichtien terminal. De nouvelles datations ont été obtenues sur la formation Cobán et ses membres D, C, B et A qui s'étagent de l'Aptien au Santonien. Les membres C (albien) et B (cénomanien) constituent les réservoirs productifs. Les calcaires à rudistes et à alveolinidés du Campanien supérieur–Maastrichtien ont été appelés à tort au Petén formation Campur. Ils doivent, selon nous, être attribués à la formation Angostura comme au Chiapas voisin, où affleurent des faciès comparables et de même âge. Une nouvelle formation est créée (formation Actela) pour les brèches calcaires de la limite Crétacé–Tertiaire et de la Zone à Eugubina du Danien inférieur. Les membres D, C, B, A de la formation Cobán et la formation Angostura représentent des cycles transgressifs–régressifs de deuxième ordre. Sur cette marge passive du Petén, les dépôts correspondent à des environnements variés comme des terres émergées soumises à une altération karstique et à des dépôts fluviatiles, des salinas, des plates-formes carbonatées marines, des shelf externes et des bassins intra plate-forme. La sédimentation a été, ici, contrôlée par une forte vitesse de subsidence, les variations du niveau marin et des soulèvements tectoniques.     

Les argiles bleues du Cambrien inférieur de Saint-Pétersbourg et leur fissuration. Implications pour des stockages souterrains

The Lower Cambrian Saint Petersburg blue clays are composed of predominant illite and chlorite, sometimes accompanied by kaolinite. The <0.1 μm fraction has a high content of illite–smectite mixed layers. Particle-size distribution is more than 50% of clay particles and about 30% of silts. These blue clays correspond to plastic (and soft) clays; they may be compared to the Callovian clays of Bure (France), where storage of natural waste is envisaged. To cite this article: M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.

Résumé

Les « argiles bleues » du Cambrien Inférieur de Saint-Pétersbourg sont constituées d'illite dominante et de chlorite, avec parfois présence de kaolinite. Des interstratifiés illite/montmorillonite sont très abondants dans la phase <0,1 μm. Du point de vue granulométrique, outre plus de 50% de particules argileuses, il existe une phase silteuse de l'ordre de 30%. Du point de vue pétrophysique, ce sont des argiles plastiques, de consistance molle. Elles sont subhorizontales et ont jusqu'à 116 m d'épaisseur. Outre l'absence de métamorphisme, malgré leur âge, leur caractère le plus remarquable est leur réseau de fracturation, bien observable en carrière. Les joints sont nets, sans remplissage ni cimentation. Les plans verticaux sont particulièrement développés. Le volume unitaire des blocs de matrice ne dépasse guère 1 m³. Des traces d'oxydation témoignent de circulations d'eau. Ces argiles silteuses anciennes peuvent aider à mieux connaı̂tre et comprendre les argilites silteuses épigénétiques calloviennes du site de Bure (Haute-Marne, France), où un stockage souterrain de déchets nucléaires est envisagé. Pour citer cet article : M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.     

Age of the last major scabland flood of the Columbia Plateau in eastern Washington

Pumice layers of set S from Mount St. Helens can be correlated with certain ash beds associated with young flood deposits of the channeled scabland. The correlation points to an age of about 13,000 ¹⁴C yr B.P. for the last major flood to have crossed the scabland. Until recently, the last major episode of flooding was thought to be closer to 20,000 yr B.P., an age inferred chiefly from the relation of the flood to glacial events of the northern Rocky Mountains. Several investigations within the last few years have suggested that the last major flood occurred well after 20,000 yr B.P. Tentative correlations of ash beds of the scabland with set S pumice layers, the relations of flood and glacial events along the northwestern margin of the Columbia Plateau, and a radiocarbon date from the Snake River drainage southeast of the plateau all indicate an age much younger than 20,000 yr. The postulated age of about 13,000 yr B.P. is further supported by a radiocarbon date in the Columbia River valley downstream from the scabland tract. Basal peat from a bog on the Portland delta of Bretz, which is a downvalley deposit of the last major scabland flood, has been dated as 13,080 ± 300 yr B.P. (W-3404).     

Geological interpretation of Landsat TM imagery and aeromagnetic survey data, northern Precordillera region, Argentina

Este estudio de caso muestra una metodología para obtener el máximo valor geocientífico de datos aeromagnéticos regionales (espaciamiento entre líneas: 1000 m), a través de su integración con imágenes satelitarias de alta resolución. En este estudio, la interpretación litoestratigráfica de las imágenes Landsat TM a escala regional (1:100,000) ha sido llevada a cabo como precursor de la interpretación geofísica, proveyendo el marco geológico-estructural de base para el análisis de las imágenes geofísicas. Este marco geológico-estructural derivado de las imágenes Landsat muestra las posiciones y vergencias correctas de las estructuras mayores; en este marco, las ubicaciones de las anomalías aeromagnéticas mayores de origen somero relacionadas con rocas extrusivas y subvolcánicas intermedias/máficas, como así también de las estructuras que controlan estos eventos magmáticos de importancia económica, pueden ser correctamente interpretadas.Los resultados del estudio indican la existencia de un centro volcánico/subvolcánico no reconocido previamente, de edad post-pérmica y pre-miocena, probablemente asociado con fallamiento regional transcurrente sinistral desarrollado a lo largo de una sutura acrecional norte-sur reactivada y a una estructura preexistente del basamento precámbrico/paleozoico. El subsecuente evento de corrimientos de tipo ‘piel gruesa’ y vergencia oeste al que está asociado el ascenso del bloque precámbrico de la Sierra de Valle Fértil, desarrolló un distintivo juego de fallas transcurrentes de orientación NO–SE en el área del centro volcánico. Estas estructuras de orientación NO–SE cortan y rotan a estructuras miocenas tardías correspondientes a la tectónica de tipo ‘piel fina’ de la faja plegada y corrida de la Precordillera. Las rocas intrusivas asociadas con el centro volcánico de edad oligocena inferida, forman anomalías dipolares parcialmente remanentes fácilmente reconocibles, están asociadas con alteración y mineralización de oro (minas Cerro Guachi, El Pescado, Gral. Belgrano) y están ubicadas a lo largo de fallas ‘en cola de caballo’ sinistrales de orientación NO–SE. Este evento tectónico-magmático relacionado con la deformación transcurrente es considerado como oligoceno y puede estar relacionado con la convergencia oblicua oligocena y la mineralización de pórfiros de esta misma edad en Chile.     

High‐resolution study of Icelandic tephras in the Kangerlussuaq Trough,southeast Greenland,during the last deglaciation

Tephra abundance data and geochemistry in Late‐glacial and Holocene sediments on the East Greenland shelf are presented. Two well‐known tephras were identified from electron microprobe analysis of tephra shards picked from ash peaks in the cores. These are the Vedde Ash and Saksunarvatn Ash, which probably were deposited on the shelf after transport on drifting ice. The radiocarbon dates (marine reservoir corrected by −550 yr) that constrain the timing of deposition of the tephra layers compare well with the terrestrial and ice‐core ages of the tephras without requiring additional reservoir correction to align them with the known tephra ages. Several prominent tephra layers with a composition of Ash Zone 2 tephra punctuate the deglacial sediments. These tephra peaks coincide with significant light stable isotope events (signifying glacial meltwater) and fine‐grained sediments poor in ice‐rafted detritus. We interpret the Ash Zone 2 tephra peaks as sediment released from the Greenland Ice Sheet during strong melting pulses of the deglaciation. Copyright © 2002 John Wiley & Sons, Ltd.     

Tephrostratigraphy of the late glacial and Holocene sediments of Puyehue Lake (Southern Volcanic Zone, Chile, 40°S)

We document the mineralogical and geochemical composition of tephra layers identified in the late Quaternary sediments of Puyehue Lake (Southern Volcanic Zone of the Andes, Chile, 40°S) to identify the source volcanoes and to present the first tephrostratigraphic model for the region. For the last millennium, we propose a multi-criteria correlation model based on five tephra layers identified at seven coring sites. The two upper tephras are thin fine-grained green layers composed of more than 80% rhyodacitic glass shards, and associated to the AD 1960 and AD 1921-22 eruptions of the Puyehue-Cordon de Caulle volcanic complex. The third tephra is a sandy layer dominated by orthopyroxene, and related to the AD 1907 eruption of Rininahue maar. An olivine-rich tephra was deposited at the end of the 16th century, and a tephra characterized by a two-pyroxene association marks the second half of the first millennium AD. In addition, we detail the tephra succession of an 11.22-m-long sediment core covering the last 18,000 yr. The results demonstrate that the central province of the Southern Volcanic Zone has been active throughout the last deglaciation and the Holocene, with no increase in volcanic activity during glacial unloading.     

Coal petrology of coal seams from the Leão-Butiá Coalfield, Lower Permian of the Paraná Basin, Brazil — Implications for coal facies interpretations

In the Leão-Butiá Coalfield, Rio Grande do Sul the coal seams occur in the Rio Bonito Formation, Guatá Group, Tubarão Supergroup of the Paraná Basin, Brazil and are of Permian (Artinskian–Kungurian) age.This study is the first detailed investigation on the coal petrographic characterization of the coal-bearing sequence in relation to the depositional settings of the precursor mires, both in terms of whole seam characterization and in-seam variations. The study is based on the analyses of nine coal seams (I2, CI, L4, L3, L2, L1, S3, S2, S1), which were selected from core of borehole D-193, Leão-Butiá and represent the entire coal-bearing sequence.The interpretation of coal facies and depositional environment is based on lithotype, maceral and microlithotype analyses using different facies-critical petrographic indices, which were displayed in coal facies diagrams. The seams are characterized by the predominance of dull lithotypes (dull, banded dull). The dullness of the coal is attributed to relatively high mineral matter, inertinite and liptinite contents. The petrographic composition is dominated by vitrinite (28–70 vol.% mmf) and inertinite (> 30 vol.% mmf) groups. Liptinite contents range from 7 to 30 vol.% (mmf) and mineral matter from 4–30 vol.%. Microlithotypes associations are dominated by vitrite, duroclarite, carbominerite and inertite. It is suggested that the observed vertical variations in petrographic characteristics (lithotypes, microlithotypes, macerals, vitrinite reflectance) were controlled by groundwater level fluctuations in the ancient mires due to different accommodation/peat accumulation rates.Correlation of the borehole strata with the general sequence-stratigraphical setting suggests that the alluvial fan system and the coal-bearing mudstone succession are linked to a late transgressive systems tract of sequence 2. Based on average compositional values obtained from coal facies diagrams, a deposition in a limno-telmatic to limnic coal facies is suggested.     

Rôles respectifs de l''advection et de la décantation sur la ride médio-atlantique (40° à 50°N)

Coring at 45 sites in the North Atlantic permitted to determine flux velocity and chemical composition of pelagic sediments. Piston cores were used to carry out a comparative study between the post-glacial period (10,000 yr. B.P. until present) and last glacial period (75,000–10,000 yr. B.P.). Special attention has been paid to the Mid-Atlantic Ridges-Azores-Iceland area, where an enrichment of chemical elements was observed with regards to “regional ocean ground noise”, perceived on an isolated seamount of the abyssal plain.This “ground noise” characterized by the presence of Pb, Rb, U, Th, illite and chlorite, is associated to a settling vertical flux since the surface brought by surface currents and wind transport since the North American shield: sediments, here, are continental soil erosion products.The ridge is clearly enriched by Ba, Br, Fe, Ti, Mn, Cu, Ni, Co and As. Ba and Br are mostly associated with planktonic carbonates. Part of Ba may be linked to the ridge's activity. Basalt weathering on the ridge supplies a part of Fe in excess. Hydrothermal activity may account for Mn, Cu, Co, Ni and As enrichment. Most of the excess observed may be explained by intrusion of advective inputs from erosion Icelandic products (Fe, Ti, Cu, Ta, Sc and smectites), probably transported by Norwegian bottom currents.Advective flux (Icelandic-Faeroan basaltic materials) and flux linked to submarine ridge activity represent 30% of inorganic sedimentation. Vertical flux (North American continental-derived terrigenous materials) represent 70% of inorganic sedimentation. These percentages are very similar to those which were calculated for the Pacific.

Résumé

Les vitesses d'accumulation (flux) et les compositions chimiques ont été déterminées pour des sédiments pélagiques, dans 45 sites de l'océan Atlantique Nord. Les échantillons, prélevés par carottage Kullenberg, ont permis de réaliser une étude comparative de la période post-glaciaire (10.000 ans B.P. à nos jours) et du dernier glaciaire (75.000–10.000 ans B.P.). Notre attention s'est portée particulièrement sur la dorsale médioatlantique Açores-Islande où l'on observe des enrichissements en éléments chimiques par rapport au “bruit de fond océanique régional” appréhendé sur un dôme isolé dans la plaine abyssale.À ce bruit de fond, caractérisé par Pb, Rb, U, Th, illite et chlorite, est associé un flux vertical mis en place par décantation depuis la surface, apporté par le vent et les courants de surface depuis le craton nord-américain; il s'agit des produits d'érosion des sols continentaux.L'enrichissement de la dorsale est net pour Ba, Br, Fe, Ti, Mn, Cu, Ni, Co et As.Ba et Br précipite en grande partie avec les carbonates planctoniques. Une partie de Ba peut être associée à l'activité de la ride. L'altération des basaltes de la ride fournit une partie du Fe en excès. L'activité hydrothermale peut expliquer les enrichissements en Mn, Cu, Co, Ni et As.L'essentiel de l'excès observé est expliqué par un apport advectif de produits d'érosion de l'Islande (Fe, Ti, Cu, Ta, Sc et smectites). Leur vecteur serait le courant de fond de la mer de Norvège.Le flux advectif (matériaux basaltiques islando-faeroan) et le flux liéà l'activité sousmarine de la dorsale représenterait 29% de la sédimentation inorganique.Le flux vertical (matériaux continentaux terrigènes nord-américain) représenterait 71% de la sédimentation inorganique. Ces chiffres sont très proches de ceux qui ont été évalués dans le Pacifique.     

Major and trace element abundances in volcanic glass shards in visible tephras in SG93 and SG06 drillcore samples from Lake Suigetsu,central Japan,obtained using femtosecond LA–ICP–MS

The major and trace element concentrations of volcanic glass shards from visible tephra layers in the SG93 and SG06 cores from Lake Suigetsu, central Japan, were determined by femtosecond laser ablation–inductively coupled plasma–mass spectrometry. The glass-shard analyses, together with the petrographic properties of the tephra samples, allow the Suigetsu tephra layers to be broadly classified into tephras derived from calderas on Kyushu Island, and from Daisen and Sambe volcanoes in the Chugoku district of southwest Japan. The layers correlated with tephras from Kuju caldera and Daisen volcano, and with the younger Sambe tephras, have adakitic elemental features. A Suigetsu tephra sample correlated with the Sambe−Kisuki tephra based on petrographic properties has an elemental pattern similar to that of the Toya tephra from Hokkaido Island, northeast Japan. This match implies that tephras from northeast Japan, as well as Kyushu–Chugoku tephras, are possible correlatives of the Suigetsu tephra layers. Both petrographic properties and major–trace element data of volcanic glass shards are essential for robust tephra correlations, and hierarchical cluster analysis proved additionally useful in statistically evaluating relationships among the tephras.     

Early Holocene coastal settlements and palaeoenvironment on the shore of the Baltic Sea at Pärnu, southwestern Estonia

Studies were conducted on 16 sections of buried organic matter (pre-Ancylus Lake and pre-Litorina Sea) and associated Stone Age cultural layers in the Pärnu area, southwestern Estonia. Buried organic beds are each part of a sedimentary sequence, which is repeated, forming two overlying sets of an orderly succession of five layers. The organic sedimentation of the lower set (set 1) occurred about 10,800–10,200 years BP, and that of the upper set (set 2) about 9450–7800 years BP. Associated with set 1 is the Early-Mesolithic settlement of Pulli, and with set 2 are the Stone Age cultural layers at Sindi-Lodja. The Early- and Middle-Mesolithic sites in Estonia are concentrated on shores of rivers and lakes to utilise of a variability of resources. The hunters and fishermen followed the ancient Pärnu River downstream to the receding shoreline of the Yoldia Sea. After about 10,700 years BP, they were forced to retreat inland in front of the transgressive Ancylus Lake shore which first inundated the Paikuse area about 10,400 years BP, and Pulli and higher sites about 10,200 years BP. The total amplitude of the transgression preceded 11 m and reached up to 14 m a.s.l. in the area. The Litorina Sea transgression reached 7 m a.s.l. after 8000–7800 years BP. The Mesolithic, Neolithic and modern sites on top of each other in the Pärnu area may suggest that, although years apart, they were inhabited by the same group of people who stayed in the area and moved back and forth together with the shifting shoreline of the Baltic Sea.     

Characteristics and Possible Source of a 1479 A.D. Volcanic Ash Layer in a Greenland Ice Core

A microparticle concentration peak in a GISP2 ice core contains volcanic glass shards of rhyolitic composition that correspond in age to the 1479-1480 A.D. Mt. St. Helens Wn eruption. These glass shards are compositionally similar to the Wn tephra and constitute 83% of the total particle population. The shards are very coarse-grained (up to 40 μm diameter), suggesting rapid transport from their source to Greenland. A major sulfate peak in the ice occurs approximately 4 months after deposition of the glass shards. This difference in depositional timing suggests primarily tropospheric transport of the ash and stratospheric transport of the sulfate aerosol. Large-scale climatic perturbations following this eruption were evidently negligible. Glaciochemical seasonal indicators suggest a late-fall to early-winter 1479 A.D. eruption.